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By S. V. Petrov

In recent years, heap leaching of gold is becoming wide spread due to low capital and operational costs that allows economically feasible processing of low-grade and cut-off grade ores. Currently, over 30 heap leach projects are operated in Russia. Some of the deposits treated by heap leach methods are almost depleted. Therefore, they will soon require spent heaps detoxification and reclamation. Traditionally, spent heaps are detoxified by chemical treatment. This process is characterized by relatively high kinetics and requires expensive reagents and additional equipment. The main disadvantage of this process is secondary contamination of the solutions by products of detoxification reactions and impurities contained in reagents. If there is enough time, spent heaps can be detoxified by natural degradation. The advantages of the proposed method are low operational costs due to use of existing heap leaching facilities and eliminating the need for chemicals for spent heaps detoxification. Residual concentrations of cyanides and thyocyanates in liquid phase (wet ore) of spent gold ore heaps after detoxification were 0.2~0.3 mg/L. Heavy metals were almost completely removed. The method was successfully used for detoxification of spent heaps at two gold mines.

Jan 1, 2014

By Kafui Nyavor

The indirect, and the direct contact mechanisms of bacteria oxidation of sulfides were studied using Thiobacillus ferrooxidans and pyrite. The aim was to determine which of the two generally aeeepted mechanisms played a dominant role, if any, during acid mine drainage (AMD) formation from the oxidation of sulfide minerals. The results show that at a pH of 4.5 where T. ferrooxidans are quite active, but where initial chemical oxidation of pyrite to Fe2+ is limited, the bacteria were unable to directly oxidize pyrite to any significant extent. Whereas, in the presence of Fe2+, T. ferrooxidallS assisted oxidation of pyrite by the indirect mechanism was observed and sustained over the pH and Eb range where the bacteria is active. The results lead to the conclusion that the direct contactmechanism of pyrite oxidition by T. ferrooxidans is insignificant. The predominant, and possibly the only, pathway involves the indirect bacteria oxidation of available Fe2+ to Fe3+, which in turn oxidizes FeS2 to generate additional Fe2+ and acidity in a cyclic process.

Jan 1, 1996

By Edwin Adoyi Ali, Zainab Shehu Aliyu, Adele Dzikwi Garkida, Muhammad Dauda

Feldspar from Matari, Nigeria was analyzed using SEM, XRD and XRF techniques for microstructural analysis, mineral phase analysis and chemical composition analysis respectively. Qualitative and quantitative XRD analyses revealed the presence of microcline 59.6%, albite 34.7% and quartz 5.71%. The XRF results showed that the feldspar contains 67.32% SiO2, 17.54% Al2O3, 11.33% K2O, 2.75% Na2O, 0.12% CaO, 0.01% MgO, 0.02% MnO2, 0.10% Fe2O3, 0.00% Ti2O, etc and 0.14% LOI. SEM/EDX analysis shows the presence of microcline feldspar as the dominant phase, exhibiting lamellar twinning. The XRD has also revealed that potash has the highest peak, indicating its high concentration. The 0.10% Fe2O3 present is within the permissible level (0.1-0.3%) for glass making and also within the potash feldspar specifications (0.17%). The Matari feldspar is a microcline type, rich in potash, alumina and silica, enabling it meet the standard specifications for alumino-silicate glass.

Jan 1, 2015

By Julie M. Melluish

The metallurgical response of the Point Leamington deposit has been studied. Two series of bench tests were conducted and various ore samples and flotation products were examined using image analysis techniques. The majority of sphalerite and chalcopyrite grains in this texturally complex ore were found to be smaller than 10 micrometres. Copper recoveries were low with losses mainly as fine inclusions in pyrite. Sphalerite recoveries were somewhat better due to a generally coarser habit. Gold and silver recoveries were also low and only solid solution silver was identified in the ore. The deposit shows poor economic prospects unless additional tonnage of high grade zinc ore can be delineated.

