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By John A. Bonucci

AMAX Base Metals R&D, Inc. has developed technology for extracting and recovering platinum and palladium from spent automobile exhaust emission control catalyst. Our most promising route is a chloride-based hydrometallurgical flowsheet in which catalyst pellets or crushed monoliths are leached in HC1 with an oxidant at 95°C without agitation. Alumina co-dissolution can be limited by thermal pre-treatment of the catalyst. The leach solutions are treated by one of several precious metals recovery techniques to produce a high grade PGM concentrate. For the new generation of three-way catalytic converters which contain rhodium, an H2S04 preleach could selectively extract much of the rhodium while leaving the platinum and palladium behind. Capital and operating costs will be discussed.

Jan 1, 1984

By J. J. Bean

Concentrating mixed sulfide-oxide copper ores by the leach-precipitation-flotation method is an old operation at the Miami Copper Co. The idea was conceived and the method developed at Miami by F. W. Maclennan and Harmon Keyes during the years 1929 to 1934, and it was these men who gave the term LPF to this process. Miami at that time had considerable reserves of mixed sulfide-oxide ore.* In the development of a suitable treatment method, it was natural that leaching of the oxides with acid and the precipita¬tion of copper from the resulting copper sulfate solution by iron was investigated. The separation… • The term oxide as used in this article includes the copper oxides, carbonates, and silicates.

Jan 12, 1960

By J. L. Huiatt, G. M. Potter, R. B. Tippin

The US Bureau of Mines and Great Salt Lake Minerals and Chemical Corp. have developed a froth flotation process for concentrating potassium salts from Great Salt Lake solar evaporites containing about 6% K2O. The crude evaporites, which were predominately halite (NaCl) with smaller amounts of kainite (KCl.MgS0, 2.7Hp0) and schoenite KeS0,MgS04.6H,0), were conditioned in a saturated brine solution., thus converting nonfloatable kainite to the floatable mineral schoenite. Schoenite was then selectively floated with a medium-molecular-weight fatty acid. Continuous small-scale pilot-plant testing indicated that 80% of the potassium could be recovered from the crude evaporites in flotation concentrates assaying about 13% K2O.

Jan 1, 1976

By Matthew D. Viergutz

MECS? HRS technology has reliably recovered intermediate pressure steam from sulphuric acid plants for more than 20 years. This steam can either generate electricity or replace steam produced by an existing fuel-fired boiler. As worldwide greenhouse gas emissions continue to rise, industries are looking for novel and cost effective solutions to reduce pollution, particularly carbon dioxide, from their plants. Waste heat recovery technologies such as HRS offer new and existing plants the opportunity to maximize energy efficiency while reducing their reliance on energy supply from external sources. This paper offers a unique look at energy recovery in sulphuric acid plants and how recent innovations in MECS? Heat Recovery System technology make HRS more financially viable ? and more green - than ever.

Jan 1, 2009

By Matthew D. Viergutz

MECS? HRS technology has reliably recovered intermediate pressure steam from sulphuric acid plants for more than 20 years. This steam can either generate electricity or replace steam produced by an existing fuel-fired boiler. As worldwide greenhouse gas emissions continue to rise, industries are looking for novel and cost effective solutions to reduce pollution, particularly carbon dioxide, from their plants. Waste heat recovery technologies such as HRS offer new and existing plants the opportunity to maximize energy efficiency while reducing their reliance on energy supply from external sources. This paper offers a unique look at energy recovery in sulphuric acid plants and how recent innovations in MECS? Heat Recovery System technology make HRS more financially viable ? and more green - than ever.

Jan 1, 2009

By Richard E. Thill

Backfilling of mine voids is used to prevent or control the effects of subsidence on surface structures. The pumped-slurry, blind-backfilling process has been particularly successful for stabilizing ground over abandoned and inaccessible underground coal mines. Using this newer technology, vast quantities of backfill material can be distributed over wide areas in underground openings from a small number of injection boreholes. The rapid and successful development of this backfilling method, however, has outstripped technology for monitoring and controlling backfill placement. Surface or borehole remote sensing methods are needed to determine where fill material is being distributed underground and how effectively the material is packed in the voids. In search for improvements in backfill monitoring and control technology, potential remote geophysical sensing, process monitoring, and tracer methods were evaluated to select candidate systems for monitoring backfill placement under the constraints imposed by the injection process and the surface and subsurface conditions. ' A multiple objective ranking matrix, based on theoretical considerations as well as pragmatic experience with systems working in related or similar conditions, was used to narrow down potential methods to several most-favored candidates. Two of the candidates were field tested under actual operating conditions at a backfilling site in the Wilkes-Barre-Scranton region of northeastern Pennsylvania. Although process and acoustic emission monitoring indicated promise for improving existing backfill monitoring technology, more extensive testing under different conditions at various sites is required to establish the validity and utility of these methods. Results indicate that no single method is adequate in itself for backfill monitoring, and that a successful system will require the Integration of several methodologies.

