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By Hideki Yamamoto, Shigeno Matsumoto, Junji Shibata

"Some fundamental studies were carried out in order to produce composite powders comprising of two or three metal oxides ~y using liquid-liquid extraction and to develop the control technology of the particle size. The combination of samarium and cobalt was selected as the two component composite powders. Both stripping and crystallization occurred at the same time by emulsifying the organic phase loading the two metals extracted with Versatic Acid 10 and the aqueous solution containing oxalic acid. The effect of aqueous pH, oxalic acid concentration and agitation speed was examined on some properties such as crystallization percent, particle size and shape of each metal oxide powders obtained in this process. The analysis by using EDX showed that the two metal oxides were distributed uniformly.IntroductionComposite metal and metal oxide powders with high purity are indispensable as industrial materials in the fields of electrical engineering, electronics and metallurgy. It is difficult to mix metal powders or metal oxide powders uniformly for the production of alloy powders. If insoluble metal salts are allowed to collect as crystallization products in the crystallization-stripping process, the conventional melting and crushing process can be avoided. After mixing of the organic phase containing metals in fixed composition, fine metal and metal oxide powders of alloy composition are produced by using a crystallization-stripping method. Versatic Acid 10 and D2EHPA, both acidic extractants, were chosen in this experiment, and the metal oxide powders were produced by using oxalic acid as a crystallization reagent. Mixed metal oxalates containing samarium and cobalt were precipitated from the mixed organic phase containing these metals. Furthermore, the physical properties of the powders, such as particle size, shape and thermal decomposition, were measured in order to evaluate them for industrial purposes."

Jan 1, 2000

By Lawrence Pelham

The demand or consumption of fluorspar has been somewhat taken for granted in recent years, except for the specific interest of those that produce, market, and/or consume the commodity. A tradition was established of thinking that as the steel and aluminum industry goes, so goes fluorspar. This is much less true today than in the past. The industry is becoming more dependent on chemical industries that feed primarily off hydrofluoric acid (HF) production. The Bureau of Mines recently published an assessment of world fluorspar reserves and resources that created a foundation of valuable data that can be used to monitor fluorspar availability. Celebrations were held this year commemorating the 100th anniversary of the isolation of fluorine. The United States and other countries continue to struggle with the controversy of ozone depletion and the effect of fluorocarbons on the atmosphere. The goals for the U.S. Government's strategic stockpile are being reevaluated. The market for fluorine chemicals is changing and diversifying, making it a challenge to assess and forecast fluorspar/fluorine demand. This paper reviews the recent past of fluorspar and helps set the stage for a more detailed assessment of this critical commodity.

Jan 1, 1986

By T. R. Madhavan

The development of contact angles on highly polished ?uraninite surfaces, using sodium oleate and dodecyl ammonium acetate as collectors, has been studied at different collector and hydrogen ion concentrations. It was found that sodium oleate in acidic media (up to a neutral: PH) and dodecyl ammonium acetate in neutral and alkaline media give good contact angles. It appears that the combined forms of these collectors, viz., oleic acid and free amine, are more important in effecting contact. W ITH the emergence of uranium as a strategic metal in the last fifteen years, considerable effort has been directed toward the commercial recovery of uranium from its ores. This has resulted in the development of a uranium technology. It is only in recent years, However, that fundamental data regarding the floatability and surface properties of uraninite and ?pitchblende have been elucidated by different methods. Contact-angle measurement is one of the important tools for tl1e evaluation of the conditions of floatability

Jan 1, 1964

By Patterson J. H

An infra-red absorption study has been made of crocidolite, country rock. and associated host rocks from Wittenoom Gorge. The spectrum of the country rock is appreciably different from those of crocidolite and the magnetite-rich host rocks which are closely similar. A process to separate crocidolite-bearing ore from country rock based on infra-red emission is therefore possible in theory.

Jan 1, 1966

By Steve Kral

Commodity price down cycles are a fact of life in the mining industry. And companies pre-pare for them as best they can. Evenso, operations are still curtailed or closed during those cycles, profits shrink, layoffs are inevitable and many companies do not survive. However, one of the few good things that occurs during down cycles is the new, innovative exploration, mining and processing technologies that come about during hard times. To survive the lean times, the mining industry turns to improved technology to decrease costs and hold the bottom line. And, because mining is a cyclical business, each down cycle brings about technology improvements that carry over into the good times.

