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By J. Matos e Silva

"Abstract Although one can think that it is very low the probability of a seism occurrence during the execution of an excavation in an urban lot protected by a diaphragm wall curtain, reality shows that whenever a seism occurs in an urban area several diaphragm walls will be affected by it. So it is advisable to consider the seismic action when designing a diaphragm wall curtain. The paper refers the main information about the seismic design of diaphragm walls according to the Eurocodes 7 and 8 and to the Portuguese Norms related to them (respectively NP EN 1997-1 2010 and NP EN 1998-5 2010), as the Eurocodes consider the possibility of each European country to adopt their own seismic parameters as the seismic risk is different in each country. Thus the so-called National Document of Application (in our case the Portuguese Norms) prescribes the seismic local parameters.1 - EUROCODES AND PORTUGUESE NORMS PRESCRIPTIONSAccording to Eurocode 8 - Part 5 and to the related Portuguese Norm NP EN 1998-5 2010, seismic actions on soils should be quantified adopting the Mononobe-Okabe method that gives goodapproaches when compared with reality.From paragraph 7.3.2.2 of the referred Norm, the horizontal seismic coefficient kh will be:"

Jan 1, 2014

The U.S. Code of Federal Regulations (Title 30) requires that a methane monitor be placed on every mining machine to continuously observe and record methane levels at the face. The monitor must provide a warning whenever methane levels are 1.0 percent or higher. An effective monitoring system will indicate a methane concentration of 1.0 percent on the mining machine before methane levels at the mining face reach 5.0 percent. Where the methane monitor is located on the mining machine is one of the most important factors that determines how effectively face methane levels can be predicted. Any change in the sampling location will result in a change in measured methane concentration. To protect the methanometer, it is usually located on the cutting boom at least 1 to 1.8 m (3 to 6 ft) outby the front cutting bits. A face ventilation system using blowing tubing was simulated in a full-scale test facility. Methane released from the face area was monitored at multiple locations on a model mining machine as well as locations near the face. Based on the relationship between concentrations measured on the machine and at the face, criteria were developed for selecting the best machine locations for monitoring methane. Recommendations are given for revising methane action levels for alternative sampling locations.

By R. V. Thurston, Edmund S. Leaver

"During the development of the sulphur dioxide leaching process for the treatment of ""mixed"" copper ores at the Southwest experiment station of the Bureau of Mines*** the pulp from treatment of roasted cupriferous pyrite with sulphur dioxide gases and water showed an unexpected amount of sulphuric acid. After following out several false premises it was found that this was due to iron in the solution, and also that this iron tended to oxidize to the ferric state if the concentration of sulphur dioxide in the roaster gases used did not rise above a certain figure. While the percentage of iron present was email it was enough to cause an entirely different set of conditions from those of the original sulphur dioxide leaching process and to promise a much wider application of the general idea. Sulphurous acid dissolves only certain copper minerals, sulphuric acid solutions certain additional minerals and ferric sulphate solutions certain further additional copper minerals, so this observation was of importance in connection with possibilities in the hydrometallurgy of the so-called ""mixed"" or partly oxidized copper ores.The work has been carried along by a number of experimenters. L. R. Eckman, junior chemist of the Southwest station, contributed largely to the early developments. L. Roberts, W. D. Bonner and C. G. Maier each in turn physical chemists at the Pacific Experiment station, (Berkeley, Calif.) have studied the reactions involved. A complete report of all the work on this process will be prepared later under the direction of O. C. Rolston. The purpose of the present paper is to place a summary of the more practical phases of this seemingly important piece of work before those interested."

