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By Aleksandar N. Nikoloski, Rorie Gilligan

Brannerite, UTi2O6, is the most common of the refractory uranium minerals and requires leaching under intense conditions to effectively extract the uranium contained within. Brannerite is often found together with apatite in metasomatic uranium deposits. Apatite and other phosphate gangue minerals can inhibit uranium leaching by generating phosphate ions which interfere with the reactions between acidic ferric sulphate and uranium minerals. As part of a detailed fundamental study on the leaching reaction mechanisms for brannerite, tests under a range of selected leach conditions were carried out with the addition of 10 g/L fluorapatite with the goal of identifying conditions where the negative effects of phosphate are reduced. Leaching was carried out for 5 hours with 0.05 mol/L Fe3+ as Fe2(SO4)3 with 0.25–1.00 mol/L H2SO4 and at temperatures between 25 and 96 °C. A single test was performed with 0.05 mol/L Fe3+ as FeCl3 and 1.00 mol/L HCl. In the sulphate system, the effect of phosphate was weakest at the highest acid concentration (1.00 mol/L H2SO4). In the chloride system, phosphate did not suppress uranium extraction, suggesting that HCl leaching could be a viable alternative for the leaching of high-phosphate refractory uranium ores.

Mar 17, 2021

By Kal V. S. Sastry

Conventional iron ore balling circuits exhibit undesirable surging behavior which is known to result from uncontrolled occurrence of the mechanisms of nucleation, coalescence and layering. This study was undertaken to investigate the mechanism of pellet growth by layering. Several laboratory experiments have been carried out to delineate the effect of feed moisture content and feed quantity. This paper presents an analysis of the experimental results and a simple model to describe the layering process.

Jan 1, 1993

By T. T. Chen

Hydrometallurgical products are difficult to characterize because of their fine grain sizes, heterogeneity, often amorphous structures and water soluble or hydrated constituents. Such products are advantageously studied using complementary mineralogical techniques including >50, ore microscopy, SEM-EDX, electron microprobe analysis, selective leaching and wet chemical analysis to determine the phases and their morphologies, to identify specific element carriers, and to elucidate the chemical reactions occurring during the metallurgical process. Sample preparation is an important consideration for these materials. For extremely fine-grained particles, or soft and brittle products such as elemental sulphur, the study of loose powder mounts provides information not available from the examination of polished sections. To demonstrate the application of the various mineralogical techniques, commercial zinc roaster calcines and leach residues, copper refinery anodes and anode slimes, and laboratory bornite leach residues were examined in detail. The various sample preparation and mineralogical methods are presented, and the use of these complementary and practical mineralogical techniques to improve the understanding of a particular hydrometallurgical system is discussed.

Jan 1, 1989

By Masayuki Kudoh, Tohru Maruyama, Yohichi. Ito

When hypo-peritectic carbon steel is quenched during unidirectional solidification, the region of fine columnar grain is observed. It is classified into two coexisting phases. One is coexisting phases of liquid, delta and gamma in the upper part of the region, and the other is coexisting phases of delta and gamma in the lower part of the region. To form the coexisting part of the three phases means that solidification in this experiment proceeds in non-equilibrium state. The size of the narrow side of one fine columnar grain coincides with the arm spacing of a primary dendrite and this result is the same as the hyper-peritectic carbon steel. However, the boundary of the fine grain in the hypo-peritectic carbon steel is formed in different location from that of the hyper-peritectic carbon steel. The former is formed in the skeleton of the dendrite, while the latter is formed in the interspacing of the dendrite. The region of the fine grain changes suddenly to that of the coarse grain when the delta phase in the coexisting part of two phases disappears completely. Therefore, the delta phase in the hypo-peritectic carbon steel might prevent the growth of gamma grain. In order to recognize it, ferrite formers such as Mo, V and Ni are added in the sample. Then, the longitudinal length of the fine columnar grain extends in the sequence of the no addition, Mo, V and Nb.