Jan 1, 1989

By Fuqiang Zheng, Yufeng Guo, Guanzhou Qiu, Tao Jiang, Xiaoming Qu

MxTi3-xO5 is the main titanium-bearing mineral in the titanium-bearing electric furnace slag (TEFS), which is produced by direct reduction-electric furnace smelting process with vanadium titanomagnetite concentrate in Panzhihua-Xichang region of China. In order to effectively utilize the titanium resource in TEFS, the thermomechanical analysis and conditions for the growing up of MxTi3-xO5 grain were investigated, which emphasized on the effects of CaF2 and cooling rate on the crystallization of MxTi3-xO5 in the melting process. The mineral phase and morphology of titanium-bearing slag were determined by XRD and electron microscope technique, respectively. The results indicated that the average grain size of MxTi3-xO5 grown up from 30 to 92 lm and the area fraction of MxTi3-xO5 reached about 66% from 61% under the conditions of 5 wt% CaF2 and cooling rate at 1 °C/min.

Mar 1, 2017

By T. H. Jeffers

The Bureau of Mines conducted laboratory tests to devise a procedure for extracting copper from low-grade discarded mill tailings. A solid extractant consisting of an organic solvent extraction reagent adsorbed on granular activated carbon was investigated and proved to be satisfactory for extracting copper directly from leach pulps. When this material was used in a cyclic leaching, stripping, and electrowinning pro-cess, 95 pct of the acid-soluble copper was recovered from oxidized mill tailings. The weathered tailings contained 0.24 pct Cu (total) and 0.20 pct acid-soluble Cu. The copper was recovered as cathodes containing, in parts per million, 1.6 Pb, 3.6 Fe, 0.5 Sb, 1.5 AI, 1.9 Mn, and <1 Mg.

Jan 1, 1985

Mineralogical and metallurgical scoping testwork were carried out to investigate the production of separate, marketable gold and platinum concentrates. The study utilized a flotation concentrate assaying approximately 5 wt% gold and 5 grams per tonne platinum. The gold-platinum mineralization was recovered from a placer deposit. Optical microscopy and scanning electron microscopy with energy dispersive x-ray analysis identified gold as zoned Au- Ag and Au-Ag-Cu alloys. Platinum primarily occurred as weakly zoned, variably magnetic Pt- Pd-Fe alloys. A combination of gravity and magnetic separations resulted in a gold concentrate grading 86.9 wt% Au (and 9.lwt% Ag) and a separate platinum concentrate grading 400 g/t Pt with recoveries of 94.5% and 96.7%, respectively. Magnetohydrostatic separation (MHS) using the Magstream 200 Separator indicated promising results.

Jan 1, 1994

By Clark D. Harrison

This paper compares the ash slagging potential of Illinois No. 6 Seam coal: as raw coal; as commercially cleaned coal processed in a baum-jig plant; and as coal cleaned to a reduced ash specification at the Electric Power Research Institute&apos;s Coal Cleaning Test Facility. The comparison is based on: ? ASTM ash fusibility data ? A slagging index ? Gravity fractionation analyses of critical mineral matter compounds ? Comparative pilot combustion tests. The first three grounds of comparison are laboratory data; and the final comparison involves burning approximately 15 tons of each coal at CONOCO&apos;s 1.5 MBtu/hr (440 KW) test combustor. The evidence of these .four comparisons indicates that lowering the ash specification of coal before combustion can significantly improve the ash slagging characteristics of Illinois 90. 6 Seam coal.

Jan 1, 1984

By E. C. Dowling, S. A. Elmquist, L. A. Kipfstuhl

The Cliffs and Associates Limited (CAL) 500,000 tpy HBI plant located in Trinidad was commissioned after modifications in early 2001. This plant employs the novel Lurgi Circored® process to reduce iron ore fines using a combination of circulating fluidized bed and conventional fluidized bed reactors in a hydrogen based. This paper will review the advantages offered by working in the Caribbean nation of Trinidad and Tobago, the Circored® processes, and plant start-up experience.

