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By T. Schoening

The exploration of the seafloor regarding the abundances of poly-metallic nodules has received growing attention recently. Image-based exploration using cameraequipped deep-sea observation systems has been introduced successfully to increase spatial resolution in the exploration process but the evaluation and interpretation of the huge amount of image data creates a serious bottleneck. In this paper we present a new software solution to the problem of automatic detection and segmentation of poly-metallic nodules in underwater images, which is not only accurate but so fast that real time image analysis is definitely in reach. Thus, an application on an AUV (Autonomous Underwater Vehicle) seems possible in the near future.

Sep 14, 2011

Cyanide is reactive to copper minerals and is not suitable to extract the gold from the copper bearing ores. Ammoniacal thiosulfate is considered an excellent alternative lixiviant for leaching copper bearing gold ores. Unfortunately the results of high reagent consumption and poor gold ex-traction were found by thiosulfate leaching of synthetic gold ores containing chalcopyrite, chalcocite or bornite and a mild refractory copper-bearing sulfidic gold ore. In this investigation, several processes have been applied to reduce the impacts of these minerals on gold leaching. The process included: the pre-oxidation of copper sulphide minerals in water or ammonia solution, the reduction of dissolved oxygen in the lixiviant (0.3 ppm DO or 0.7% oxygen), adding phosphate anion in the leach or pre-leach stage, and the addition of a strong copper ligand (e.g., EDA and DETA). The results indicated that the gold extraction could be improved to 93% with the thiosulfate consumption being reduced to less than 8 kg/t. The dissolution of copper minerals was found to be the major reason for increased consumption of thiosulfate and the highly reductive leached surfaces are responsible for the reduced gold extractions.

Jan 1, 2014

By B. J. Scheiner

Extraction of silver from silver mill tailings by an electrolytic oxidation procedure was investigated by the Bureau of Mines. Various parameters affecting silver extraction, such as electrolysis time, particle size, and dissolution of the silver as the tetrachloro or cyanide complex, were studied at 30° C with an electrolyte concentration of 20 weight-percent sodium chloride. Resulting silver extractions ranged from 77 to 90 percent, depending on the tailings being treated. Concomitant extraction of mercury ranged between 90 and 95 percent. Power consumption was 52 to 90 kilowatt-hours per ton for the tailings investigated. Comparative experiments using direct cyanidation resulted in extraction of 46 to 82 percent of the silver and 20 percent of the mercury. Cyanide consumption ranged from 3.3 to 9.4 pounds per ton of tailings, depending on the tailings being treated. Silver and mercury were recovered from leach solutions by precipitation on iron powder, followed by conventional distillation and fire refining steps.

Jan 1, 1972

By Lana Alagha, Fardis Nakhaei, Jose L. Corchado-Albelo, Noelia Munoz-Garcia, Michèle Heitz

Sulfide tailings from past and present mining activities are important hosts of critical elements and precious metals. This review paper presented a literature survey on the recovery practices of some critical minerals containing Te from sulfide tailings with a special focus on the physical beneficiation and hydrometallurgical separation methods. Finally, a conceptual framework and possible processing flowsheets were proposed. The findings of this review will be useful for the researchers in the field of geochemistry, mineral processing, and metallurgy to evaluate the separation processes for reprocessing of mine tailings for the recovery of critical minerals.

Feb 1, 2024

By D Maschemeyer

The cobalt production of the Chemical Metallurgical Division of Sherritt Gordon Mines Limited was supplemented, from May, 1962, to June, 1964, by processing 3,500 tons of a calcined cobalt-nickel concentrate. This paper describes the reduction roast -aqueous sulphuric acid leach process and the operating practices employed in recovering cobalt, nickel and copper from this oxidized by-product of a lead-copper operation. Incorporated in this paper is a description of how this process was integrated with the existing ammonia leach -hydrogen reduction process for the recovery of nickel and with the soluble cobaltic ammine process for the recovery of cobalt. Introduction T HE Chemical Metallurgical Division of Sherritt Gordon Mines Limited at Fort Saskatchewan, Alberta, has recently completed ten years of operation utilizing the ammonia leach process for the recovery of nickel, cobalt and copper from sulphide concentrates, matte and other materials amenable to this process. A continuing development program, along with the expansion of certain facilities, has enabled the refinery to attain a production rate of 31, 000,-000 pounds of nickel per year by hydrogen reduction. This represents an increase of approximately 85 per cent over the original design capacity of the plant.

