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By J S. J van Deventer, D C. Shallcross

New developments are taking place in the recovery of gold from leached pulps that are based upon the adsorption of the metal cyanide species onto ion exchange resins. Despite the success of several resin-in-pulp pilot plant operations in the Western World and large-scale plants in the former Soviet Union, the process is yet to gain recognition as a viable alternative to the carbon-in-pulp process. An experimental research program has investigated the use of a variety of different types of resins for the recovery of gold, but to-date no resin studied has the desired properties of high selective loading capacity for gold cyanide and a simple inexpensive elution procedure. In addition very little is known concerning the physical strength of resins and their ability to resist shattering due to osmotic shock during cycles of adsorption and elution. The ability of ion exchange resins to enhance the leaching of refractory and re-adsorbing ores has not been investigated. This paper highlights the necessary factors that need to be addressed before commercialisation of ion exchange technology for gold extraction is feasible.

Jan 1, 1998

By Neville Rockhouse

This paper examines the interrelationship of conducting full risk assessments in the context of the coal mining industry and under the framework of the Health's Safety in Employment Act 1992. In the context of Occupational Health's Safety, Risk Management is a holistic management process that can be used by individuals working in all organisations and from all industries. The Australian New Zealand Standard 4360: 2004 defines a Risk as being; The chance of something happening that will have an impact on objectives. This definition is followed by several notes that include: a risk is often specified in terms of an event or circumstance and the consequences that may flow from it, risk is measured in terms of a combination of the consequences of an event and their likelihood, and risk may have a positive or negative impact. For the purposes of this paper, the above definition will be adopted. This paper examines the newly expanded approach of the fully documented risk management process in the New Zealand coal mining industry. This is done in the context of the coal mining regulations but more importantly by using the framework of the Health & Safety in Employment Act 1992. This legislation under Section 6 requires all employers to, Take all Practicable Steps to prevent harm coming to employees while at work and to others who might be at or in the vicinity of a workplace. When the term 'all practicable steps' is studied, one can clearly see that such steps should be the same steps taken that a prudent and reasonable person would have taken given the same type of circumstance. Due to the fact that in New Zealand parliament made statutes is administered by a Government Department, means that their breaches will be heard before a judge in the District Court. Under the Westminster System of Justice, a basic dictum of that court in matters relating the occupational health and safety is that a breach needs to be satisfied to a specific standard. That standard is, 'Beyond a reasonable Doubt'. One of the primary benefits of adopting a proactive approach to risk management is that if the industry were to adopt similar approaches, then this mythology could be seen as an industry standard. As such, the approach carries the same status in a court of law, as that of an Approved Code of Practice.

Jan 1, 2007

By Carsten Rühlemann, David Friedmann, Bernd Friedrich, Thomas Kuhn

"This paper explores the option of direct reduction smelting of the nodules from the German license area in the equatorial NE Pacific in a submerged arc furnace (SAF). An optimized slag design is proposed to separate the larger Mn-bearing stream from the valuable metals (i.e. Ni, Cu, Co, Mo). The slag optimization allows a maximum of Mn to be retained in the manganese-silicate slag on the one hand and a maximized metal recovery in a FeNiCuCo alloy on the other. This way, the goal is to make use of the complete nodules (“zero-waste”) instead of extracting only the metals Ni, Cu, and Co, which make up about 3 wt%. The process closely relates to the “Inco Process” by the Ocean Management Inc. (OMI) of the late 1970s, which was a consortium of INCO (International Nickel Company, CAN; today Vale Canada), Preussag AG & Metallgesellschaft AG (GER), DOMCO (JPN), and Sedco (USA). However, the manganese containing slag is investigated in more detail to recover FeMn, FeMnSi and/or SiMn. To optimize the process modern tools such as thermo-chemical modeling in FactSage™ have been used. [1,2]Polymetallic deep-sea manganese nodules may offer a decreased dependency of raw material imports for Germany and the EU. Currently, four European countries (United Kingdom, Belgium, Germany, and France and an Eastern European consortium (InterOcean Metal)) hold exploration licences for these nodules in international waters in the equatorial NE-Pacific. The license areas each cover 75 000 km2 of the seafloor and are located in the Clarion Clipperton Fracture Zone (CCZ) south east off Hawaii at water-depths between 4000 and 6000 m. The nodules may be used as a resource for industrially important metals such as Cu, Ni, Mn as well as for technology metals like Co, Mo, V and Zn. The average chemical composition of nodules from the German license area is presented in Table 1. [3,4]"