Dec 1, 1923

By Yi Luo

In dealing with various subsidence cases, accurate predictions of mining induced subsidence are the basis for correct assessment of subsidence influences and subsequent mitigation efforts. There is a good demand for a reliable tool to perform the subsidence predictions and related tasks. A comprehensive and integrated subsidence prediction model, CISPM, developed by the senior authors in the later 1980?s and early 1990?s (Peng and Luo, 1992) is one of such tools. Built on solid mathematical models and calibrated by a large number of collected subsidence cases, CISPM provides a rich set of features needed in subsidence engineering and research works. Its reliability and usefulness have been proven by numerous field applications. This upgrade of CISPM will not only preserve its original features and reliability but also provide some new needed features and a more user-friendly working environment.

Jan 1, 2008

By R. I. Jaffee, J. G. Dunleavy, W. Hodge, H. R. Ogden

IN a search for an improved conductor for use in field wire for the L. S. Army Signal Corps, an alloy of copper and silver was developed from which it was possible to obtain 29 B & S ga. strands with tensile strengths in excess of 160,000 psi combined with an electrical conductivity of over 70 pct IACS. Such a favorable combination of strength and electrical conductivity has not been reported previously in the rather extensive literature covering this subject. The properties obtained from various binary alloys of copper and silver, together with the method of fabrication of these alloys which has been developed to obtain the properties desired in fine wire strands, are discussed in this paper. LITERATURE The effect on the electrical conductivity of copper of the various elements in solid solution is shown in Fig I, taken from published data by J. O. Linde and others.' It will be noted that silver in solid solution depresses the electrical conductivity to a lesser extent than any other element for which data are given, and is followed rather closely by cadmium, and then by chromium. Zinc, which lies between cadmium and chromium, has so high a solid solubility in copper that the data for zinc are scarcely comparable to the data for the other two in the range covered. Not many data are available on the strain hardening of copper-rich Cu-Ag alloys. Corson2 reports a 3 pct Ag alloy properly cold worked and annealed to have 100,000 psi tensile strength and 90 pct IACS conductivity. On straight cold working, Hessenbruch3 reports 101.000 psi for a 5 pct Ag, 0.3 pct Be alloy, and 129,000 psi for a 30 pct Ag, 0.5 pct Be alloy. Here it would he expected that much of the strain hardening came from the silver content of the alloys. The copper-rich side of the Cu-Ag diagram, according to Stockdale,4 is shown in the upper part of Fig 2. The electrical conductivities for copper-silver alloys annealed at 750 and 350°C, taken from the work of Johansson and Linde,5 are shown in the lower part of Fig 2. The sloping line corresponds to the conductivity of solid solutions of silver in copper, and the horizontal offshoots correspond to the conductivity of the two-phase alloys in equilibrium at the two temperatures shown. The electrical conductivities are very high, even for the 750°C anneal. The potentiality for age hardening from supersaturated alpha copper solutions appears to be excellent from the solubility line, but Smith and Lindlief6 have shown that the response to age hardening of solution-annealed alpha alloys is not good. They found that the tensile strength of a 5 pct Ag alloy aged at various temperatures was not as great as in the quenched condition, even though, anomalously, the hardness increased from RB68 to RB78 by annealing for 4 hr at 400°C after a 750°C quench. Weist7 also found that the alloys increased in hardness

Jan 1, 1948

By Mark J. Klein

The precipitation of nitrogen in quenched and aged CY-35 at. pct Re was followed by internal-friction and electrical-resistivity measurements. It is shown that the precipitation kinetics of nitrogen from solution are many orders of magnitude lower in this alloy than in chromium. The reluctance of nitrogen to precipitate from sol~ction can be attributed to the composilional r-eadjustnzents required in the z.icinity of a chromium nitrade particle for gowth to occur. AS part of an investigation of the mechanism by which rhenium increases the low-temperature ductility of chromium and other Group VI-A metals, it was of interest to compare the concentration of interstitial elements retained in solution in chromium with that of a ductile Cr-Re alloy. The presence of certain interstitial elements in chromium has been shown to decrease its ductility1-5 and, of these interstitials, nitrogen is believed to have the most detrimental effect on mechanical properties. Thus, a comparison of the disposition of nitrogen in chromium with that in a ductile Cr-Re alloy might provide information about the mechanism whereby rhenium enhances the ductility of chromium. In previous internal-friction studies it was shown that the equilibrium solubilities of nitrogen in chromium and Cr-35 at. pct Re did not differ greatly.= However, results indicated that the actual concentration of nitrogen retained in solution at ambient temperatures is likely to be considerably greater in the alloy than in chromium because the precipitation kinetics of nitrogen are greatly retarded by the addition of rhenium. The objective of this investigation was to study the kinetics of nitrogen precipitation in Cr-35 at. pct Re in greater detail and to obtain information concerning the mechanism of nitrogen precipitation in this alloy. The properties studied were internal friction and

