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By Milton Manrique

The thermal decomposition of ilmenite concentrates in a non-transferred arc; thermal plasma flow reactor was investigated. The plasma torch was operated using argon-helium and argon-nitrogen mixtures as plasma gases. The effect of power, feed rate and particle size was studied. Products were characterized by XRD, SEM, TEM and ICP techniques. Free energy minimization plots were used to predict the thermodynamic behavior of the system under different operating conditions. The results of this investigation showed a significant segregation process where titanium-rich products are collected in the reactor, while iron-rich products are collected in the quenching box and filter. The average size of the product is in the sub- micron range. Titanium nitride was formed and condensed in the reactor zone when using an argon-nitrogen mixture as the plasma gas.

Jan 1, 1998

By D. W. Bridges, Donald R. Peterson, Masami Hayashi

Techniques are described for recovering about 80 pct of the cobalt and nickel contained in superalloy scrap by anodic dissolution of the scrap and simultaneous electrodeposition of a pure cobalt - nickel alloy at the cathodes in an electrolytic cell partitioned by permeable diaphragms into separate anode and cathode compartments . Superalloy scrap was alternatively prepared for subsequent anodic dissolution either by melting and casting massive scrap into suitably sized anodes , by packing moderate - sized discard scrap in inert metal baskets that subsequently served as anodes , or after concentrating the superalloy portion of grinding debris , by magnetic separation to reject corundum or other abrasives , slagging any remaining abrasives from molten grindings , and finally casting the superalloy metal into anodes . In the processing , purified electrolyte -- 1 N in NiSO4 and in NiCl₂ , and 0.1 N in CoSO4 and in CoCl2 --was charged to the cathode compartments and discharged from the anode compartments at a rate sufficient to overcome the backward migration of ionic impurities from the anodes to the cathodes . Discharged electrolyte was purified by reacting it first with SO2 and next with limestone , and then recirculated to the cathode compartments , in which a 50 pct cobalt - 50 pct nickel alloy was deposited on either blanks of stainless steel or starting sheets of cobalt - nickel alloy . The process was made self - sustaining by either adding H2SO4 to the catholyte feed to throttle the rate of cobalt - nickel deposition , thereby compensating for the slower rate of cobalt - nickel dissolution from the anode and losses occurring in electrolyte purification , or alternatively , adding H₂SO4 to

Jan 1, 1964

By A. J. Oliver, C. E. O’Neil, I. J. Itzkovitch, V. A. Ettel

A new solvent extraction process for the separation of cobalt, copper and zinc from nickel sulphate process streams has been developed. It involves selective extraction of these elements with a quaternary ammonium thiocyanate dissolved in an aromatic diluent. The chemical principles of this process have been investigated and are described, together with background physico-chemical data relating to the use of this solvent. Long-term testing in a continuous "mini-plant" circuit gave high-purity nickel and cobalt products (Ni/Co —200011 and Co/Ni ~1000/1 respectively).

Jan 1, 1976

By R. S. Dean

[Methods s of preparing the manganese metal that has been used in chemical and metallurgical investigations have passed through a cycle. Most of the investigations made before the turn of the century, used Moissen's pyrophoric manganese.3/ This material was made by electrolysis into a mercury cathode and distillation in vacuo. The material was essentially pure, and investigations in which it was employed (with proper precautions against oxidation) led to accurate results on tie intrinsic behavior of metallic manganese.]

Jan 1, 1941

By Sameh M. Khella

This paper discusses the application of deep CFA piles for the foundation of structures in different ground stratifications with a focus on the application in Queensland region. Design, construction techniques and quality measures implemented during these procedures are described. Testing methods and verification of capacity, integrity and performance of these piles are also demonstrated. Case studies for this application are presented with an appreciation of this solution within the provided project conditions of each case. Examples of successes and challenges encountered over the course of application of deep CFA in Queensland are mentioned. Limitations of the technique and less favourable situations for its implementation are also highlighted.

Nov 1, 2022

By J H. Park, R R. Kim, H S. Park, H J. Kim

This study focuses on the recovery of valuable metals, specifically silver (Ag) and palladium (Pd), from copper-containing sludge (with copper content less than 20 per cent) generated during PCB processing and from spent petrochemical catalysts used in vapour decomposition during oil refining processes. The present results indicate that an increase in the mixing ratio of alumina-based spent catalyst leads to a decrease in the recovery rate of Ag and Pd. The recovery rates for Ag and Pd range from 84 per cent to 96 per cent and 80 per cent to 98 per cent, respectively. This trend is attributed to the increased emulsification of copper droplets containing Ag and Pd in the slag. The emulsification is caused by the decrease in the settling velocity of the copper droplets due to the increased viscosity of the slag as well as by the decrease in the slag-metal interfacial tension due to an increase in sulfur content at higher mixing ratio of spent catalyst.