Jan 1, 2000

By Sanja Miskovic, Manjunath Basavarajappa

In this study, a coupled CFD-DEM (Computational Fluid Dynamics-Discrete Element Method) approach is used to simulate two-phase, solid-liquid flow within the flotation cell. Turbulence plays a key role in flotation cells and level of turbulence is affected locally by the presence of particles. Turbulence in the flow is modelled using Reynolds Averaged Navier-Stokes (RANS) based k-e model. Using particle transport and spatial distribution, mixing mechanism for differed sized particles are analysed. By including the effects of particle-particle collision, particle rotation, and particle translation, as well as the volume occupied by the particles in the fluid, CFD-DEM approach can be used to accurately predict the motion of particles in the turbulent solid-liquid flows with strong coupling. Electrical resistance tomography (ERT) is used to investigate the effect of impeller size, shape, off-bottom clearance and impeller speed on mixing and suspension behaviour inside flotation cell. The effect of flotation impeller design, impeller size, and off-bottom clearance on flow hydrodynamics is investigated. In the case of moderate and high solids loading (> 10 %w/w), energy is dissipated through inter-particle interactions and four-way coupling becomes important (Derksen 2003). The main goal of this study is to understand the effect of particle size and concentration on flow dynamics at high Re in highly turbulent systems using advanced modelling and measurement techniques. Experimental measurements obtained by ERT) system allowed detailed mapping of temporal hold-up profiles of the dispersed phase. Impeller size and off-bottom clearance are found have significant effect on the particle suspension characteristics.

Jan 1, 2014

By R. C. Philp, Allan Gibb

INTRODUCTION. THE term matte is applied to smelting-products so extremely diverse in composition and physical properties that it appears impossible to devise any generic formula to represent, chemically, the manner in which the varied proportions of the almost unlimited possible constituents combine with each other. Mattes produced in copper-smelting, in distinction from those produced in smelting-operations in which the recovery of copper is secondary to that of other metals, cover a narrower range in composition. The copper-content of such mattes vary from 20 to 80 per cent., and even this range is much smaller in general practice since it is found advantageous, when possible, to produce mattes with about. 50 per cent. of copper in the first operation. Further, it is unusual that arsenic or antimony occurs in copper-ores in sufficient proportions to form arsenides or antimonides in such quantities that they will separate out from the furnace-products, as is common in lead-smelting. Generally, the mattes produced in copper-smelting are composed mainly of copper (usually greater than 35 per cent.), iron and sulphur, the remaining elements being usually in proportions sufficiently small to allow of their treatment as impurities, rather than as essential constituents of the mattes. In modern practice of smelting copper-ores in blast-furnaces the tendency is to approach pyritic smelting as nearly as pos¬sible, the furnaces being low and the air supplied being largely in excess of that required for complete combustion of the carbonaceous fuel. Hence the atmosphere of the blast-furnace thus used is usually oxidizing or Dearly neutral? and, as a consequence, the reduction of metallic iron that was a necessary evil of former practice is of unusual occurrence in operations where the main object is the recovery of copper. Hearth-accre-

Nov 1, 1905

The steam-filtration process for dewatering solids involves the application of slightly superheated steam to a filter cake during filtration. The mechanism by which the technique promotes water removal has been deduced from bench-scale experiments on coal and on granular iron ore concentrates. The mechanism, along with some of the applications and limitations of the process, is presented. Introduction I N the steam-filtration process, slightly super-heated steam is applied to the filter cake during filtration to remove more water than can be extracted by conventional filtration. Although this process was developed by Burton for coal filtration (1), it should have far wider applicability; certainly, it could be used to treat any mineral product, because only low-temperature steam is needed and most conventional filtration equipment can be easily adapted to it. As few restrictions apply to this process, however, it is important that its more obvious advantages and disadvantages be appreciated and, especially, that the criteria on which economic evaluations can be based are understood.

Jan 1, 1965

By L. F. Christianson

The presence of salt in crude petroleum has been known for many years, but recently the percentage of chloride salts of calcium, magnesium, and sodium produced with some crude oils has increased to such an extent that the removal of the salty compounds is imperative for some refiners and their presence causes considerable apprehension for others. The exact reason for this increase of salts is not known definitely, but in all probability a combination of factors contributes to the condition. The most important are acidizing of wells, development of new fields producing crude oils of greater salt content, and the depletion of old fields with an attending increase in the production of emulsified brine. Due to handling