Jan 1, 2002

By J. W. Thompson

"The Republic of Colombia on December 30, 1919, enacted a new petroleum law. The Act is expressly limited to mineral oil, natural gas, bitumen, wax and fossilized resin and to asphalt intended for export.The law is not only intended to encourage local investors, but to attract foreign capitalists for oil development. Provision is made for a special edition ion of the law in such languages as the Government may deem necessary to give it extensive circulation within the country and abroad. The published editions must contain the provisions of the law relating to alienship and naturalization.All public lands, or what are termed unclaimed lands, are open to flee prospecting for the purpose of discovering the deposits named in the law, A prospector must obtain from the Government a, license which binds him to deliver to the Government topographic plans of the lands prospected, together with reports of their prospective yielding capacity. This license does not vest the li¬censee with any preferential right for contracting or leasing and may be drawn by the Government at any time.If a discovery is made by a licensee of any of the deposits named and he desires to exploit the same, he must present a memorial or application to the Ministry of Public Works, stating:- (a) the location and municipal district in which deposit beds are found; (b) boundaries of the zone of exploitation, which shall not be more than 5,000 or less than 1,000 hectares; (c) the names and nationality of all persons for whom the lease is sought and the action and time within which,they propose to make the exploitation; (d) the name of the corporation and its legal representatives with their residences; (e) if an alien, he must state his willingness to comply with the law relative to alienship and naturalization; (f) agreement to abide by all of the provieions of the law with regard to Government supervision, payment of taxes, rate of lease and causes of forfeiture; (g) the rate of rent or royalty that the applicant offers to pay, together with any other circumstances that may make the proposed lease advantageous to the Nation."

Apr 1, 1920

By Kimberlie Staheli

A new sanitary sewer was installed in Pleasant Hill, California using microtunnelling methods. The project consisted of 693 meters of 1372 mm and 1981 mm concrete pipe. A Herrenknecht AVN 1200 was used to install the nominal 1372 mm pipe in three drives. The machine was then fitted with an oversized shield used to install the large diameter pipeline. This articulated shield allowed the excavation of a 2362 mm diameter hole with a 1524 mm machine-- a technique new to North America. This paper reviews the design considerations for the articulated shield and reports on the project challenges and solutions to overcome these challenges.

Jan 1, 1995

By L. S. Beck

"The Athabasca region forms part of the Churchill province of the Canadian Shield and is underlain by an Archean or Aphebian assemblage of rocks that underwent severe metamorphism and granitization during the Hudsonian orogeny (1750-1950 m.y. ago). In places, the eroded orogen is overlain by unmetamorphosed cover rocks (in-cluding the Martin and Athabasca formations) of probable Paleohelikian age. Basic dykes cut all the rocks of the region.There are innumerable vein-type pitchblende deposits and many syngenetic occurrences of uraninite in crystalline basement rocks. Evidence is presented to show that pitch-blende was emplaced during the final stages of the Hud-sonian granitization and followed the crystallization of syngenetic uraninite transitionally. In terms of P-T condi-tions, the pitchblende deposits belong essentially to Lindgren's mesothermal group.Based on the postulated uranium metallogenesis, the possibilities of finding further deposits of pitchblende and other types of uranium deposits are discussed."

