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By W. E. Benton

Diatomite or diatomaceous earth is a siliceous sedimentary rock principally made up of the skeletal remains of the diatom, a microscopic, single-cell aquatic plant related to algae. The unique structure, chemical stability and physical properties are the major attributes of diatomite not met by other forms of silica. The production of diatomite was down in 1982 vs. 1981, reflecting the worldwide recession. The principal markets for diatomite products continue to be basically filtration and fillers. The outlook is for small but steady growth into the 1990s.

Jan 1, 1983

By AIME AIME

Gentlemen, we have ten questions on our list and a number of us here probably have other questions to ask. Therefore, we arc going to allocate the time to these different questions so that we will try to be finished by 4:30; from then until 5 o'clock, if any of you have any questions on subjects not related, you will be free to ask them. Mr. Morton and I have changed the order of the questions. Instead of what is now first, we have put No. 3 first, progress on basic-roof construction, inasmuch as we feel that it is quite important. At this time, H. S. Robertson, of Harbison-Walker, is going to give you a short talk, with slides, on what has been done to date on this subject.

Jan 1, 1940

By P. P. Gregory

NATURAL petroleum gas occurring in the oil-bearing reservoirs is found to exist either as free gas associated with the oil and/or in solution in the oil. In some virgin fields practically no free gas is encountered under the reservoir conditions of pressure and temperature, although in other fields a considerable section of the ``pay" horizon is occupied by free gas. In other words, a given oil field may or may not have a gas cap before the exploitation takes place. However, when the reservoir pressure is reduced to a point below the critical saturation pressure by withdrawals of fluids from the producing formation, the gas dissolved in the oil inevitably begins to come out of solution and becomes free gas. Under the con-trolled methods of production and drilling, a portion of this gas is pro-duced with the oil to the surface and a portion of it remains within the reservoir to accumulate at higher structural levels toward which it migrates by virtue of its low specific gravity. The rate of growth of a gas cap in a-given structure depends primarily upon the rate of decline in the reservoir pressure. If the rate of pressure decline is rapid, the gas cap likewise will grog rapidly. On the other hand, shrinkage in the gas-cap area was noted in some fields in which reservoir pressures were increasing.

Jan 1, 1938

By P. Somasundaran, Y. H. C. Wang

A detailed study of carrier flotation of kaolin clay using calcite showed the major beneficiation mechanism to be enhanced aggregation between anatase and calcite under intense agitation conditions. To develop an understanding of this selective aggregation, surface charge characteristics of kaolinite, anatase, and calcite were studied under simulated flotation conditions. Zeta potential of all these minerals tended towards a constant negative value in oleate solutions under certain conditions possibly due to adsorption or precipitation of oleate on them. However, whereas the zeta potential of anatase in the oleate solutions was not influenced by the agitation level, that of kaolinite was found to be strongly dependent on the agitation intensity. The effect of oleate on zeta potential of kaolinite was reduced by an increase in agitation intensity. It is suggested that oleate is much more firmly bound to the surface of the anatase and that this preferential attachment is responsible for the enhanced selective aggregation of the anatase with calcite. Agitation level plays a major role in carrier flotation since intense agitation is considered to enhance both the chemisorption of oleate on anatase and preferential detachment of calcium oleate precipitate from the kaolinite surface, all of this producing a large difference in the surface Properties of anatase and kaolinite, and hence in their tendency to aggregate with calcite.

Jan 1, 1983

By Frank H. Buchella

Principal factors influencing equipment selection can be grouped into five basic categories. Tonnage Requirements, Ore and Waste Loading, transporting, and ground preparation equipment are largely determined by tonnage requirements. Generally, the greater the tonnage requirements, the larger the equipment size selected. Large size equipment is appropriate for a production of about six million tons (total) per month, medium size for three mil- lion tons, and small size for one million tons or less.