Jan 1, 2017

By L. Rintala, P. Latostenmaa, T. Kalliomäki, O. Forsén, I. Lehtiniemi, M. Lundström, J. Aromaa

Conductivity is a typical physico-chemical property that has a substantial effect on electrical energy consumption in the electrorefining process. The objective of this study was to examine the validity of regression models predicting the conductivity of industrial copper electrorefining electrolytes. The models were based on data measured with synthetic solutions on a laboratory scale. The variables included in the models were temperature and the concentrations of copper, nickel, arsenic and sulfuric acid. Both first-order and combined effects of the variables were investigated. The measured data were analyzed using MODDE 8.0 modeling and design software. The validity of the models was investigated by comparing the predicted values with tankhouse conductivity measurements taken at the Boliden Harjavalta Copper Refinery in Pori in Finland. During the tankhouse tests, the conductivity and temperature of the industrial electrolyte were measured, and the composition of the electrolyte was analyzed. The measured conductivity values were compared with the predicted conductivities calculated using the developed models. The conductivity model developed in this paper was shown to be more accurate than previous models and suitable for industrial use.

By Nicolas Reynier

The separation of radionuclide during rare earth element (REE) production is an important requirement for developing the Canadian REE mining industry. Separation of actinides from REE is often a large concern in the rare earth industry because of the need to manage the radioactive nuclides. A patented process developed for actinides extraction from radioactive wastes was applied to REE ore. Objectives were to optimize the process for REE leaching from ore, and separate radioactive impurities from sulphuric and nitric liquor by ion exchange (IX). Ore leaching was optimized using a surface response plan to ensure statistical significance. In optimized conditions, solubilization yields ranged from 90–95% for Th, 60–75% for U, 48–55% for LREE, and 59–75% for HREE in sulphuric and nitric media. Both media were compared for radionuclide removal from rich REE-bearing mineral liquor by IX. Actinides separation ranged from 92–97% for Th and 69–96% for U in sulphuric and nitric media.

By A. C. Johnson

This circular is one of a series published by the Bureau of Mines describing mining and beneficiation methods and costs at various mining operations throughout the United States. Inclusion of the Abbott mine in this series is of particular interest, as the complex geology and the character of the deposits make their exploitation a unique operation. The mine operates on a high-cost, comparatively small-scale basis, and only the persistence of an aggressive management has enabled it to maintain its rank among the major mercury producers of California. Rising costs and decreasing metal prices, which continuously threaten the low profit margin, are reflected in increased efficiency of operation. This report summarizes past operations and describes, in detail, the geology and ore deposits; exploration and mining methods; and furnacing and condensing operations. It covers the entire operation from initial exploration to the actual production of mercury. Comparative production costs for 1944 and 1958 are of special interest.

Jan 1, 1962

By T. T. Campbell

Although secondary recovery of lead and lead-tin alloys has been common practice in the United States during recent years, there is little published in-formation concerning recovery techniques. Available information does not cover metal recovery from wet dross skimmings. This investigation by the Bureau of Mines was undertaken to develop techniques that would allow lead-tin alloys to be recovered from wet dross skimmings containing large amounts of zinc chloride. A process was developed, on a laboratory scale, for recovering lead-tin alloys from wet solder dross skimmings. Straight water leaching, either with or without a second leaching operation carried out with a Na2C03 addition for removing chloride, produced a dross that could be smelted without further treatment. Overall recoveries averaging 92 percent of the metal values in the dross were obtained in the form of lead-tin alloys, which had an average tin content of 16 percent and lead content of 84 percent. The recovered alloy contained less than 0.02 percent zinc, as determined by both chemical and spectrographic analyses.

Jan 1, 1956

By Will H. Coghill

The jig men of the Tri-State (Joplin-Miami) zinc district complain about the flakiness of their mill feed. They believe that the flakiness of the composite grains of gangue and mineral are to blame for losses of zinc; that is, that the flaky grains in the jig tailings have higher zinc tenor than the cubical grains. Although the evidence which follows contradicts this belief, no effort is made to give a final and conclusive answer. On the other hand, there is outlined a positive and mechanical method which the operator may use to pursue this and similar investigations. DISCUSSION OF SCREENING METHOD Hand-sorting is obviously not satisfactory for separating cubical grains from flaky grains because the personal influence can not be removed. Screens, however, may be used with success. A set of each of two types of screens is required; namely, the square-hole type and the rectangular (rectang, oblong) type. The square-hole screens must be of the double Tyler scale; that is, the order of the sieves should be after the fourth root of two instead of the customary square root of two; close sizing is important. The size of the rectang screens may be selected by trials so that a part of the material already closely sized on the square-hole screens, will pass the oblong holes. Obviously, the cubical grains will remain on the rectang and the flaky grains will pass through. Hence the mode of operation is to screen first on square-hole screens and then split the products on the oblong-hole screens.