Jan 1, 1970

By Š. Šachlová, T. Lokajícek, M. Petružálek, T. Svitek, A. Štastná

During the past 20 years, alkali silicate reaction (ASR) as a cause of concrete deterioration has been studied by a wide range of experimental methods such as microstructural and macrostructural analysis, bulk chemical analysis, X-ray and neutron diffraction analysis, etc. All of these data are compared with expansion values of mortar bars (following ASTM standard C 1260). Recent studies indicate the useful application of non-destructive methods with the aim of better reflecting mechanical properties and the degree of deterioration of real concrete. Ultrasonic testing methods (including ultrasonic pulse velocity UPV) are widely used to determine material mechanical properties and the changes induced by a variety of mechanical or chemical processes. However, only a few laboratory studies of ASR focused on ultrasonic testing of mortar bars. Due to this fact, a heating chamber was designed and constructed to enable ultrasonic sounding of mortar bar specimens while stored in accelerating solution. Regular ultrasonic sounding of mortar bars reveals significant dependence of ultrasonic data such as longitudinal P-wave velocity, signal energy, signal amplitude and signal frequency on mortar bar storage time. Ultrasonic data were subjected to time domain as well as frequency domain analysis. Different storage conditions were used to determine the effect of ASR on ultrasonic parameters. Mortar bars, prepared in the same manner with one type of aggregate, were stored in cold or warm water or in an accelerating warm medium. Ultrasonic data accurately reflects the differences in hardening and deterioration of tested mortar bars due to different storage conditions. Ultrasonic results showed very good correlation with the results of ASTM standard expansion tests and much higher sensitivity to ASR-induced concrete deterioration. Expansion tests showed 1% measured length differences in comparison with up to 80% resolution of ultrasonic data. The ultrasonic testing proved to be a suitable laboratory method for investigating ASR-related processes and could lead to an improvement of standard testing procedures.

Jan 1, 2015

The challenges of nature for the recovery of metals for a sustainable future continue to present in diverse ways. Base metal deposits are becoming lower grade and more complex. Rare earth metal demand is soaring and must certainly be met from new sources outside of China. Precious metals have soared in value due to increased industrial usage and the importance of these metals as financial instruments. Many of the future sources of precious metals are complex and difficult to process. The field of hydrometallurgy plays an important role in providing technology for extraction of these metals for a sustainable future. Selected examples from the base, rare and precious metals fields will be used to illustrate how current developments are providing metals for our future. The recovery of rare earths by beneficiation, leaching, purification, precipitation will be described from a multi-mineral deposit in Canada. The recovery of metals from complex base and precious metal ores may be accomplished using chloride ? assisted high temperature pressure leaching. Finally, by way of example, the enhanced Galvanox? process for treatment of chalcopyrite concentrates using silver-activated pyrite as a catalyst will be illustrated. This process offers a viable alternative to the conventional smelting of chalcopyrite copper concentrates.

Sep 1, 2012

By P M. Dight

Shotcrete usage in declines and developments has become pervasive as operators strive to achieve production improvements. Issues of mix control, fibreload, thickness control, temperature and curing conditions all play a part in the quality control. Often to overcome some of the quality control issues designers over specify the strength requirements in order to meet their operational constraints. Adherence to the standard civil testing requirements of 28 days moist cured at 21ºC without properly calibrating these results to the changing environment underground leads to contractual disputes. There are a number of standard tests specified including cylinder tests, cored tests, beam tests and round determinate panel (RDP) panel tests. The logistics of storing these samples and then transporting them to concrete testing laboratories without due regard to temperature changes with time can influence the results. All the samples can be readily handled by personnel except the RDP panel. The standard RDP panel is 800 mm diameter by 75 mm thick and requires an ITH machine at the mine and a fork lift at the laboratory to move it around. This paper will examine the possibility of a panel which provides scalable results to the standard RDP panel but can be easily handled by personnel and/or tested on site with suitable equipment. This allows for faster turn around and better quality control for the sample prior to testing. This enhances the identification of quality control issues at the mine and improves safety.

Mar 21, 2011

By G Chen

Magnesite and dolomite are two salt-type minerals. The surface characteristics of these two minerals are almost the same. It is very difficult to remove dolomite from magnesite ores by flotation process. The present study was performed to develop a new collector and a better flotation scheme for magnesite from dolomite. The flotation tests show that there exists a significant difference in flotability between magnesite and dolomite when dodecyl phosphate synthesised with dodecanol, phosphorus oxychloride and other chemicals is used as collector. Sodium silicate was used as the modifier to improve flotation selectivity. It was found that sodium silicate selectively depressed magnesite at pH 4.5 - 7.5. The separation of magnesite from dolomite was achieved in a reverse flotation which resulted in a 76.1 per cent yield of magnesite with a grade of 47.3 per cent at 100 ppm dodecyl phosphate and 75 ppm sodium silicate. The flotation mechanism was investigated by characterising surface electrical properties and measuring the adsorption density of the reagents on magnesite and dolomite.