Jan 1, 1967

By L. H. Cole

FOR many years Industrial Minerals, or as they were formerly called, 'the Non-Metallic Minerals', compared with the metallics, were considered of only minor importance and as such were given scant attention in the technical press as well as in the public press. Those days are, however, happily passing, and thanks, to an appreciable extent, to the constant endeavour of the Industrial Minerals Section of this Institute, established in the fall of 1932 industrial minerals are now assuming the importance to which they are entitled. The term 'Industrial Minerals', when first adopted in this sense by the Institute, was thought to be original in its application, but it is interesting to note that it had been used many years previously by the Queensland Geological Survey in the following publication: SALT Article 1 in Industrial Minerals by B. DUNSTAN, Chief Government Geologist (Publication No. 268, in Part) Queensland Geological Survey, Department of Mines, Brisbane 1920 In Queensland, however, the term embraced some of the metals as well as the non-metallic minerals proper. The lead furnished by Canada in this matter bore rapid fruit, and already the term 'Industrial Minerals' is widely used, not only throughout Canada but in the United States as well.

Jan 1, 1939

By L. H. Banning

Recent dry-top electric smelting tests at the Northwest Electrodevelopment Experiment Station, Albany, Oreg., indicate that a high-titanium slag and a good grade of pig iron can be produced from alluvial Idaho ilmenite. A total of 120 tons of concentrates were smelted during this investigation, to yield an average of 0.5 ton of slag and 0.3 ton of pig iron per ton of ilmenite. Power consumption averaged 1,400 kv.-hr. per ton of ilmenite, at a feed rate of 400 to 500 pounds per hour, when operating at an electrical energy input of 290 to 370 kilowatts. The optimum operating voltage appeared to be 110 volts, phase-to-phase. Graphite electrode consumption averaged 15.6 pounds per ton of ilmenite smelted. Magnesite furnace refractory withstood the corrosive action of the hot metal and slag better than carbon refractory.

Jan 1, 1955

By Charles L. Kimbell

The final tables of this chapter, tables 25-50, extend and expand the statistical series on production that was started in the 1963 edition of the Area Reports: International Volume of the Minerals Yearbook and that was subsequently updated and expanded in the 1965 and 1967-90 editions. Continuing the practice started in 1989, a column has been included in each of these tables providing a 5-year average for 1987-91, inclusive. This should provide a clearer picture more rapidly of the role of each major producer over the 5-year period. The listing order of major producers, however, continued to be, as in past years, in descending order of rank in the year of review, 1991. This group of tables now includes each of the crude minerals that ranked from? 1st to 19th in 1983 terms of value of their output (as well as four others of lesser rank). These 23 crude mineral commodities accounted for 93 % of the estimated value of world crude mineral production in 1983. In addition, world output of five key downstream products-aluminum, steel, cement, nitrogen in ammonia, and refined oil-is included because of their significance as products.

