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By A H. Clemens, T A. Moore

This paper discusses a number of technical issues related to marketing coal. It outlines how the results of research undertaken in New Zealand and overseas can help producers address a range of technical factors that impact on production costs and marketability. The paper also discusses trends in coal utilisation for power generation and how new technologies may require coal with different characteristics. Research and development into options for CO2 sequestration are discussed including carbon storage in forests, and removal of CO2 from flue or fuel gas in power stations, and its disposal.

Jan 1, 1997

By V. D. Tathavadkar

Chromite ore is of immense importance for the extraction of metallic chromium and chromium chemicals. The mineralogy and crystal structure of chromite phase are therefore important part of our investigation on the extraction chemistry of chromium species. In this investigation, we have studied the effect of the processing parameters, i.e., the temperature and the oxygen potential on the microstructure and composition of mineral phases formed in the Cr2O3 ?Al2O3 -FexOy -MgO system. In particular the importance of the spinodal decomposition reaction is emphasized in the extraction of chromium as sodium chromite and sodium chromate. Experiments were carried out in order to study the differences in the crystallography of different chromite minerals. Phase equilibria in natural chromite minerals were investigated by calcining chromite mineral in air, argon, and 5% hydrogen + argon atmospheres over a temperature range from 200 to 1200 °C. The effect of the oxygen partial pressure and temperature on the phase constituents of the calcined product has been discussed. The microstructural changes were examined using scanning electron microscope (SEM) and the changes in elemental composition in different phases were analysed by electron probe micro analyser (EPMA). The results obtained from EPMA studies were used to calculate lattice parameter of the spinel lattice, and these values were compared with the values obtained from X-Ray powder diffraction data. On the basis of the experimental data, the mechanism of the spinodal decomposition of complex spinel phases is described under the influence of oxygen partial pressure and temperature.

Jan 1, 2000

By L. A. Haas

The U.S. Department of the Interior, Bureau of Mines, is conducting laboratory-scale research to determine the leaching conditions required with sulfuric acid for extracting base metal from a matte with a copper-to-nicke1 ratio of 6 to 1. The matte (61.2 pct Cu, 9.7 pct Ni, 3.3 pct Fe, 21 pct S, and about 5 oz of precious metals per ton) was prepared from Duluth Complex (Minnesota) ore by smelting a bulk sulfide flotation concentrate. The matte was pre leached at atmospheric pressure to selectively extract 20 pct of the nickel, and the undissolved solids were referred to as the matte residue. Autoclave leaching of the matte residue extracted over 95 pct of the nickel, copper, and iron. The remaining leach residue in the autoclave contained over 100 oz of precious metals per ton. The leaching conditions required were matte grind of greater than 98 pct minus 325 mesh, pulp concentration of 50 g/1, total pressure of 100 psig with oxygen at 150° C or 400 psig with air at 180° C, 50 g/1 H2S04, 700 rpm agitator speed, and 6 hours of leaching time. The leaching time was decreased to 2 hours by increasing the agitator speed to 1,300 rpm. Sulfuric acid concentration greater than 50 g/1 did not appreciably enhance the base metal extraction, but with less acid, residues with higher iron concentrations were obtained. Supersaturation of the liquor was prevented at 150° C by using a 1ixiviant that contained 30 g/l Ni and 20 g/1 Cu.

Jan 1, 1979

By Warren G. Burres

or more than 50 years the Portland Cement Association has represented the United States cement industry in matters relating to the technology and use of cement and concrete. Interestingly enough, PCA?s emphasis has been on concrete and its uses rather than on Portland cement. The cement industry realized long ago that cement is basic and serves its fundamental purpose as an ingredient in concrete. Cement could never be successful if concrete were not. Work with the users and specifiers of concrete had to be done at its end point of application--in a building, bridge, dam, highway or home. PCA, over its half century of existence, has been dedicated to this job. I should like to talk to you today on the less technical side of concrete--what it has been--what it is today--and what it can offer in future construction. Concrete, in many forms, has a long background extending from such notable historic times as the Roman Empire. Here, concrete made from pozzolanic cement from the slopes of Mt. Vesuvius was used to construct the Coliseum, home of the Roman circus; for the Appian Way, the ancient forerunner of the Interstate system; and the miles of aqueducts throughout Europe, many of which still carry water. In 1811 Joseph Asppin, an English bricklayer, made the first modern cement by the artificial mixing of pulverized limestone and clay materials. Ht,