Jan 1, 1982

By Pierre Roy, Claude Gosselin, Maryam Sadeghi, Michel Bourassa, Christian Rochefort, Claude Bazin, Gautier Mahieu, François Lavoie, Marilène Renaud, David Cataford

"Spirals are gravity concentrators used for the concentration of iron oxide minerals from ores. This paper presents the mineral size recovery curves observed for spirals operating in two Canadian iron ore processing plants. The size recovery curves are presented for rougher, cleaner and re-cleaner spirals. The partition curves observed for the spirals are significantly different than those observed for typical gravity concentration devices such as hydrocyclones or hydraulic classifiers. The size recovery curves show the complex behaviour of the minerals as they flow down a spiral and are analysed with a view toward process modelling and simulation. Initial simulation results show that gains in the iron recovery can be achieved by increasing the recovery of coarse iron oxide particles in the rougher spirals.INTRODUCTION Spiral concentrators are gravity based separation devices used for the preparation of coal, iron and different heavy minerals ores (Wills, 1992). The classification of the particles in spirals is based on the combination of gravity, centrifuge, drag, lift and Bagnold forces (Atasoy and Spottiswood, 1995; Burt, 1984; Bouchard, 2001). Several papers are dedicated to the analysis of the forces acting on the particles flowing down a spiral (Das and al., 2007; Sivamohan and Forssberg, 1985; Holland-Batt and Holtham, 1991; Holtham , 1992). Most of these papers aim at the development of a general model for the simulation of the classification of the particles for coal ore processing. Few papers deal with the operation of spirals for processing iron ores (Hyma and Meech, 1989; Srivastava, 2001; Dallaire et al., 1978) and fewer papers present results for spirals used as cleaners following a rougher stage. Since the classification in spiral classifiers is dependent on the particle size and specific gravity a partition or performance curve commonly applied to classifiers (Mai Manga et al., 2012) is used here to analyse spiral operation. Few papers were found to describe the operation of spirals in terms of partition curves (Atasoy and Spottiswood, 1995; Holland-Batt and Holtham, 1991; Richards et al., 2000). Most of the investigations presented the application of a model to simulate the position of coal particles of various sizes and specific gravities along the trough of a spiral (Kapur et al., 1996; Holland-Batt and Holtham, 1991). In addition most of the available literature on spirals deals with one stage of concentration by spirals (Dallaire et al., 1978; Das and al., 2007; Sivamohan and Forssberg, 1985) while industrial circuits usually consist of rougher and cleaner spirals."

Jan 1, 2014

By Sherwin F. Kelly

PLAIN mining engineers usually avoid any gathering of geo¬physicists because of the incomprehensibility of their discussion to the uninitiated. This being so, gradients, gravity and gammas will be deferred to the end of this review, the first part of which will be devoted to what has been done in applying geophysics to the solution of real field problems. From the West, J. J. Jakosky reports that International Geophysics has had its activities fairly well 'divided between mining (both placer and lode), oil structural work, and clans-site and reservoir investigations. In oil exploration, electrical methods are used for depths down to 2500 ft., beyond which they utilize seismic methods. They find in their placer work that the many 'magnetic anomalies encountered in the bedrock of the Southwest render the electrical techniques more satisfactory, and with them they are obtaining thickness and tonnage of gravels, depth to and contour of the underlying bedrock as well as important structural features therein, and water-table elevations.

Jan 1, 1934

By Ulf B. Andersson, Christina Dahnér-Lindkvist, Bruno Figueiredo, Jessa Vatcher, Jonny Sjöberg, Joel Andersson

Hydraulic fracturing to precondition the rock mass in high seismic risk environments has great potential. Unfortunately, there are many unanswered questions about how to best implement a hydraulic fracturing program at individual mine sites, and even how to best use our engineering tools to evaluate these plans. To give the hydraulic fracturing field tests at LKAB’s Kiirunavaara Mine the best chance of success, fully-coupled, discontinuum numerical modelling Itasca’s 3DEC code was used together with statistical simulations of the fracture network. For modelling purposes, it was assumed that hydraulic fracturing successfully reduces seismic risk through 1) the creation of hydraulic fractures along a plane at each injection site, and 2) activation of existing discontinuities. A variety of scenarios for the mine were evaluated, which focused on site specific uncertainties (such as the spacing of the pre-existing discontinuities) and practical solutions (such as the hydraulic fracture spacing, selection of injection medium, and hydraulic fracture site location relative to production). The discrete fracture network (DFN) realizations were developed using available statistical data for discontinuities near where hydraulic fracturing was planned.