Jan 1, 1993

By G Stanway, P Mahoney, C Griebel

The Mining Innovation – State of Play was initiated three years ago by VCI in partnership with the University of Western Australia. The ambition was to create a ‘think tank’ type platform to support industry discussion on how it is performing in terms of innovation at a strategic level, what needs to change in the industry ‘ecosystem’, and how businesses may more effectively develop their strategy and architecture to innovate for competitive advantage.The drivers for this ambition were straightforward. The industry recognises itself as being conservative with respect to innovation and it knows the business and community endowment dividend from getting better at innovation is large; however, much of the material that seeks to provide insight on innovation tends to be drawn from industries that do not have the same high capital, long life cycle and market uncertainty characteristics as that faced by mining. Material that does focus on mining innovation is orientated towards technical innovation, not innovation strategy. There exists a significant knowledge gap, and filling it is valuable to both mining businesses and communities.The 2014 Mining Innovation State of Play report (Stanway, Griebel and Mahoney, 2014), based on a survey of over 230 mining executives, uncovered a range of insights but left several questions unresolved. The people with the best perspective on these questions are CEOs. They can see the business issues with sufficient clarity and have the influence to shape both the industry and its organisations, as seen in Figure 1. Discussing these questions with the view to progressing our collective understanding was the primary reason this interview series was conducted.Unsurprisingly, interviewing 15 CEOs and Chairpersons from different industries and commodities, across the globe resulted in a broad range of views. The discussions were frank and often blunt in assessing the short comings in the industry and suggestions for improvement. This degree of candour is hugely valuable as a basis for improvement. In the end, four key areas emerged as a basis for improvement.CITATION:Stanway, G, Griebel, C and Mahoney, P, 2017. Mining Innovation State of PlayTM – iron ore insights, in Proceedings Iron Ore 2017, pp 439–442 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By E. Ferguson

In evaluating refractory designs for cast house applications, thermal calculations are frequently performed to determine cold face shell temperatures, temperature profiles and metal freeze plane locations within the refractory layer, and heat loss in the steady state condition. A problem arises when looking at molten metal transport crucible designs in that these structures are usually operating under non-steady state conditions throughout their production cycle. Because the molten metal temperature varies with time, and material properties such as thermal conductivity are temperature dependant, mathematical solutions are at best... complicated. This paper presents a relatively simple, iterative solution, that can be set up on a standard computer spreadsheet program, to calculate heat transfer in non-steady state conditions. These calculations can provide curves for (1) molten metal temperature vs time and (2) cumulative heat loss vs time, given variable starting conditions, to aid in the evaluation of molten metal transfer crucible refractory designs.

Jan 1, 2004

By Robert L. Somerville

As more phosphate deposits are discovered and new mines are developed, the necessity of critically evaluating various rocks for phosphoric acid production recurs ever more frequently. This need is accentuated by the increasing number of, fertilizer plants being constructed on deep water at various locations to serve world markets and to take advantage of locally-available sulfur or sulfur-bearing ores. A major proportion of all phosphate rock mined is consumed by wet-process plants and this acid in turn is consumed, usually captively, in the manufacture of fertilizer. It is apparent, therefore, that the first question asked by the developer of a new deposit is - How will it work in a wet-process plant? and conversely, when developing a deep water, project, one of the early studies required is - Which of the available rocks shall we use? What is the correct price to pay? How do we compare one rock with another? The economic importance of even minor aspects of these questions

Jan 1, 1966

By Eleanora I. Robbins, Motoaki Sato

Many problems associated with acid mine drainage (AMD) are caused by the complex way molecular oxygen (O2) oxidizes reduced matter at surface temperatures. In aqueous solution, O2 kinetically "prefers" to go through the formation of hydrogen peroxide (H2O2) as an intermediate. Being innately unstable, H2O2 is quickly decomposed back to water and oxygen in the presence of dissolved Fe and Mn, both catalysts for the decomposition. Direct addition of H2O2 to AMD produced similar results. Ozone (O3) is a much faster and stronger oxidizer than either O2 or H2O2. In the laboratory, O3 rapidly precipitated Mn, Fe, Ni, Co, Pb, and Ag even in acidic solutions. The experiments indicate that AMD can probably be processed with ozone and metal oxides/hydroxide recovered in flow systems using only septic-tank-size reactors and small sedimentation ponds.

