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Overview ?Oil Sands Background ?Water Use in Surface Mining ?Tailings Disposal ?Water Balance for Surface Mining ?Implications of Emerging Regulations ?Water Management Framework ?Tailings Performance Criteria (Directive 074)

May 1, 2009

By Willard S. Morse

In my paper on "The Lixiviation of Silver-Ores by the Russell Process at Aspen, Colorado" (page 137 of the present volume), attention was called to the decrease in "chlorination " during the washing of the roasted ore with water, to remove soluble salts, before leaching with hyposulphite and Russell solutions. This decrease in " chlorination," which is due to conversion of the silver chloride to some other form not soluble in hyposulphite solutions, and which, for the sake of brevity, will be termed the "going-back" of chlorination, has been a serious obstacle to the successful operation of several leaching-works, and was at Aspen the only difficulty encountered. I have never seen any explanation of the cause of this failure to extract, in actual practice in the mill, the amount of silver chloride shown by laboratory-leachings to be present in the roasted ore; and the purpose of this paper is to record the conclusions arrived at concerning the cause of the phenomenon, and the data upon which they are based. The average decrease in chlorination by washing with water in the Aspen ores for a period of fourteen months was as follows:

Jan 1, 1896

By F. E. Harris

It has been said that carbon is "ubiquitous" with reference to iron alloys. Certainly at temperatures where carbon and iron form the solid solution, austenite, it may be readily added to, or removed from, steel surfaces. Differences in concentration potential are the sole requirements for carbon flow. To measure the rate of carbon flow, a proportionality factor, D, is arbitrarily expressed in units of (length)2 X (time)-'. If the term used for carbon concentration is weight Pet C, as is customary, then a factor must be found, changing this term to One of weight Per unit volume when the diffusion coeficient, D, is used in flow formulae. The determination of D values for carbon is complicated since D varies with the concentration itself. The Matano method has often been employed for systems involving a variant D. This method expresses all evaluation of unsteady flow whereby D is given a relationship with the numerical value of C-x slopes. The author contends that this solution is incorrect, except when D is invariant. The primary purpose of this paper is to support this contention. Here diffusion is controlled under two conditions of flow. The first part deals with the steady state; the second part considers unsteady flow under definite restrictions. Beginning with the fundamental concept, the development is continued until equations for C-x curves are obtained. The solution is then subjected to experimental data. It is realized that a great amount of reliable data is required for a rigorous proof. KO such research is claimed. Instead an attempt is made to set forth the physical significance of the diffusion mechanism, and particularly to express the factors which influence the flow of carbon in austenite. Of equal significance is the implication that gaseous media may be employed with reasonable accuracy in making these determinations. The Steady State Diffusion of Carbon in Au~tenite The fundamental experiment defining diffusion in solid metals may be readily performed for carbon in gamma iron.' For this experiment a thin plate of medium carbon steel is chosen. The surfaces of this plate may be taken as two parallel planes which may be considered infinite for points well in the Center of the planes. These two planes are held at different concentrations of carbon at a constant temperature. This temperature, 1700°F for example, is one where the single phase: carbon in solution with gamma iron, exists. When these conditions are held for a sufficient time the concentration of carbon of the different points of the solid ment down towards its steady state value. At points well removed from the ends, the concentration will remain the Same along planes parallel to the surfaces of the plate.