Jan 1, 1938

By L. F. Christianson

The presence of salt in crude petroleum has been known for many years, but recently the percentage of chloride salts of calcium, magnesium, and sodium produced with some crude oils has increased to such an extent that the removal of the salty compounds is imperative for some refiners and their presence causes considerable apprehension for others. The exact reason for this increase of salts is not known definitely, but in all probability a combination of factors contributes to the condition. The most important are acidizing of wells, development of new fields producing crude oils of greater salt content, and the depletion of old fields with an attending increase in the production of emulsified brine. Due to handling

Jan 1, 1938

By Grano S. R, Ralston J

It is the perennial problem most metallurgists face when examining data collected from laboratory float tests and plant surveys - there are more numbers than we know what to do with! The objective of this paper is to analyse and interpret a set

Jan 1, 1994

By S Bouzalakos, W Timms, H Malli

Combining ultramafic mine tailings and acidic mine drainage via mineral carbonation to sequester carbon dioxide, presents an opportunity to minimise waste on mine sites. Low pH mine water with trace element concentrations can be effectively treated by high magnesium mine tailings, a useful source of finely ground reactive matrix. By using milled tailings for mineral carbonation, there are negligible energy requirements for communition of ore rocks to reduce particle size. This study aimed to assess the technical applicability of reacting ultramafic tailings and acidic mine water through mineral carbonation technology in the mining industry. Dissolution has been identified as the rate limiting stage in mineral carbonation; hence the study focused on identifying optimal dissolution conditions. Ultramafic tailings (particle size <100 µm) derived from serpentinite ore, were reacted with a typical mine water that was synthesised in the laboratory. Through variances in the solid to liquid ratios and temperature of dissolution, a maximum five per cent magnesium dissolution efficiency was reached at 50 g/L and 100°C. The acidic mine water was neutralised (from pH <2 to pH ~6) and iron, copper and zinc ion concentrations reduced significantly during the formation of solid precipitates. Carbonation was undertaken by injecting carbon dioxide into the magnesium-rich solution to form stable carbonates. The experimental work demonstrated proof of concept; however, dissolution efficiency and carbon dioxide sequestration was low, indicating that further research would be required before larger scale implementation.CITATION:Malli, H, Bouzalakos, S and Timms, W, 2015. Ultramafic mine tailings to treat acidic mine water and lock away carbon through mineral carbonation, in Proceedings Tailings and Mine Waste Management for the 21st Century , pp 133–136 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

By E. Isokangas

The production of minerals for economic use is a two-stage process, involving mining to extract the mineral from the ground, and processing to convert the mineral into a marketable product. Generally, mining and processing have been viewed as self-contained entities. Both have separate objectives, separate cost centres and key performance indicators (KPIs) that do not reflect the customer/supplier relationships that inherently exist. However, mining and processing operations are inter-connected and therefore intimately inter-related with the performance of one operation affecting the performance of another. Optimizing each stage separately without considering the whole system often misses potential economic benefits and energy savings. During the past fifteen years, the authors have been involved in implementing a holistic methodology ?Mine to Mill Process Integration and Optimisation (Mine to Mill PIO)? to maximize the overall profitability of the operation rather than just optimizing any individual process in a mining operation. Metso Process Technology and Innovation (PTI), along with their project partners, have conducted several projects to significantly increase their production- generating typically 5% to 20% higher throughput and improve the overall mine and concentrator performance through PIO methodology. This proven methodology has applications ranging from greenfield projects to long-standing operations with AG/SAG, HPGR or conventional grinding circuits. This paper explains the Mine to Mill PIO methodology and discusses the benefits of such an approach on the energy consumption, the overall costs and benefits of mining operations. The paper also summarizes several case studies illustrating the use of PTI methodology in a variety of applications. Keywords: integration, optimization, simulation, modeling, mine-to-mill, comminution, blast, drill, crushing, grinding