Apr 26, 2022

Metsim is proving to be a powerful tool when designing a heap leach operation. The most useful outputs arc determining the fluctuations in pregnant solution recovery rate, make-up water rate, gold recovery rate. and pond levels. Detailed data are needed for input: a pad loading schedule, a mining rate schedule for each ore type, column leach test data for each ore type, column tests on water dynamics (ie hourly flow-out versus-in during saturation and drain-down), monthly rainfall and evaporation data, and proposed pond dimensions. These data allow 'what if' studies on application rates, leach rates, loading rates and other variables of interest. Examples will he given of modelling both a rectangular pad and a valley fill operation.

Jan 1, 1994

By Craig S. Hartley

An approximate expression is obtained for the energy of a closed dislocation loop in equi1ibriu)n with a constant net stress. The result obtained is valid for loops in isotropic or anisotropzc materials provided that they are suJficiently large that the energy per unit length of a segment of the loop can be approximated by that of an infinite straight dislocation tangent to the loop. It is shown that this approximation leads to very close agreement with a more rigorous calculation of the elastic energy of a circular glide loop. The Gibbs-Wulff Form, GWF, of a dislocation is the closed planar loop which has the smallest elastic self-energy of all possible loops having the same Burgers vector and enclosing a fixed area, A.' The energy of such a loop is related to the net resolved shear stress* required to expand the loop and to the stress required to activate a Frank-Read source.223 In the following sectiorls the problem of determining the form of the GWF is discussed and an approximate method for calculating its elastic self-energy is presented. It is demonstrated that the approximations employed lead to no serious errors when applied to a calculation of the elastic energy of a circular glide loop. This method is then used to obtain a closed form expression for the energy of GWFs in isotropic and anisotropic materials. THEORY Burton, Frank, and cabrera4 have proved that the relationship of the equilibrium shape of a two-dimensional array of atoms under the influence of the Gibbs free energy associated with unit length of its boundary, G(O), is that the polar plot of G(0) vs 0 is proportional to the pedal of the GWF.* The angle 0 is measured "The pedal of the polar graph ofG(0) vs0 is the envelope of tangents to the eraph.relative to some crystallographic reference direction. The difficulty in applying this result to a closed dislocation loop arises from the self-interaction of the loop. For a dislocation the energy analogous to G(0) is a function of the total configurati~n.~ Consequently the relation which determines the GWF is an integro-differential equation rather than the simple differen- tial equation which results when G(8) is a function of 0 alone. Mitchell and smialek3 and Brown~ have used the self-stress concept introduced by ~rown' to calculate the shapes of dislocations in equilibrium with an applied stress. In this approach the glide force on an element of the dislocation loop due to the interaction of the element with the rest of the loop is equated to the glide force exerted by the local applied stress. The shape of the loop is then adjusted so that the two forces above are equal at all points on the loop. It is possible to calculate the energies of such loops by noting that, for equilibrium with an applied stress, the energy is equal to pijbiAj (summation convention) where bi is the Burgers vector, p.. is the local net stress tensor, and Ai is a vector directed perpendicular to the plane of thd loop with magnitude equal to the area of the loop. Also Brown' has calculated the energy of a hypothetical polygonal GWF using the above technique and anisotropic elasticity. However, his indicated solution for the energy in the general case of an arbitrary GWF is only slightly less involved than an iterative solution of the integrodifferential equation referred to earlier. In the present work the approximation employed by DeWit and Koehler' is used to calculate the energy of a closed loop in equilibrium with an applied stress. That is, the energy of a loop segment, ds, is approximated by the product of ds and the energy per unit length of an infinite, straight dislocation in a cylinder coaxial with the tangent to the loop at the angular position of the segment. This is known as the "line tension" approximation. The inner cutoff radius of the elastic solution defines the core radius, while the outer cutoff radius is determined by some characteristic dimension of the loop. Actually, both of these radii vary with the edge-screw character of the segment. The effective core radius changes because of the orientation dependence of the Peierls width of a dislocation,8 and the outer radius should be the radial distance from the circumference of the loop to the center of symmetry of the area enclosed by the loop.g However, since the energy varies logarithmically with the ratio of these radii while depending directly on the effective elastic constants, only the effect of the latter is considered. This approximation also neglects the self-interaction of the loop segments. For small loops this will doubtless be extremely important, but for large glide loops produced by plastic deformation the self-interaction is not nearly so important in determining the energy of the loop. This point is illustrated by the following calculation of the energy of a circular loop. Consider a circular loop of radius R which lies in the XI - x, plane of an infinite isotropic continuum and whose Burgers vector makes an angle $ with xs. The first-order solution for the elastic self-energy is:'

