Search Documents

By J. C. DeSantis

Thin, highly reflective rhodium films with metal compositions greater than 98% (elemental -weight percentage) have been deposited by chemical vapor deposition using Rh(allyl)3 (ally1 = q3-C3H5) in the presence of a hydrogen plasma. Uniform, crystalline films that adhere well to several types of substrates result from depositions at temperatures as low as 150°C. Depositions using H2 (no plasma), or an argon plasma yields material that is amorphous, contains a significant amount (>14%) of residual carbon, and has a dramatically slower growth rate. The composition of these materials does not vary significantly from that of the materials obtained from the in vacuo thermal deposition with Rh(allyl)3.

Jan 1, 1992

By P. Pięta, A. Surowiak, T. Niedoba

In a flotation process of copper ore three factors were measured: copper grade in concentrate (β), copper grade in tailings (J) and recovery of copper in concentrate (e). The experiment was conducted by means of the Jameson cell. The factors influencing the quality of the process were particle size (d), time of separation (t), type of the collector (k) and dosage of the collector (s). The considered vector function was then [β(d, t, k, s), J(d, t, k, s), e(d, t, k, s)]. Optimisation achieved was based on determining the values of the adjustable factors (d, t, k, s). The goal was to obtain the highest possible values of functions β and e (maximum) and the lowest possible values of function J (minimum). To this purpose the taxonomic methods were applied. Keywords: Flotation, copper ore, lithology, flotation agents, particle size distribution, taxonomic methods

Jan 1, 2020

By Ali Dehghani Ahmad Abady

In Sarcheshmeh Copper Complex, a molybdenite floatation concentrate was produced by selective removal of copper impurities with 7 stages of cleaner floatation banks, that contains around 1% copper and 54.5% molybdenum. Mineralogical studies, physical and chemical characterizations showed that the sample contained 91% molybdenite (MoS2), 2.6% chalcopyrite (CuFeS2), 0.2%Covellite (CuS), 1.6% pyrite (FeS2) and 4.6% other nonmetallic impurities. In the present study, the removal of the copper sulfide was investigated by ferric chloride leaching for achieving a molybdenite concentrate with copper content less than 0.3%. Therefore, the application of response surface methodology (RSM) for modeling and optimization of the influence of three control parameters including ferric chloride (FeCl3) dosage, reaction temperature and reaction time, each varying in five levels, were considered, and the mathematical model for prediction of %Cu removal from molybdenite concentrate was derived. This study showed that RSM could effectively be applied for the modeling of ferric chloride leaching, and finding an economical optimum condition to achieve maximum de-coppering efficiency while consuming minimum leaching reagents. The optimum dissolution conditions to maximize Cu extraction were 200 kg/t for ferric chloride dosage, 120 min for reaction time and 80 °C for reaction temperature with a prediction of 83.20% Cu dissolution. Keywords: molybdenite concentrate, ferric chloride, leaching, response surface methodology (RSM)

Sep 1, 2012

By Gwendolyn D. Hood

The U.S. Bureau of Mines developed a dewatering technique for treating wastewater that was tested on waste slurry from a commercial tile company in Alabama. Raw wastewater samples were pretreated with 10 Ib calcium chloride and 10 lb Wyoming bentonite per 1,000 gal of slurry. After pretreatment, polyethylene oxide (PEO) at dosages varying from 0.05 to 0.20 lb per 1,000 gal was mixed with the waste slurry, forming strong, tough floes that were separated from the clarified water using a trammel. The flocculated slurry was dewatered to a consistency that could be handled for subsequent disposal in a landfill. The clarified water quality was equivalent to that of the company's present treatment system.