Jan 1, 1965

Froth flotation is an industrial process commonly used for the separation of mineral particles. Bubbles sparged in a pulp collect and carry hydrophobic particles to the top layer of a flotation cell, the froth zone. There is a strong correlation between the stability of the froth phase and the flux of solids. However, flotation units placed in series operate, as a whole, in a non-steady state regime with the concentration of particle decreasing from one cell to the next resulting in a decrease in froth stability, which can compromise the recovery of valuables. Organic chemical reagents, frothers, are generally added to prevent fine bubbles from coalescing and to increase the stability of the froth phase. Frothers represent the second largest group of mining chemicals. It is crucial to understand the resulting properties of the frother on the froth phase in order to select the most suitable reagent for a particular operation. The bubble coalescence dynamic of three different surfactants, 1-pentanol, poly (propylene glycol), and tri (propylene glycol) methyl ether, were investigated in this study. In the first stage, the stabilisation mechanism of bubbles in a solution of surfactant was investigated using a specifically designed experimental setup. The coalescence behaviour of bubble pairs was recorded using high-speed video imaging in which information such as the coalescence time and the deformation of the resultant bubble upon coalescence could be extracted. The results were then compared between the different surfactants for several concentrations. It is shown in a study that the coalescence time increases with surfactant concentration until the Gibbs-Marangoni effect is suppressed by bulk diffusion. Conversely, the oscillation of the resultant bubble was found to be affected only at concentrations at which the film is saturated. The implications of the effects of surfactant type and concentration on the coalescence time and bubble oscillation in froth flotation are discussed. Keywords: froth flotation, frother, bubble coalescence

Sep 1, 2012

By S. B. . Tyrrell

This paper describes research carried out to develop and optimise a process to extract lithium from the processed waste of spent lithium ution of lithium salts can be used to produce a pure lithium hydroxide solution, From this, lithium carbonate is produced, the major precursor for other lithium chemicals and for new lithium batteries. Hence, the recycle loop can be closed. Significant variation in the composition of the battery waste has been observed. Small amounts of metals other than lithium and certain anions can present technical difficulties such as electrode dissolution and membrane fouling. Pre-treatment of the waste, together with an optimum combination of cell materials and operating parameters has been found to enhance separation and alter the energy consumption of the process.

Jan 1, 1999

By Yannick C. Beaudoin

Southern Explorer Ridge (SER) is an anomalously shallow, intermediate-rate spreading ridge located 200 kilometers off the west coast of Vancouver Island, Canada. It ranges in depth between 2600 m (deepest basins) and 1760 m (bathymetric minimum). At least 60 sulfide deposits are known to be associated with hydrothermal vent fields along the ridge. For the first time geological data, including deposit locations, collected from 15 marine expeditions to SER since 1983 have been assembled in a GIS format. GIS processing techniques were employed to plot the distribution of base metal concentrations for recovered sulfide samples. The highest base metal concentrations are found in the vicinity of the Magic Mountain site (main active vent field), and also proximal to a side scan sonar anomaly referred to as AGOR 171. Individual samples near these locations have yielded values as high as 29.3 wt\% Cu, 34.3 wt\% zinc, 0.97 wt\% Pb, 2.0 ppm gold, and 664 ppm silver. Sample paucity is the key limiting factor that prevents adequate assessment of the areas economic potential.

Jan 1, 2001

By J. F. Smith

A series of studies of emissions from large coal-fired steam generators have included measurements of the concentrations of oxides of sulfur and oxides of notrogen. The sampling equipment, method of sampling, and analytical techniques used for processing of these samples are detailed. A method based on the precipitation of benzidine sulfate was developed for determining both SO3 and total oxides of sulfur in the presence of interfering acidic components in the stack gases. In addition, difficulties encountered with sampling and analytical techniques are also described.