Jan 1, 1928

By G. V. S. Murthy

Beach Placer Ilmenite is an important source for production of titanium metal, titania slag and pigment grade titanium dioxide. Besides, these well known applications for which Ilmenite is mined and processed, there are other emerging processes that are being tried for obtaining highvalue products. Synthesis of Ilmenite based materials for varistor applications and direct electrochemical reduction of Ilmenite to produce ferrotitanium are two such attempts being discussed in this work. In this paper, recent efforts undertaken to study the electrical and magnetic characteristics are discussed. Ilmenite, FeTiO3, is one of the mixed-valence transition metalbearing minerals, inwhich Fe can be in two different oxidation states, Fe2+ and Fe3+.. Similarly, Ti can be in Ti3+ and Ti4+.Ilmenite is inherently suitable for making Varistors, which are devices, used for limiting the transient voltage surges in a circuit. Varistors produced from Ilmenite can withstand harsh environments seen in nuclear reactors and outerspace. Electrochemical reduction of Ilmenite can be used to prepare ferrotitanium directly without any reductant. The process essentially involves removal of oxygen from the mineral through electrolytic action using calcium chloride as electrolyte and graphite as anode. At a temperature of 950°C, it is shown to be possible that all the oxygen can be removed from the Ilmenite sample, which passes through the electrolyte, to form CO/CO2 at the anode. The process has immense potential for cost effective production of titanium metal as well. Results of the above developmental works are presented in this paper. Keywords: beach placer ileminite, varistor applications

Sep 1, 2012

By Zhiqian Zhang, Chao Wu, Chao Li, Hongxu Li, Chuanqi Jiao

"Many used electronic and optical products contain cerium of rare earth oxides, but it is difficult to recover such rare earth compounds by traditional metallurgy methods. The proposed supercritical water metallurgy is a novel way, perhaps it will be very helpful for rare element recycling, but the thermodynamic properties at such special systems is not clear. In the paper the H20-CeO-CeO2 and H2O-CeO2-Ce2O3 ternary system phase diagram were produced under the pressure of30MPa with different temperature of350°C, 375°C and 400°C. The stability existing area of possible cerium compounds and different ions like Ce2+,Ce3+,Ce4+,W,HO2-,0ff ,CeOH2+,CeO+ and CeO2· were determined.IntroductionCerium is an extensively used metal element playing an important role in the rare earth elements. CeO2 is an apparently simple binary oxide with cubic fluorite structure [l]. Ce0O gives rise to a range of important technological applications because of its oxygen storage capacity at moderate temperatures as below: CeO2=CeO2.x+ X/2O2 [2]. The oxygen storage phenomenon gives ceria important technological uses in different fields as automobile exhaust purification catalyst [3-4], fluorescent powder, ultraviolet absorption material [5], polishing powder, fuel cell materials [ 6], and gas sensors, etc. The excellent properties of CeO2 nano powder make its synthesis and preparation become one of the hot spots of world scientists study."

Jan 1, 2013

By Michel Dagbert

In the exploitation of porphyry-type deposits, the quality of the ore is mostly defined according to its grade. Besides the simplest distinction, ore-waste, several grade categories may exist and they correspond to the different ways in which the ore is further processed. At the time of mining the selection of the different categories is done from extensive information available from blast holes. But planning has to be done before this information is available and it is necessary for the geologist to forecast, from exploration and development data alone, the possible outcome of the selection done later on a block, a level, or the whole deposit and ultimately predict the ore reserves and value of the deposit. A good statement of this problem has been presented at the 1976 AIME annual meeting by Williamson and Hueller (1976). They have shown that, if the cut-off values are directly applied to the estimated grade of blocks, a gross overestimation of the recovered tonnage of ore (14%) will occur. This problem, now termed "the vanishing tons problem" (DaVid, 1977) seems to be common in many open-pit operations and it has been explained several times (DaVid, 1972; Huijbregts, 1975). In order to solve it l.Jilliamson and Mueller proposed a solution based on compiling masses and masses of blast hole data available from mined-out portions of the deposit. They derived empirical correction factors which provide for every block, given its estimated grade, the expected tonnage and average -grade of each category of material within that block. The purpose of our work is to repeat the same exercise but ignoring the blast holes data i.e. we want to derive the correction factors from the only DOH data. Doing this, we are more in the real conditions where the valuation of the mine and are reserve analysis has to be made before production actually starts. Two possible ways to achieve this goal will be investigated and the emphasis will be on recently

