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By Beatryz C. Mendes, Márcio Sampaio S. Moreira, Rita de C. S. S. Alvarenga, Juliano Correa

Over the last decades, modern technology to build wood structures have been substantially developed. Building solutions for floor systems of wood-concrete mixed T-beams with wood web and concrete flange stand out among these technologies. This work describes an experimental investigation of the performance of bond connectors made of round steel bars for wood-concrete mixed elements. Symmetric three-member specimens were built. The middle member was made of concrete and the other two were made of wood. The first kind of connector consisted of steel bar designed as straight pins with head, normally driven through the wood. The second kind consisted of arc-shaped connectors directly embedded into the wood or bonded using epoxy adhesive. The specimens were then tested in compression. The compressive strength and the force-displacement curve were obtained, in order to evaluate the failure mode and obtain the stiffness in the ultimate (Ku) and serviceability (Ks) limit states. The stiffness values were calculated in the interval corresponding to the secant straight line between, respectively, 10–40 and 10–70% of the ultimate strength. The obtained results indicate high strength and ductile failure mode for all of the cases. Bond stiffness gains were verified when using the arch-shaped connectors.

Mar 1, 2017

By Jianjun Tang, Wenjuan Bai

This paper presents a new method of formulation design for multi-component composite explosives. Based on the thermochemistry of the detonation process, the mathematic model of formulation design is established by optimization mathematics. Using the heat of detonation as target functions and taking the constraint conditions such as oxygen balance and costs etc into consideration, this model can provide an optimal solution quickly by means of personal computer. Using this method, the calculation and the simulation tests for a series of constituent sets and various constraint conditions can be conducted easily. In this way, the optimal formulation for the explosive can be determined, on the basis of the maximum heat of detonation and the lower cost.

Jan 1, 1997

US 4,201,749-In the Bayer process production of alumina wherein aluminum hydroxide is precipitated from a sodium aluminate solution for use as seed, sodium oxalate and caustic components are removed from the precipitate by washing it first with a washing liquor which is saturated with sodium oxalate but has little content of caustic, and secondly with hot water. Substantially no sodium oxalate is recycled, yet loss of sodium aluminate is minimal. K. Yamada, T Harato, and H Kato, assigned to Sumitomo Aluminum Smelting Co Ltd May 6, 1980 8 pp. (423-127). Filed. 5-8-79 (37,145) Priority. Japan, 5-8-78 (53/54,803). Same¬British 2,020,642, dated Nov. 21, 1979.

Jan 1, 1982

By Michael E. Allen

The building of sanitary and storm drainage sewers in urban or environmentally sensitive areas often requires the use of tunnel construction procedures. While hydraulic considerations may require only small diameters, traditional tunneling techniques make small sizes the least economical. Current state-of-the-art techniques using highly mechanized systems of pipe jacking can provide cost effective solutions to the problems of construction of small size tunnels. The characteristics of mechanized pipe jacking allow rapid advances under difficult ground conditions. The basic pipe jacking cycle is used with a variety of excavation systems to permit the contractor to satisfy engineering as well as economic parameters. These characteristics and several of the systems available are outlined.