Jan 1, 1968

By Toivo Toivanen

The paper begins with a brief history of the nickel industry in Finland, and then deals with the introduction of the flash smelting process. The main part of the paper is devoted to nickel refining, which is studied under four main headings -grinding, leaching, electrolyte precipitation, and nickel electrowinning. Flowsheets are illustrated, and the equipment used is described. Analyses of the material in the various stages, from concentrate to high-grade nickel matte, are also presented. N ICKEL made its appearance in the Finnish mining industry forty years ago, when a nickel deposit was discovered at Petsamo in Lapland. Mond Nickel Co. received the concession for this deposit from the Finnish Government, and the Petsamon Nikkeli Company constructed a mine and a nickel smelter (1), the completion of which was prevented by the 1939 Winter War. The mine and smelter were, however, completed soon afterwards in spite of World War II,

Jan 1, 1964

By William Harrison, Robert H. Trent

GENERAL DESCRIPTION History The most striking feature of mining in the United States has been the infrequent use of longwall systems. This system, which accounts for the majority of coal production in Europe, Japan, and other countries, is only recently growing out of its infancy in the mining of normal coal seams and is still untried in the mining of thick coal seams in the US. Its use in the mining of metal and nonmetal ore bodies has been virtually ig¬nored, except for isolated instances in trona, copper, and uranium. Longwall mining is believed to have originated in Shropshire, England, towards the end of the 17th cen¬tury (Laird, 1973). Although the method used would be considered primitive by today's standards, many of the basic concepts have remained unchanged. Longwall mining of coal in the US was first introduced before the turn of the century, but it never gained acceptance as it did in Europe. Historically, longwalling was a cyclic method where a single cut of coal was removed from the face on the producing shift each day, and the work of building stone packs in the gob and manually moving roof support was completed on the off shifts. Due to the amount of dead work, productivity was extremely low. In Europe, however, longwall methods were required despite the high costs involved, because only by this method could coal under heavy depth be mined with any reasonable degree of recovery. Reserves of coal lying under shallow cover, and therefore minable by room¬and-pillar methods, were long ago inadequate to supply most of Europe's coal requirements. In the US coal min¬ing has historically proceeded laterally with the new mines in virgin areas to replace old mines; in Great Britain, Germany, Japan, and many other countries, mining must proceed downward to greater depths. The depth of cover for most coal operations in the US is shallow, i.e., 61 to 305 m (200 to 1000 ft). This, combined with large reserves, has made room-and-pillar methods almost universally applicable. However, longwall systems were tried around the turn of the century. Whenever used, it was frequently noted that the opera¬tion was under the direction of men with foreign ex¬perience and was tried under ideal conditions. Some of the mines that were using longwall or had tried longwall prior to 1910 were the Radiant mine, CO; Vinton Coal Co., PA; Cambria Steel Co., Johnstown, PA; Grundy County and Spring Valley, IL; and unnamed mines in Washington, West Virginia, Kentucky, Iowa, and Kansas. As late as 1961, there was one circular longwall in operation at Centerville, IA. The first modern-day op¬eration to take advantage of European technology and longwall methods was Kaiser Steel Corp. at its Sunnyside mine near Price, UT. Due to deep cover and extremely poor roof conditions, combined with a need for in¬creased production, Kaiser management decided a new method was required and turned to longwall in 1961. The first longwall consisted of an Anderson Mavor shearer loader, British Jeffrey-Diamond conveying equip¬ment, and Dowty roof supports with a capacity made up of two and three 27-t (30-st) capacity props. After nor¬mal start-up problems, this unit averaged over 454 t (500 st) per shift (White and Palacios, 1976). During and after World War II, technology in hy¬draulics and controls had advanced to the point that self-advancing supports and hydraulic props were being developed. In 1960 only I % of West German produc¬tion was from mechanized longwall faces. This in¬creased to 37% in 1970 and 63% in 1973 (Kohlgruber, 1974). In 1976 there were 246 coal mines operating in the United Kingdom. Although this is only 50% of those operating ten years ago, the production has increased 42%, mainly through improvements in longwall equipment and methods (Hunter, 1976). In France and other European countries, the devel¬opment of longwall mechanization has been similar in seams up to 2.44 m (8 ft) thick. In seams that exceed 9.14 m (30 ft), a variety of longwall caving has been developed for coal seams with dips of 0 to 1.6 rad (0 to 90°). Those with the greatest success will be discussed later. As noted, the development of longwall mining to its present state of the art has mainly taken place since World War II with substantial gains in the last ten years. Mechanized longwall has been the result of several re¬lated major innovations (Jackson, 1975) 1) Development of the flexible armored face con¬veyor which can be installed along the face and moved forward without disassembly. 2) Development of face machines such as single and double drum shearer and coal plows which operate in conjunction with the armored conveyors. 3) Development of self-advancing hydraulic roof supports which now include chocks, chock shields, and shields. 4) Reliance of caving of the immediate roof based on proper planning and development. 5) Use of pneumatic slowing to enable extraction below overbuilt areas. The most recent developments in the mining of coal by longwall in the US include the introduction of shield supports at Kaiser's York Canyon mine in New Mexico, single-entry longwall development at Kaiser's Sunnyside mine, and Mid-Continent's advancing longwall system in Colorado. Metal and nonmetal longwall systems in the US have included the mining of copper at White Pine, MI; uranium in Utah and New Mexico, and trona in Wyoming.

