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By M. E. Poad

In 1986, a cooperative effort by the Homestake Mining company, the U.S. Bureau of Mines and the University of Utah was initiated to determine shaft stability while recovering high grade ore in a nearby pillar. Premining finite element simulations indicated the shaft would remain in elastic ground. Six years have elapsed and, despite some initial concern during the first lifts, it appears that the bulk of the original reserve will be safely and profitably recovered. An integrated application of rock mechanics tools from laboratory testing through numerical modelling to mine measurements and observations contributed substantially to the operational success of the project.

Jan 1, 1994

By N. B. Prenn

Many recent projects have been developed and mined based upon imaginary reserves. Imaginary or "geo-fantasy" reserves have cost many companies millions of dollars. The significant and varied technological advances in the mining arena have done little to curb reserve calculation problems. These advances may have served to increase the prevalence of reserve problems by putting more tools in the hands of personnel not properly trained or experienced in reserve estimation. This paper will discuss potential problems related to calculating reserves, which include: SAMPLING ERRORS -obtaining a representative sample. -Decay analysis of wet RC drilling -Bias introduced by sample preparation. -Assay bias; Coarse gold. -Specific gravity samples. GEOLOGICAL ERRORS -structural boundary definition. -Separation of high grade and low grade zones. -Incorrect continuity assumptions MODELING ERRORS -Too much influence of high grade samples. -Improper method of calculation. -Assumed range of influence. -Errors in the data. ENGINEERING ERRORS -Inaccurate assumptions. -Inadequate metallurgical testing. -Designed bottlenecks.

Jan 1, 1992

By V 9. 0 / 300 dpi

In the time period from the early 1980's to the present, longwall roof support technology has evolved tremendously. Chock supports and caliper shields were replaced by 2-leg or 4-leg lemniscate shields. The lemniscate linkage for which the support is named offers numerous advantages to the sup-port both as a fabricated structure and to its performance in the mining application. The hydraulic system, which is the dynamic element of the roof support, was essentially unchanged in early lemniscate shields with the exception of the complexity of additional hydraulic circuits to power a canopy tilt cylinder and canopy side-seals. The control of these fluid-powered functions was provided by direct manual control of valves energizing individual functions onboard the roof-support or the adjacent roof-support. This control valve-gear was comprised of multiple individual valves arranged in a "bank" or integrated into a single hydraulic distribution block with a single operating handle to select any independent function.

Jan 1, 1993

By H. P. Greenwald

THE Committee on Rock-Dusting was formed after the fall meeting of the Coal Division in Chicago in 1938. Its primary task was to study the recommended American practice for rock- dusting coal mines to prevent coal-dust explosions as approved by the American Engineering Standards Committee. After approximately two years' work he committee concluded that although certain portions of the recommended practice could well be revised, information needed for a logical revision was not at hand, and it was inadvisable, therefore, to make revisions