Jun 19, 2024

By R. Vracar, D. Sinadinovic, Ž. Kamberovic

The paper presents a study on the oxidation of polymetallic gold ore by oxygen in an autoclave. It presents optimum parameters of autoclave leaching of sulphide refractory ore in self-generated sulphuric acid solutions aiming to get products with favourable technological characteristics from which precious and other useful metals can be recovered. A high partial oxygen pressure (1.5 MPa to 2 MPa), high leaching temperature (190°C to 200°C), pulp density 80 g/L to 240 g/L, ore fraction size 76 µm and leaching time up to 4 hours yield good results in rich ores. The full extent of copper and zinc conversion as well as a high extent of iron conversion has been achieved, while lead, gold and silver and a minor part of iron remain as a solid residue among gangue minerals.

Jan 1, 2001

By A. Ghasemi

An alumina-silica coating was deposited on a nickel substrate by sol-gel process, and the structures and composition were evaluated, The sols were made from aluminium and silicon alkoxide, and an acid catalyst including HCl, To produce adherent silica coatings on nickel, various additives such as surfactant, viscose additive and drying control chemical additives were introduced to the system, and appropriate drying and firing cycles were applied after dipping in solution. The hot corrosion and oxidation resistance of the coating at different temperatures were investigated, The structure and uniformity of the coatings were examined by scanning electron microscopy (SEM), The results indicate that a uniform coating of alumina silica can be produced on a nickel substrate by optimizing the composition and process variables of the sol. Coatings can protect substrates from oxidation and hot corrosion at different temperature up to 1000°C, but is not very effective for hot-corrosion resistance at 1000°C.

Jan 1, 2005

Jan 1, 1963

By Felicia F. Peng

The manganese removal from aqueous solution containing high Mn2+ concentration by adsorption and oxidation was studied using manganese oxide particles as the adsorbent. The operating parameters including pH, flow rate, initial manganese concentrations, and oxidant dosage affect the performance of Mn2+ removal were evaluated in a laboratory packed column. In the multi-column adsorption tests, each additional column doubled the time for complete manganese removal. No further decrease of pH was also observed once it was lowered to pH 4.5 to 5. This finding implied the possibility of complete high manganese removal without further pH adjustment during adsorption. Oxidation of Mn2+ by dissolved oxygen was found to be insignificant for manganese removal for high Mn2+ concentration. Adsorption was the predominated mechanism involved with manganese removal. Extremely low H+/Mn2+ stoichiometry compared to the reported values was measured. These low values suggested that different adsorption mechanisms such as chemisorption other than H+/Mn2+ ion exchange might play an important role at low pH. This paper presents the quantity and explanation of the results obtained for the mechanism of adsorption and oxidation of high concentration manganese on the manganese ore particles.

Jan 1, 1997

By W. Pawlos

"The paper will present the methods of visual observation and recording of movement paths of coal grains of different physical properties in the paramagnetic liquid. The paths were recorded with a video camera in the working chamber by means of a specially constructed device, acting as a periscope, which were then transformed into digital images.Experimental movement paths were confronted to the paths obtained in a theoretical way by means of solving differential equations of movement. The outlet level of a grain of the same physical properties from the separator is a random variable with normal distribution which modal value is equal to the outlet level of a spherical grain, calculated from the solution of grain movement equations. At these assumptions it is possible to calculate the height of the passage from the separator working chamber to separate a given product with a given separation accuracy, measured by a probable error and to determine separation conditions."

Jan 1, 2003

By R. E. Burleigh

'Gold-telluride mineralization was deposited in quartz veins which cut a Late Cretaceous tonalite pluton emplaced near the southern margin of the Peninsular tectono-stratigraphic terrane in south-central Alaska. The gold-bearing veins formed shortly after the development of a widespread Cu-Mo sheeted quartz vein system. Early mineral assemblages consist of quartz, white mica, pyrite, and arsenopyrite (wall rock only). Subsequently, pyrite. sphalerite, chalcopyrite, zoned tetrahedrite and gold precipitated within multiply fractured veins. Late stage galena, tellurides (altaite, nagyagite, coloradoite), and Pb-Sb or Pb-Cu-Bi sulfosalta with gold constitute bonanza ore assemblages that are variably associated with quartz, white mica, ankerite, and calcite. Fluid inclusion evidence coupled with mineral assemblage paragenesis suggests the depletion of volatiles (C02, H2S) and cooling resulted in the precipitation of high grade gold mineral assemblages.