Jan 1, 2004

By D. Tao, R. Honakey, B. K. Parekh

The dewatering of stable phosphatic clay suspensions generated from phosphate beneficiation in the central Florida is an issue of practical and theoretical importance. Because of its tiny particle size and surface charge, the phosphatic clay takes up to 20-30 years to settle in water and causes environmental, aesthetic, economic, and handling problems. An efficient and cost-effective dewatering/consolidation process for phosphatic clay is of great interest to the phosphate industry in Florida. In this paper, the consolidation and dewatering behavior of phosphatic clay was studied by use of anionic flocculants with and without sand addition. The effects of pH, initial polymer concentration, polymer dosage, polymer addition steps, and metal cations (K+, Ca2+, and Al3+) on the flocculation of phosphatic clay have been studied. Experimental results indicated that clay suspensions were well flocculated at pH 10.5 by DPW-1-1355 and Magnafloc 5250 flocculants acquired from Ciba Specialty Chemicals. Sand particles from phosphate flotation added to the clay slurry promoted flocculation and increased clay consolidation. K+ showed good performance to improve the flocculation characteristics by neutralizing clay surface charge. The adsorption mechanisms of flocculants on clay particles were also discussed in this paper.

Jan 1, 2006

By Jesus P. Manzano

The report of which this paper is a summary was made in 1890 for the Compania Investigadora Mexicana y Americana. Since the region examined covers 900 sq. kilom., chiefly of wooded arid rocky hills, almost without roads, and for the most part uninhabited, While the examination had to be made in two months, of which period more than 15 days were continuously rainy, I need not say that this account is not complete and thorough. I. Geography and Topography. The center of this zone, 19 kilom. SW. of San Luis Potosi, is situated in lat. 21° 24' N., and long. 2° 3' W. of Mexico City. The altitude ranges from 1866 m. (that of San Luis) to . 2816 m. (that of the Realito mountain), in the Sierra de Sail Luis. The topography is hilly—partly wooded, partly bare. The principal more level areas are the Bledos valley on the south, and portions of the haciendas of Tepetates, San Fran cisco and Santiago, on the west. The water-supply is scanty. The two streams that cross the Zone, the Santiago and Bledos rivers, carry water nearly the year through, though much reduced in the dry season. Other streams are torrents of less importance. All the waters of the valley and Sierra of Sail Luis arc absorbed or sink, not passing beyond Soledad de los Ranchos. The Continental di vide is within the Zone, some waters going west to the Pacific, others east to the Gulf of Mexico. II. Geology. Concerning the geology of this district I condense the fol lowing from the memoir, Las Minas de Guanajuato, prepared for the Minister of Fomento by Senor Pedro Lopez Monroy, mining engineer, with which I am entirely in accord. He says, ill substance:

Jan 1, 1902

By Y. X. Zhao

This paper briefly describes the characteristics and induced factors of coal mining bumps based on the investigation of recent bumps accidents occurred in China. According to the theory of non-equilibrium thermodynamic and dissipate structure, the process of strain energy accumulation and dissipation in the ?Coal-Surrounding Rock? system (CSRS) is discussed during the preparation of coal bumps. In addition, a series of experiments are conducted to analyze the relationship between bump-prone property and micro-structural characteristics of coal. The process of coal bumps induced by propagation of fractures and deterioration of coal mass properties are also analyzed systematically.

May 1, 2009

By B. Samoski

In late 1994, EPA and OSM acknowledged that efforts by any one agency or by the many different agencies to remedy the water quality impacts of decades of contamination from abandoned coal mine lands in Appalachia would not be successful if their disjointed efforts were not unified and if the local watershed organizations were not included. The result of the collaboration between EPA and OSM was the creation of a statement of mutual intent which was a pledge by government agencies, watershed organizations, and the industry to restore watersheds degraded by acid mine drainage from abandoned coal. The presenter will describe the evolution of this pledge from a paper promise to on-the-ground remediation projects.