Jan 1, 1948

By F. E. Harris

It has been said that carbon is "ubiquitous" with reference to iron alloys. Certainly at temperatures where carbon and iron form the solid solution, austenite, it may be readily added to, or removed from, steel surfaces. Differences in concentration potential are the sole requirements for carbon flow. To measure the rate of carbon flow, a proportionality factor, D, is arbitrarily expressed in units of (length)2 X (time)-'. If the term used for carbon concentration is weight Pet C, as is customary, then a factor must be found, changing this term to One of weight Per unit volume when the diffusion coeficient, D, is used in flow formulae. The determination of D values for carbon is complicated since D varies with the concentration itself. The Matano method has often been employed for systems involving a variant D. This method expresses all evaluation of unsteady flow whereby D is given a relationship with the numerical value of C-x slopes. The author contends that this solution is incorrect, except when D is invariant. The primary purpose of this paper is to support this contention. Here diffusion is controlled under two conditions of flow. The first part deals with the steady state; the second part considers unsteady flow under definite restrictions. Beginning with the fundamental concept, the development is continued until equations for C-x curves are obtained. The solution is then subjected to experimental data. It is realized that a great amount of reliable data is required for a rigorous proof. KO such research is claimed. Instead an attempt is made to set forth the physical significance of the diffusion mechanism, and particularly to express the factors which influence the flow of carbon in austenite. Of equal significance is the implication that gaseous media may be employed with reasonable accuracy in making these determinations. The Steady State Diffusion of Carbon in Au~tenite The fundamental experiment defining diffusion in solid metals may be readily performed for carbon in gamma iron.' For this experiment a thin plate of medium carbon steel is chosen. The surfaces of this plate may be taken as two parallel planes which may be considered infinite for points well in the Center of the planes. These two planes are held at different concentrations of carbon at a constant temperature. This temperature, 1700°F for example, is one where the single phase: carbon in solution with gamma iron, exists. When these conditions are held for a sufficient time the concentration of carbon of the different points of the solid ment down towards its steady state value. At points well removed from the ends, the concentration will remain the Same along planes parallel to the surfaces of the plate.

Jan 1, 1948

By Patrícia Mundim Campos Faria

The process of particle size reduction by grinding is inherently inefficient and involves high capital and operating costs. In particular, ball milling is one of the important unit operations in the iron ore pelletizing process. The mill product, due to its physical properties, determines the efficiency of subsequent stages of classification, filtration and pelletizing, thus impacting the quality of iron ore pellets. The work demonstrates the application of the population balance model in the optimization of a full-scale ball mil circuit grinding pellet fines with the aim to evaluate the optimal solids concentration to improve iron ore pellet quality. Initially, detailed experimentation was carried out in a 25.4 cm diameter batch mill and a relationship for mill scale-up using a linear population balance model in wet grinding systems was established. The selection and breakage parameters and the specific selection functions were determined for pellet feed iron ore. It was possible to identify the non-normalizable nature of the breakage functions of the ore studied, which were modeled properly. Afterwards, as a result of incorporating the specific selection functions and breakage functions into the linear population balance model, it was possible to predict product size distributions in the pilot and plant scale mills (0.416 and 5.18 m diameter, respectively) from data obtained in the 25.4 cm diameter mill. Finally, with this scale-up procedure it was possible to appraise the plant scale optimization via laboratory scale grinding mill tests. The effects of changing percent solids were assessed in order to improve the industrial mill performance and the optimal value should be in the range from 76 to 80%.

Aug 1, 2018

By Roger Nendick

The recent developments in refractory precious metal ore processing (Bio-oxidation, Autoclaving), and the revitalization of the more traditional roasting processes have attracted great attention in recent years and are indeed the focus of todays symposium. It must always be remembered, however, that the term refractory ore by definition means that the material 'must be capable of being treated at a profit". Given the high cost of the refractory processes, the requirement to be treated at a profit requires very close scrutiny during the evaluation phase of the property development. The M.G.M. film company has the latin motto Ars Gratia Artis meaning Art for Arts Sake. Ingeniatore Gratia Ingeniatoris (a very crude attempt at saying Engineering for Engineerings Sake) should not be the motto for mining companies intent on exploiting refractory gold deposits, but rather the wittily tilted heading for this paper "Take the money and run like a thief". The following hypothetical case studies show that the high technology solution is not always the best financial solution.