Jan 1, 1973

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

D. 1 Most Effective Salts A. Ammonium Phosphates Monammomium phosphate and diammonium phosphate (salts of ortho phosphoric acid) are superior to the triammonium salt in fire-resisting properties. Of these two, the monammomium salt is chemically the more stable. It is also held very retentively by a number of woods, thus reducing leaching out of the salt if exposed to water. Saturated aqueous solutions of mon- or di-ammonium phosphates have vapor preservatives corresponding to an atmospheric relative humidity of 9Z to 93 percent, the wood, will, therefore, not attract any moisture at humidities below this figure. Low concentrations (1 lb dry fire-retardant per cubic foot of the dry, treated timber) will stop flame and high concentration (5 lbs. per cubic foot) will prevent smoldering. B. Ammonium Sulphate In low concentrations ammonium sulphate has only a small effect on flame propagation, but its effect is marked when concentrations of the order of 20 percent are employed. It has no appreciable effect on smoldering. It is more corrosive to metals than are the phosphates, but is less corrosive than ammonium chloride or magnesium chloride. It is possible to leach it out of wood by prolonged and continuous action of water The vapor pressure of the saturated solution corresponds to 81 percent atmospheric humidity.

Jan 1, 1976

By Lynn I. Kelley

Industrial-mineral production contributes on the order of CDN$1.5 billion per year to the economy of Saskatchewan, Canada. Potash is the primary industrial mineral produced in the province, followed by aggregate, sodium sulphate, salt, potassium sulphate, peat, clays, silica sand, calcium-chloride brine, and "clinker." Potentially economic deposits of kaolin, diamond, and building stone are under evaluation. All of the major deposits of commodities discussed here are located south of lat 56°30'N. Most of the locations are presented on Figure 1 POTASH Saskatchewan supplies approximately 30% of the world's demand for potash. Eight conventional underground mines and two solution mines produced an all-time high of more than 13 million metric tonnes of potash (KC1) (8 million tonnes K2O equivalent) in 1997, valued at over CDN$1.4 billion. All of the mines exploit the middle Devonian Prairie Evaporite. The four potash-bearing members of the Prairie Evaporite underlie much of southern Saskatchewan and extend southward into North Dakota and Montana and east- ward into Manitoba (Fig. 2). Halite and anhydrite separate the potassic members. The evaporite beds locally are interrupted by solution structures (anomalous ground). Some of the structures may be related to deep-seated tectonic features.

Jan 1, 1999

The development of reliable and accurate solution sampling systems plus on-line atomic absorption spectrophotometers and voltammetric analysers at Pasminco Metals - EZ's (PMEZ) zinc refinery at Hobart, Tasmania, has led to extensive implementation of On-Stream Analysis (OSA) throughout the hydrometallurgical circuit. These systems complement industrial autotitrator and colorimetric analysers and with the comprehensive use of a powerful integrated Distributed Control System (DCS), provide extensive monitoring and control of all the important in solution' parameters for the plant. Samples can be left unaltered, or filtered or settled, to remove solids. They are then precision diluted and pneumatically transported to analyser shelters, where they are analysed for zinc, acid, copper, cadmium, lead, antimony, cobalt, nickel, mercury and ferrous, ferric and/or total iron. The range of analyses depends on the sample itself. The results are used for feed forward and/or feedback control of reagents where possible, or simple trend monitoring and out-of-specification alarming when closed loop control is not practical. The overall system reliability and accuracy is such that many daily composite plant samples are no longer analysed off-line. Operator sampling has also been reduced, and in two places, autotitrators with automatic sample pre-treatment have been installed for preparing and analysing samples collected by operators.

Jan 1, 1993

By G. L. Oldright

THE economic manufacture of sulfuric acid by the ordinary chamber process usually involves production on a large scale and a plant that is costly to construct. The nature of sulfuric acid makes it costly to transport any great distance. For these reasons, the metallurgist has not found it feasible, at times, to beneficiate ores amenable to leaching, and a. need exists for a local process that will produce acid cheaply on a small or large scale. To leach ores containing residual sulfides, an oxidizer, such as ferric sulfate, is needed in solution. Precipitation with scrap iron is one of the cheapest methods of removing some metals from solution, giving a plant of low first cost and supplying a source of cheap ferrous sulfate. The other ingredient needed for the process is SO2 roaster gas; the addition of which, as, described below, will give both ferric sulfate and sulfuric acid. Where roaster gas is a waste or obnoxious, product, the expense. for materials is still further lessened. The use of ferric sulfate and sulfuric acid as a solvent lends itself, well to the utilization of scrap iron as a precipitant, and the stages of the process fit in well together as an economic whole.