Jan 1, 1982

By X. -G. Chen, K. Liu

Nowadays, great interests are rising on aluminum alloys for the applications at elevated temperature, driven by the automotive and aerospace industries requiring high strength, light weight and low cost engineering materials. As one of the most promising candidates, Al-Mn-Mg 3004 alloys is found to possess considerably high mechanical properties and creep resistance at elevated temperature resulted from the precipitation of a large number of thermally stable dispersoids during heat treatment. In present work, the effect of Fe contents on the evolution of microstructure as well as high temperature properties of Al-Mn-Mg 3004 alloys has been investigated. Results show that the dominant intermetallic changes from a-Al(MnFe)Si at 0.1 wt.% Fe to Al6(MnFe) at both 0.3 wt. % and 0.6 wt. % Fe. In the Fe range of 0.1 to 0.6 wt.% studied, a significant improvement on mechanical properties at elevated temperature has been observed due to the precipitation of dispersoids, and the best combination of compression strength and creep resistance at 300°C is obtained in the alloy with an intermediate Fe content (0.3 wt.%) with finest size and highest volume fraction of a-Al(MnFe)Si dispersoids. The superior properties obtained at 300°C makes 3004 alloys more promising for high temperature applications. The relationship between the Fe content and the precipitation of stable dispersoids as well as the materials properties has been discussed.

Jan 1, 2015

By OTTO HERRES

TO operate the bituminous coal industry in the United States in 1929 cost $770,237,000, of which $30,739,000 was paid for purchased power and $34,947,000 for new machinery and equipment. Equipment aggregated 3,124,000 hp. A mining industry that spends $65,000,000 a year for power and machinery is likely to be fairly well mechanized, and when the machinery in use takes three million horsepower to drive it, the probabilities are that mechanization has been in progress in at least some of the mines for quite a few years. Mechanization in its broadest sense implies machine cutting, power drilling, mechanical loading, electric haulage, mechanical sizing and cleaning, and lesser applications of machinery to mining operations. But the introduction and development of mechanical loading has been the feature of coal mining recently and its extraordinary progress is causing great changes within the industry. First, let us look at the records. The quantity of coal loaded mechanically in bituminous mines was:

Jan 1, 1933

By T. L. Carstensen

The Miami In-situ mine of BHP Copper is located in Globe-Miami, Arizona. The mine leaches mineralized leach capping over a supergene enriched sulfide deposit, and has produced over 500 million lbs of copper during the last 50 years. The Miami unit has identified several opportunities to enhance and expand in-situ production. A computer block model consisting of strict geologic controls, mineralogy, and metallurgical data was developed to assist in the determination of the leachable copper resource. An understanding of the accessibility and solubility of the resource to leaching solutions and the integration of hydrogeologic and hydrometallurgical information was necessary for completion of this project.