Jan 1, 1988

By L. Bratek, K. Jaworek, M. Czaplicka

Methods for arsenic compound removal from aqueous solutions include processes such as: coagulation, adsorption, membrane techniques, electrochemical and biotechnology techniques. Advanced oxidation using both UV radiation and strong oxidizing agents such as ozone and hydrogen peroxide may also decompose these compounds. It is known that effluents from metallurgical processes contain inorganic arsenic compounds in addition to the organic compounds such as: dimethylarsinic acid and phenylarsonic acid. This paper presents the conditions that lead to the formation of deposits containing mainly arsenic, such as pH, the wavelength of the radiation and the type of oxidant, for this type of effluent.

Jan 1, 2014

By C. A. Schempp

STUDY of the adaptability of Tintic Standard ores to concentration dates back to somewhat before January, 1921, when the chloridizing mill at Harold, Utah, was put into operation. The operation of this mill has been fully covered in the TRANSACTIONS (Vol. 73). The process consisted essentially of a chloridizing roast followed by a percolating leach with a nearly saturated solution of common salt, acidified with sulfuric acid; precipitation of silver on sponge copper, and of copper and lead on tin-plate cuttings. This mill was built to treat the low grade siliceous ores having an average content of

Jan 1, 1933

By Alton B. Cook

In the Scurry Reef field, Scurry County, Tex., a study was made to determine the physical properties of the oil in all parts of the reservoir by a new method developed for this study. The method involved correlation of data from a survey 1 of the gravity of the produced oil, from measurements of gas-oil ratios on key wells selected to give representative data for the entire reservoir, and from laboratory analyses of reservoir oil samples. A field survey was made of the API gravities of the produced oil by testing oil samples from 107 key wells. Precise gas-oil-ratio tests were made on 45 key wells that were producing under comparable separator-operating conditions. Subsurface-oil samples were obtained from seven wells, selected to provide reservoir oils ranging approximately from a minimum to a maximum in saturation pressure. The physical properties of the subsurface-oil samples were determined, and correlations were made of these laboratory data with the field gas-oil-ratio test data. These correlations were then used to estimate physical properties of the oil throughout the reservoir. A logical procedure of determining the variations in physical properties of reservoir oils in most fields is to obtain and analyze subsurface-oil samples from enough key wells to provide an ample coverage of the field. Under this procedure, data from a large number of samples would be needed to provide the desired information on the Scurry Reef field, as it is one of the largest known in the United States.

Jan 1, 1955

APPLICATIONS for loan contracts for the exploration, development and mining of strategic and critical metals and minerals are now being accepted by the Department of the Interior. The RFC is authorized and directed by Executive Order 10161 to make such loans but the Secretary of the Interior must pass on the necessity for the loan. Applications should be addressed to James Boyd, acting deputy administrator, Defense Minerals Administration, Department of the Interior, Washington, D.C. rather than to the Field Offices of the Bureau of Mines as was first planned. Application forms are not yet available but it has been learned that data accompanying the application should include the known quantity and grade of reserves, the anticipated rate of production, the equipment, supplies, and man power required for the additional production, etc.

Jan 12, 1950

By C. M. Wai

"Metal species in solid and liquid materials can be extracted by supercritical carbon dioxide containing a suitable ligand. This in situ che1ation-supercritical fluid extraction technique offers several advantages over conventional solvent extraction including minimization of organic liquid waste generation and exposure of personnel to organic vapors. One unique feature of this technique is that metal species can be removed from solid materials directly using supercritical carbon dioxide as a solvent. Several ligand systems including dithiocarbamates, B-diketones, organophosphorus reagents, and macrocyclic compounds have been tested for metal extraction in supercritical carbon dioxide. This novel extraction technique may have important applications for metal recovery and mineral processing.IntroductionSupercritical fluid extraction (SFE) offers several advantages over conventional solvent extraction including the minimization of organic liquid waste generation and exposure of personnel to organic vapors.[1] The high diffusivity, low viscosity, and T-P dependence of solvent strength are some attractive properties which make supercritical fluids excellent candidates for extraction and recovery of organic compounds from solid materials [2] Carbon dioxide is a gas of choice for SFE because of its moderate critical constants (Tc = 31 °·C and Pc = 73 atm), inertness, and availability in purified form. After extraction, the fluid phase is depressurized to separate organic solutes from CO2 gas and the gas can be recycled for repeated use. The SFE technology has been applied to industrial scale operations such as the preparation of decaffeinated coffee and hop extracts."