Jan 1, 1943

By Anthony T. C. Goh, Zhiye Zhao, Laddu B. Jayasinghe, Hongyuan Zhou, Yilin Gui

"Ground vibrations from blasting are undesirable and they are very short in duration with high principal frequencies and high amplitude. Structural response to that kind of excitations may differ significantly from that generated by lower-frequency earthquake vibrations. In practice, the damage to nearby structures to generated ground vibrations has been controlled by various codes and regulations available. However, the existing vibrations limits are not always applicable, as they depend on the geological conditions of the site and the dynamic characteristics of the structure. This paper investigated the influence of the rock-soil interface on the response of pile foundation to ground-borne vibration from rock blasting, through numerical simulations using finite element software LS-DYNA. It is found that the slope of the rock-soil interface greatly influences the location of damage and the extent of damage on the pile. The bottom of the pile is subjected to a larger blast pressure and stresses are highly concentrated at the pile bottom. Thus, the pile bottom can fail in shear before it reaches its plastic moment capacity.INTRODUCTIONDrilling and blasting is the widely accepted method to large-scale rock breaking activities in civil engineering constructions due to its cost effectiveness, higher efficiency and ability to break hard rock. However, ground vibrations from blasting are undesirable and it can cause damage to nearby structures. In practice, the damage to nearby structures to generated ground vibrations has been controlled by various codes and regulations available. The existing vibration limits are not always applicable, as they depend on the geological conditions of the site and dynamic characteristics of the structure.Pile foundations are commonly used as foundations of high-rise buildings and bridges to transfer the heavy loads from the superstructure above through weak compressible soil strata into deeper, competent soil layers which have adequate capacity to carry these loads. In engineering practice, many piles are normally designed to carry mainly vertical loads and very little lateral loads, as typically the vertical loads (the gravity) are significantly larger than the horizontal loads such as wind loading. However, in recent years, there have been a number of reported case studies of translational soil movements that have induced stresses and bending moments that have damaged pile foundations and in some cases resulted in collapse of the superstructure. Typical lateral load include nearby construction activities such as an excavation for a basement or slope, the construction of a road embankment or a tunnel, as well as earthquakes (Abdoun 1997; Goh et al. 1997; 2003; Chen et al. 1999; Dobry et al. 2003; Boulanger et al. 2007; Black et al. 2007)."

Jan 1, 1900

By S. A. Luciani

"In 1957, an asbestos orebody was discovered in the northern sector of the Ungava Peninsula of the Province of Quebec, an area now identified as Asbestos Hill. The deposit is situated on a plateau 1700 feet above sea level and 42 miles inland from Hudson Strait. It is a bleak, iso. lated location of typical arctic environment. Fifteen years were to pass before the first shipment of ungraded fibre was made in 1972. These years we1•e occupied with field surveys and investigations, diamond drilling, engineering design, evaluation of investment and operating costs, and construction. The problems normally associated with mine development were further complicated by location, isolation, and the extreme cold and permanently frozen ground of the arctic regions. Unique to an isolated arctic operation are the organization of support facilities and services, procurement and retention of personnel, construction of access roads and airports, and scheduling of product out and supplies in during the short summer period of sea navigation."

Jan 1, 1976

By A Van den Bulck, K Verbeken, O Vergote, I Bellemans

Viscosity is one of the most important physicochemical properties during pyrometallurgical operations. In the sub-liquidus regime, an important factor is the presence of suspended solid particles, yet its influence is not well-described in earlier literature, despite the significance of this factor. This project aims to determine the influence of spinel particles (Zn(Al,Fe)2O4) on the rheology of a multiphase synthetic PbO-SiO2-ZnO-Fe2O3-CaO-Al2O3 slag system. Three data sets with a wellcontrolled methodology and three different spinel sizes (small (13 μm), medium (34 μm) and large particles (76 μm)) were published previously, using a custom-built high-temperature rheometer. This study presents an additional data set of slag viscosity measurements, performed using a different apparatus, the Anton Paar FRS 1800, to verify the consistency of the earlier determined viscosity behaviour. Within this data set, no consistent trend could be found between the predicted wt per cent spinel and the relative viscosity. Therefore, additional quenching experiments were conducted to identify the morphology and experimentally determined volume fraction of the spinel particles in the slag. These measurements revealed a difference in spinel size across the samples and corresponding viscosity behaviour, emphasizing the importance of spinel particle size on slag viscosity. Once the spinel size was taken into account, consistent viscosity results (relative apparent viscosity and flow index) were observed across the two devices. This study confirms that, once all parameters affecting slag viscosity are considered, the viscosity behaviour of a heterogeneous slag can be uniquely determined. The resulting optimised slag viscosity models can be used to predict viscosity before processing, addressing relevant phenomena such as slag tapping, slag foaming and copper droplet settlement.

