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By G. Hoffmeyer, I. Ream

"Several copper projects exclusively utilizing in-situ recovery methods are currently under development in Arizona. Favorable conditions for In-Situ Copper Recovery (ISCR) include a saturated orebody, fracture hosted mineralization, hydraulic conductivity sufficient to effectively inject and recover solutions using wells, and a relatively flat background hydraulic gradient. Safe operation of an ISCR project requires that the operator have the ability to induce and maintain localized hydraulic gradients, thereby controlling the movement of injected and recovered solutions. Benefits of ISCR include reduced initial capital, and a greatly reduced environmental footprint. THE ISCR METHOD EXPLAINED The method chosen to extract a mineral from a deposit is driven by characteristics such as its size, grade and depth of burial. Large lower grade deposits that require significant excavation to access using surface methods are potential candidates for in-situ recovery. ISCR may also be ideal for smaller deposits due to the lower initial capital. However, regardless of the size of the deposit, certain hydrogeologic conditions must be present for ISCR to be successful. In-situ recovery methods do not require excavations of rock from the surface or underground, resulting in a dramatic reduction in surface disturbance when compared to conventional mining. With the ISCR method, what is visible above ground is the processing plant, well heads, piping, process solution impoundments and evaporation ponds. There are no waste rock piles, tailings impoundments, leach pads, or impacts associated with blasting and hauling. Other benefits include reduced initial capital, reduced dust and noise, and lower water use. Early testing of the in-situ copper recovery method by Occidental on the Van Dyke deposit east of Phoenix and by Kennecott at Safford Arizona in the 1970s produced encouraging results, but the permitting regime for a large-scale operation was not yet in place. Additional testing and commercial application of in-situ copper recovery techniques have expanded since the 1980s, most commonly in conjunction with open pit or underground mining operations. For example, several operations in Arizona (San Manuel, Miami East and Tohono) have used in-situ techniques to extract additional copper following conventional mining from parts of the deposits adjacent to open pits or underground workings. Where the rock has been broken up by conventional methods, the method is called “in-place” leaching. The US government has also been involved in assessing in-situ techniques. For example, joint research was conducted by the US Bureau of Mines and industry on the Santa Cruz deposit in Arizona; and both federal and state agencies have been involved to establish the comprehensive permitting regime that exists today. Currently there are several projects in Arizona being evaluated as stand-alone ISCR operations."

Jan 1, 2016

By F. F. Hintze

Petroleum production in the Rocky Mountain district during 1929 registered a small decline from that of the previous year, conforming with a gradual decrease in the amount of oil produced during the last few years. A number of causes may be mentioned to account for this result, chiefly overproduction in other regions and the apparent desire of operators in this territory to conform to the policy of proration and retrenchment adopted by special agreement among operators in many of the fields. Unit operation has been adopted to control oil production from the Sundance sands in the Salt Creek field, Wyoming, in line with the general effort to stabilize this phase of the industry and prevent excessive drilling of new wells. Another factor which greatly retarded development in the Rocky Mountain region was the executive order of President Hoover issued in March refusing the award of new prospecting permits to future applicants and threatening cancellation of all existing permits upon which actual drilling had not been done as specified by law. Only four states in the Rocky Mountain region are important oil producers. In 1929 Wyoming led with an average daily output of 52,600 bbl., followed by Montana, with 10,730 bbl.; Colorado, with 6500 bbl., and New Mexico with 2700 bbl. daily average. These states bear the following percentage relation to total production in the Rocky Mountain district: Wyoming, 72; Montana, 15; Colorado, 9; New Mexico, 4., (Table 1.) The total average daily production was approximately 73,000 bbl. and the total production of all four states during the year was 26,534,606 bbl. This is 2.7 per cent. of the total oil production of the United States during this period. Colorado Although Colorado is not a large producer of oil and natural gas, its oil operations are widely distributed over the state. The Florence field is one of the oldest oil fields in the country, and there are good reasons for believing that the state will retain its place for many years to