Jan 1, 1981

By M. C. Miller, M. R. Tek, D. L. Katz

Previous studies have shown the influence of geometric variations on the drawdown and buildup behavior of a well completed in a homogeneous, porous medium containing a single-phase fluid. Other papers have shown the influence of leakage across caprocks on drawdown tests on water wells and aquifers. This paper presents two additional cases: the influence of an adjacent, expansible source of fluid, and the effect of caprock leakage on the measured in situ permeability and compressibility. Methods are developed for evaluating the influence of these two deviations from a uniform aquifer upon the in situ permeability and compre.ssibility indicated by pump tests. INTRODUCTION In relatively uniform porous media, saturated with a single-phase fluid, the effective reservoir permeability and compressibility of the water porous bed system may be obtained from drawdown and build-up data on wells, such as the initial wells drilled in aquifer storage reservoirs (Homers and Katz et al.7). In considering the drawdown and build-up behavior of wells adjacent to storage reservoirs, or of wells in an aquifer adjacent to an unknown gas field, questions arise as to the quantitative effect of the presence of compressible fluid on the measured permeability and compressibility of the formation. The solution to this problem is presented, using a constant pressure line source at some distance from two wells, one of which is pumped and the other used as the pressure observation well. The solution is presented in terms of the geometry of the wells and their relationship to the constant pressure line. It is known that caprock leakage can interfere with the determination of an aquifer in situ permeability and compressibility (Mantush4, Hantush and Jacob3 and Witherspoon and Muellerll). This paper presents an added case of the effect of leakage through a caprock of known thickness and permeability on well tests starting with a reservoir of constant pressure above the caprock and contributing to the aquifer as a result of the pump test. Again, both a pumping well and an observation well are postulated. These two cases are presented together since both a compressible fluid nearby and. caprock leakage show similar deviations from expected in situ permeability and compressibility results, and the solutions are similar in form. EFFECT OF A NEIGHBORING CONSTANT PRESSURE SOURCE ON IN SITU MEASUREMENTS Bixel, Larkin and van Poollenl presented a paper showing the influence of a discontinuity of the properties of a fluid formation system on drawdown and build-up performance. Their case is related to the present study but may be distinguished from it in that their numerical work and resulting graphs relate only to the performance of the pumping well itself. Incorrect values for in situ reservoir properties may be obtained from pump test data if the skin effect of the well and after-flow are not considered. Analysis of this problem by the authors indicated that the more reliable method of evaluating the influence of an adjacent gas field or expansible source was to use one well for pumping and another well at some distance from it for observing the aquifer pressure performance. An expansible source of hydrocarbon near a pumping well may be approximated by a line of constant pressure for a pump test. Fig. 1 illustrates a pumping well and an observation well near a line of constant pressure. Pressure behavior of an observation well during a drawdown pump test near a line of constant pressure is given by the diffusivity equation:

Jan 1, 1967

By P Hayward a, P Evans, K Prince, F Radke

Operating efficiency is becoming paramount as the mining industry moves towards globalisation and conglomeration. Mining companies are continuously searching for new technologies that can improve plant efficiency, by reducing operating costs and maximising metal recovery. Identification of how gold losses occur within an operating plant is crucial for determining appropriate operating strategies for improved metallurgical performance. Classical mineralogical and metallurgical techniques enable the operator to identify where losses occur in terms of particle size and mineral associations, however how the gold is hosted within the mineral grains (for example, as solid solution or as fine micro-inclusions) is more difficult to determine. This paper provides details of the testwork methodology, and resultant laboratory study to improve gold recovery.

Jan 1, 2004

By D. M. Francois-Bongarcon

The idea of parameterizing reserves has only been formalized and scientifically applied for a few years. Its most fully developed application, that of open pits, has been operational only since 1976. Two new versions which have just been issued provide a complete solution to the problem and also a powerful tool for mine planning, and they open up a new field of investigation. This paper describes the basic principles for parameterizing reserves, their application for open-pit mines, the algorithm used, the physical interpretation of the results obtained, their economic use as well as the first prospects offered by a complete parameterization in tm of (I. ti), or of the metal price.

Jan 1, 1984

By R. L. Grayson, Y. J. Wang

This paper presents an application of goal programming (GP) to major mining machinery purchases based on historical operating data on mechanical downtime and production. The GP technique, an extension of integer programming, is used to maximize an objective function comprised of deviations away from management-preferred financial goals. Different capital budgeting techniques are used to evaluate capital proposals, and the results of these analyses are combined and weighted in a maximization of profits objective function. The GP method gives an optimal solution to a multiple goal problem. A sensitivity analysis is performed to determine the effect of a variable production improvement condition or a variable budget control con¬dition on proposal selection.

Jan 1, 1984

By Milton E. Wadsworth, Ximeng Zhu

Impurity metals can markedly influence the anodic dissolution of gold in the presence of cyanide. Several important findings related to the influence of lead are reviewed and some new observations presented. Based on the effect of pH, the scan direction, and voltage, it may be shown there are three separate voltage regimes where lead influences the anodic dissolution of gold. These are related to Pb°/ HPbO2, Au-Pb /HPbO2, and HPbO2/PbC2; oxidation-reduction reactions which provide low resistance paths for electron exchange. The gold dissolution rate was determined by direct solution analysis and is compared to the rate implied by electrochemical measurements.

Jan 1, 2005

By K. O. Bennington

The thermodynamic properties of synthetic acmite, NaFe3+Si206, were determined by the Bureau of Mines. The enthalpy of formation was determined by hydrofluoric acid solution calorimetry. The values of the standard enthalpy of formation at 298.15 K, ?Hf°298.15, from the elements and from the oxides, ?H°298.15, are ?Hf°298.15 = -615.87 ±0.71 kcal/mole, ?H°298.15 (from oxides) = -32.08 ±0.53 kcal/mole. Various experimental data were combined with other data from the literature to calculate all the related thermodynamic properties in the range of 298 to 1,263 K. The standard Gibbs energy of formation is ?Gf°298.15 = -575.8 kcal/mole.