Aug 21, 2024

By R. E. MacDougall

Very few mineral properties spend their entire lifespans from discovery to depletion in the hands of one owner. More likely, properties will have several owners, and partial interests may change quite often. Similarly, mineral companies are bought and sold with frequency, in recent years at what appears to be an accelerating rate. The reasons for selling a property can be manifold -need for additional capital in other parts of the business, need for development capital, realization of a large gain at a perceived high point in the market, pessimistic commodity outlook, retirement of principals, or resolution of estate problems. Regardless of the reasons for a sale, there are specific steps that logically follow. Spruce up the business, package the information, market the property, negotiate the terms, close the sale, and make sure it stays sold. Adherence to certain very basic ground rules in property sales can maximize the profits and minimize the effort.

Jan 1, 1990

By Syd S. Peng

According to accident statistics (l, 2), roof fall accidents occur quite frequently at the intersections of underground? openings and account for up to 30% of the roof fall fatalities. But this figure will certainly go up considerably if roof falls not associated with any fatal accident are included in the analysis. Unfortunately, nonfatal roof falls are seldom documented. In the underground coal mines, there are two types of entry intersections. One is the three-way (V type) and the other is the four-way (T type) intersections. A three-way intersection occurs whenever the mainline track haulageway turns at an angle into a section haulageway. The four-way intersections by far the most common type in the U.S. under-ground coal mines are formed by the intersections of two entries which are oriented perpendicular to each other or by the intersections of entries and crosscuts. However, crosscuts are frequently driven at an angle to the entry to facilitate machine movements. The four-way intersections formed by this method of crosscut development are angled. At the intersection of two underground openings, the diagonal roof span is wider than the width of each individual opening. This is one of the major reasons why roof falls occur more likely at the intersections than in the entry between pillars. Consequently, special intersection support plans are usually employed (Figs. 1 and 2) for intersections. The most popular practices are to decrease roof bolt spacing 1 ft. less than or to increase roof bolt length 1 to 2 ft. longer than those employed in the entry between pillars (3). The increase in bolt length or decrease in bolt spacing can be applied to all of the bolts in the intersection or employed only for the strategically located bolts depending on the individual mine practices. These rather generalized practices seems to be adequate for some areas but in many cases inadequate for others. Occasionally, the neighboring two lines of chain pillars are staggered such that the crosscuts in one row of chain pillars face the centers of the chain pillars in the neigh-boring rows. This layout forms T-type three-way intersections which are also inadequate for most weak roofs (3, 4). A study was therefore initiated to develop special techniques for intersection supports. The first phase of the study was the analysis of the stress fields for the underground entry intersections. A three-dimensional stress analysis was necessary for this purpose. Unfortunately, the three-dimensional problems of complicated boundary conditions are beyond the existing analytical methods. The three-dimensional finite element method (FEM) was therefore employed in this study. In the analysis, square pillars of 40 feet wide and an entry height of 8 feet were assumed while entry widths varied at 14, 20 and 26 feet. This model was selected to simulate the mine where roof falls data were collected. The second phase of the study was the collection of field data. The sizes of the roof falls including heights, lengths and widths were collected and analyzed. In the third phase study, the results of the first and second phases were compared and discussed. The analysis of field data revealed an arching zone within which roof falls occurred. The arching zone above an entry obtained empirically was compared with the calculated stress contours. Assuming that the bolts must be anchored in the rock strata outside the arching zone, the preferable systems of bolting were proposed. Also the amount of pretension required to inhibit sliding between layers was discussed.

Jan 1, 1978

By Diogo Fonseca, José Manuel, Nuno Fernandes, Blessing Taiwo

This research focuses on enhancing the synergy between blasting and primary crushing operations in quarries. A blast operation at dstgroup aggregate quarry in northern Portugal was simulated to fine-tune blasting techniques aimed at optimizing fragmentation indicators. The methodology involves conducting precise blast drill hole surveys, generating detailed terrain 3D models, and integrating these models into blast simulation software to enhance accuracy and optimize production efficiency. The study applies these simulations to test blasts, evaluating improvements in cost-effectiveness, crusher power consumption, and fragmentation efficiency using both aerial and terrestrial image analysis technology. The quarry key performance indicators (KPIs) guide the blast design simulations, ensuring practicality and relevance. The case study blast revealed that implementing optimum blasting techniques can enhance crusher throughput, reduce operational costs, and improve safety. This paper is part one of a three-part technical series where we aim to create a sampling procedure and establish a reliable baseline for the current state of operation. This baseline will be used in subsequent follow-up technical papers to make recommendations and improvements. The outcome of this study provides a framework for quarry operations seeking to enhance their efficiency.