Jan 1, 1997

By P. T. Brooks

Semipilot scale tests were made to demonstrate a newly developed electrorefining process which could be extrapolated to commercial scale in producing high-purity nickel and cobalt from crude nickel metal and high-grade ferronickel. The new process comprises application of solvent extraction techniques to remove and separate cobalt and iron from nickel and the electrodeposition in diaphragm cells of pure nickel and cobalt from chloride-based purified electrolyte. Using water insoluble organic amines, the solvent extraction operations enabled production of commercial-sized nickel and cobalt cathodes of higher purity than that of commercial electrolytic metals. The solvent extraction operation for separation of cobalt from nickel was made simpler than the conventional method. Furthermore, the solvent. extraction operation for iron removal made possible the electrorefining of ferronickel without the prohibitive loss of nickel resulting from the method ordinarily used for iron removal.

Jan 1, 1970

By Isa Nozari, Asghar Azizi

The extraction of copper from sulfate leaching liquor was investigated using Acorga M5640 commercial extractant in kerosene diluent. The effects of important factors such as the extractant concentration, contact time, liquor pH, and temperature were examined on the separation factor Cu/Fe and the extraction efficiency of copper. The results indicated that nearly 92.32% copper was extracted from the leach liquor at 10% (v/v) Acorga M5640 concentration, 1:1 aqueous/organic phase ratio, 20 min contact time, pH 2.5, and 25 °C temperature. Also, the further increase in the values determined had no positive impact on the extraction of copper. Under these conditions, the separation factor Cu/Fe was obtained about 29.64. The extraction mechanism was studied applying the plot of log(D) – 2 pH against log [extractant] and it proved the association of two moles of Acorga M5640 for the extraction of one mole of copper. McCabe–Thiele diagram was constructed and a single-step extraction process was found to obtain themaximumextraction. Additionally, thermodynamic datawere investigated and the extraction process was endothermic and non-spontaneous at 298 K (ΔH = 27.05 and ΔG = 15.52 kJ mol−1). Moreover, the loaded organic phase was stripped and 80.94% copper was recovered after 20 min using 10% sulfuric acid concentration.

Jul 31, 2020

By Robert T. MacMillan

An essentially chemical technique has been developed on a small scale for the efficient utilization of certain domestic titaniferous iron ores. Three main steps are involved: (1) Sintering the ore at 1,050° C. with carbon and soda ash to reduce the iron to metal powder, retaining the titania in the slag, (2) separating the powdered iron from the slag, after wet grinding, by magnetic or gravity methods, and (3) sulfuric-acid decomposition of the titania fraction to produce pigment and certain byproducts. The technique was first applied to the tailings from the Bureau of Mines bauxite-concentrating plant at Bauxite, Ark. A good grade of powdered iron was produced from this material. Subsequently, the work was diverted to the study of the titaniferous magnetite from the MacIntyre Mine at Tahawus, N.Y., because of the potentially higher recoveries of iron, titanium and vanadium. Ninety percent of the iron in this ore has been recovered as an iron powder analyzing 90 percent metallic iron and containing 2 to 3 percent TiO2. The remaining titania was found in the slag and was recovered as pigment-grade TiO2 by application of a suitable technique. The vanadium was distributed between the TiO2 fraction and the alkaline liquor resulting from the wet-grinding and magnetic-separation operations, with only a minor proportion retained by the metallic iron.