Jan 1, 1970

By A. Landsberg

Kaolinitic clays are potentially a vast domestic resource for aluminum. Utilization of this resource could decrease or eliminate the nearly complete dependence of the United States on foreign raw materials for this important metal. Furthermore, processing of clay to aluminum through anhydrous chloride metallurgy could reduce the high electrical energy requirements of the conventional Hall-Heroult aluminum reduction process. Several anhydrous chloride processes have been proposed; however, unresolved technical problems have prevented their commercialization. In particular, an acceptable chemical means has not been found to extract aluminum from clay as a highly pure anhydrous aluminum chloride. This Bureau of Mines report identifies and discusses the important chemical problems involved in achieving an acceptably rapid, self-heating, selective chlorination reaction and the subsequent separation of iron chloride byproduct from the anhydrous aluminum chloride.

Jan 1, 1983

By L. J. Barnes, R. O. Koch, J. H. Versteegh, C. J. N. Buisman, P. J. H. Scheeren

Several water treatment options have been studied and piloted. A process based on activity of sulphate reducing bacteria combines sulphate removal and heavy metal removal in one process step. The anaerobic bacteria reduce the sulphate to sulphide and consequently metal sulphides will precipitate. The final design for the commercial scale plant is described.

Jan 12, 1992

By Jaques A. L, Heinrich C. A

Mt Todd lies towards the south end of the Pine Creek Geosyncline, sandwiched between the Cullen Batholith and the Edith Falls Basin, in an area of regionally metamorphosed sandstones, siltstones and shales. The Batman deposit, some 3 km west of Mt Todd is a sheeted quartz vein system hosted within greywackes of the Palaeoproterozoic Burrell Creek Formation (Finniss River Group). The gold-bearing quartz veins, trending 010¦-020¦ and dipping 60¦-70¦E, are commonly 0.5 to 5 cm wide and occur at intervals which are from 10 cm to 1 m apart. Gold tends to be restricted to the quartz veinlets and immediately adjacent country rock. Grade Control utilises two 4 m 'collar' samples which are collected from each 8 m production blasthole. The irregular distribution of the quartz veins and erratic gold mineralisation has resulted in a disseminated 'salt and pepper' type of gold occurrence, with only a poorly defined footwall. Delineation of ore and waste blocks for mining uses an approach which combines the smoothing effect of kriging with a pragmatic view of the raw data. Large ore blocks with simple geometry help to minimise mining dilution, reduce block variance and give good reconciliations to interpreted ore tonnes and grade. Daily mine face advance is reported against truck counts and provides continual comparison with budgeted production. All data processing uses Gemcom software, together with Lotus spreadsheets.

Jan 1, 1994

By W. J. Fene

The lowest number of fatalities from coal-mine explosions in the United States in any year since records have been kept was the total of 8 in 1949 and again in 1950. Even incomplete records as far back as 1870 reveal a larger annual loss of life from explosions. From 1890 to 1948 the lowest annual loss was 32 in 1946. A smaller total of 15 fatalities was reported in 1952. Figure 1 shows the total yearly loss of life from explosions in all coal mines since 1880. Those in anthracite mines alone are shown by the shaded area. The erratic variation of the chart line shows the difficulties that have confronted the industry in the struggle to control and eliminate mine explosions. Potential hazards have existed in marry mines without realization that only a small change in conditions could initiate a disaster. Many disasters causing great loss of life occurred in mines that had been regularly operated without incident for long periods. Although the number of coal-mine explosions causing great lose of life has been kept down in recent years, the exceptions still make the record anything but satis¬factory. There have been almost no widespread explosions for several years, but in a few instances many lives were lost from afterdamp. Although the violence and spread of mine explosions may be controlled, the loss of life may be heavy if many of the men happen to be in the path of the smoke and gases. For these reasons, the strictest controls must be maintained to eliminate all factors that might combine to cause even a small ignition of gas or dust.

Jan 1, 1953

PRESIDENT BUBB: Gentlemen, this gathering marks the thirty-third mile- stone of the Rocky Mountain Coal Mining Institute. The Chair earnestly hopes our discussion of valuable papers which have been prepared so painstakingly by our members and friends of the Institute will assist us in the solution of problems common to our industry. The reading of the minutes will be the next order of business. For your guidance it has been customary in the past to dispense with the minutes on motion from the floor, inasmuch as the minutes are printed. May I have a motion to that effect? MR GILBERT DAVIS (Dawson, New Mexico): I move that the reading of the minutes be dispensed with. (The motion was regularly seconded, voted on and carried).