Jan 1, 1981

By S. L. Gubin, T. V. Ignatova, A. V. Levshin, D. O. Sharkovsky

"Flotation process applied for concentration of unoxidized ferruginous quartzites by PJSC Mikhailovsky GOK (MGOK) is based on wet magnetic separation of strong magnetic minerals. However quality of the resulting concentrate (Fe65-66%) is insufficient for production of metallics. Quality upgrade of magnetite concentrate via flotation has been implemented by MGOK to produce premium quality magnetite concentrate.Flotation is a challenging process due to sensitivity to varied amounts of reagents, fine and coarse mineral ratio, particle contact (retention) time and temperature of feed. Tomah’s PA-14 reagent (USA) has proven efficient for application in flotation of MGOK’s magnetite concentrate.Objective of this work is to select and prove applicability of selective agents for flotation upgrade of magnetite iron ore concentrate.Series of flotation tests has been carried out with application of new highly selective collecting agents produced by Akzo Nobel (Sweden), Clariant (Germany) as well as Akzo Nobel’s and Tomah’s cationic collector mix to improve performance efficiency of flotation process. Tomah’s flotation agents and Akzo Nobel’s Lilaflotproved to be the most effective for purposes of concentrate quality upgrade to Fe69.0% via flotation.Testing Method: Following scientific research methods were applied for testwork: system analysis, mathematical statistics, observation, comparison, trial (experiment).To determine key process factors a series of pilot tests was carried out. Most of the testwork was performed by PJSC Mikhailovsky GOK’s Central Process Laboratory.Work Results:-optimized flotation performance modes were defined to ensure production of three types of low-silica concentrate, i.e. containing SiO25%, SiO24% and below SiO23% by weight. Most efficient selective agents applicable for flotation have been defined. Mixture of higher aliphatic amines has proven to intensify selective flotation of quartz. It enables higher yield of chamber product maintaining desired quality of concentrate.Achieved process operation and performance factors have been revaluated.Value for Advancement and Expansion of Mineral Processing:Flotation of concentrate has enabled expansion of PJSC Mikhailovsky GOK’s production capacity, improved production quality, helped to maintain sustainability and competitive advantage of the company."

Jan 1, 2018

By Yizhong Yuan, Dao Li, Nannan Xue, Tao Liu, Yimin Zhang

A new multi-stage counter-current circulation leaching process for extracting vanadium from stone coal was proposed, and the main factors on multi-stage counter-current circulation acid leaching process were investigated. The results show that the vanadium recovery could reach 86% under the conditions of sulfuric acid concentration of 4 M, liquid to solid ratio of 2 mL/g, temperature of 95 °C, reaction time of 60 min, mean particle size of 125 µm and circulation acid leaching stage of three. The losses of vanadium in acid leaching solution appeared during the four-stage acid leaching process. The strong adsorption performance of new formed KAl(SO4)2(H2O)12 crystal was main reason.

Jan 1, 2014

By James Vaughan

Ionic liquids are solvents of interest for applications such as electro- plating, winning and refining of metals. Of particular interest is the possibility of processing reactive metals such as aluminium, magnesium and titanium that cannot be deposited from aqueous solutions. Aluminium has been electro deposited from AlCl3 : ionic liquid mixtures at low temperatures relative to conventional Hall-Héroult smelting. Imidazolium ionic liquids are have been used in the past due to their relatively high ionic conductivity and cation stability. The less studied and less expensive phosphonium ionic liquids systems may provide a viable alternative to imidazolium ionic liquids for certain applications. New information regarding the physical properties and electrochemical behaviour of phosphonium ionic liquid systems is presented.

Jan 1, 2006

By R. E. Head

At the microscopic laboratory of the Bureau of Mines Intermountain Experiment Station, Salt Lake City, Utah, efforts are being made to devise methods of differentially coloring finely crashed minerals as a means for their identification. Staining would facilitate sight recognition of minerals under the microscope and would be of great value in the study of crushed ores, concentrates, and tailings. Since the treatment of ores for their beneficiation is primarily based on the recovery of the minerals containing the clements of value, it is extremely important that these minerals should be known and that a method for quickly determining them when in minute fragments should be available. Herein lies one of the greatest uses for color methods. In many cases it is a difficult matter for even the trained petrographer and mineralogist to identify finely crushed minerals quickly. Although ordinary petrographic methods are accurate, they are often time--consuming and are not suitable to the needs of millmen who require, especially in the examination of tailings a method for determining minerals by inspection.