Jan 8, 1925

By B. H. Johnston, B. N. Doyle

Introduction In 1983-84 Kidd Creek Mines Ltd. in Timmins, Ontario, started up the second commercial zinc pressure leaching plant based on the Sherritt Gordon Mines Ltd. direct pressure leach process. The first plant using this process was that of Cominco Ltd. at Trail, B.C. (Parker, 1981; Martin and Jankola, 1985). The Kidd Creek plant was constructed to take advantage of the extra capacity that the existing purification, cell house, and casting sections had in comparison to the roasters and acid plant. In addition, pressure leaching offered flexibility in other areas such as treatment of low grade concentrates. The process design package and the detailed design of the autoclave system was carried out by Sherritt. The detailed design for the rest of the plant was done by Cambrian Engineering Ltd. under the direction of Kidd Creek. The construction and commissioning of the plant has been described earlier (Johnston, 1983). This paper describes, briefly, the application of the direct pressure leaching process for zinc concentrates and the integration of the pressure leaching plant into the main zinc plant at Timmins. It discusses some of the startup problems and changes made to the plant. The damage following a fire inside the autoclave is also described. The subsequent repair and recommissioning of the autoclave has enabled Kidd Creek to demonstrate the originally sought advantages of pressure leaching and to take advantage of their extra cell house and casting capacity to produce more zinc. Process principles The development of the direct pressure sulphuric acid leach of zinc sulphide concentrate at temperatures above the melting point of sulphur and at elevated oxygen pressure has been described in detail in a number of papers (Martin and Jankola, 1985; Johnston, 1983; Veltman and Bolton, 1980; Kawulka et al., 1975; Veltman et al., 1977). The most significant aspect of the process is that sulphidic sulphur is converted to elemental sulphur in reactions that can be simply described as follows. ZnS + H2SO4 + 1/2 O2 ZnSO4 + S° + H2O (1) FeS + H2SO4 + 1/2 O2 FeSO4 + S° + H2O (2) The rates of these reactions increase with temperature. However, at temperatures above the melting point of sulphur, 12°C, the presence of a surface active agent is necessary to prevent the occlusion of the sulphide particles by elemental sulphur and the consequent termination of the leach. The zinc that is dissolved according to reaction (1), after purification of the zinc sulphate solution, is recovered by electrowinning. The iron that is put into solution according to reaction (2) is further oxidized to the ferric state and subsequently, as the acidity decreases, precipitates as hematite or as complex basic sulphates. MINERALS AND METALLURGICAL PROCESSING Examples of this are shown below. 2FeSO4 + H2SO4 +1/2O2 - Fe2(SO4)3 + H2O (3) Fe2(SO4)3 + 6H2O - Fe2O3.3H2O + 3H2SO4 (4) 3Fe2(SO4)3 + 14H2O - 2(H3O)Fe3(SO4)2(OH)6 + 5H2SO4 (5) (hydronium jarosite) The conventional zinc process involves concentrate roasting to produce zinc oxide and sulphur dioxide. The zinc oxide is leached in spent electrolyte and the sulphur dioxide is converted to sulphuric acid. The pressure leaching process can, therefore, be used to replace conventional concentrate roasting, sulphuric acid manufacture, and atmospheric leaching with one unit operation. Integration of pressure leaching into the Kidd Creek flowsheet A block flowsheet of the Kidd Creek zinc plant, with the new pressure leach plant integrated, is shown in Fig. 1. The original plant, which was constructed in 1972, is based on standard electrolytic zinc plant technology. Concentrates are dead roasted to remove sulphur. Sulphur dioxide is treated to produce sulphuric acid. Calcine is leached in two stages using cell-house electrolyte. Iron is precipitated as jarosite and solutions are purified to remove copper, cobalt, nickel, and cadmium to provide feed for a partially mechanized cell house. Zinc is plated from solution, and the resulting cathode is melted, cast, and sold (Johnston, 1983). The integration of the pressure leaching plant into the main zinc plant is relatively simple. As shown in Fig. 1, a fraction of the zinc concentrate and spent electrolyte are fed to the pressure leach autoclave, while part of the calcine from the roaster is used as a neutralizing agent in the oxidation step along with. the jarosite leach solution. The main exit stream from the pressure leaching plant is the slurry discharged from the oxidation step, consisting of neutral zinc sulphate solution, unreacted calcine, and precipitated iron oxides. This slurry is transferred to the neutral leach step in the main zinc plant. The leach residue from the pressure leaching step, consisting of basic iron sulphate and elemental sulphur, is washed and impounded along with the jarosite residue produced in the main plant.