Jan 1, 2010

By O. N. Carlson, W. M. Paulson

A phase diagram is proposed for the Y-C system based on the vesults of thermal analyses, microscopic obsevvations, and X-ray diffraction studies. Three intermediate phases occur in the system: a congru-ently melting fcc phase with a wide range of homogeneity about the composition Y2C, an intermediate solid-solution region between 55 and 58 at. pct C, and a bct dicarbide melting congruently at 2415°C. All three compounds undergo a phase transformation at elezlated temperatures. A continuous serzes of solzd solutions exists between the fcc phase and the high-temperature form of YC2 with a maximum in the solidus at 2000°C and 30 at. pct C and a minimum at 1805°C and 54 at. pct C. THIS investigation of the Y-C system was undertaken as part of a nuclear materials development program. Yttrium-base alloys are of interest as possible containers for liquid metals, and carbides are currently receiving increased attention as high-temperature materials for advanced reactors and other applications. Previous work on this system was limited in scope, and the results were somewhat inconclusive and at times contradictory. Spedding et al.&apos; reported the existence of a triyttrium carbide having an fcc structure with a wide range of homogeneity and Dean et a1.2 reported the existence of a rhombohedra1 phase having the stoichiometry of Y2C. Bachella et a1.3 observed that the latter was the result of ordering of carbon atoms in the fcc solid solution. The ordering range was placed at 800" to 1000°C. Vickery et a1.4 reported a high-melting compound which they identified as yttrium dicarbide, and Spedding and coworkers1 determined the structure of this phase as bct with lattice parameters a = 3.66 and c = 6.17A. Samsonov et al.5 reported the melting point of YC2 as 2300" * 50°C. Recently Bowman et a1.6 found a transformation in the dicarbide from the tetragonal to an fcc form at 1320 20°C. Samsonov and coworkers7 reported a monocarbide of yttrium melting at 1950" * 20°C and also a sesqui-carbide melting at 1800" * 50°C. The existence of the latter has also been indicated by others,1&apos;8 but neither compound has been definitely established. The Y-C phase diagram shown in Fig. 1 was proposed by Chubb and Keller8 in 1964 based on the data available at that time. The tentative nature of this diagram together with the uncertain status of the compounds indicated that additional work on this system was needed. EXPERIMENTAL PROCEDURE Yttrium metal of 99.9 pct purity was prepared for use in this study by the reduction of YCl, with calcium to form a sponge product.9 The major impurities in this material were as follows: 100 ppm C, 150 pprn H, 20 ppm N, 300 to 1000 ppm O, <20 ppm Ca, <100 ppm Cr, <80 ppm Cu, 150 ppm Fe, <30 pprn Mg, <400 ppm Ta, and <100 ppm Ti. Alloys were prepared by arc melting yttrium sponge together with pieces of high-purity graphite rod in a purified argon atmosphere. Homogeneity was insured by repeated melting, inverting the ingot between melts.

Jan 1, 1969

By L. Villa, O. Suarez, D. Arias, L. G. Corretge

The deposit comprises two vertical, lenticular bodies emplaced in the allochthonous block of a Variscan thrust. Epigenetic mineralisation occurs as replacement of carbonated volcaniclastic rocks of Cambro-Ordovician age. The dominant sulphide minerals are sphalerite and galena with minor chalcopyrite; the main non-metallic mineral is quartz and there is hydrothermal silicification, chloritisation and sericitisation. Sulphur isotope values for sphalerite and galena are heavy and reflect the fundamental relationship between delta-34S in ZnS and in PbS, suggesting isotopic equilibrium. Four sphalerite-galena pairs yield temperatures between 163 and 218 degrees C, in good agreement with the 187-207 degrees C estimated by the Ga/Ge-sphalerite geothermometer. The ore sulphide was leached by the hydrothermal solution from diagenetic pyrite in the host rocks and disseminated sphalerite and galena in Cambrian carbonates

Jun 19, 1905

By Raj Thamburaj

"Over the last few decades, the emphasis on affordability and reduced cost of ownership has necessitated the development of innovative processes to carry out repairs in aero engine components. Conventional weld and braze repairs have evolved into advanced, sophisticated processes using state of the art knowledge in lasers, robotics and materials technology. This paper illustrates past and present scenarios in an attempt to illustrate progress that has been made in this area. The problems encountered in the past have been detailed along with the solutions that have been developed and commercially implemented to address these issues. Apart from technical progress, this presentation also addresses the progress made in business approaches and in Certification/Regulatory issues surrounding aero engine repair. Progress in Technology Repair technologies have also been the embryo from which new and revolutionary manufacturing technologies have evolved as well. Electron Beam Free Forming and LENS are examples of how a completely new manufacturing concept can evolve what was originally only a process to join metals. The current and future potential of these spin offs is discussed providing examples of application. While several problems have been solved over time with the implementation of advanced repair technologies, the demands of the industry have created new challenges. The paper describes these issues, outlines potential solutions and discusses the future of repair technologies in terms of the far reaching influence it is sure to have in design, manufacturing, maintenance management and life extension. Progress in Business Trends.Business approaches to repair and maintenance have also gone through considerable change with the introduction of ""Power by the Hour"" and other similar arrangements between the companies responsible for engine overhaul and the end-users. Program Based Logistics (PBL) is yet another innovation to provide a win-win situation for the repair service provider and the end user. This paper traces the development of these business initiatives and highlights successful applications. Progress in Repair Certification, Regulatory Issues.Understanding of the issues surrounding certification of repairs has also evolved with time and regulatory issues have been clarified considerably. Procedures for analysis and testing are much clearer and ""Check Lists"" are being drafted for certifying repairs on various engine components. The PMA phenomenon has added yet another dimension to the issues regarding certification and these are discussed as well."