Jan 1, 1971

By Paul H. Atkinson

"Sampling in the mineral processing industry has always been a subject which has received considerable discussion. There have been many volumes written on theory, techniques and practical application of sampling. However, until recently, the companies were not completely aware of the potential savings available with properly designed sampling systems both to assist in pieces: control and final product values.Definition In our discussion today, we will define sampling as the operation of removing a part, convenient in quantity for analysis, from a whole, which is of much greater hulk, and removing it in such a way that the proportion and distribution of the quality to be tested, i.e. size of particle, moisture content, specific gravity content, mineral and chemical composition, are the same in both the sample and the whole.Application It has been well established that undetected errors can result in large economic losses, thus most firms depend upon some type of sampling and sample analysis as a control in their continuous processing of materials. Despite the large investment in facilities and personnel the ""analysis"" of a sample can be no more accurate or reliable than the sample on which it is being based. The importance of sampling is recognized by a great many but it is appreciated by only a few, largely because it is sometimes one of the items which is taken for granted."

Jan 1, 1976

By Alfredo Valdivia, Dominic Reda, Vojtech Gall

The design and planning for the construction of a new passageway to improve access and circulation to better accommodate anticipated increased passenger flow within Grand Central—42nd Street Station. The passageway includes the break-in of an over 100-year-old station cavern with an innovative design implementing a protective structure above the existing track to allow for safe train operations and passenger circulation during construction. Construction of the new passageway follows the Sequential Excavation Method. This paper will present the innovative solutions that went into the preliminary design and planning considering construction access, site logistics, risk management, structural retrofitting, instrumentation and monitoring, and impact assessments.

Jun 13, 2023

By P. I. James, M. R. Baker

Este artículo analiza la nueva producción de cobre a partir de "minerales de desecho" de baja ley usando la tecnología de Blue Planet Strategies DEMET™ (Dynamic Electrode Mining Effluent Treatment, por sus siglas en inglés), que tiene como objetivo salvar la brecha de procesamiento entre la solución débil de lixiviación en operaciones de extracción por solventes/electrowinning (SX/EW), removiendo electroquímicamente los metales a partir de corrientes débiles y a la vez generando productos concentrados en metales objetivo en un análogo funcional de extracción por solventes (SX). Se estudió el tratamiento de la débil solución de lixiviación pregnant (PLS por sus siglas en inglés) y se usó para estimar los impactos económicos y de producción para una hipotética lixiviación en pilas de cobre brownfield y una operación aumentada DEMET usando SX/EW para tratar el "mineral de desecho." Se presenta la remoción de cobre a un 86% de eficiencia en las placas por debajo de 0,1 g/L de cobre con un consumo de energía de 0.55 kWh/lb de cobre y una concentración del producto mayor a 10 g Cu/L. El modelamiento arrojó aproximadamente $2/ lb para la producción total de cobre y costos de tratamiento menores o iguales a $1/lb con un inmediato aumento del margen bruto de operación del 12% para el brownfield incrementado. Se indicó también un aumento de la vida de la mina con un margen bruto promedio de 38% en la producción aumentada de "mineral de desecho" con valores de cobre de $3.25/lb.

Jan 1, 2014

In this study, flotation of fine galena, chalcopyrite and pyrite was performed after grinding with different extent of oxidation-reduction condition adjusted by grinding media. Sodium dithionite and iron ions were added in mill to simulate pulp potentials and iron oxidation species produced by grinding media, respectively. The types and quantities of the metal oxidation species on mineral surfaces were determined by EDTA extractions, while the surface electrical properties of minerals and interaction of different types of metal oxidation species were studied by zeta potential measurements. It was found that the nature and concentration of the absorbed metal oxidation species were dependent on oxidation atmosphere controlled by the iron amount of grinding media. These species interacted with each other and had an important role in determining flotation of fine galena and chalcopyrite as well as activation of fine pyrite by lead and copper.