Jan 1, 1930

By S. P. Kinney

Sulfur has been one of the most troublesome elements encountered since the earliest days of iron smelting, and this problem will become of increasing importance as the higher sulfur coke is used, because of the rapidly diminishing supply of low-sulfur coals suitable for the manufacture of metallurgical coke. The deleterious effect of sulfur in iron and steel is well known; therefore, except in special cases, it is desirable to make the iron produced by the blast furnace as low in sulfur as possible. Sulfur enters the furnace in all of the raw materials, but principally in the coke. It comes out of the blast furnace distributed between the iron and the slag; very little passes out of the furnace with the gases. The mechanism of the reactions that cause the sulfur of the coke to pass into the slag and iron has not been studied to any great extent, although the character of the end products, and the conditions controlling the distribution of the sulfur between the iron and slag, are fairly well known. In the iron, the sulfur occurs as ferrous sulfide; or manganese sulfide in case of iron high in manganese. In the slag, the sulfur is present mostly as calcium sulfide. The presence of free sulfur1 and sulfates in blast-furnace slags is to be accounted for on the basis of oxidation of the calcium sulfide after the slag is tapped. The generally accepted reaction for the relation between the ferrous sulfide in the iron and in the coke, and the calcium sulfide in the slag, is that given by Howe? FeS + CaO + CDFe + CaS + CO

Jan 1, 1923

By S. P. Kinney

Sulfur has been one of the most troublesome elements encountered since the earliest days of iron smelting, and this problem will become of increasing importance as the higher sulfur coke is used, because of the rapidly diminishing supply of low-sulfur coals suitable for the manufacture of metallurgical coke. The deleterious effect of sulfur in iron and steel is well known; therefore, except in special cases, it is desirable to make the iron produced by the blast furnace as low in sulfur as possible. Sulfur enters the furnace in all of the raw materials, but principally in the coke. It comes out of the blast furnace distributed between the iron and the slag; very little passes out of the furnace with the gases. The mechanism of the reactions that cause the sulfur of the coke to pass into the slag and iron has not been studied to any great extent, although the character of the end products, and the conditions controlling the distribution of the sulfur between the iron and slag, are fairly well known. In the iron, the sulfur occurs as ferrous sulfide; or manganese sulfide in case of iron high in manganese. In the slag, the sulfur is present mostly as calcium sulfide. The presence of free sulfur1 and sulfates in blast-furnace slags is to be accounted for on the basis of oxidation of the calcium sulfide after the slag is tapped. The generally accepted reaction for the relation between the ferrous sulfide in the iron and in the coke, and the calcium sulfide in the slag, is that given by Howe? FeS + CaO + CDFe + CaS + CO

Jan 1, 1923

By V. M. Bystritsky, M. G. Sapozhnikov, G. M. Nikitin, A. B. Sadovsky, Yu. N. Rogov

"At present kimberlite ore is processed in crushers or grinding rolls with subsequent grinding in wet mills down to a size of 0.2 mm. The basic disadvantage of the standard diamond processing technology is that crushing kimberlite ore can damage the most valuable large diamonds of few carats. Tagged neutron method offers a possible solution to this problem. It allows detecting diamond inside kimberlite ore without its disruption. The results of the tests of the neutron separator prototype carried out at the Lomonosov processing factory of PJSC Severalmaz are discussed. The possibility to detect the diamond in the rock whose size is 10 times larger than the size of the diamond is demonstrated.INTRODUCTION At present standard diamond processing technology implies disintegration of kimberlite ore in crushers or grinding rolls down to a size of 0.2 mm. It inevitably leads to high probability that large and most valuable diamonds could be damaged. The fraction of diamonds which lost integrity in the process of ore enrichment could be as large as 35-65% [1]. Tagged neutron method (TNM) [2] offers a possible solution to this problem. It allows detecting diamond inside kimberlite ore without its disruption. The main idea of the TNM is irradiation of an object by fast 14.1 MeV neutrons from binary nuclear reaction d + 3H ?4He + n (1) and detecting (tagging) the 4He (a-particle) that accompanies neutron. That gives possibility to determine direction of the neutron momentum. Those tagged neutrons irradiate kimberlite ore under investigation and produce gamma rays via inelastic scattering reactions with nuclei"

Jan 1, 2018

By Peter A. Dawson, Rod L. Leonard, Karen S. Christensen

An investigation has been completed of the technical and economic feasibility of construction of a processing facility for gold extraction from arsenical tailings, grading nearly 12 g/t, stockpiled near Snow Lake, Manitoba, Canada. The tailings dump is comprised of arsenopyrite (45%), pyrrhotite (12%), and gangue constituents. The majority of the gold occurs as fully encapsulated particles or as a solid solution in the arsenopyrite grains. The chemical composition of the Snow Lake tailings (referred to as "ore" throughout the remainder of the text) is shown in Table 1.