Jan 1, 1977

By Richard S. Kunter

Artech Recovery Systems, Inc has developed a low pressure and temperature? leach process called the "Cashman Process" to extract metals from arsenical flue dusts and residues and fix the arsenic in an environmentally stable form as ferric arsenate (scorodite). The process was pilot tested at Hazen Research in an integrated plant including continuous recycle from August 1989 to October 1989 during which several tons of flue dust were processed. Based on this pilot program, the process was deemed technically feasible and produced commercially salable products. Residues from this pilot program were subjected to a long-term stability test jointly designed by PTI environmental services and the USEPA. The process, its versatility, and the nature of the products is discussed in some detail.

Jan 1, 1992

By Norbert Asamer, Stefan Purrer

Depending on the product or the material grade, conventional deburring machines, such as e.g. with rotating hammers, are in many cases not capable to reliably or completely remove burrs from the edges of a continuously cast product. Burr, however, is generated at the front and/or tail ends of a slab, bloom or billet as a result from torch cutting. Likewise, traversal grinding of the slab’s rolling surfaces can also cause burr at the long side edges of the slab whereby such burr can even be more difficult to remove. Based on their experience and know-how with abrasive machining processes (abrasive cutting, high-pressure grinding) over a period of more than 50 years up to now, BRAUN has developed a highly flexible deburring grinding machine for applications which are too difficult for conventional deburring techniques. BRAUN’s deburring grinding machines were successfully introduced to the steel industry and have proven their worth under normal production conditions already. The subject paper describes the key features and advantages of BRAUN’s machine design and the operational results from the first already completed projects.

Oct 1, 2019

By Dwight L. Sawyer, Roy T. Sorensen

The Bureau of Mines has investigated the recovery of alumina by hydrochloric acid leaching of calcined kaolinitic clay . Bench- scale studies indicated that horizontal belt filtration was a pprraaccttiiccaall method for separating the siliceous residue from aluminum chloride liquor generated in the leaching step . Miniplant -scale continuous testing was performed to evaluate the filter circuits and to compare filtration response of different calcined kaolin feed materials and of different agitatorbaffle designs in the leaching reactors . Soluble alumina recovery with a single filter ranged from 94 pct with minus 10 -mesh feed more than 96 pct with minus 35-mesh or misted feed . Process advantages were confirmed for the calcined misted kaolin feed material prepared by a Bureau-developed misting process . With two filters in series , an overall filtration rate of 100 lb solids /hr.ft - 2 of filter area was attained with a soluble alumina recovery of more than 99 pct . More than 99.5 pct alumina recovery was obtained with a thickener and a two - filter circuit for either the minus 35-mesh or the misted feed . Modifications in leaching reactor design made to decrease particle- toparticle attrition were successful and significantly increased filtration rates and decreased flocculant requirements .

Jan 1, 1965

By Toshihiro Kuzuya

A hydro metallurgical process has been developed for the recovery of metal values such as Co, Ni and rare earths from the electrode materials of spent nickel metal-hydride(Ni-MH) secondary battery. MmNis_xCo. (Mm : Misch metal) intermetallic compound could be separated from the electrode materials mixture by sedimentation. A typical chemical composition of MmN5-xCox was approximately, in mass%, 56.0%Ni, 13.4%Ce, 10.6%La and 7.9%Co. The time dependency of leaching intermetallic compound with sulfuric acid solution was examined with processing factors such as sulfuric acid concentration, temperature and agitation intensity, The leaching of rare earth metals proceeded very rapidly, reaching completion in less than 1.8ks. On the other hand, the slow leaching of nickel was observed. The percent of nickel leached at 328K could only reach about 70%.

Jan 1, 2003

By D. J. Murdock

Cominco Ltd. has developed a number of innovative technologies for electrowinning. The paper discusses the application of these technologies to the copper industry. Tankhouse and cell design will be discussed in addition to anode cleaning and cathode handling. Specific examples of the application of this technology to the copper industry are cited.