Jan 1, 1987

By Francis Clark

WHEN 60:40 brass is heated to 825° C., given a drastic quench to obtain the beta solid solution, and reheated, various changes take place in the structure. Reheating at 200° C. causes a fine, granular, sorbitic structure to appear which has been considered alpha solid solution. These particles coalesce at higher temperatures of reheating, and at 470° C., the alpha forms twins. A further study of these transformations was considered worth investigating. EXPERIMENTAL WORK The object of the experimental work was to study the effect of mechanical work on rolled 60:40 brass, quenched and reheated, and the mechanism of twinning in the alpha reeds of a furnace-cooled specimen. It was desired to determine the effect of mechanical work on the transformations taking place on reheating the quenched material, both at 200 and at 470° C. A study of the nature of the structure resulting from the breakdown of the beta at 200° C. and a study of the mechanism of twinning above 470° C. were considered problems for investigation. The question of the twinning of the alpha reeds was also an important phase of the work. With high-power magnifications, there was hope of following these processes.

Jan 1, 1927

By Franklin B. Woodbury

As part of its goal of helping maintain an adequate supply of minerals to meet national economic and strategic needs, the U.S. Department of the Interior's Bureau of Mines is evaluating alternative technologies to treat oxidized taconites. Since process control is an essential element in the application of these process technologies, research was performed with a prototype monitoring system. A Californium-252 neutron source and a thermal neutron capture- gamma ray spectra analysis method was utilized to measure the amount of iron and the percent solids in the process slurries. The concentrate and tailing streams in a 410-kilogram-per-hour (900- pound-per-hour) pilot plant employing a selective flocculation and cationic flotation process were monitored. The results obtained showed that the thermal neutron capture-gamma ray reaction can be used to provide process control parameters.

Jan 1, 1979

By Stanislaw Nawrat, Waclaw Dziurzynski

An increasing concentration of coal production, especially in the circumstances of intensive methane inflow makes the coal mine managing staff apply new techniques of safe mining. It paves also the way for scientists to develop new directions of investigations and implementation of state-of -the- art technical solutions. Simultaneously, it could be noticed that the funds assigned for expansive 'En situ ' investigation are continuously decreasing. Better and better results are reached when applying computer technique in calculations of the parameters of ventilation process. Recent theoretical and experimental investigations of air and gas (methane) flow in longwall areas with caving, combined with the implementation of methane drainage system allowed to create, a mathematical model and consequently to elaborate a computer supported numerical simulation of discussed phenomena. The mathematical model has been modified and the simulation program was prepared in such a way that the software is convenient for a user looking for an optimal solution. The paper presented the methodology of optimal choice of following parameters: - ventilation system - rate of flow through the wall. The procedure takes into consideration keeping a safe level of concentration methane in air flowing through the longwall as well as the criterion of maximum methane concentration within the methane drainage pipe line. Results of variant computer simulation regarding the longwall with caving are shown in graphs and tables.

Jan 1, 1995

By W. A. Wright

The use and abuse of social media restate common employee relations issues. Business solutions to these issues require advanced preparation. Employers should establish and enforce social media policies to guide their reactions to employees? social media posts that reflect on the employer and its business.