Jan 1, 2006

By T. Harrison

Surface coal mines in West Virginia are receiving stringent NPDES discharge limits for total recoverable selenium. With limits in the low parts-per-billion range, selection and implementation of proper sample collection and analytical methods are imperative for quality assurance and control and for consistency in results. Given the typical oxidized form of selenium in the water, the low limits and the large and variable flow rates from the watersheds, end-of-pipe treatment is difficult and cost-prohibitive to implement. Discharge locations in the remote and steep terrain exacerbate the problem. To evaluate options for end-of-pipe treatment at a Patriot Coal Corporation surface mining operation in West Virginia, CH2M HILL performed wastewater characterization for a range of key constituents and selenium species at three outfalls for selection and preliminary sizing of appropriate treatment processes. A preliminary evaluation of base and wet-weather flows was done to understand flow variability considerations for discharges. A conceptual evaluation of technologies to treat selenium to permitted levels was conducted in con-junction with order-of-magnitude life-cycle cost estimates.

Jan 1, 2010

By F. Magweregwede, S. Khan

Circular economy opportunities for the mining sector are presented in this paper. A literature review was undertaken, followed by qualitative data gathering through survey questionnaires and unstructured interviews, and stakeholder engagements through workshops. The circular economy opportunities were identified and categorised according to the three circular economy principles of designing out waste and pollution, keeping products and materials in use, and regenerating natural systems. Opportunities aligned with the first principle include increased ore extraction efficiency processes, water recovery and recycling, substitution of raw materials, technology and waste utilisation for carbon capture and biotechnology. The second principle includes opportunities such as zero waste-to-landfill strategies, repurposing of mine waste, re-mining of tailings, recycling metals and processing of residues, and urban mining of electronic waste. Opportunities aligned with the third principle include the adoption of renewable energy, green hydrogen production, repurposing of post mining landscapes, and eradication of alien invasive vegetation. Furthermore, the challenges of implementing circular economy in the mining sector are discussed. The current rate of waste generation from mining activities far exceeds the rate of reuse and repurposing. Recycling of large tyres and characterisation of hazardous electronic waste also pose challenges. The most implementable circular economy opportunities in the mining sector are those aligned with the second principle of keeping materials in use. The high impact opportunities aligned with the first principle of designing out waste and pollution, and the third principle of regenerating natural systems, are more difficult to implement as they require large investments.

Dec 15, 2025

By L. Rosato

In the past decade, as a result of increasing iron loads, Canadian Electrolytic Zinc (CEZinc) has become a pioneer in understanding the critical factors that affect the roasting of concentrates with high pyrite contents as well as those factors governing the effects of high iron loads on the leaching circuit. De-bottlenecking efforts in the roaster and acid plant section of CEZinc have given rise to a better appreciation of the impact of iron on roaster productivity. High standards for impure solution quality, zinc recoveries and residue disposal have all led to an increased comprehension of the limits of the leaching circuit and the optimization potentials with respect to iron and ferrites. In this paper, the impact of iron on the roasting and leaching circuits of CEZinc will be reviewed and special emphasis will be given to some of the more recent process optimization and improvement activities.

Jan 1, 2006

By V. A. Leão, A. M. Silva, S. M. Bertolino, B. C. S. Ferreira, D. Guimarães

Although not considered a high risk pollutant as compared to toxic metals and acidity, environmental agencies worldwide are proposing regulations to control sulphate in effluents and drainages by setting a threshold value varying between 250 mg/L and 500 mg/L. The aim of this study was thus to compare four different techniques for removing sulphate ions from mining/metallurgy effluents. The first alternative studied was sulphate removal by precipitation as ettringite. Treating a synthetic solution containing 1650 mg/L sulphate at 22±1 ºC resulted in removals close to 85% during continuous precipitation. Sulphate sorption was also investigated using three different ion exchange resins as well as limestone. Fixed bed experiments produced sulphate loadings of up to 70 mg SO4 2-/L resin, at pH 2.0. In neutral wastewaters, limestone is also a potential adsorbent producing a maximum particle loading of 19 mg/g. Sulphate sorption on limestone seems to be an alternative to treating mine waters with sulphate concentrations below the 1200-2000 mg/L range, where lime precipitation is not effective. Subsequently, sulphate removal by sulphate reducing bacteria was also investigated and it was observed that reactor’s hydrodynamic conditions and the choice of substrate are important factors for the process. The different technical aspects of each technology are addressed.