Jan 1, 1929

By William H. Walton, Joel Dellaria, Jeffrey R. Hill

The City of Chicago has a world-renowned skyline and is known for its provocative architecture. The subsurface conditions in the city have allowed for construction of these significant structures. The skyline is supported on caissons as they are called in Chicago or drilled shafts in other locations. Despite the significant strides the industry has made in advancing the drilled shaft, the use of other specialty geotechnical construction techniques like micropiles has not been overlooked in Chicago and the surrounding areas. Micropiles have been utilized to underpin famous existing historic structures like Orchestra Hall any many others. Engineers have used 200 to 600 kip micropiles to underpin compromised, inadequate, or damaged caissons. The paper will discuss the use of drilled shafts, micropiles, and ground improvement over the last 30 years in Chicago using a curated collection of case histories. It will also examine advancing the industry beyond its current technical limitations using these techniques. INTRODUCTION 20,000 years ago, glaciers from the Chicago region left behind sheets of glacial clay till underlain by dense, over consolidated glacial till below: limestone bedrock, found about 100 ft below street level. An unusual feature in this profile is the soft Chicago Blue Clay. Chicago has been called the birthplace of the Skyscraper and drilled shaft foundation, both of which came about in the 19th century. After the Great Fire of 1871, tall new structures were built rapidly and designing a successful foundation was trial and error. The first deep driven wood pile and caisson foundations bypassed the problem layer and found solid support on hardpan till or bedrock below (Schock and Risberg 2013). Once the drilled shaft foundation became acceptable to the Chicago engineering and construction community, building heights and complexity grew dramatically. As the city grew, building foundations were being repurposed. There was also the need to underpin structures for additional loads and shallow foundations for adjacent construction. Hand-dug drilled shafts were an option for some of these restricted access and low headroom sites but a new technique, micropiles, would prove to be the future of retrofit and hard to construct foundations. Micropiles were introduced on a limited basis to the United States market in the 1970s and 80s. In the early 1990s, the Chicago market began to latch onto micropiles and their use has grown significantly as a solution to the most complex foundation problems a maturing skyline has to offer.

Jan 1, 2019

By Arvid E. Anderson

The paper describes the unique operating features of the Lebanon Concentrator Plant wherein both magnetic concentration and froth flotation are used. Chalcopyrite is selectively floated by the use of dual collectors, Aerofloats and secondary butyl xanthate. Both potassium ethyl xanthate and sodium isopropyl xanthate (dual collectors) are dissolved and emulsified with pine oil for the flotation of the pyrite. Sketches describing the plant operations are presented and plant operating metallurgical results obtained are also given. The optimum production of minerals by the froth flotation process is normally achieved [ ] smooth operating conditions, The process, because of its many variables, becomes an art as well as a science. Therefore, any phase of the operation which will aid the operator in his control of the numerous variables will help produce a smoother operating plant, One of the most important variables which the operator deals with is the addition of reagents, These are usually costly items and should be used discretely with minimum amount of waste, The danger is that ,this emphasis may reduce the reagent amount to a point below that required, or, on the other hand an excessive amount is added, Both conditions usually yield poor results. The drea of the metallurgist is to provide the operator with the tools enabling him to produce a good mineralized froth at all times. Normally the operator has no control concerning the type of reagents which he must use. This has usually been worked out for him in the laboratory and by plant-scale tests. He does have limited authority to control the amounts of the reagents at his disposal. This, I believe, is as it should be. However, the operator should be provided with the best combination of reagents for his particular job. The providing of this combination of reagents for his particular job, The providing of this combination is often difficult, yet it is very important in order to yield good results, With this in mind, the dual collector idea was introduced for the selective flotation of chalcopyrite, and also later for the flotation of pyrite at the Concentrator Plant of the Bethlehem Cornwall Corporation in Lebanon, Pennsylvania, Supplying several types of collectors has given the operator an additional effective tool, even though great variations are encountered in ore tonnage treated and in ore composition, This paper deals with the use of the dual collectors and with the addition of the reagents in the form of a pine oil emulsion, or more accurately, a pine oil suspension. It is hoped that other operators may find the ideas helpful. There does not seem, to me, to be definite scientific fact which would substantiate the necessity for the use of dual collectors. However, in actual operations, the metallurgical results at Lebanon became more uniform with the use of dual collectors, I look upon it as an "insurance policy" which greatly aids the operator during those periods when he is having trouble, One theory has been advanced, i.e. one collector has a greater tendency to float the coarser minerals, whereas the other one may float the finer ones. Consequently, a combination of the two collectors will result in optimum recoveries, There has been some evidence that this is true, but it is not conclusive, on the other hand, the use of a xanthate-pine oil suspension (or emulsion) should speed up the surface reaction of the collector with the sulfide minerals, result¬ing in more uniform flotation, This has definitely happened in our particular case. A more interesting unexplainable observation has also occurred; i.e., the xanthate solution does not appear to lose its strength as rapidly when it is in the form of an emulsion (or suspension), This was first observed when a 50 gallon drum of a 20% ethyl xanthate solution was taken to Wilmington, Delaware, for a laboratory test, using a homogenizer to produce the xanthate-pine oil emulsion. Upon arrival, the drum of xanthate had developed a considerable internal pressure, The relief of this pressure was accompanied by a strong odor, When the emulsion was returned to Lebanon for the plant test orders were issued to release the pressure prior to emptying the emulsion. Nopressure had developed within the drum and there was no unusual odor present, Since this time it has been observed that xanthate pine oil suspensions have greatly decreased the possible decomposition of the xanthate solutions. In fact, suspensions have been exposed for more than a month without apparently effecting their reactions in the flotation plant. On the other hand, we found that the regularly mixed concentrated xanthate solutions, after standing for several days, did not give the same results as the freshly made ones. This effect was greatly reduced by the use of xanthate pine oil suspension (or emulsion)