Jan 1, 2005

By D. Naden

Sulphuric acid leaching is the most common method of recovering uranium from its ores and in the following discussion various alternative low cost routes are investigated for recovering uranium from milled ore acid leach liquors. Historically uranium has been recovered from dilute impure leach liquors by packed bed ion exchange (IX), solvent extraction (SX) or a combination of both. All three process routes as commonly practised require complete separation of leached solids and liquids, as well as extensive solids washing in order to reduce soluble uranium losses to a minimum. Separation and washing are costly and often require equipment covering large areas of land. The size and capital cost of the post leach solids washing operation is controlled by the ease of washing the slimes fraction of the ore and the key to the problem of cost reduction, as many others have realised, lies in the ability to separate the slimes fraction of the ore from the more easily washed sands, to wash the sands in low cost equipment and to recover uranium from the slimes stream. Sands and slimes are usually defined in this context as the material larger than, and smaller than, 325 mesh (44 microns). The proposed flowsheets which minimise solid-liquid separation and washing have usually incorporated ion exchange (Refs 1,2,3), and resin in pulp is in fact practised in several mills in the USA (Ref 1). The resins used in these flowsheets and [cranium] recovery throughout the world have been strong base resins which load rapidly and are moderately selective for the uranyl sulphate complex anion over the range of pH which is conveniently achieved in an acid leach operation. Strong base resins are, however, not as selective as weak base resins and weak base liquid reagents owing to the adsorption of competing anions, some of which find their way into the product while others act as resins poisons. Ion exchange using strong base resins must therefore be followed by a more selective weak base SX purification step if pure yellow cake is required.

Jan 1, 1976

By E. G. King

In continuation of the study of thermodynamic properties of the common interoxidic compounds of ferroalloy elements, this report gives the results of low-termperature heat-capacity measurements and entropy evaluations of the monotungstates of sodium, magnesium, and calcium. Previous reports4 5/ of this laboratory dealt with low-temperature heat capacities, entropies, and heats of formation of the sodium vanadates. Heat-capacity measurements of the monotungstates of sodium, magnesium, and calcium (Na2W04, MgW04, and CaW04) were conducted throughout the temperature range 51° to 298° K. The entropies at 298° K. were evaluated and then combined with entropy data for the elements and oxides to obtain entropies of formation. This information is an essential part of the data needed for thermodynamic appraisals of chemical reactions of these substances. No similar data for any tungstate are to be found in the literature.

Jan 1, 1961

By W. J. Stickney

"Over-all recovery of cadmium has been increased at the plants of the Hudson Bay Mining and Smelting Co., Limited, since the construction of a slag fuming plant and baghouse where smelter flue dust is recovered. This pa-per outlines the distribution of the cadmium in plant products from the concentrator to the refining department.The leaching of cadmium-bearing precipitates from the zinc plant is also discussed. This consists of a two-stage leach; first with sulphuric acid and then with copper sulphate. Details of the leaches are outlined along with the safety measures practised in handling the hydrogen and arsine evolved.The paper describes the final preparation of electrolyte for the refining cells by purification for copper and thallium. Deposition of cadmium, using a polyacrylamide as an addition agent, is discussed.An outline is given of the melting procedures, under either sodium hydroxide or zinc chloride, and of the sub-sequent treatment of the dross to recover entrained cadmium and thallium."

Jan 1, 1966

By Yuan Zeping

This paper describes the distribution and removal of the main impurities in the pyrometallurgical process ?at the Guixi Smelter. The paper discusses in detail our converting schedule?of3S-SB and injecting deeply a mixture ofNa2CO) and CaO flux into the converters to enhance impurity removal.

Jan 1, 1998