Jan 1, 2002

By R. L. Grayson, L. L. Probert

"A three-year project focusing on the depth profiling of respirable coal mine dust particles using scanning electron microscopy coupled with energy dispersive X-ray analysis resulted in the development of statistically classified particle-behavior models. The models depict the changing silicon fraction for particles at 5-, 7-, 9-, and 11-keV accelerating voltages, thereby giving a clear indication of the nature of various types of mineral particles. This paper focuses on the results for respirable quartz particles sampled from five underground coal mines across the US. Through statistical analysis of results the relationship between the fraction of surface available quartz in respirable dust samples and coal rank is established for three Pennsylvania coal seams. IntroductionThis is the last in a series of papers detailing the results of SEM/EDX-based analyses of respirable coal mine dust particles collected from field sampling. Previous papers have detailed preliminary results and the statistical validity of the methodology (Grayson, Andre, and Simonyi, 1990; Grayson, 1991). This paper presents the final results of the analysis of respirable dusts from five coal seams with a range of coal rank:• Lykens Valley seam (anthracite), eastern Pennsylvania• Brookville (A) seam (mid-vol bituminous), central Pennsylvania• Pittsburgh seam (high-vol B bituminous), western Pennsylvania• No. 6 seam (high-vol C bituminous), Illinois• Wadge seam (sub-bituminous A), ColoradoSEM/EDX-based techniques were applied to try to clarify the role of quartz as an etiologic agent in coal workers' pneumoconiosis (CWP). It was hypothesized that previous studies were hampered by the restrictions of bulk analysis techniques and that particle-level analyses were needed to answer a number of questions concerning the role of quartz in CWP and its progression.Since 1985, a large number of the respirable dust samples submitted to MSHA are analyzed for free silica (Tomb, Parobeck, and Gero, 1986). Our reasearch shows that conventional bulk analysis techniques may not give a true indication of the biologically available, or active, quartz in mine dusts. Analytical evidence indicates that respirable dust samples may contain many quartz particles that are occluded, or coated, resulting in a bulk analysis for ""free silica"" that may not be indicative of the biologically available quartz surface."

Dec 1, 1996

Mine rehabilitation is a sustainability issue that has been revisited ad infinitum; however, the persistent lack of demonstrated on-the-ground performance and an increasingly intractable rehabilitation liability in Queensland continue to erode the credibility of the mining industry and regulatory bodies. For at least ten years the need to change the current, process-based approach to rehabilitation to an outcomes-based approach has been apparent. The ISO 14001 series temporarily diverted attention from this important point, however it would appear the limitations of an ISO 14001 approach are now more widely accepted. It is proposed that a successful outcomes-based approach cannot be achieved without meaningful community engagement. The apparently intractable nature of the rehabilitation issue will continue to generate conflict and criticism unless all stakeholders are encouraged to participate in the process of developing robust and practical outcomes for rehabilitation. Sharing the responsibility will ensure the best possible outcome. It is important to recognise the valuable resources inherent in community groups, many of whose committed volunteers have considerable expertise in relevant areas. Community groups should not be seen as adversaries but as allies in the process of solving problems that affect the wider community. Several projects that can be seen as test cases for the engagement of stakeholders exist, and in this paper the process of achieving multiple stakeholder engagement in the context of Environmentally Sustainable Development is discussed.

Jan 1, 2002

By Paul E. Lamoureux

Introduction The Author As the pail of smoke and wartime destruction gradually rises from the surface of the earth, from all countries, statesmen assemble to discuss and prepare pacts and treaties which are designed to, once more, bring people of all nations to understand each other and live in harmony. Scientists and engineers throughout the world are also undergoing a drastic reconversion in their ideas and objectives. No longer do they think only in terms of destruction and twist their brains to develop more devastating weapons or to surpass production records of war machinery. They have turned their eyes and ambitions to more pleasant tasks and are taking stock of wartime developments in materials, fabricating procedures, and equipment, many of which had been carefully shrouded with a veil of secrecy, and are applying their new knowledge to the fabrication or improvement of the tools of peace. The next few years will see the gradual elimination of scores of substitutes and makeshifts, expedients which the constantly changing law of supply and demand' under wartime stress necessitated. The universal search for satisfactory substitutes, however, has resulted in a general awakening of plant engineers to the possibilities of materials with which they were relatively inexperienced, with the result that, in many instances, what was considered a substitution at the outset turned out to be more satisfactory than the original material, and, in reality, can be considered a worthwhile development. Not only have materials been explored, but existing fabricating processes have been reviewed, and others, built around the properties and characteristics of new materials, created.