Jan 1, 1990

By M. I. Kalashnikova

Gipronickel Institute has developed the technology of treatment of difficult to concentrate sulphide Pb-Zn concentrates (Zn-19,9%, Pb-8,4%, Cu-0,34%, Fe-8,8%, Ba-6,8%, S-18,7%, Ag-106 g/tonne). The technology consists of pressure leaching, impurity removal from leaching solution, electrowinning and Pb-Ag containing cake treatment. Despite low zinc content in initial concen-trate the technology allows production of solution which is suitable, after standard procedure of impurity removal, for electrowinning with production of zinc grade SHG. Comparing to the standard technologies the flowsheet developed provides the lesser expenses per zinc unit because of decreasing of liquid to solid ratio at pressure leaching stage. The initial concentrate is characterized along with low content of principal metals by high con-tent of barite, which makes flotation of pressure leaching residue more difficult. That is why in this case the hydrometallurgical treatment was chosen. At optimal parameters of chloride leach-ing found during laboratory experiments the principal components extraction was 99.5% for Pb and up to 92% for Ag.

Jan 1, 2006

By M. Niinae, Y. Nakahiro, T. Wakamatsu

In some cases, the extraction and separation efficiency of metals with a combined extractant are better than those with either extractant alone. However, the extraction and separation efficiency of metals with a combined extractant are not always better than those with either extractant alone. As part of the fundamental studies on the extraction and separation of metals with combined extractants, the extraction and separation efficiency of Au and Fe(III) added as an oxidizer in the leaching of Au from a sulphuric acid solution containing thiourea, and the extraction and separation efficiency of Nd and Sm from hydrochloric acid and sulphuric acid solutions were examined. The combined extractants for Au and Fe(III) were di(2-ethylhexyl) phosphosphoric acid (D2EHPA)/tri-n-butyl phosphate (TBP), D2EHPA/trioctyl phosphine oxide (TOPO). tri-n-octylamine (TOA)/TBP and TOA/TOPO, and those for Nd and Sm were D2EHPA/TOA. D2EHPA/TOPO. 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (EHPNA)/TOA and EHPNA/TOPO

Jan 1, 1994

By Sergey Gudkov, Yuri Yemelianov, Stanislav Balikov, Andrey Boldyrev, Andrey Bogorodsky

"The results of POX of refractory gold-bearing concentrates using halide-ion as a lixiviant for precious metals and activated carbon as an adsorbent are given. It was found that gold did not recover to the solution when halide was added during POX. Silver partially dissolved in the solution. When halide-based reagents and activated carbon were added during POX, gold dissolved and loaded onto the activated carbon. The degree of sulfides oxidation was 99.3-99.6%. The recovery of gold onto granulated carbon was 94.7-94.8% when using chlorine-bearing lixiviants: NaCL, CaCL and carnalite and 98-99% when using KJ and KBr. This treatment process of refractory gold-bearing concentrates combines sulfide oxidation, dissolution and adsorption of precious metals. The results of the metals recovery achieved using this process can be compared with the recovery during POX-cyanidation. In this case, sodium cyanide was not used. This allows the reduction of capital and operational costs due to the absence of cyanidation, CIL and detoxification of leaching tailings circuits."

Jan 1, 2014

By J. O. Glanville, L. H. Haley

Ice frozen from a dilute chemical solution is mechanically weaker than ice frozen from pure water. This phenomenon is the basis of a practical method for reducing the strength of a mass of frozen coal. If a chemical additive is applied to moist coal prior to its shipment during freezing weather, the resulting frozen coal can be more easily broken than in the absence of the chemical additive. This greatly expedites the unloading and handling of coal during winter. There has been considerable research into the nature and mechanical strength of ice frozen from various solutions. In this paper, literature relating to this process as well as literature relating to the chemical treatment of coal and mineral particulates is reviewed. Some important articles are discussed and speculations made about the nature of the ice-weakening process. A laboratory evaluation of the effects of chemical additives on the mechanical strength of ice and frozen coal has been made. An apparatus designed for this purpose is described, and some results obtained with it are discussed.