Jan 1, 1987

By T. Miura, Y. Mori, H. Aoki

In a flash smelting furnace, easily combustible concentrate particles excessively oxidized and melt. The excessively oxidized molten particles then collide with less oxidized solid ones to create uniform oxidized molten particles. This collision phenomenon plays a very important role in achieving high smelting performance. The authors developed a mathematical model describing above combustion phenomena. This model incorporated fluid flow, heat and mass transfer, chemical reactions and collisions of concentrate particles. Both gas flow and particle motion were calculated using the Eulerian method. Copper concentrate was assumed to consist of chalcopyrite(CuFeS2). Considered in the concentrate reactions were the decomposition of CuFeS2, and the oxidation of the resulting sulfur(S) and pyrrhotite(FeS) to produce magnetite(Fe30 4) and sulfur dioxide(S02). Moreover a reaction due to concentrate particle collisions, in which Fe304 in the excessively oxidized molten particle reacts with FeS in the less oxidized particle, was also considered. The particle collisions were assumed to occur according to a collision probability rule obtained by computational experiments. Particle growth in diameter was described as a change in the volume fractions of particle phases. When applied to a commercial flash smelting furnace, this model reproduced the particle growth and component transfer as observed in the actual furnace.

Jan 1, 2007

By Corale L. Brierley

The effect of hydrogen peroxide (H2O2) on growth and respiration of Thiobacillus, thiooxidans, and Thiobacillus ferrooxidans, organisms involved in acid leaching of copper sulfide minerals and uranium oxides, was examined. Oxygen uptake and growth by T. thiooxidans were inhibited after contact with 0.82 mM H2O2. Inhibition of oxygen uptake by T. ferrooxidans occurred at 8.24 mM H2O2, and growth was inhibited after 6 hours exposure to 2.06 mM H2O2. Higher concentrations of H2O2 can be used without detriment to thiobacilli if it is dissipated prior to reaching the oxidation pond or dump surface. INTRODUCTION In recent years, hydrometallurgical processes for recovery of metal values from low-grade ore minerals have played an increasingly important role. Dump leaching of low-grade copper waste materials in the western United States now yields 11.5% of the total U. S. copper production. Although scavenger operations in uranium leaching have been successful, the state-of-the-art of in-situ

Jan 1, 1977

By NIM REPORTS

Notices CONFRRENCE ON COMPUTRRS IN ENGINEERING The above Conference, which is being organized by the Electrical and Electronics Board of the Institution of Engineer!!, Australia, ill to be held in Sydney on 16th and 17th May, 1974. It is being planned in conjunction with the Sixth Australian Computer Conference and will be held during the week immediately preceding the latter. NIM REPORTS Report No. 1495 A method for the determination of ekmental sulphur on the surface of sulphide minerals. Report No. 1500 The chromatographic separation and determination of nobk metals in matte-leach residues. Report No. 1505 The production of the refractory aluminium saicates, with special refererence to South Africa. Report No. 1517 Computer-controlled flotation plants in Canada and Finland. Report No. 1526 Heat of solution as a control of aqueous-ammonia concentration. Report No. 1529 South African costs of equipment for the metallurgical industry (197).

Jan 9, 1973

By X. Cao, R. Wang, H. Han, Y. Hu, Z. Wei, W. Sun, H. Tang, J. Wang

Flotation reagents play a vital role in mineral flotation. In the past century, most studies focused on the modification of anion or cation collectors and the synergistic effect of mixed collectors, which have contributed to research. In this study, we reviewed brand-new reagents, metal-organic/inorganic complexes, with the functional group of metal ion, which are totally different from the traditional anion or cation collector and show absolute specificity for some minerals. For example, Pb-BHA complex collector was developed to realise the atmospheric flotation of scheelite due to the absolute specificity for calcium minerals. Calcium oleate collector was found to be the effective species in the flotation of calcium minerals, and has been employed to selectively separate fluorite from calcite. Selective adsorption of Al-Na2SiO3 polymer on calcite surfaces proved the self-assembly of H2SiO3 polymer using Al3+ had stronger selectively adsorption ability than Na2SiO3. Also that Fe3+-starch complex was a better depressant for iron minerals than caustic starch and contributed to a more efficient reverse flotation. In conclusion, metal ions are good templates for molecular assembly and can be used to control the structure of metal complexes and exhibit special properties, which provide possibilities for the design of new flotation agents. Keywords: Metal-organic/inorganic; flotation; collector; depressant

Jan 1, 2020