Sep 1, 2012

By W Mahoney, F Clement, E Saraiva

Prefabricated waterproofing sheet membranes are extremely complicated to install in underground sections with complex geometries and, despite being already subjected to quality tests in the factory, the installed membrane often exhibits leakages due to different reasons. Main sources of leaks are the required high amount of welding seams and damages caused during installation of reinforcement, as well as overstretching and poorly installed secondary concrete linings. Also the design of the tunnel lining is strongly influenced and limited by the use of prefabricated waterproofing sheet membranes. The use of sprayed waterproofing membranes for more than a decade has contributed to durability and serviceability, as well as to increasing sustainability of tunnel linings. The presented sprayed waterproofing membrane MasterSeal 345 is an advantageous alternative to prefabricated waterproofing sheet membranes under typical tunnelling conditions, especially in geometrically complex areas, such as in lay-by niches, cross passages and crossover caverns, where installation of conventional waterproofing membranes is inherently difficult, and locating leaks is challenging. This membrane has been successfully used in underground projects with different waterproofing design concepts and under diverse hydro-geological and environmental conditions for over a decade. It provides tunnel designers with different options and optimisation for the design of the tunnel concrete lining. Additional advantages to owners, contractors and designers from the use of the sprayed membrane include flexibility in the design, increased productivity and flexibility in working programming, as well as improved logistics, resulting in significant program and cost savings and reduced long-term maintenance costs. This paper describes the key features of this sprayed waterproofing membrane, its application range and limitations, the waterproofing concept, design options and related benefits. Further, guidance for membrane application and quality control and a summary of two recent project references in the United Kingdom and in Switzerland are provided.CITATION:Saraiva, E, Clement, F and Mahoney, W, 2014. The use of sprayable waterproofing membranes in underground structures – concept, design options, benefits and limitations, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 323–332 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By P D. "Takis" Katsabanis

The phenomenon of sympathetic detonations in blastholes is investigated by comparing experimental observations and numerical modelling results. Numerical modelling using the TDL computer code and Forest Fire decomposition rates for commercial explosives has shown the importance of blasthole diameter, impedance of the stemming and host rock. Comparison with experimental observations has also shown that sympathetic detonations cannot always be treated as shock to detonation transition. Examination of previous results which have been obtained from calibrated low amplitude shock experiments reveal that there is an ignition threshold prior to the detonation threshold. The difference between the two thresholds is more pronounced in the case of air bubble sensitized products. The ignition threshold can be very important under the confinement provided by the blasthole and the conditions of application. It also correlates well with the pressures expected at the gap distances of interest in the practical application. It is suggested that critical energies are used as the criterion for cross initiation in blastholes. Practical suggestions based on the numerical calculations and experiments based on these calculations are also given and discussed.

Jan 1, 1991

By Lixin Qian, Tiejun Chun, Yifan Wang, Huan Wang, Hongming Long, Zhengwei Yu

To solve the problem that the sintered liquid phase fluidity characteristic of low silica (w(SiO2) < 3 wt%) and high silica (w(SiO2) > 7 wt%)) iron ores were different from actual sintering production with using the common method based on w(CaO)/w(SiO2), a new improved method based on n(Fe2O3)/n(CaO) was proposed. The differences between two methods for iron ore fluidity detection were studied. The results show that when the common method is used to detect the liquid phase fluidity, as the content of SiO2 increased from 2.12 to 11.68 wt%, the amount of CaO addition augmented from 7.88 to 32.65 wt% and the corresponding fluidity index changed from 0 to 5.68. The fluidity index has a linearly positive correlation with the content of SiO2. The improved method could significantly reduce the effect of the change of CaO addition on the fluidity characteristic of iron ore which caused by the difference of SiO2.

Mar 1, 2018

By E. A. Brocchi, P. K. Jena

Complete extraction of copper from Salobo chalcopyrite concentrate can be achieved in less than 10 minutes by chlorination of the dry concentrate with Cl2 at 450 degrees C and in 5 minutes by chlorination of an aqueous slurry containing 5 wt% concentrate at 30 degrees C. In general, slurry chlorination appears to be faster than dry chlorination. The kinetics of dry chlorination of copper sulphide are controlled by an adsorption mechanism with an activation energy of 6.1 kcal/mole. The rate is independent of chlorine partial pressure when pCl2 exceeds 0.4 atm. In slurry chlorination the dissolution of copper sulphide follows a topochemical reaction model and the rate of chlorination decreases with increase in pulp density and also temperature. Dissolved chlorine appears to take part in the reaction in atomic or ionic form.