Jan 1, 2000

By J. H. Canterford

The adsorption of uranium onto Wyoming bentonite was measured in carbonate media over the pH range 8 to 11. Uranium was removed from solution onto the solids by a rapid reaction, proposed to be adsorption of the anionic uranyl tricarbonato complex onto edges of the clay platelets, and a slow reaction that may be precipitation of a hydroxide. The changes in uranium content of the aqueous and solid phases of a uranium ore carbonate leach slurry were also measured as the slurry was progressively diluted. There was an increase in the uranium content of the solids as the pH of the suspension was lowered, as observed with the Wyoming bentonite. Results indicate the conditions that should be met with respect to pH control to prevent the problem of excessive uranium adsorption in the counter-current decantation washing circuit of a conventional leaching process, as well as in the leaching and restoration phases of carbonate solution mining.

Jan 1, 1985

By E. S. Machlin, S. Weing

GRAIN boundary stress relaxation has been the subject of several investigations in recent years, but as yet the phenomenon is not well understood. One of the major difficulties has been the lack of a sufficient amount of data with which to evaluate any proposed mechanism. Little information is available on the effect of small amounts of substitutional solutes on grain boundary stress relaxation. It is with this important phase of the problem that this investigation is concerned. The influence of substitutional solutes on grain boundary stress relaxation has been recently investigated in copper by Pearson: and in aluminum by Dorn et al.' Pearson studied the effect of zinc, gallium, germanium, and arsenic on the relaxation peak of OFHC copper.* The pure OFHC copper decreased the peak intensity and a second peak appeared at a higher temperature. This latter peak was termed the alloy grain boundary peak. At the lowest binary concentration studied, approximately 1 atomic pct, the primary peak was almost completely obliterated. Pearson found that the activation energy calculated from the alloy grain boundary peak for all solutes, irrespective of the concentration, was 44,000 cal per mol. Pearson concluded that the increase in activation energy from 33 to 44 kcal per mol is not continuous but abruptly changes from the lower to the higher value. As no attempt was made to investigate the intermediate range of concentration and hence calculate the possible variation of the activation energy for the initial grain boundary peak, this conclusion is hardly valid. In contrast to these results, Dorn et al. studied the effect of zinc, silver, copper, germanium, and magnesium on the grain boundary stress relaxation of aluminum. No change in the energy of activation was observed for binary alloys of the flrst four solutes, but a linear increase was found for increasing concentration of magnesium. Saturation was not found up to the maximum of 1.6 atomic pct. The energies of activation were obtained by plotting the horizontal displacement of the dynamic modulus curve vs temperature for two vibrational frequencies. As the modulus is proportional to the square of the frequency, this requires the measurement of the torsional frequency over a range of temperature. However, the technique does not lead to an unambiguous interpretation of the grain boundary

Jan 1, 1958

By Mark S. Sanders

This report discusses the development and testing of prototype gloves for underground mining work. An analysis of HSAC hand-finger injuries revealed three high-risk jobs: laborer, mechanic, and roof bolter. Laboratory tests of dexterity and protection were performed using six off-the-shelf gloves. Two prototype gloves were developed. Both were Kevlar-cotton blend knit gloves. One had polyvinyl "Ks" screened on the palm and fingers, and a hand pad sewn into the palm. The other prototype had the palm and fingers coated with a sol id layer of polyvinyl and had no hand pad. Field tests revealed that the solid-coated gloves were preferred by workers, but that the polyvinyl melted when working with hot drill steels.