Jan 21, 2025

By G. St. J. Perrott, N. A. Tolch

"The testing of explosives for permissibility for use in coal mines was begun by the technologic branch of the United States Geologic Survey in February, 1909, and continued by the United States Bureau of Mines from July, 1910; this testing has been carried on from year to year as the explosives were submitted by manufacturers. As a result of these many years of testing for permissibility a large amount of data has accumulated regarding the characteristics of permissible explosives. The manufacturer expects a sample of explosive submitted for test to meet the requirements for permissibility, otherwise the sample would not be submitted. However, in spite of the careful regulation and preparation of the formulas a certain percentage of explosives fails to pass the gallery tests. It is therefore interesting to note the proportion of failures at the gallery for a given composition of explosive. The fact should be emphasized that this discussion deals with all explosives submitted for test, both those which passed the tests and those which failed to pass. Explosives that failed to pass the tests were never designated as permissible explosives and have never appeared on any list of explosives permissible for use in coal mines.The Bureau of Mines classifies permissible explosives in two ways, according to the quantity of poisonous gases produced and according to the characteristic ingredient of the explosive.4 In this paper only two types of the latter classification are considered, as follows:"

Dec 1, 1929

By K. W. Major

"This chapter outlines the organization of mine/ mill complexes in Canadian mining companies. Many factors unique to the Canadian mining industry will affect the design of the organization in the future: geographic location, the size and the type of orebody, etc. Mining companies cannot choose where new operations will be located, that is dictated by the location of the orebody. New mines are seldom started near established communities. Rather, the towns usually grow up near the mines. The remoteness of most Canadian mining operations has caused severe problems in attracting and/ or retaining all levels of employees. This means that training has a high priority within each operation.Another factor affecting mine/ mill organizations is the size of the operation. Larger operations generally require more departments and increased specialization to manage equipment and manpower effectively. Thus, for mine/mill complexes, organizational charts are less standardized than in other industries. It is often necessary to organize around the work force rather than develop a chart and then acquire the trained personnel to fill the diagrammed positions.The information presented in this chapter has been derived from the responses received from a survey of Canadian mining operations.Principles of OrganizationOrganization can be defined as deployment of personnel to accomplish definite goals. In the mining industry, the major goals are typically the projected number of tons and grade of ore mined on a daily, weekly, monthly and yearly basis. Organizing involves establishment of authority relationships with provisions for both vertical and horizontal co-ordination within the company structure. Vertical co-ordination is the delegation of responsibility and communication of goals and reporting of progress between the supervisor and subordinate. Horizontal co-ordination is communication between departments at positions of equal authority to determine methods of achieving predefined goals. The organization structure must reflect the objectives and plans of the company, and must clearly define areas of authority.Two criteria for effective organization are departmentalization and manpower planning."