Jan 1, 1983

By E. Northcott, I. M. LeBaron

Before describing the electrostatic processing of feldspar, it might be well to review some of the basic definitions and terminology of feldspars. The feldspar minerals constitute a group of alumino-silicates of potassium, sodium, and calcium. Barium feldspar sometimes occurs naturally but is very rare. Hardness varies between 6 and 6.5 and specific gravity between 2.5 and 2.8. Color is generally white or pale shades of red, yellow, or green. The approximate chemical composition of the principal feldspars is given in Table I. The albite (sodium aluminum silicate) and an orthite (calcium aluminum silicate) feldspars are the end members of a series called plagioclase. These two molecules form a complete solid solution series ranging from pure soda feldspar at one end to the pure lime feldspar at the other end. Intermediate solid solutions are known as oligoclase, andesine, labradorite, and bytoconite. The general structure throughout this series is the same. Sodium and calcium may replace each other and silicon and aluminum may replace each other in the structure.

Jan 10, 1958

By R. V. Ramani, S. Tan

In this paper, several commonly used computer truck-dispatching criteria are evaluated. A computer-oriented truck-dispatching and production simulator was developed to provide data for comprehensive cross comparison among the dispatching criteria. The definitions, primary considerations, characteristics and performances of these dispatching criteria were investigated. From the simulation results, it was concluded that, in general, no one criterion can dominate all others. However, several dispatching criteria that have good potential to increase performance can be identified. All basic dispatching criteria, including minimizing truck waiting time, waiting shovel with minimum waiting time, minimizing truck saturation, maximizing truck momentary productivity or optimization of truck routes, provide local optimal solutions. To obtain a direct global optimization solution for this complex stochastic process does not appear to be likely Therefore, the search for an optimal dispatching criterion that will fit all conditions may not be realistic. It may be necessary to search for a hybrid combination of the several truck dispatching criteria that have good potential for a given situation. An approach to selecting such a hybrid dispatching criterion is presented.

Jan 1, 1993

By A. J. MOORE

When the writer first saw the square-set timbering, he was at once impressed with the fact that the frames made by the sets, along the lode and across it, were composed of panels with rectangular openings, and it was puzzling to understand howsuch a collapsible construction could resist pressure that came unevenly on it. Later he learnt that the sets did not satisfactorily resist such pressure, but mullock filling had, to a great extent, to undertake this duty for them. So it appeared that the setswere practically an expensive scaffolding, enabling the miners to work in the face and carry the stope forward, till the filling was put in behind them to take the pressure of the roof and sides of the excavation. Of course some of the pressure is takenby the sets, but this is because "the set timbers prevent the filling being done perfectly; if it were practicable to remove the sets before filling, the filling by itself would more effectively support the back and wall, than do the combined sets andmullock. On the whole, therefore, the sets can hardly be said to be of much benefit where pressure has to be resisted. Despite this, the system has been of immense service in mining wide lodes, but for all that, it can only be pronounced a makeshift.This is no reflection on Deidesheimer, the famous originator of the square set, for, as will be shown later on, this way of...

Jan 1, 1912

By J. S. Browning

The physical properties and specific gravity ranges of various liquids and salt solutions used for laboratory sink-float separations of rocks or minerals are presented. The test equipment and techniques employed by the Bureau of Mines in making sink-and-float separations of particles as coarse as 3 inches to as fine as 400 mesh are described. Also discussed are methods of recovering and reclaiming the liquids or salts from the minerals and wash solutions, as well as the hazards encountered and precautions to be followed while working with the materials. The laboratory use of various liquids for separating minerals of different specific gravities has been recognized for many years. During this time, laboratory sink-float procedures have proven their utility as a rapid and moderately accurate means for determining the mineral content of ores, test products, and plant products in certain nonmetallic concentrating operations, such as those producing mica, spodumene, kyanite, and so forth. These procedures also have been used as analytical tools for determining the mineral content and associations of other metallic and nonmetallic ores.