Jan 1, 1947

By Roland B. Hoag, Roger G. Webber

Sulphate concentration in groundwater is a good measure of the extent of oxidation of sulphides, provided that sulphide minerals are the primary source of the sulphate. A study was conducted near the Eustis Mine in Quebec to determine where and how the sulphate in groundwaters originated. Atmospheric precipitation is the only source of sulphate other than oxidation of sulphides, and in this study area it is equal to 0.01,. millimole per litre. The oxidation of sulphides can be divided into subsurface oxidation (mainly inorganic processes) and surface oxidation (including both organic and inorganic processes) . The maximum sulphate concentration due to subsurface oxidation of sulphides depends on the solubility of 0 2 in water and is 0.25 millimole per litre. Surface oxidation is, therefore, responsible for any amount greater than atmospheric plus subsurface contributions (0.29 millimole per litre). Surface inorganic oxidation occurs in waters with a pH greater than 15 and is controlled by the kinetics of the oxidation processes. Organic (bacterial) surface oxidation is dominant only in acid (pH< 1.5) waters. The bacterial action accelerates the oxidation of sulphides, and large quanttties of sulphate may be introduced into solution.

Jan 1, 1976

By Gerry Doeksen

The paper deals with three case studies: (a) the handling of wet concentrates (5 to 8 per cent moisture) through feed bins; (b) the handling of the same product in rail cars; and (c) the handling of dry concentrates (less than 0.5 per cent moisture) through feed bins. In each case, the paper discusses the problems of rat-holing. In each of cases (a) and (c), there is a discussion on the consequent extreme variations of feed rates coming from the feeders, making automation of process control difficult to impossible. Currently available bin-flow theory and flow property tests are used as aids in redesigning the bins. The paper concludes with illustrations of the final results after the redesigned hoppers were installed and tested. There is also a discussion on the advantages of the new mass-flow bins on adjacent feeder performance.

Jan 1, 1970

By R. Hurman Eric

Within the Ag-Pb-S ternary system, the boundaries of the immiscibility region together with the tie-line distributions were re-established at 925°C by the equilibrium-quenching technique where samples were kept in evacuated and sealed silica capsules. Activities of Pb were measured by the dew-point method along the Ag-Pb binary at 925°C, 1100° and 1200°C. positive deviations were observed and the results were modeled by the Krupkowski formalism. Activities of Ag, Pb, and S, along the ternary miscibility gap were calculated at 925°C by utilizing the boundaries binary thermodynamics, phase equilibria and tie-lines. Activities of PbS within the pseudobinary Ag2S-PbS mattes were also measured by the dew-point technique and the results were again modeled by the Krupkowski formation Where negative deviations were observed.

Jan 1, 2003

By Y. M. Jubeli

"Abstract - Gamma-ray spectrometry, an effective tool in geological mapping, was used to define boundaries between various lithological formations in three adjacent areas of Central Syria, namely, the Syrian Desert, Ar Rassafeh Badiayat and the Northern Palmyrides mountains. This paper describes the role of an airborne gamma spectrometric survey which was orginally undertaken to assist uranium exploration. Interpretation of the total count data obtained through the survey has led to significant modifications and corrections to the previously published distribution map of the palaeogene phosphate rocks.Another important result of the survey is the discovery of four previously unknown phosphorite horizons in the Rasm Al-Aawabed area of the Northern Palmyrides. In addition, previously unknown phosphatic horizons are outlined in the other study areas. The importance of this technique as an effective prospecting method, not only for U but also for exploring for the economically important phosphorite formations in Syria, is emphasized. Furthermore, its role in geological mapping is stressed, especially in areas that lack sufficient geological data."