Jan 1, 1989

By Chu Yong Cheng

Synergists can be used in solvent extraction to improve the selectivity of extractants for metals. Research work carried out by the SX group at the AJ Parker Cooperative Research Centre for Hydrometallurgy / CSIRO Minerals has shown that the pH isotherm of nickel with Versatic 10 was significantly lowered by the addition of the synergist Acorga CLX50. The paper discusses how this synergistic shift can be used to alleviate a gypsum formation problem at Bulong nickel laterite operation in Western Australia. Metal pH isotherms were obtained with Versatic 10 and synergist CLX50 using synthetic leach solutions. In terms of pH50, the extraction order of the metals with 0.5 M Versatic 10 alone was Cu > Zn > Ni > Co > Mn > Ca > Mg, whilst the extraction order with Versatic 10 and 20% by volume CLX50 was Cu > Ni Zn > Co > Mn > Ca > Mg with the pH50 (Mn-Co) significantlyincreased. This is significant because the isotherms of valuable metals Ni, Cu, Co and Zn shift more towards low pH than those of the waste metals Mn, Mg and Ca, resulting in a possible good separation of Ni, Cu, Co and Zn from Mn, Mg and Ca. The use of intermediate precipitation, solids/liquid separation and re-leach in the three Western Australian nickel plants make these processes complicated and costly in capital and operation. The research work carried by the SX groupat the AJ Parker Centre has led to the development of direct SX (DSX) processes to recover nickel and cobalt from leach solutions using synergistic organic systems. Semi-continuous tests with a BHP Billiton pilot plant leach solution showed that Ni and Co together with Zn and Cu were separated from the major impurities, Mn, Mg, Ca, and Cl, in the first SX circuit. The co-extracted impurities were easily scrubbed. After stripping, Ni and Co together with Zn and Cu were concentrated, resulting in a much smaller second SX circuit in the down stream processes.

Jan 1, 2003

By F. W. Bloecher, A. M. Gaudin

THIS paper describes the results of a series of tests carried out to determine the partition of dodecylamine between distilled water and the surface of quartz at various concentrations of dodecylamine acetate in solution. An adsorption-column technique was utilized for this purpose. Ralston and Harwood, of Armour and Co., had synthesized marked dodecylamine acetate for us.' In their preparation which we employed, 0.0007 pct of the total carbon was the radioactive isotope, carbon fourteen. Unmarked dodecylamine acetate of high purity was also prepared by them for our use. The presence of carbon fourteen in the dodecylamine enabled us to analyze quantitatively for dodecylamine on the surface of quartz, using a radioactive-tracer technique. The method used was that known as internal gas counting of carbon dioxide, formed by oxidation of the amine. This method has already been described, "3 ' and the reader is referred to these papers for details of the analytical method and procedures. and surrounding liquor, a technique analogous to chromatographic columns was utilized. The experimental setup is shown in fig. 1. The dodecylamine-acetate solution was made up in a volumetric flask and poured into the glass funnel shown. It was allowed to drip slowly onto the quartz bed, the rate of flow from the funnel reser- voir being controlled by a hose clamp. The quartz column was contained in a small, fritted-glass filter (size 20 mm, C). The beaded top edge of the filter was cut off to enable the holder and contents to fit into the open end of the 30/45 joint on the combustion tube. This combustion tube is used in the analytical train described in a previous paper.' A piece of gum-rubber tubing joins the bottom of the fritted-glass filter to a filter flask, which in turn is connected to a vacuum line, or water aspirator. The rate of flow of amine solution through the bed was

Jan 1, 1951

By F. W. Bloecher, A. M. Gaudin

THIS paper describes the results of a series of tests carried out to determine the partition of dodecylamine between distilled water and the surface of quartz at various concentrations of dodecylamine acetate in solution. An adsorption-column technique was utilized for this purpose. Ralston and Harwood, of Armour and Co., had synthesized marked dodecylamine acetate for us.' In their preparation which we employed, 0.0007 pct of the total carbon was the radioactive isotope, carbon fourteen. Unmarked dodecylamine acetate of high purity was also prepared by them for our use. The presence of carbon fourteen in the dodecylamine enabled us to analyze quantitatively for dodecylamine on the surface of quartz, using a radioactive-tracer technique. The method used was that known as internal gas counting of carbon dioxide, formed by oxidation of the amine. This method has already been described, "3 ' and the reader is referred to these papers for details of the analytical method and procedures. and surrounding liquor, a technique analogous to chromatographic columns was utilized. The experimental setup is shown in fig. 1. The dodecylamine-acetate solution was made up in a volumetric flask and poured into the glass funnel shown. It was allowed to drip slowly onto the quartz bed, the rate of flow from the funnel reser- voir being controlled by a hose clamp. The quartz column was contained in a small, fritted-glass filter (size 20 mm, C). The beaded top edge of the filter was cut off to enable the holder and contents to fit into the open end of the 30/45 joint on the combustion tube. This combustion tube is used in the analytical train described in a previous paper.' A piece of gum-rubber tubing joins the bottom of the fritted-glass filter to a filter flask, which in turn is connected to a vacuum line, or water aspirator. The rate of flow of amine solution through the bed was