Jan 1, 1990

By Ahmad Saberian

Five salt samples 20 to 40 cm tall, sealed on all sides except one, were exposed to a series of dissolution tests in various brine solutions and at different temperatures. Solvents were in the 50 to 96% saturation range and the temperatures varied between 40°F and 150°F. The collected dissolution data sets for vertical salt surfaces were analyzed and three were selected to be used for developing a general relation. After various curve fitting efforts, an empirical relation for salt dissolution rate as a function of brine temperature and salinity was developed.

Jan 1, 1985

By Roger Thunvik, Carol Braester

Excavation of cavities below the ground water level induces water influx from the surrounding aquifer. An estimate of the rates of flow prior to excavation operations may be of valuable information for the mining engineer. The present paper deals with water influx into cavities of the tunnel type, e.g., mine galleries, tunnels, etc. The solution of the flow problem was obtained by a numerical finite difference method. The results are presented in dimensionless form as a function of the parameters characterizing the location of the cavity in the aquifer.

Jan 1, 1981

By Charles A. Edwards, Kenneth D. Merrill

The Construction of the Northeast Extension of the Baltimore Metro involved soft ground, compressed air tunneling. During the tunneling, gasoline and dry cleaning fluid contamination were encountered. Innovative approaches and solutions were developed to address these problems. Special emphasis was on the problem of compressed air pushing gasoline vapors into surrounding communities, resulting in an extremely dangerous situation and a public relations nightmare. Guidelines and standards were established for working in this contaminated environment. Also, through a proactive approach by all parties, all claims and disputes have been resolved.

Jan 1, 1995

By B. Towson, R. F. Dalton, G. W. Seward

This paper reviews the successful application of oxime reagents for the solvent extraction of copper and considers the role that well focussed research initiatives can play in bringing further radical change to the metallurgical industry. Particular reference is made to the Cuprex Metal Extraction Process (CMEP), for the treatment of low grade or difficult to treat sulfide concentrates, using the reagent Acorga CLX- 50 to recover the copper and the reagent Acorga ZNX-50 for the recovery of zinc from chloride solutions. Other new extractants, currently in development, are also referenced.

Jan 1, 1994

By J. L. Hendrix, R. B. Dix

A study was made of the United States Bureau of Mines chlorine-oxygen leaching process for complex sulfide concentrates. The investigation sought to determine the kinetic order and mechanisms involved in the reactions between galena and sphalerite with chlorine. The influence of copper on the extraction rates was also studied. It has been shown that the rates of reaction of chlorine in aqueous solutions with sphalerite and galena are both zero order at 373 K with rate limiting step being the chemical reaction. Addition of cupric chloride increased the extractions of both lead and zinc.

Jan 1, 1981

By Joe W. Siefke

The world-class Kramer sodium borate deposit is being developed by modern open pit operations near Boron, California. The deposit is a bedded, lenticular sedimentary sequence of borax and kernite crystals together with claystone. The borates dip south into a structural basin-bounding fault and were formed in the bottom muds of a permanent shallow lake. The lake was fed boron and sodium-rich solutions from a thermal spring source of volcanic origin. In addition to deposit geology, present day geotechnical concerns such as groundwater and slope stability will be discussed.

Jan 1, 1995

By John T. Bartlett

With more stringent environmental and economic constraints being placed on mining operations, it has become necessary to optimize each process to minimize energy and raw material consumption and reduce waste discharge. In most cases, detailed process analysis is required to detect inefficiencies and provide alternative solutions for process improvement. HETSIM, a microcomputer process modeling and simulation system, is routinely used to analyze communition, hydrometallurgical, pyrometallurgical, and coal preparation processes. The process modeling techniques used in METSIM, including process control simulation, will be presented and illustrated using actual plant processes.

Jan 1, 1987

By Carl S. Westerberg

Coal preparation practice and trends follow, among other factors, production trends in any given area. Considering an area the size of a state, some broad predictions may be made after a review of the annual production records. As this paper is concerned with coal cleaning in Utah, data on its production record are pertinent. Table 1 shows the percentage relation of coal production in Utah to the national total as a single figure up to 1935 which includes all recorded production. From 1935 through 1947 these data are presented by years. It is evident from these data that the production of Utah coal is ascending. The reason for this trend is industrial growth in the West resulting in a population shift which accounts for more people than the normal increase would supply together with Utah's relatively fortunate geographical location and its abundance of good-quality coal. Utah is also hopeful of supplying more coal in the future for West Coast power generation.I Utah is not unique among coal-producing states in anticipating greater production in the future. Coal Age states, " . . . it is now evident that a billion-ton yearly production of anthracite and bituminous by 1960 is not impossible." At present it is about 610,000,000 tons, the all-time high in 1947 was approximately 687,803,000 tons. In view of the trend outlined above, obviously more new mines will be required to produce the necessary tonnage. These in turn will require more mechanical cleaning capacity. Whether the required new plants will be built by present operators of mines and mechanical cleaning plants or by others now in the business of producing coal or expecting to enter it is of no consequence in this discussion. The fact is— they will be built.