Jan 1, 2014

By Qian Li, Honggui Han, Jun Wang, Shichao Yu, Chunxiao Zhao, Maoxing Hong, Rui Liao, Xingxing Wang

In this study, bioleaching experiments, synchrotron X-ray Diffraction (SR-XRD), X-ray absorption near edge structure (XANES) and X-ray Photoelectron Spectroscopy (XPS) were conducted to investigate the intermediates and surface species of bornite leached by mesophilic mixed bacteria of Leptospirillum ferriphilum, Acidithiobacillus caldus and Sulfobacillus thermosulfidooxidans. CuS, Cu9Fe9S16 and S8 were the main intermediate species during bornite bioleaching by mesophilic mixed bacteria, and CuFeS2 was also detected. The surface species of S2− and S2 2− would be polymerized to Sn 2− during bioleaching. The formation of element sulfur and the increase of its content were confirmed by the fitted results of XPS spectra. The presence of polysulfide and element sulfur did not inhibit the bornite bioleaching. The formations of CuS and CuFeS2 were confirmed by the results of Cu K-edge XANES spectra.

Mar 1, 2018

By L. Pan

As an air bubble approaches a mineral surface, a thin liquid film (TLF) is formed in between. The excess pressure (p) in the film determines the kinetics of drainage, which is of critical importance in flotation. We have developed a new method of monitoring the kinetics for both stable and unstable wetting films and analyzed the results using the Reynolds lubrication theory. It has been found that initially a TLF is thinned by the Laplace pressure (pcur) due to changes in bubble curvature and subsequently by the disjoining pressure (?) created by the surface forces present in a wetting film. In the present work, we have derived an analytical expression for determining ? from the temporal and spatial profiles of TLFs on mineral surfaces. The results show that ? > 0 in a film formed on a hydrophilic surface and ? < 0 in a film formed on a surface hydrophobized by collector. Thus, the role of collector in flotation is to create a hydrophobic force and hence a negative disjoining present in wetting films. It is also found that smaller bubbles can create higher Laplace pressure, which helps the TLF drain faster.

Sep 1, 2012

By Vijaya Bhushan Rao, Ali Semercioglu, Jason Redgers

Large diameter steel water tanks with high storage capacities impart heavy loads deep into the ground, generally requiring deep foundations to adequately support them. The use of ground improvement as a sustainable and cost effective alternative is tempting but the design of the foundations for such heavily loaded, thin-shelled structures have to meet several performance requirements such as bearing capacity, limiting the specified total settlements, typically limiting the radial differential settlement to 13mm over 10m along the circumference and dishing settlement from edge to center of 1/120 as per standard API 650 Appendix B as well as the mitigation of liquefaction induced settlement risk. Any inadequacy in the soil investigation, geotechnical design, or misrepresentation of stresses of the foundations may lead to serviceability compromise or potentially catastrophic failures. Therefore, the selection of the foundation is dependent on the availability of suitable ground report and the limitations imposed by operational requirements. Two such case studies are evaluated and compared in this paper, with tank diameters ranging from 41 to 106m in the Kingdom of Saudi Arabia, (KSA) which were founded on two types of soils and supported on deep foundations i.e., stone columns and bored cast-in-situ piles.