Jan 1, 1961

By Komosa T, Muir D. M

Mixtures of ammonia and cyanide at low concentrations leach gold selectively from copper-gold ores. The effects of various reagent compositions on three different ore types containing between 0.3 - 1.5 per cent Cu are reported. It is shown that the results and optimum compositions vary according to the ore, which is attributed in part to the mineralogy and adsorption of solution species on the mineral surfaces. The solution chemistry of the Cu-NH3-CN system indicates that Cu(CN)a - and Cu(CN)3 species are involved in the leaching mechanism. Rotating disc studies on pure gold and copper are reported which show that the Cu(CN)32- species leach gold at about half the rate of CN but leach copper at the same rate. The presence of ammonia retards the leaching rate further. Mixtures of Cu(CN)a3- and NH3 effectively leach gold from Telfer tailing without leaching copper. The role of ammonia appears to be to control the precipitation of copper rather than the kinetics of leaching.

Jan 1, 1991

By R. H. Lien

The Bureau of Mines developed a flue gas desulfurization process as part of its goal of minimizing the undesirable environmental impacts associated with energy and mineral-processing plants. The modified citrate process involves absorption of sulfur dioxide (S02) in a buffered citric acid solution. The S02-loaded solution is regenerated by countercurrent contact with steam in a packed tower. The wet S02 product is then dried and can be liquefied or further processed to make sulfuric acid. Test data from process investigation unit studies are presented. Material balances, flowsheets, and cost estimates are given for recovering S02 from copper smelter reverberatory gas, lead smelter sintering machine tail gas, and power-plant stack gas. Operating cost estimates show the process will add $0.04 per pound of copper, $0.01 per pound of lead, and $0.015 per kwhr to the cost of the respective operations. These costs could be substantially reduced if a source of waste heat was avail-able to provide the process steam requirements.

Jan 1, 1982

By Mary Ellen Bruce Large, Antonio Marinucci, Silas C. Nichols

Tip post-grouting of bored pile (drilled shaft) foundations refers to a method where cementitious grout is injected beneath the tip of a shaft to improve the overall performance of the constructed foundation. This technique, when performed satisfactorily and in the appropriate ground conditions, enhances axial load-displacement performance by improving the mobilization of pile’s resistance. Potential benefits associated with tip post-grouting include reduced settlement under loading, better alignment of load transfer curves, and improved ground beneath the base of the bored pile. However, to be able to realize the benefits attributed to this method, the design, construction, of both the bored pile and the post-grouting system must meet a minimum level for quality assurance. The various factors affecting the successful installation and performance of a bored pile (e.g., workmanship, base cleanliness, borehole integrity, and concrete placement) have been discussed by numerous practitioners and researchers in the available technical literature. For a conventional (i.e., ungrouted) bored pile, acceptance is based on a combination of visual inspection, material testing, and the results of integrity and/or performance testing of the constructed pile. A properly executed tip post-grouting program can be a relatively comprehensive and complex process, which is typically evaluated throughout the construction process based on the results of prior projects and/or on test pile(s) at the particular site. For tip post- grouting programs, verification procedures and acceptance criteria should be established during and incorporated into the design process to ensure design intent and objectives are achieved. Project specifications should be produced to ensure performance requirements are achieved. This paper will present and discuss factors affecting the successful execution of tip post-grouting, including grouting criteria, instrumentation, reliability and uncertainty with the method and outcome, and verification and acceptance. INTRODUCTION Constructing bored piles (drilled shafts) is increasingly more challenging given the lack of ideal site locations, tight project site confines, difficult or restricted access, greater demands on drilling equipment, and close proximity to adjacent structures. To evaluate the feasibility of bored piles as an appropriate foundation system, a myriad of factors is evaluated during design, including site conditions and constraints, budgeting and scheduling, reliability and risk exposure, presence of and depth to adequate load bearing soils/rock, and the magnitude of the imposed loading. Moreover, updated design codes increased load demand per element, and improved material strengths have led to more complex foundation designs, larger foundation elements, and significant increases in load magnitude. Monopile (monoshaft) foundations have been utilized where one large bored pile is used in lieu of a group of piles connected via a pile cap. In addition, to accommodate the design criteria, site conditions, and imposed loading, the geometry of the bored piles being designed and installed have been as large as 13 feet (4 m) or greater in diameter and to depths in excess of 260 feet (80 m).