Jan 1, 1950

The mining and resources industry in general has relied on macro separation technologies (greater than 1 micron) through processes which include: ò sedimentation ò flocculation and coagulation screening and filtration ò absorption ò magnetic separation ò chemical leaching and precipitation Essentially, these processes and technologies provide the industry with an effective arsenal to handle most separation requirements to date. Dewatering of solutions is one of the most significant requirements of the resources industry, as practically all mining endeavours use water in their process for leaching, extraction, cooling, dilution or for potable drinking water.

Jan 1, 1989

By Walter F. Pond, Kendall E. Born

Production of crude oil in Tennessee during 1935 approximated 20,000 bbl., an increase of about 5000 bbl. over 1934. The total production for the state is an estimate, since the only definite figures available are those for Scott and Morgan counties, where 12,377 bbl. were marketed during 1935, an increase of 4305 bbl. over the preceding year. The oil fields of Scott and Morgan counties are near the eastern margin of the Cumberland Plateau where Pennsylvanian sediments rest uncon-formably upon the Mississippian. Near Glenmary, in Scott County, the production is from the middle Mississippian, probably near the top of the St. Louis limestone. Accumulation is due to a low, east-west anticline which has been cut by a fault. This field is now 20 years old and only a few wells are pumped at present. Oil was Struck along Boone Camp Creek in Morgan County in 1924 and there has been small production since that time. The oil comes from the middle of the Fort Payne formation of lower Mississippian age at a depth of 1400 ft. Geologic work in the area has shown that a terrace and porosity conditions in the Fort Payne formation account for the accumulation. The production figures on a number of small producing wells in Clay and Overton counties are not available. As pointed out by Glenn1, the installation of small local skimming or topping plants in the fields has curtailed the shipment of crude oil out of the state and as a result it has been impossible to secure accurate production figures in these counties. The operators, in most cases, are reluctant to give information, and there is no state law requiring them to do so. Based upon information available to the writers, it is believed that between 7000 and 8000 bbl. is a fair estimate of the production in Clay and Overton counties during 1935. More than 500 wells have been drilled in Clay County, the majority of which were drilled east of Cumberland River. Some eight small oil fields have been developed in the county within the past 12 years, a

Jan 1, 1936

By Kendall E. Born, Walter F. Pond

Production of crude oil in Tennessee during 1935 approximated 20,000 bbl., an increase of about 5000 bbl. over 1934. The total production for the state is an estimate, since the only definite figures available are those for Scott and Morgan counties, where 12,377 bbl. were marketed during 1935, an increase of 4305 bbl. over the preceding year. The oil fields of Scott and Morgan counties are near the eastern margin of the Cumberland Plateau where Pennsylvanian sediments rest uncon-formably upon the Mississippian. Near Glenmary, in Scott County, the production is from the middle Mississippian, probably near the top of the St. Louis limestone. Accumulation is due to a low, east-west anticline which has been cut by a fault. This field is now 20 years old and only a few wells are pumped at present. Oil was Struck along Boone Camp Creek in Morgan County in 1924 and there has been small production since that time. The oil comes from the middle of the Fort Payne formation of lower Mississippian age at a depth of 1400 ft. Geologic work in the area has shown that a terrace and porosity conditions in the Fort Payne formation account for the accumulation. The production figures on a number of small producing wells in Clay and Overton counties are not available. As pointed out by Glenn1, the installation of small local skimming or topping plants in the fields has curtailed the shipment of crude oil out of the state and as a result it has been impossible to secure accurate production figures in these counties. The operators, in most cases, are reluctant to give information, and there is no state law requiring them to do so. Based upon information available to the writers, it is believed that between 7000 and 8000 bbl. is a fair estimate of the production in Clay and Overton counties during 1935. More than 500 wells have been drilled in Clay County, the majority of which were drilled east of Cumberland River. Some eight small oil fields have been developed in the county within the past 12 years, a