Jan 4, 1992

By C. L. Molina

The U.S. Geological Survey (USGS), in cooperation with the Bureau of Land Management (BLM), Geological Survey of Wyoming, and U.S. Bureau of Mines (USBM), will produce an estimate of the amount of available coal in an area about 55 Ian (35 miles) south of Gillette, Wyo., where the Wyodak coal bed is 8-27 m (25-90 ft) thick. Available coal is coal that actually is accessible for development under current regulatory, land-use, and technologic conditions. Local coal-development considerations include roads, ranches, railroads, pipelines, power lines, wildlife and archaeological sites, alluvial valley floors, cemeteries, and the Hilight oil and gas field and gas plant. Some of these considerations would be mitigated so that surface mining may proceed; others presently preclude mining in their vicinity.

Jan 1, 1995

By I. Casasbuenas, K. A. Nguyen, E. I. Ngoma, H. Kim, D. Borja, J. H. Park, R. A. Silva, S. Choi

"This study aimed to determine the optimum operating parameters of a continuous bioleaching system to leach arsenic (As) from mine tailings using a mixed mesophilic bacterial culture. The microbial consortium, previously adapted for effective growth at high pulp density and metal concentrations, was mainly composed of Leptospirillum ferriphilum, and Acidithiobacillus caldus. The mine tailings, collected from the Janggun mine (South Korea) contained 11% (w/w) of As. The tests were performed in a laboratory-scale unit composed of three reactors connected in series following a cascade configuration. Agitation speed, air supply, solid concentration, residence time and temperature were systematically optimized by assessing the leaching activity. Several parameters were monitored on a daily basis, including the As released into solution, iron oxidation rates, pH, cell concentration, dissolved oxygen and redox potential. Overall, improvement of oxygen transfer, by optimizing the agitation speed and air supply, presented the most tangible impact on the leaching performance. The highest As leaching efficiency observed in this study was 82%, which supports the feasibility of the process. INTRODUCTION Worldwide, around of 65 billion tons of mine tailings are produced every year (Jones & Boger, 2012). These materials comprise the waste minerals produced after ore beneficiation. Mine tailings usually contain heavy metals (e.g., Cobalt (Co), Lead (Pb), Zinc (Zn) and Arsenic (As) (Falagán, Grail, & Johnson, 2016; Nguyen, Lee, Park, & Lee, 2014). The exposure of these materials to the environment can produce serious health damage and environmental degradation (Martin, Dowling, Pearce, Sillitoe, & Florentine, 2014). Mine tailings management represents a major issue in South Korea. There are more than 1,000 abandoned mines containing stockpiled mine tailings within the territory (Choi, Park, Hong, Park, & Kim, 2013; Kim, Kim, Ahn, Ko, & Lee, 2005; Lee, Lee, & Kim, 1998). These tailings comprise high concentration of arsenic. Therefore, the Korean Government has directed its efforts to developing eco-friendly technologies, for the arsenic detoxification of mine tailings Continuous bioleaching is explored as a remediation technology (Borja et al., 2016). The present study aimed to develop a mixed mesophilic bacterial culture for optimal growth at high metal and solid concentration; and optimize the operating conditions of a continuous bioleaching unit. This investigation forms part of a larger study aimed to develop a bioleaching technique to treat Janggun mine tailings (Borja et al., 2017; Ngoma et al., 2017)."

Jan 1, 2018

By J Li

Cannington Mine has been developing through paste backfilled stopes since the year 2000. These paste drives have been used as either production drill accesses or long-term bypasses. Prior to this study, the ground support requirements for each paste development cut were: an initial 50 mm layer of fibrecrete, weld mesh bolted with 2.4 m split sets, followed by a second coat of 50 mm fibrecrete. Both layers of fibrecrete and the layer of mesh were to be installed before the next cut could be bored and fired. This support regime proved successful at Cannington, however, the total cycle time for each cut was lengthy due to the installation and curing times associated with each layer of surface support. In an effort to reduce the cycle time a study was carried out, with the aid of RocScience’s Phase2 numerical modelling software. The modelling reviewed all of the parameters controlling the stability of a newly excavated development cut. The parameters studied included the early strength of fibrecrete, the ground support load capacity, and the strength of the paste fill masses which varies depending on the cement content. As a result of the study, the ground support standard was revised. The revision has significantly decreased the cycle time as well as fibrecrete consumption, all the while maintaining the safety of personnel and equipment.

Mar 21, 2011

Jan 1, 1880