Oct 1, 2022

By Jack J. Ayotte, Michael R. Nadon

"Today&apos;s demand for better and more efficient methods inspires new approaches to construction and mine development.A project at Asarco&apos;s Aquarius Mine provided a challenge that resulted in the adaptation of a civil construction technique to a mining application.This paper describes the construction of an escapeway shaft to surface from the mine&apos;s 150m level. The prime consideration was to provide the most cost-effective method of establishing a shaft collar in the 145 ft (44 m) of water-bearing overburden. This problem was resolved with the employment of the drilled in-caisson method.The remainder of the 500ft (152m) deep shaft was raise bored and portable hoisting equipment was used to install a permanentmanway and shaft liner.IntroductionHaving completed the first phase of exploration development in 1982, J.S. Redpath Limited was engaged to carry out an engineering and cost study to investigate the feasibility of re-opening Asarco&apos;s Aquarius Mine near Timmins, Ontario. The scheme was to develop the proven ore reserves and proceed with shrinkage stoping while carrying out further exploration development and diamond drilling.One significant and costly component of the project was the provision of an escapeway shaft to supply additional ventilation as well as a second means of egress from the mine. The major complication to this task was the presence of 145 ft (44 m) of water-bearing overburden at the site. The first and obvious approach was to use conventional ground-freezing methods as had been employed previously on .this property for the initial development shaft. This being the only ""sure"" method available at the time of the budget estimate, it was used as a basis for the study but its considerable projected cost and time demand inspired further investigation into other possible solutions.After considerable research and several brainstorming sessions, a Redpath team came up with an approach whose basic procedures had been used extensively in the civil construction field, although they were novel to the mining industry."

Jan 1, 1987

By Jochen Petersen, Jean-Paul Franzidis, Allan Nesbitt

This study presents a method for the determination of intra-particle diffusivities in ion-exchange resins for the purposes of evaluating the state of resin degradation during service. The method uses a zero length column (ZLC) in a closed circuit with variable speed pump and reservoir. The intra-particle diffusion is determined from absorption data by using the Nernst-Plank approximation along with the ‘mass transfer factor’ - which is a product of the mass transfer coefficient (kf )and the concentration of the adsorbing ion in the liquid at the surface of the resin - in a computer algorithm fitting simulated curves to experimental data.. Through this approach the changed intra-particle diffusivity, of a gel-type acid resin, over a 1000 loading and elution cycles, is shown.

Jan 1, 2014

By Diane Schwegler-Berry, Vincent Castranova, Chang-geng Moe, Jane Y. C. Ma, Mark D. Moore, Joseph K. H. Ma, Carl J. Malanga, Ji-Hee Kane

"Effects of Bisbenzylisoquinoline Alkaloids on Alveolar Macrophages: Correlation between Binding Affinity. Inhibitory Potency and Antifibrotic Potential. CASTRANOVA, V., KANG, J-H., MA. J. K. H., Mo, C-H., MALANGA, L. J., MOORE M. D., SCHWEGLER-BERRY, D.. AND MA. J. Y. C. (1991). Toxicol. Appl. Pharmacol 108, 242-252. The Chinese have conducted extensive studies concerning the medicinal properties of plant products. In this investigation the ability of three bisbenzylisoquinoline alkaloids to inhibit particle-induced activation of alveolar macrophages was evaluated and this inhibitory potential was correlated with the ability of those drugs to bind to membrane components. Tetrandrine. i.e.. an herbal medicine used as an antifibrotic agent in China, was a potent inhibitor of particle-stimulated oxygen consumption, superoxide release, and hydrogen peroxide secretion by alveolar macrophages. Tetrandrine also exhibited substantial binding affinity for membrane lipids and alveolar macrophages. In contrast, tubocurine, an analogue with little antifibrotic potential, exhibited low binding affinity and had little effect on macrophage activation. Methoxyadiantifoline, an alkaloid of unknown antifibrotic potential, exhibited inhibitory and binding properties similar to those of tetrandrine. The data indicate that a strong relationship exists between the antifibrotic potential of these alkaloids and their ability to bind to alveolar macrophages and inhibit particle-induced activation of these phagocytes. These drugs should serve as useful probes to evaluate the role of alveolar macrophages in pulmonary fibrosis. © 1991 Academic Press, Inc.Chronic silicosis is a fibrotic disease resulting from occupational exposure to silica dust. It is manifested initially by an increase in the quantity of pulmonary surfactant (Dethloff et al., 1986). However, in later stages it is characterized by an increase in collagen formation and the development of concentric hyalinized nodular lesions in the lung (Ziskind et al., 1976). Although mechanisms for the progression of silicosis have not yet been completely defined, activation of alveolar macrophages by respirable silica particles is believed to play an important role in the etiology of this disease. Studies from our laboratory have shown that both in vitro and in vivo silica exposures result in a stimulation of macrophage release of reactive products capable of damaging the lung parenchyma (Castranova et al., 1990; Goodman et al., 1990). In addition, exposure of al¬veolar macrophages to silica results in the release of fibrogenic factors which enhance the proliferation of fibroblasts and the synthesis of collagen by these pneumocytes (Leibovich and Ross, 1976; Bitterman et al., 1982, 1983).The bisbenzylisoquinoline alkaloids, which represent the largest group among the iso-quinoline compounds isolated from the plant kingdom, are known to exhibit a broad rangeof pharmacological activities. Tetrandrine, for example, an alkaloid isolated from the root of Stephania tetrandra, has been tested for its antitumor, antihypertensive, and antisilicotic effects (Kupchan and Atland, 1973; Zeng et al., 1985; Yu et al., 1983). It is currently used in China as a treatment for angina, hypertension, and silica-induced pulmonary fibrosis (Li et al., 1981). Several related bisbenzylisoquinoline alkaloids such as methoxyadiantifoline and tubocurine have also been evaluated for medicinal effects. Methoxyadiantifoline has been shown to exhibit effects on the cardiovascular system similar to those reported for tetrandrine (Jia et al., 1988). However, to date, the antifibrotic activity of methoxyadiantifoline has not been evaluated. In contrast to tetrandrine, tubocurine, a structural analogue of this drug, has been reported to be relatively ineffective against fibrosis (Mo et al., 1982)."