Jan 1, 2010

By M. L. Goble

"Inco Metals Ltd. (Manitoba Division) operates a mining, milling, smelting and refining complex, 500 miles north of Winnipeg in central Manitoba. The Thompson Mill is presently operating at 12,000 S.T.P.D. on ore from both underground and open pit mines. The ore is treated in two separate milling and flotation circuits utilizing a common crushing system which is located inside the main mill building. The milling facility employs approximately 43 operating employees, 30 maintenance employees and 20 staff in supervisory or process development roles.In recent years an increasing awareness of the potential hazards of contaminants in the work place has made it mandatory that all employers maintain careful and accurate records of the work environment to which each employee has been exposed during his working career.The importance of this record keeping and general observation of the work place cannot be over emphasized. Proper monitoring of the work place provides an accurate and complete record of the contaminants and physical agents to which an employee is exposed during his work career. This can aid in studies which might be conducted in the future and can also be used as a basis for instituting improvements to the workplace."

Jan 1, 1980

By K. F. Unrug

The method of coal pillar design involves primarily two aspects, the geometry of the pillar and the strength of the coal. However, the strength of the coal has to be emphasized with respect to the entire pillar dimension rather than isolated strength values of coal samples taken and measured from different locations. The presently applied pillar design systems do not specify clearly what the coal sample strength really represents. The intention of this paper is to introduce the concept of seam strength as opposed to the current practice of using coal strength as a prime design criteria in the formulation of pillar calculations. Seams are most of ten composed of multiple layers of coal, partings, and bone in different configurations, changing within the vertical section of the seam even in relatively close locations. The difference in strength between the weakest and strongest component of the coal seam could be as much as five times or more. An experimental approach based on multiple compressive tests performed on coal samples from the Coalburg and the Warfield seams from Eastern Kentucky was undertaken. The analysis of the results lead to the conclusion that for pillar calculations both the weighted mean of the seam strength and the strength of the weakest stratum should be considered rather than the relatively vague aspect of coal strength The design of pillar dimensions based on the above mentioned aspects should assure a more realistic design performance.