Jan 1, 1997

By H. Blaha, H. Wagner

"Room and pillar workings in salt mines are preferred sites for underground waste disposal. A critical issue in selecting waste disposal sites is long-term behaviour of such workings. The long-term behaviour of salt pillars is controlled by the pillar geometry, i.e. the height, width and length of pillars and the level of pillar stress. The latter has a strong influence on creep characteristics of salt pillars whereas the width to height ratio of salt pillars determines the strength of pillars and the deformation characteristics of salt pillars.Three different regimes of pillar creep behaviour of salt pillars can be distinguished, namely a stress level below which the rate of creep approaches a value of zero, a stress range where the rate of creep is constant and finally a stress level above which the rate of creep accelerates. Long-term stability of room and pillar workings can be assured only when the pillar stress level falls within the first stress regime. Strength and creep tests on model salt pillars have shown that at stress levels below 40% of pillar strength the rate of creep approaches a value of zero, between stress levels of 40% and 65% the rate of creep is constant but increases with stress level. Above pillar stress levels of 65% the rate of creep accelerates.Long-term measurements of pillar deformation and surface subsidence above relatively shallow room and pillar workings in salt mines have confirmed these observations. Long-term strength of salt was found that be between 60% and 65% of short term strength. The evaluation of salt pillar behaviour on the basis of critical pillar stress levels was found to be superior to the traditional factor of safety concept because it allows relating pillar deformation measurements to actual pillar conditions. The approach described in the paper was used successfully to evaluate the stability of room and pillar workings in a salt mine and to design strategies to stabilise critical pillar workings."

Jan 1, 2015

By M. D. Everell

Le Centre de Recherches minérales (CRM), qui est un organisme de recherche appliquée du ministère de l&apos;Energie et des Ressources du Québec, a été créé en 1969, dans le but de procurer un support scientifique et technique à l&apos;industrie dans le domaine des mines et de la métallurgie. Pour atteindre ses objectifs, le CRM met à la disposition de l&apos;industrie un personnel spécialisé et compétent dont une quarantaine d&apos;ingénieurs et de scientifiques. Etant donné la nature même de l&apos;industrie minérale, ce personnel est très versé dans l&apos;étude des problèmes diversifiés des domaines de la technologie minière, du traitement des minerais, de la métallurgie extractive et de l&apos;analyse minérale. Ce Centre de recherches met également à la disposition de l&apos;industrie une usine-pilote permettant de reproduire les résultats du laboratoire au moyen d&apos;un appareillage de type industriel, d&apos;obtenir des échantillons en quantité suffisante pour une exploration du marché et de familiariser du personnel avec les opérations normales de l&apos;industrie. Certaines de ses contributions récentes au développement de l&apos;industrie minérale du Québec seront présentées.

Jan 1, 1985

By Ertugrul Alp

Alp & Associates - Who We Are ?? Canadian consulting company (1999-?) ?? Principal Consultant: Dr. Ertugrul Alp, P.Eng. ?? Over twenty-five years experience serving the chemical, mining, pulp & paper, energy, steel, and transportation industries, and government clients. ?? Ph.D. in Mechanical Engineering, University of Waterloo ?? Experience: ?? Westinghouse Canada, Atomic Power Division, Manager, Analysis and Modelling ?? Concord Environmental (later Bovar Environmental), Principal, Manager, Air Quality and Risk Assessment ?? Arthur D. Little, Associate Director, Safety & Risk Practice Leader in Canada ?? Member: NATO CCMS Pilot Project on Disaster Preparedness (1991-1993) ?? Chair: MIACC Risk Assessment Expert Committee, 1995-1999 ?? Member: MIACC Committees on Land Use Planning and Pipelines (1993-1998) ?? Member: CSA/Q850 Risk Management Standard Technical Committee ?? Member: CSA/Z1002 OHS Risk Assessment Standard Technical Committee ?? Member: CCPA/CSChE Process Safety Management Committee (1999-?) ?? Member: ISO-31000 Risk Management Standard Canadian Advisory Committee ?? Chair: CSChE Process Safety Management Committee (2005-2006) ?? Chair: CSChE Expert Committee on Risk Assessment (1999-2005) ?? CSChE 2007 Process Safety Management Award

May 1, 2008

By Michael J. Brown

It is often necessary to undertake some form of pile testing to verify design calculations. Historically this has been limited to static and dynamic tests. Newer rapid testing methods such as Statnamic are seeing more frequent use. This form of testing can be advantageous due to short set up time and test duration. Although the methodology suffers from a lack of formalised guidance and may prove difficult to analyse in certain soil conditions. This paper investigates the suitability of Statnamic testing and analysis for a range of soil and pile types as well as different installation methods through a number of case studies undertaken in the UK. Recommendations are made on test specification and analysis.

Jan 1, 2006