Jan 1, 2018

By Kazunori Matsushita, Frank Vespi, Emi Walder, Mitsuo Nozu

During the runway expansion project at the Fort Lauderdale-Hollywood International Airport in Florida (FLL project), therewere complicated geotechnical issues with a number of cavities in the limestone-loose sand mixed ground thatexisted in many areas below the existing ground. Collapsing the cavities and compacting the runway foundation to secure the take-off and landing of aircrafts was a necessary requirement for the project. The Mammoth Vibro-Tamper (MVT) which produces less vibration and noise level, was proposed and accepted as the alternative to the originally specified Deep Dynamic Compaction (DDC) for the runway with its length of 1.5 miles and area of 570,000 square yards. In this report, the shallow compaction effect and reduced ground vibration with the MVT are presented in comparison with the DDC which was utilized on the same project in a different area of the airport. INTRODUCTION MVT was developed by Fudo Tetra Corporation in the 1960’s and has been widely used in Japan (more than 14,400,000 square yards). For example, at the Kansai International airport, a large area including aprons was compacted with the MVT. It is capable of compacting up to approximately 5m in depth by using a heavy steel plate (3m x 3m) and a strong vibrator motor (V-180, 10Hz) on top of the steel thick plate with specified time duration. We were involved in densification work with the MVT at the Fort Lauderdale Airport Project (Figure 1) from June, 2012 to February, 2014. Deep Dynamic Compaction (DDC) was originally specified as the compaction method to secure the relative density over 70% in every 2,000 square yards grids, however, we proposed the application of MVT to reduce the vibration risk and it was accepted as the alternative (Figure 2). The compaction work was completed in February 2014, without causing any delay in regard to the residual settlement due to the high embankment (H=60ft=18m).

Jan 1, 2018

By D. L. Morgan, J. A. Butterfield

"Geological data, production trends and current projects underway suggest that enough molybdenum will be available from more diversified sources to meet the world's growing demands. The growth in molybdenum consumption has been primarily related to its beneficial effects as an alloying agent in steel. This rapid growth has been deliberately fostered by stable prices, adequate supply and application research. The molybdenum industry is now in a process of change which has been seen in several other metals, such as aluminum and nickel. As supply sources have become more diversified, the market has become more competitive. The recent drop in consumption has led to excess production capacity, accumulation of substantial producer inventories and increased market uncertainties. While consumption is expected to increase in the next two to three years, it will take some time to absorb the excess capacity and inventory. The increased proportion of by-product capacity indicates that prices may become more variable. Producer discipline will be required to prevent serious price erosion in times of surplus. Future prices may not continue to increase with inflation. For the longer term, several factors favour the increased consumption of molybdenum. Engineering requirements are becoming more severe and molybdenum alloys can help to meet these changing needs. In addition, consumers can rely on a large and increasing supply of molybdenum. A 7 per cent growth rate in consumption can probably be sustained through the next decade, but new applications and reasonably stable prices will be needed to make this possible."

Jan 1, 1972

By Pierre Choquet

"The whole work carried out both in situ and in laboratory by a research group of the West German collieries is presented. This work has led to a design method of steel arch supports for gate roadways that gives full satisfaction in this particular coalfield. The method accounts for mining depth, the mining system (advancing or retreating), thickness of the coal seam and other parameters.Full statistics are then given on gate roadway supports of the ECCS (European Community for Coal and Steel) coalfields. They were collected by the author in order to show that the West German method can be applied to other coalfields as the long wall systems which are generally being used are very similar. Design calculations are conducted for each coalfield's case. They show that the method would have been able to predict in most cases the support actually used.Utilization of the design method is recommended to the Cape Breton Development Corporation 's mine operators because mining conditions, even though different from European ones, present a number of similarities which make it possible to apply the design method to their particular case.This procedure might be profitable in mines facing support problems in their levels and for any planning of future projects"

Jan 1, 1986