Jan 1, 1936

By E. H. Jr. Dix

OF all the alloying elements used in commercial aluminum alloys, copper stands out as by far the most important, and it is perhaps for this reason that the constitution of the aluminum-copper system has received the attention of a number of experimenters covering a period of approximately 20 years. It would be expected that during this time the equilibrium relations had been thoroughly and exactly worked out. In a general way this is true, but there is a surprising lack of agreement in the details of the high aluminum end of the diagram, particularly in regard to the solid solubility of copper in aluminum, which has been given variously as 2 per cent. to 5 per cent. at the eutectic temperature. The importance of this is much greater than might at first appear to one unfamiliar with modern commercial aluminum alloys. This is true because, with one exception, the susceptibility of the strong alloys to heat treatment depends, in part at least, upon the solid solubility relations of copper in aluminum. In 1919, Merica, Waltenberg, and Freeman1 published the first detailed information on these solubility relations. They found that the solubility of copper decreases with falling temperature from about 4 per cent. at 5.25° C. to about 1 per cent. at 300° C. and is apparently still diminishing at lower temperatures. In 1921 there was published a brief account of the results obtained in the National Physical Laboratory, Teddington, England.2 This laboratory, however, reported that 5 per cent. of copper is soluble in aluminum at 540° C., and that this amount decreases to about 3 per cent. at 20° C.

Jan 2, 1926

By Jim Wickens, Vince Lofftus, Mark Kravetz

"This paper discusses how Bald Mountain Gold Mine (Ely, NV) dramatically reduced mercury production by treating process solutions with a liquid reagent based on organic sulfide chemistry. Cherokee Chemical Co. Inc. (Vernon, CA) markets this reagent as UNR 81 1A.A summary of the bench tests comparing various reagents is given. The ensuing plant trial is discussed and successful mercury removal results are presented. Data is presented to show that early removal of mercury in the process reduces the amount of mercury collected at retort. Data is also presented to show that use of this reagent does not reduce gold recovery. Plant trial treatment costs are discussed. Finally, the potential of this technology to substantially reduce closure costs as compared to traditional mercury removal options is discussed.INTRODUCTIONBald Mountain Mine produces gold. Mercury is a costly by-product of gold production because no revenue is generated from mercury. Traditionally, mercury leaches out with gold and follows the gold throughout the processing circuit until it is eventually condensed and collected at Retort. Minimizing or eliminating mercury production minimizes worker health and safety risks, minimizes environmental liability, and reduces costs. In the long term, minimizing mercury production will make mine closure easier and less costly.Bald Mountain Mine dramatically reduced mercury production by treating process solutions with liquid reagents called UNR 811 and UNR 811A. Several reagents were bench tested before proceeding with a plant trial. The reagent complexes the mercury to form an insoluble organic sulfide precipitate. In independent tests, the precipitate passed acid mobilization tests and is considered stable."

Jan 1, 2001

By Warren B. Weeks

The development of the relatively deeper fields discovered during 1937 helped build the 1938 production to 18,456,760 bbl., an increase of 6,295,910 bbl., or 51.6 per cent over 1937, and the largest production for south Arkansas since 1930. Schuler and Rodessa accounted for the increased production as well as for over half of the wells drilled in the state. There were 243 holes drilled during 1938, of which 200 were completed as oil or gas wells. Of the 29 wildcat wells completed, 25 were dry, 3 found oil in the Smack-over limestone, while 1 made a small oil well in the Nacatoch sand. This was less than half the number of wildcats drilled the previous year, but nearly twice as many field wells were drilled. The old depth record of 7973 ft. was exceeded twice during the year, with the present record of 8332 feet. Trend of Prospecting The porous "Reynolds" oolite of the Smackover limestone1 has been the object of most of the wildcat prospecting during the past two years. Seismograph work, which brought 22 crews into this area during 1938, was largely pointed toward a study of the structure of this limestone formation. Thirteen dry wildcats have been drilled to this formation and five pools have been opened in it since it was first found to be productive at Snow Hill in the spring of 1936. With the failure of "updip" prospects to produce, activity moved southward and basinward. Success in five instances in Columbia and south Union Counties has spurred activity in this area. Much of the acreage is under lease and half a dozen deep limestone tests are assured for the current year. Fig. 1 shows the location of the principal oil fields in south Arkansas, as well as one or two minor producing areas. The fields are numbered in the order of their discovery. It is shown that most of the recent discoveries are from the deeper formations. Dry wildcats that penetrated

Jan 1, 1939