Jan 1, 1935

By John D. Morgan

The U.S. economy annually needs over 4 billion tons of new mineral supplies. The value of domestically produced energy and processed materials of mineral origin exceeds $175 billion annually, but domestic production of both raw and processed minerals is not keeping pace with demand.

Jan 1, 1974

By Georgene Renner, William R. Yernberg, Steve Kral

Advanced Terra Testing (ATT)is a full-service geotechnical testing laboratory. It specializes in rock and soil mechanics and geosynthetic materials testing. ATT provides services to the global mining industry. The company has performed more than 1,000 projects for more than 300 commercial and government clients. Services include coal pillar design testing, leach pad material and performance testing, tailings pile consolidation testing and closure and remediation services. Rock and soil mechanics tests include unconfined and triaxial strength, shear and tensile strength, permeability, index testing, consolidation, liquifaction potential, elastic moduli determinations, heap height versus percolation rate, long-term batch testing and dynamic loading tests.

Jan 1, 2003

By Roy G. Mead

BECAUSE of its magnitude, and the type of occurrence, the deposit of boron minerals in the Kramer district, Kern County, California, is unlike any other in the world. Discovery of this vast deposit has brought about many changes in the borax industry, so a discussion of the geology, and the occurrence, would not be complete without a brief history of the development of the borax industry. Until the discovery of boron minerals in the desert regions of California and Nevada some seventy years ago, borax was imported from Tibet and India, principally for medicinal purposes, at almost prohibitive prices. Following the discovery of commercial deposits of boron minerals in California and Nevada, and the subsequent development of new uses for borax and boric acid, the consumption has steadily increased until today borax is used in some form or other in every household.

Jan 1, 1933

By Wieland D. R., Hurst R. E., A. R. Hendrickson

Analysis of acidizing techniques, in correlation with reservoir data and a backlog of past treatments, has resulted in the development of a valuable engineering guide for planning acidizing treatments. Such treatments fall into three categories: (I) acid injection into the pores of the matrix; (2) acid injection into natural formation fractures at less than parting pressure; and (3) combination acidizing-fracturing treatments in which acid solutions (without propping agents) are injected at treating pressures sufficient to open and extend fractures through which the acid flows. Because the spending tirnze of acid during a specific well treatment does not change appreciably, maximunl penetration is attained when the first increment of injected acid is completely spent. Additional acid injection cannot be expected to further extend the benefits of the treatment. Depth of penetration will depend upon the reaction rate of the acid under treatment conditions, the injection rate of the acid into the matrix or fractures and the area-volume relationship existing in the flow channels. Based on Darcy's flow formula, extremely low injection rates must be used in order to keep bottom-hole injection pressures below formation fracturing pressure. As a result, only limited penetration of unspent acid will occur. Treatment records indicate that, in most acidizing treatments, formation parting pressures are exceeded, greatly extending acid penetration. Under these conditions, stimulation benefits are limited to the fracture area produced during the spending time of the first increment of acid injected into the formation. This area may be calculated from laboratory and well data to estimate depth of penetration. This, in turn, may be correlated with productivity data to assist The art of gas and oil well acidizing has been characterized by many changes in treating materials and techniques since its inception. These developments have been designed to provide greater production increases. prolong production declines and shorten payout time. Such improvements have been based primarily on data derived from laboratory research and field experience. As more of the variables influencing these treatments have been recognized and evaluated, acidizing has become less of an art and more of a science. Recent studies of fracturing treatments,' in light of individual well conditions and the results of thousands of fracturing treatments, made possible the formulation of an engineering guide that is now being used to select optimum treating techniques and to forecast probable results of such treatments. A similar analysis of the factors controlling acidizing treatments has been made and is the basis for this paper, The findings herein can be used as a guide in the selection of acidizing solutions and techniques, tailored to fit specific well conditions and to provide optimum stimulation per dollar cost. Acidizing treatments may be classified into three basic categories—(1) treatments in which the acid is injected uniformly into the pores and flow channels of the matrix, (2) treatments in which the acid enters natural fissures and fractures in the formation at less than fracturing pressures and (3) injection of acid into the formation at a pressure sufficient to open and extend fractures into the rock through which the acid penetrates (without the inclusion of a propping agent). TYPE 1 — MATRIX ACIDIZING This category consists of treatments in which acid solutions are injected into a homogeneous carbonate