Mar 1, 1992

By Biswajit Samanta, Pranjal Pathak

A multimine mineral value chain (MVC) consists of multiple mines in the upstream supplying raw materials to multiple destinations in the downstream. The short-term mine production scheduling problem of a multimine MVC aims to determine the optimal extraction sequence and destination allocation of blocks from all the mines collaboratively to meet the quality and quantity requirements of all the processing plants in each period, subject to all relevant technical and operational constraints of the mining system. It is carried out at shorter scales of days/weeks/months under the purview of long-term production scheduling. An optimal short-term production schedule for MVC involving multiple mines that share the same infrastructure (processing units, stockpiles and waste dumps) requires coordination across the network of mines. Optimizing the short-term production schedules independently at each mine fails to capture the benefit of collaboratively generating schedules for all the mines, resulting in suboptimal schedules. Additionally, in short-term production scheduling, the operations are modeled in greater detail with additional decision variables and constraints to model the more complex multimine MVC situations. This makes the large-scale instances of the problem computationally intractable for standard mixed-integer programming (MIP) solvers. This work presents a customized genetic algorithm (GA)-based heuristic approach to obtain near-optimal solutions to the industrial-scale instances of the short-term production scheduling problem of multimine MVC within a reasonable computation time.

Oct 1, 2022

By F. Wang, P. Rosario, A. Vazirizadeh

Advances in data science, machine learning, and artificial intelligence are transforming mining and mineral processing, and making them more algorithm intensive. The paradigm is shifting from one of detection and control to one of prediction and optimisation. To build up reliable prediction and optimisation models these steps should be passed: collect, aggregate, cleanse, and process large amounts of complex, structured, and unstructured data as a first stage. Next, the right tools must be used to extract meaningful features from the operational data for the build-up of a prediction model. A grinding circuit is one of the challenging areas in terms of determining its overall efficiency and the prediction of product quality. In a processing plant, some of the KPIs are typically unmeasurable or infrequently measured for real-time application, e.g. ore grindability and grind size. However, these variables are required to calculate the grinding circuit efficiency and to model the operation performance. In this paper, advanced analytic tools have been used to extract one selected KPI (cyclone overall P80 or final grind size) and its relationship with measured variables for an industrial dataset. The results illustrate that the performance of the grinding circuit can be predicted for real-time monitoring by means of measured data. Keywords: Grinding circuit, data-driven, machine learning, process modelling, hybrid modelling

Jan 1, 2020