Jan 1, 1996

By M. H. Ali

Codelco, a multi-process primary copper producer, is undertaking a full life cycle inventory (LCI) of all its commercial products based on copper and molybdenum. During this work, many questions have surfaced regarding the contribution of process unit design to specific aspects of a product's LCI and, more importantly, how such designs could be improved using a life cycle perspective. Management strategy efforts were undertaken to improve the LCI footprint, however it was found that the corrective actions were almost impossible to apply at the operation level in plant, given the ongoing timing pressures of extractive mining, and costs saving priorities. Additionally, it was found that most of the important comparative differences between operations had structural reasons. In this circumstance, the LCI practitioner group from 1M2, and the environmental managers from Codelco, decided to shift its efforts to place the critical LC1 aspects to the design process of future developments. Hatch Associates has developed unique tools in their Sustainable Plant Design (SPD) package that compliment and enhance LCA methods; these effectively drive sustainability into the heart of the design process. By using LCA and SPD in a project design phase, you cannot only address potential hotspots, but also decide on materials, location and size of certain facilities to optimize for energy efficiency. Moreover, you can avoid the shifting of environmental burdens upstream or downstream within the plant and finally it is extremely useful in identifying opportunities for greenhouse gas reduction.

Jan 1, 2007

By Torma A. E.

Biotechnological processes are considered to be cost effective especially for situations where the recovery of metals from 'Very large volumes containing trace metal concentrations (less than 10 ppm) is concerned. Microorganisms, alive or dead, or their products can be highly efficient and selective biosorbents for metal concentration. It is important that the metal bound to the biosorbent can be stripped by suitable agent(s) and regenerated for repeated use. The stripped solution should be concentrated enough to be introduced into the common metal recovery circuit. The industrial acceptance of biosorption processes is dictated by increased competitive advantage over other processes. This paper reviews the pertinent literature?, regroups the information, and points out future possibilities for the mineral and metal processing industries.

Jan 1, 1992

By K. Morsi, P. Mehra

"Spark plasma sintering has gained a considerable amount of attention over the past decade, due to its rapid sintering rates, and low temperature requirements, but has so far been usually limited to the production of simple geometries. The present paper examines the current-activated production of extended geometries through the process of spark plasma ""extrusion"". Of interest in the present study is exploratory research into the effect of electrical current activation on the reactive consolidation of powder systems to form intermetallic materials.IntroductionSpark Plasma Sintering (SPS) has been the subject of intense research over the past decade [ 1,2, 3,4,5,6]. The process boasts unique advantages which include ultra fast heating rates, shorter sintering times and lower sintering temperatures than needed in conventional sintering. The process is however limited to the generation of predominantly simple geometries. Recently one of the authors investigated the spark plasma extrusion of aluminum, where an aluminum powder compact is directly (Joule) heated through an applied DC electric current. Here extended geometries can be generated under the influence of electric current. A number of heating sources were identified including the heat source from current, i.e. Joule heating, frictional heating and heat from the deformation energy. However in the case of reactive powder systems, an extra ""one-time"" transient heating source can be supplied. By considering combustion synthesis of powders, this heating source is derived from the reaction between elemental powders to exothermically form a product at some ignition temperature [7]. This exothermic energy heats the compact to the maximum ""combustion temperature'', which could be hundreds of degrees higher than the ignition temperature. Hence a high temperature processing window (of short duration due to heat losses to the surroundings) becomes available in which the material is most suitable for stress-induced deformation and consolidation. For reactive spark plasma extrusion, two scenarios can be envisioned. The first is where the reactive powder compact is ignited through the application of current, and extruded within the high temperature processing window (also under the influence of current). The second scenario is to allow the heat of deformation/friction to heat the material during extrusion, to simultaneously force a reaction and consolidation. Here it is expected that the processing window will be very small if feasible."

Jan 1, 2011