Jan 1, 1985

By P. K. Fedotov

Annually at least 5% percent of world power consumption is involved in the process of ore dressing while ore processing technology. Such rate of energy consumption demonstrates the importance of a given process study in the human life-sustaining activity. Examining of interparticle destruction being under external stress pressure in ore responses this problem solution at the greatest degree. The technology of destruction in the roll press is of great interest. The use of the given equipment allows to save a significant amount of energy by means of the built-in ore destruction mechanism. Examination of stress-strain fields which determine the level of interparticle destruction between the rolls in the ore layer enables to specify both level of ore destruction and power consumption. The mathematical computer modeling for the deformable environment use based on the finite-element method (FEM) allows to carry out the given research. We use FEM solution for elastic contact problem for the most complete study of power consumption employed in ore and interparticle destruction. This problem solution allows also to examine energy consumption expenses spent for ore crushing in the roll press. Also we have identified the mechanism of ore in a layer of the particles under pressure roller press. It is established that high level of performance and reduction of energy consumption in interparticle destruction of ore in the layer due to the appearance of the gradient of normal stresses in contact of particles of mineral raw materials. The algorithm has been developed determining crushing product particle size distribution of fractured particles in the layer, using the Bond’s theory of crushing. The use of our FEM model reduces the time of equipment selection for new plant and at the design stage to reduce the risks of errors in the choice of roller presses.

Jan 1, 2018

By C. E. BOCKUSD

WHEN Mr. Bain asked me to lunch with you he requested that I say a few words as to how the Institute could be helpful to the bituminous coal industry. I feel like saying, "Thank you, what have you?" I do not want to trace in detail the story that is old already to many of you. On the other hand it does take some little stage-setting to illustrate what is the matter in the bituminous coal industry, a trouble that must some day be cured. There has been something over a century of bituminous coal production as a real business in this country. True, Joliet and Marquette discovered coal in Illinois in 1673, according to published accounts of their travels, and shortly thereafter Father Hennepin also found Illinois coal in 1689. Coal was mined near Richmond in 1750, and Richmond shipped coal to New York and Philadelphia in 1789. But it was not until 1838 that the production of bituminous coal in this country totaled a yearly output equal to the minimum for one class A mine today, for that was the first year that production exceeded 200,000 tons.

Jan 1, 1930

By Steven J. Page

Researchers have developed a model to describe airborne respirable dust (ARD) generation on surface coal mine drills. By measuring a few basic parameters and using a graph, a drill operator or engi­neer can estimate the relative severity of drill dust emissions as well as how much of a reduction in ARD can be obtained by changing any given parameter. Geometric parameters include: drill deck cross-sectional area, shroud leakage associated with the deck shroud as well as the operational parameters of bailing air­flow, and dust collector airflow. The rela­tionships yield predictive ARD values which fall in the range measured on oper­ating drills for collector/bailing air flow ratios greater than 2. Overexposure to airborne respirable crystalline silica dust can cause serious or fatal respiratory disease. Exposures of sur­face coal mine rock drillers to respirable crystalline silica are of particular concern. In a 1992 alert on silicosis in rock drillers, the National Institute for Occupational Safety and Health (NIOSH) reported on 23 cases of advanced silicosis (acute, acceler­ated, and chronic) ranging in ages from 25 to 60 with drilling tenures ranging between three and 20 years.1 Most of the cases involved drill operators in their 30?s and 40?s, indicating high silica exposure levels are associated with their occupation. A more recent lung x-ray surveillance study of a 664 volunteer population of surface coal miners showed that the prevalence of silicosis-like abnormalities was 9%.2 The two most significant factors associated with these abnormalities were increasing age and years of drilling experience.