Jan 1, 1951

By E. E. Malouf

With the continued development of low-grade porphyry copper deposits by open pit mining, substantial amounts of copper-bearing strip material have been accumulated in waste dumps adjacent to the many large mines. Since the end of World War II, the production of copper from leaching these copper-bearing wastes increased from approximately 4% of the total copper production to 10% by the early 1960's. Projected increases will probably raise this figure to 20 to 30% by the early 1970's. Furthermore, a gradual recognition of the economic feasibility of leaching mined-out areas is evident and will undoubtedly contribute additional production. Waste dumps in canyons and gulches on the periphery of open pit mines, mine stopes, caved areas, and abandoned open pits often contain substantial quantities of leachable rock ranging in concentration from 0.1 to 0.4% copper. Recent developments in the leaching of copper, mainly the recognition of bacterial oxidation of sulfide minerals combined with better under- standing of the control of the salt content of the leach solutions, both by adjusting the pH and/or by hydrolysis, are resulting in a greatly expanded recovery of copper from these hitherto uneconomic mine rejects. 11.5-1. Mechanism of Leaching. Leaching processes for the extraction of metal values from mine ore or waste may be classified for convenience as either chemical leaching or bacterial leaching. Chemical leaching is considered to be the extraction of soluble salts by metathesis in acidic, basic, or neutral water solutions. The reactions involved may be evaluated by chemical thermodynamics. Bacterial leaching, although a chemical process, is dependent on biological catalysis and this is generally a much more complex process. This justifies its separate treatment in the application to leaching. Acid ferric sulfate solutions are commonly employed in the mining industry to leach valuable metals from metal sulfide ores. The leaching mechanism is a reduction-oxidation reaction in which minerals are oxidized at the expense of ferric sulfate. Such chemical leaching is profitable when

Jan 1, 1968

By E. A. Holbrook

IT may be taken for granted that a mine official knows his duties, as outlined by the bituminous mining laws of the State, he knows how coal should be mined and transported, and he has judgment on any possibly unsafe condition in his mine. Certainly, if he is weak on any of these points, there are definite ways in which he can acquire the needed knowledge. If with this knowledge the mine official has the necessary practical experience to bring self-confidence, he stands before the world as a man who knows his job. There is, however, another side to his work, one not found in hooks, a side even that may not be learned at the face even though one spends a lifetime there. The actual duties a mine official knows and performs are the tangible and definite things about his work. There are other things which may be termed intangible, because they are hard to pin down and see, and. which appear to be of equal importance in successfully handling a job and which in time determine the very success of the company itself.

Jan 1, 1930

By Leslie F. Tedsen, John E. Dorn, Alan E. Flanigan

It is necessary occasionally to use aluminum-alloy sheet where moderately elevated temperatures are encountered. Considerable attention has been directed toward determining the influence of "artificial aging" on the room-temperature properties of the precipitation-hardenable alloys, as testified by numerous company reports and by references I to 4. Investigations on the properties at elevated temperatures are few, however, and have not always covered the range of times and temperatures of greatest interest. The present investigation was instituted to overcome this deficiency. The work was done for the Office of Production Research and Development of the War Production Board, under the supervision of the War Metallurgy Committee, as a part of the "restricted" Project NRC-548. It has been released for publication by the Office of Production Research and Development. AS is well known, the high-strength aluminum alloys achieve their remarkable properties as a result of precipitation-hardening. In production they are subjected to a solution heat-treatment followed by quenching, to retain the supersaturated solid solution. The solution treatment is followed by "aging" (precipitation-hard- ening) either at room temperature or at a suitable elevated temperature. A considerable increase in tensile and compressive yield stresses results from precipitation at room temperature ("natural aging"). Through the elevated-temperature process ("artificial aging") it is possible to obtain values of yield stress considerably higher than those attainable by natural aging. The increase in yield stress is accompanied by a smaller gain in ultimate tensile stress and by a decrease in elongation. During the first stages of artificial aging the yield stress increases steadily until it reaches a maximum value. In this condition the material is said to be "fully aged." Further exposure results in "averaging," attended by a steady decrease in yield stress. In the production of the artificially aged materials, temperatures and times are selected to achieve full aging. The following important characteristics are associated with the process: 1. The higher the temperature, the more rapidly is the fully aged condition attained. :7