Jan 1, 1950

By H. Weissenbaeck, B. Nowak, M. Oesterreicher, R. Stastny

The producers of certain metals like nickel and cobalt increasingly face a shortage of easy-to-mine and easy-to-process ore bodies. Their focus is shifting towards alternative raw materials which in turn demand new, different extraction techniques. One potential route for processing a ferrous ore with a non-ferrous target metal is atmospheric leaching with hydrochloric acid followed by purification of the pregnant leach solution (PLS). For the separation of iron from the PLS, and, in turn, the extraction of the non-ferrous compounds, the following flow sheet is proposed. Pre-concentration of the PLS, oxidation of ferrous (if present) to ferric chloride, hydrolysis of ferric chloride leading to the precipitation of hematite and the evaporation of hydrochloric acid, followed by crystallization of non-hydrolysable metal chlorides by means of sparging hydrogen chloride into the solution. Hydrogen chloride required in the latter step is produced internally by super-azeotropic distillation of regenerated hydrochloric acid. The liquid filtrate from the crystallization step is recycled to hydrolysis. Depending on the specific composition of the PLS, the hematite produced contains only traces of other impurities, whereas the crystallized mix of non-hydrolysable metal chlorides – containing also the target metal in enriched form – contains ferric chloride only in an amount referring to the filter cake moisture. These crystals can then undergo further hydrometallurgical separation and extraction processes. As an example, this flow sheet is proposed for treating nickel laterite ores. Experiments related to the demonstration of crucial assumptions in the flow sheet are presented. Based on those experiments a mass and energy balance of the flow sheet was calculated and is presented here together with a table of the major consumables in order to provide a basis for an operating cost estimate and other process economics.

Jan 1, 2016

By Aysan Molaei, Kristian E. Waters

"Solvent extraction is the one of the most common techniques for recovering metal ions from aqueous systems. However, it is not efficient in the extraction of low concentration metal ions from aqueous solutions. Predispersed solvent extraction (PDSE) is an alternative method for solvent extraction which implies colloidal liquid aphrons as extracting agents in order to reach higher interfacial area and lower reagent consumption. This work investigated important parameters in PDSE of nickel ions from dilute aqueous solutions by fractional factorial design of experiments. Four experimental parameters, the initial extractant concentration, initial surfactant concentration, equilibrium pH and phase volume ratio (organic to aqueous ratio) were investigated. The important parameters were determined as well as important interactions between these parameters. It was found that extractant concentration, phase volume ratio, and equilibrium pH are the most significant experimental parameters. However, the interaction between surfactant concentration and other parameters was determined as significant interactions.INTRODUCTIONNickel is one of the key components found in cars, mobile phones, rechargeable batteries, kitchen appliances, and steel industry (Anyadike, 2002). It is one of the most important metals produced by Canada which is in the five top nickel producers in the world. Despite a 24% decrease in the nickel prices from 2011 to 2014 the nickel global mine production increased by 36% between these years (U.S. Geological Survey, 2015; Nickel - Statista Dossier, 2015), which shows the increasing demand for nickel. This high demand leads producers to consider the production of nickel from low grade ores and other secondary sources such as process wastewaters. The removal of nickel ions from process wastewater is also important due to environmental considerations. Nickel is known to be a human carcinogen and it may cause serious lung and kidney problems, pulmonary fibrosis, gastrointestinal distress, and skin dermatitis if it exceeds the critical level (Borba et al., 2006; Fu & Wang, 2011)."

Jan 1, 2016

By H. Pearce, A. E. Lewis, A. Ochieng

Hydrodynamics and mixing are fundamental to the operation of mineral process systems such as flotation cells and metal precipitation reactors. The computational fluid dynamics (CFD) technique has been employed in the present work to study the hydrodynamics in a mixing vessel stirred with either a Rushton turbine or a pitched blade impeller. The multiple frame of reference (MFR) approach has been used to model both impellers. A draft tube was used only in the Rushton turbine stirred vessel. The flow profiles for the pitched blade impeller have been studied in three regions; below the impeller tip, at the middle of the tank, and near the liquid surface. The simulation results were compared with literature data obtained using a laser Doppler velocimetry in the three regions of the vessel, and it was found that the model predictions were better in the impeller region. There was a poor prediction of the experimental results in the region closer to the liquid surface; however, this was improved when the turbulence parameter (C2) in the k-e model was set to a higher value. The value of the impeller clearance at which the Rushton turbine generates an axial impeller type flow has been determined and it has been shown that, at this clearance, a draft tube can be used to enhance axial flow in a Rushton turbine stirred reactor.

Jan 1, 2003