Jan 1, 2008

By M. R. J. Wyllie

The relationship between the electromotive force (E.M.F.) across a shale barrier and the concentrations of sodium chloride solutions on either side has been investigated. It is shown that the action of a shale barrier is analogous to a glass membrane separating two acid solutions of different hydrogen ion concentrations. The shale behaves as a sodium electrode and is responsive to the activities of the sodium ions in the two solutions in such a way that the potential can be calculated by means of the Nernst equation. This conclusion is confirmed by laboratory experiments. In a borehole the total E.M.F. of a shale cell is the algebraic sum of the ~otential across the shale and a boundary potential. The relationship between total E.M.F. and the resistivity ratio of two sodium chloride solutions is indicated for a number of formation temperatures. The E.M.F. thus predicted is then compared with the .elf potential read from an electric log and good agreement is demonstrated. Based on both the self potential and resistivity curves of the electrical log. a method is given for calculating connate water content in a bed having in-tergranular porosity and containing both connate water and hydrocarbons. INTRODUCTION The first paper on electrical well logging by C. and M. Schlumberger and E. G. Leonardon in 1934' attributed the self potential curve principally to streaming potentials, i.e. to electroki-netic effects. Almost immediately great difficulties were encountered in reconciling many of the curves they obtained with this interpretation. and a ~econd paper' by the same authors soon appeared. In this second paper self potentials were attributed to the combined effects of streaming potentials and electrochemical potentials, the electrochemical potential being considered the result mainly of the interaction of fluids of differing salt concentrations, i.e. a boundary potential, and partly of potentials set up at the faces of impermeable materials. Some experiments involving a gray clay for the impermeable material were quated. The Schlumbergers and Leonardon deduced from the equation for a simple boundary ~otential that the electrochemical potential, as opposed to the electrokinetic potential, could be expressed in the form E=Klog- .......1 pe where K is a constant, pm the mud resistivity. p, the resistivity of the connate water in a porous bed. However, no general expression for the constant K was obtained. Although the literature between 1934 and 1943 contains a number of quotations of their results, the valuable work of the Schlumbergers and Leonardon was not extended so that the electrochemical potential has been generally attributed wholly to boundary potentials between the mud in the borehole and the connate waters in porous formations. Unfortunately, however, the fundamental premise of all these papers, that a boundary potential can give rise to current flow in a borehole, is thermodynamically untenable. As will be shown. the fact that the electrochemical potential can be fairly accurately express as E = K log pm/pc, a form in which a boundary potential may also be written, is partly fortuitous. The boundary potential is indeed an integral part of the expression for the electrochemical potential in a horehole, but in magnitude it represents only about 20% of the total potential. In 1943 an important step in the elucidation of electrochemical potentials was made by Mounce and Rust3 who showed that if a wall of shale separated two compartments which contained saline solutions of different concentrations, and if the two solutions were themselves brought into contact in the pores of a porous inert membrane (such as unglazed porcelain) a current flowed through the shale and saline solutions. The direction of positive current was from the shale into the more dilute solution. The paper of Mounce and Rust, while repeating some of the observations of the Schlumbergers and Leonardon, seems to be the first to show that the shale was the seat of a genuine electrochemical effect capable of causing current flow. In the same paper Mounce and Rust pointed out the similarity between the fundamental conditions of their experiment and the conditions which existed when a bed of shale in the ground was simultaneously in contact with a porous sand containing saline connate water and mud fluid of salinity different from that of the water in the sand. Since it is now generally recognized that the S.P. curve measures ohmic potential changes in the mud fluid in the well bore resulting from changes in current flow, it is apparent that currents having their origin in the electrochemical interaction of mud filtrate and connate waters with shale beds are a very important portion of the total S.P. The work of Mounce and Rusta and others appears to indicate that, in general, the electrochemical portion of a particular kick on a S.P. curve far exceeds any electrokinetic potentials resulting either from streaming potentials or Dorn effects. The Dorn effect, or sedimentation potential. arises when small particles are allowed to fall through certain fluids under the influence of gravity. a difference of potential being observe? between two electrodes placed at different levels in the stream of falling particles. The Dorn effect is unlikely to affect seriously the S.P. curve as now measured. A successful analysis of the electrochemical aspects of the S.P. log should

Jan 1, 1949