Jan 1, 2011

By John C. Robbins

A new technique for the determination of trace levels of uranium in solution has been developed. A compact laser emits short, but intense, ultraviolet pulses to excite the green fluorescence of a uranyl-complex formed by the addition of a proprietary reagent to the sample. Organic species present in most natural waters also fluoresce quite intensely, but their emission does not last appreciably longer than the excitation pulse, in contrast to the relatively long persistence of the uranyl fluorescence . Electronic 'gating' is employed to separate the long-lived contribution, rejecting substantially the organic emission. Results using the laser fluorescence method on many sets of natural waters of various origins have been compared against corresponding values generated by independent laboratories. Correlation has been generally good over a range from less than 0.1 to more than 100 ppb U. Solid samples have also been analyzed after extraction of the uranium into solution. Accuracies adequate for most exploration purposes have been achieved, but further work is required to determine effects of interferences in samples with complex matrices. The transport and deposition of uranium in natural waters is controlled by the organic and inorganic chemistry of the waters involved. It is suggested that interpretation of very low uranium levels will be aided by additional measurements of conductivity and organic content, with subsequent statistical treatment.

Jan 1, 1978

By J. N. Cram

"The comments given are to help allay generally accepted ideas that the handling of arsenic as arsenic-trioxide (As2o3J in and from off gas pyrometallurgical operation fumes is difficult, hazardous and expensive. It need not be any of these things if the basic and rather unique chemic3l and physical properties are understood and taken care and advantage of through present day technologies. These particular characteristics are:-(1) As2o3 sublimes and re-condenses, at a relatively low temperature;(2) As2o3 is, for practical in-plant purposes, insoluble in water at ambient temperatures and quite soluble in water just below the boiling point;(3) residual suspended and dissolved As 2o3 can be removed from water by complete dissolution with very little sulfuric acid, followed by the addition of small amounts of ferrous sulfate and calcium chlorate, with oxidation to the ferric and arsenite state and precipitation of an insoluble ferric calcium arsenate, thereby lowering the As2o3 content of solutions to acceptable levels. Even lower levels of non-toxic forms of arsenic solids and residual As2o3 in the water solutions can be attained by also using phosphate, and lime, along with the above.A background re past arsenic processing methods, present day operations, plus predictions re future trends, and hazards, are outlined."

Jan 1, 1979

By J. M. Marek

The determination of the proper cutoff grade for an open pit metal mine is based on economic criteria and the operating philosophy of the mining company. Previous papers have dealt with the balance of a fixed mine production capacity versus economic return. Mine production capacity is often controlled by the amount of mining equipment and the working area in the pit. A complete cutoff grade strategy is a balance of economic return of mining higher grade material versus the capital costs of additional production capacity and the operating cost of moving the waste and low grade material to assure proper ore release. An approach to the problem is presented which is based in part on work by previous authors and provides guidelines to proper cutoff grade strategy encompassing the time value of money and variable commodity prices.

Jan 1, 1985

By Young C. Kim, Francis Martino, Ish Chopra

For the past two and one-half years, various emission control strategies were jointly developed by the University of Arizona and the Homer City Owners to com- ply with the clean air requirements at its Homer City Power Plant. Some of the available options for the SO2 emission control by the Homer City Owners were:l)cleaning of run-of-mine coal,2) scheduling of mining operations at its captive mines, 3) blending the captive mine coal with externally purchased low sulfur coa1,and 4) placing a partial FGD system. This paper describes two specific emission control strategies developed and implemented. These are: 1) production scheduling at the mining face to minimize sulfur variability, and 2) external purchasing of low sulfur coal for further blending. The main objective of this paper is to share our experiences on implementing the developed strategies. This paper emphasizesthe need for proper mine planning on a short-term basis, if the power plant is to meet the desired objective.