Jan 1, 1946

By Leslie F. Tedsen, Alan E. Flanigan, John E. Dorn

It is necessary occasionally to use aluminum-alloy sheet where moderately elevated temperatures are encountered. Considerable attention has been directed toward determining the influence of "artificial aging" on the room-temperature properties of the precipitation-hardenable alloys, as testified by numerous company reports and by references I to 4. Investigations on the properties at elevated temperatures are few, however, and have not always covered the range of times and temperatures of greatest interest. The present investigation was instituted to overcome this deficiency. The work was done for the Office of Production Research and Development of the War Production Board, under the supervision of the War Metallurgy Committee, as a part of the "restricted" Project NRC-548. It has been released for publication by the Office of Production Research and Development. AS is well known, the high-strength aluminum alloys achieve their remarkable properties as a result of precipitation-hardening. In production they are subjected to a solution heat-treatment followed by quenching, to retain the supersaturated solid solution. The solution treatment is followed by "aging" (precipitation-hard- ening) either at room temperature or at a suitable elevated temperature. A considerable increase in tensile and compressive yield stresses results from precipitation at room temperature ("natural aging"). Through the elevated-temperature process ("artificial aging") it is possible to obtain values of yield stress considerably higher than those attainable by natural aging. The increase in yield stress is accompanied by a smaller gain in ultimate tensile stress and by a decrease in elongation. During the first stages of artificial aging the yield stress increases steadily until it reaches a maximum value. In this condition the material is said to be "fully aged." Further exposure results in "averaging," attended by a steady decrease in yield stress. In the production of the artificially aged materials, temperatures and times are selected to achieve full aging. The following important characteristics are associated with the process: 1. The higher the temperature, the more rapidly is the fully aged condition attained. :7

Jan 1, 1946

By R. B. Sosman

INTRODUCTION IT is well known that ferric. oxide, Fe.-,03, is paramagnetic, while magnetite, Fe304, is classed among the highly ferromagnetic substances. But magnetic data on oxides intermediate in composition between Fe-03 and Fe304 have been almost completely lacking. Fe203 and Fe304 form a solid-solution series, according to present evidence.' In this series the properties change continuously from Fe203 toward Fe304, as the percentage of FeO increases from zero toward 31.03, which is the percentage in magnetite. It is possible that there is a break in the series near Fe304, but it has not yet been possible to establish the existence-of such a break experimentally. The occurrence of solid solution ill this series is shown by the dissociation pressure, or oxygen pressure in equilibrium with the oxides, which falls continuously over the range from Fe203 to Fe304. The oxygen-pressure curves at 1,100° and 1,200° are shown in Fig. 1. The existence of solid solution is also demonstrated by the continuous change in optical properties from Fe203 over to a composition containing about 18 per cent. FeO, at which point the opacity of the oxide becomes so great that it is im-possible to obtain measurements at higher percentages of ferrous iron. Natural oxides of iron intermediate in composition between Fe2O3 and Fe304 are much more common than is generally supposed. If a mineral oxide is not strongly attracted by a small hand magnet and if it gives a red streak, it is usually labeled "hematite." If it is strongly attracted by the hand magnet it is usually labeled "magnetite" without further tests. As we shall show later, oxides containing from 1 up to 31 per cent. FeO can be thus erroneously lumped together as "magnetite." It is a fact, nevertheless, that the great hulk of natural oxides of iron lie fairly near either Fe203 Or Fe304 in composition. The reason will be

Jan 6, 1917