Jan 1, 1958

By J. Jung, W. Keller, A. Zucht

"The agitator design for nickel high pressure acid leach autoclaves (HPAL) is critical with regard to the process result, i.e., the recovery rate. Further considerations during the design phase are the avoidance of acid hot spots which reduce the lifetime, due to corrosion of the wetted parts, including components manufactured from titanium. Besides the process knowledge to design HPAL autoclaves, tools such as, Computational Fluid Dynamics (CFD) supplemented by lab testing allow the design of optimized agitation systems. This paper describes the effect that different feed point locations have on instantaneous blending of the reactants. Furthermore, experiments and CFD show where abrasion issues might occur and how to obtain information about the static and dynamic forces acting on internals. We show how simulations can be validated by lab testing to ensure that the CFD models are applied in an appropriate way.INTRODUCTIONAgitated systems in hydrometallurgical processes have to comply with multiple process tasks and in many cases have to withstand extreme operation conditions such as pressure up to 50 bar, elevated temperatures of up to 250°C and exposure to very acidic or alkaline environments and abrasive ores. The process tasks range from instantaneous mixing of reactants, homogeneous suspensions of up to 65% wt. solids with coarse and heavy particles, enhancing the solid-liquid mass transfer for leaching, dispersing large volumes of reactants (gas-liquid, liquid-liquid mass transfer) and moreover to transport generated heat e.g., from exothermic reactions through the vessel walls or internal heat exchangers if required. For economies of scale, agitator systems have reached sizes of 5000 m³ for large open leach tanks with impeller diameters of approx. 6 m, while autoclaves nowadays have exceeded 5.5 meters in diameter with a power demand for a single compartment drive between 300 - 400 kW. In parallel all process industries require a more efficient use of resources, to generate less by-products and higher yields, while ore-bodies tend to be less qualitative and new process routes (e.g. direct leach) are developed. Besides all these facts the mixing solution must be robust and economic. In this paper we want to address our approach in the development and designing of HPAL agitation equipment."

Jan 1, 2012

By G. Cavanough, A. Torrance

Emulsions have been developed for over forty years to become the most common water-resistant explosives used in the mining industry. An emulsion is a common commodity, with many examples in our day to day lives of one immiscible liquid dispersed in another. They have varying degrees of stability from a few seconds to years. What makes their application in explosives unique is twofold. They contain a high concentration of salts in the dispersed phase and also have a far larger volume of dispersed phase than continuous phase. The continuous phase contains at least 75% by weight of an oxidizer such as ammonium nitrate dissolved in water. The crystallization point of these solutions is often >60oC which means that the formation of the emulsion has to occur at an elevated temperature. Once the emulsion is cooled, its structure helps to prevent the formation of crystals in an otherwise unstable system. At room temperature there is a considerable potential for the small oxidizer droplets to crystallize which is countered by the strength of the oil layer and also the size of the emulsion droplet. If the emulsion droplet is too large then crystals can form which may lead to rapid deterioration of the emulsion and overall crystallization, accompanied by a temperature rise as the heat of crystallization is released from the emulsion. The size of the emulsion droplet is critical in preventing crystal growth and subsequent droplet coalescence and emulsion break down. One method of examining emulsions and understanding their structure is to use optical microscopy to measure droplet size and also emulsion deterioration from shearing, temperature cycling and when contaminants are introduced, such as detergents, different oil types, coating agents and dust particles. This paper reports on advanced techniques to quickly assess emulsion quality and stability