Jan 1, 1983

By J. M. Davidson, F. Fraas, J. E. Conley

"A number of Reports of Investigations pertaining to the extraction of potash from cal¬cined polyhalite have been made by various members of the Nonmetallic Minerals Experiment Station of the United States Bureau of Mines. These reports describe results obtained in the study of samples of polyhalite (2CaS04.K2S04.MgS04.2H20) from deposits of possible com¬mercial importance in Texas and New Mexico.3Storch and Clarke6 in their initial paper presenting data on the properties of Texas polyhalite demonstrated the desirability of calcination and subsequent hot extraction with water as a satisfactory pronedure for treatment of this potash-bearing salt. Their preliminary data have been supplemented by an additional report7 dealing more particularly with the leaching of raw and calcined polyhalite with water and with saturated sodium chloride solu¬tions. Further data8 have been reported as a result of experiments made in a small labora¬tory rotary-tube furnace under various calcination and extraction conditions. Hot water was used as the leaching solution in all of these tests.In addition to the data on calcination and extraction, two processes as proposed by Storch and Clarke have been published by Wroth,9 and more recently a number of very promising processes have been proposed by Storoh and Fragen.10"

Apr 1, 1932

By Kazutoshi Haga, Batnasan Altansukh, Atsushi Shibayama, Ryuji Oinuma

"Recently, the arsenic grade in copper ores has been increasing year by year. Arsenic bearing minerals (enargite (Cu3AsS4) and tennantite (Cu12As4S13)) coexist with typical copper minerals such as chalcopyrite (CuFeS2). The removal of arsenic from copper ores that contain relatively high arsenic content is essential due to its adverse impact on the environment and the resulting economic consequences. In this study, arsenic removal and dissolution behaviour of Cu and As from enargite (Cu3AsS4) were investigated using ferric sulphate (Fe2(SO4)3) solutions containing sodium chloride under high pressure oxidation conditions. The effects of numerous parameters including the concentration of Fe2(SO4)3 and NaCl, temperature, total pressure, leaching time and particle size were studied while other variables such as pulp density and stirring speed were fixed at 100 g/L and 750 rpm. The results showed that more than 60% of the copper was dissolved in a 0.1 M ferric sulphate solution under the high pressure oxidative conditions, whereas the leaching rate of arsenic was less than 20%. SEM observation revealed that elemental sulphur was deposited on the surface of enargite forming a passivation layer and the residue was agglomerated. Those phenomena may cause a decrease in the copper leaching rate. It was found that more than 80% of copper was dissolved in the ferric sulphate solution in the presence of 0.34 M sodium chloride under the conditions optimized, whereas the dissolution of arsenic in the mixture did not exceed 2%. XRD analysis of the solid residues from the leaching experiments used ferric sulphate and mixtures of ferric sulphate and sodium chloride showed arsenic to be present as scorodite (FeAsO4).INTRODUCTION In recent years, there has been an increase of the arsenic (As) content of copper ores due to the gradual depletion of high grade copper ores. In some copper deposits, arsenic occurs in the form of minerals such as enargite and tennantite. The removal of arsenic in ores containing copper is critical to the production of pure copper and the management of the environmental challenges caused by the smelting process. Due to the environmental risk caused by arsenic emission and the deteriorated quality of the copper product, smelting of enargite concentrates is not an effective method for the extraction of copper (Padilla et al., 2010; Safarzadeh et al., 2014; Long et al., 2012). Therefore, a number of studies have been carried out to develop arsenic removal technologies from copper ores using various methods such as hydrometallurgy (Curreli et al., 2009; Tongamp et al. 2010), pyrometallurgy (Dalewski., 1999; Padilla. et al, 2012) and bio-oxidation (Ehrlich, 1964; Sasaki et al., 2010). Several hydrometallurgical leaching processes like sulphuric acid, alkaline sodium sulphide and sodium sulphate and ferric sulphate leaching have been developed to treat enargite ores and concentrates. The alkaline sodium sulphide leaching process has been developed for the removal of arsenic from enargite (Anderson, & Twidwell, 2008; Parada et al., 2014). The mechanism of the dissolution of arsenic from enargite in sodium sulphite solution is"

Jan 1, 2016