Jan 1, 2024

By K. R. Janowski, A. B. Chase, E. J. Stofel

Ruby crystals of exceptional optical quality have been grown from fluxes composed of Bi2O3 + PbF2 or Bi2O3 + BiF3. Careful control of growth conditions was required to minimize the number of growth defects consisting primarily of dislocations, occluded flux, and growth twins. Slow growth rates coupled with the addition of small amounts of La2O3 as a flux dopant were helpful in producing nearly perfect crystals. Chromium concentrations up to 1 pet were incorporated into these crystals without adversely affecting their perfection. Crystals up to 10 mm in diameter having as few as one to ten dislocations per crystal were typical of those produced under optimum growth conditions. Under these same conditions the occlusions were eliminated, and growth twins were either eliminated or reduced to one to three twin boundaries per crystal. INTEREST in the nature of lattice imperfections produced during the growth of ruby crystals (Al2O3-corundum structure) has been stimulated recently by the need for ruby lasers of good optical uniformity. As a result, ruby crystals grown by the flame-fusion (Verneuil) process have been studied in detail and have been found to contain high densities of dislocations (106 to 107 dislocations per sq cm) and mosaic structures that impair their optical quality.'-3 Attempts to improve the quality of Verneuil-grown crystals by controlling the growth variables have not been entirely successful. On the other hand, rubies grown by the flux process have received little attention even though their more nearly equilibrium growth conditions suggest that they would have fewer growth defects. Nelson and Remeika have shown recently that small flux-grown rubies can indeed be made into very low-loss lasers. However, they did not report information on crystalline imperfections in these crystals.4 Stephens and Alford have reported briefly on defects found in a flux-grown corundum crystal but they neither described these defects in detail nor related them to the method of growth.5 The present investigation was undertaken to establish the relationship between growth conditions and crystalline perfection of flux-grown rubies, sapphires, and other crystals of the corundum family. EXPERIMENTAL PROCEDURE The corundum crystals used in this study were grown by slowly cooling solutions of A12O3 in molten-salt solvents of PbO + PbF2, Bi2O3 + PbF2 or Bi2O3 + BiF3. The materials employed were Linde A (a Al2O3 powder) with reagent-grade chemicals as solvents. Some of the solutions also contained small additions (1 pet or less) of one or more of the transition metal elements chromium, manganese, iron, and titanium as crystal dopants. La2O3 was added to some of the solutions to alter the growth habit of the crystals. The La2O3 promoted the occurrence of growth facets parallel to (0112) and {1011} planes, where the indexing system is the morphological system described in detail by Kron-berg6 and used throughout this paper. The melts from which the crystals were grown were prepared by mechanically mixing the various constituents and placing them in platinum crucibles. The covered 50- and 100-ml platinum crucibles were heated in muffle furnaces at 1250°C for short periods of time (1 to 4 hr) and then program-cooled at either 2° or 4°C per hr to 1000°C. At this lower

Jan 1, 1965

By G. J. Mei

Separation of hematite and iron-containing silicate gangue - aegirine by Flotation using fatty acid collector and (NH4)2SiF6 depressant was investigated in this paper. The flotation tests with single minerals show Ammonium hexafluorosilicate (AHFS) is a selective depressant for aegirine in hematite flotation in weakly acidic medium, which can strongly reduce the flotation recovery of aegirine in the pH range of 4~5 while has no evident effect on the flotation of hematite. The results of flotation tests with actual ores show the separation of hematite from aegirine gangue by forth flotation was possible, and good selectivity was achieved. Chemisorptions were observed on aegirine mineral surface treated by AHFS solution by using SEM and IR spectrum measurements. On the basis of coordination chemistry, a comprehensive mechanism, which reasonably explains the selective depression of AHFS for iron-containing silicate, is also proposed.

Jan 1, 2014