Jan 1, 1985

By E. B. Hunt

Paraffin deposition has been studied in the laboratory under conditions simulating deposition in well tubing. A theoretical analysis has been made of the cooling of the oil and the precipitation of paraffin from the oil as it flows up the well tubing and through surface flowlines. It is proposed that paraffin deposits are initiated by the precipitation of paraffin directly on or adjacent to the pipe wall and grow by diffusion of paraffin from solution to the deposit. This mechanism is consistent with laboratory and field observations, and has proved useful in the design and interpretation of laboratory paraffin-deposition tests. Tests have been made of the effect of plastic pipe coatings and chemical additives on paraffin deposition. INTRODUCTION Paraffin deposits which form in well tubing and surface flowlines interfere with production and must be removed. Over the years much progress has been made in developing and improving methods of removing these deposits after they form. Much less progress has been made in developing methods of preventing or inhibiting the formation of paraffin deposits. This is due, it is believed, to the lack of knowledge of the mechanism of paraffin deposition, the absence of satisfactory laboratory testing methods and the difficulties in evaluating the results of field tests of preventive treatments. The present investigation was undertaken to elucidate the mechanism of paraffin deposition and to develop suitable laboratory tests for studying the inhibition of paraffin deposition in well tubing and surface flowlines. Current theories on the mechanism of paraffin deposition have been evolved from field observations, from laboratory studies of various factors which might be involved in paraffin deposition, and from laboratory paraffin-deposition tests.1-9 Paraffin deposits have been formed in the laboratory by immersing a cold finger into a hot wax-oil solution and by flowing hot wax-oil solutions through cooled pipe or over cooled plates. These laboratory conditions differ in important features from field conditions, and the observed deposition behavior is not entirely field-like." Thus, there is reason to question the field applicability of the results of these tests. The present investigation was undertaken to determine how to perform and interpret laboratory paraffin-deposition tests to obtain information on the inhibition of deposition in the field. The paraffin problem in the broadest sense encompasses the formation of any predominantly organic deposit in well tubing, surface flowlines and other equipment in contact with crude oil or gas. The present investigation was limited to paraffin deposition involving the precipitation of paraffin wax from solution by cooling and its concentration in a deposit on a cooled surface. This probably excludes its applicability to those problems arising from asphaltic-base crudes, but not those arising from paraffin-or mixed-base crudes. This also excludes its applicability to emulsion and congealing oil problems which are often included as part of the paraffin problem. The phenomenon of cooling appears to be the controlling factor in paraffin deposition involving the precipitation of paraffin wax and its concentration in the deposit. Deposits of this type are usually found in the field only where cooling occurs. Early in this laboratory investigation, it was not found possible to form deposits under constant temperature conditions from a wax-oil slurry, either by steady flow through pipe or by gas-lift up a pipe. Thus, the investigation was limited to situations involving cooling. THEORY The relationships involved in establishing the temperature profiles in an oil stream as it flows up well tubing with a linear (geothermal) pipe-wall temperature distribution or through surface flowlines with essentially constant pipe-wall temperature are presented in the Appendix. The relationship between radial distance in the pipe and the rate of cooling of the oil is then combined with a relationship between cloud point and rate of cooling to develop the pattern of formation of a wax cloud in the oil. The following discussion of paraffin deposition under various laboratory and field conditions is based upon this development which is presented in the Appendix. PARAFFIN DEPOSITION IN SURFACE FLOWLINES The average temperature of the oil coming out of a well is somewhat higher than the ground temperature. Thus, the oil continues to cool on its trip through the surface flowline, and wax deposition can occur. The temperature distributions calculated from Eq. A-4 are given in Fig. 1. As can be seen, almost all the cooling occurs in the first 500 ft from the wellhead. In addition, the radial temperature gradient near the wall decreases rapidly with distance and becomes very small after a few hundred feet. Thus, growth of a paraffin deposit would be expected to decrease rapidly with distance from the wellhead and become negligible after a few hundred feet, since growth is dependent on concentration gradient. Wax precipitation and diffusion of wax to the already

By Carlos Collado, Oscar Jimenez, Francisco Diaz, Rodrigo Bernal, Carmen Salinas

Water is a strategic resource for the mining industry. The rising cost has forced the industry to become more efficient in their use, reduce and recycle waste as much as possible. The importance of having a reliable water balance is increasingly urgent, because the resource is scarce and vital to the sustainability of human life, animal and ecosystem. Conventional flowmeters can suffer disruptions or failures by corrosion, fouling, presence of elements in the water as acids, salts and suspended solids. Use of radiotracers is advantageous to determine fluid velocities that are transported through pipes, as they are detectable by means of the radiation emitted, the same way for surface flows, such as natural watercourses and drainage from tailings dams, fluorescent tracers are those with the best advantages. For velocity measurements in pipelines a Iodine-131 tracer solution, around 5 mCi was injected into the suction of the pumps. The technique used is the transit time between detectors at known distances and determining the time of passage of the radiotracer. For measurements of surface fluxes using the fluorescent tracer Rhodamine WT by tracer dilution technique, injecting the tracer at a constant rate and measuring it known concentration diluted downstream. This work has been performed in Minera Los Pelambres, located in the IV Region of Chile, measuring the flow rate pumped from 12 pools with 1-7 pumps operating, obtaining speeds of 0.56 to 2.62 m/s. In pumping wells three facilities have been measured at speeds of 0.111-0.223 m/s, plus six surface flows with flow rates of 8.45 to 357.2 L/s.

Jan 1, 2014

By Jorge Ganoza

Hay varios ejemplos recientes de proyectos que no han llegado a los niveles de producción o a los resultados del modelo financiero desarrollado durante el estudio de factibilidad. Las personas responsables de decidir la inversión en los proyectos deben poder percibir los problemas potenciales y los grandes riesgos, cuando hay decisiones mal tomadas en el estudio de factibilidad y en la etapa de construcción inicial. Si bien es cierto que no hay diseño de ingeniería perfecto, los problemas pueden evitarse si —tal como propone este artículo— se siguen las etapas de estudio necesarias, desde la toma de muestras hasta la ejecución e interpretación de los resultados de las pruebas metalúrgicas.

Nov 30, 2018

By K. C. Strebig, C. W. Schultz, A. A. Selim

For some time researchers have attempted to in- crease drilling efficiency (and therefore reduce costs) by adding certain chemical agents to the circulating medium. The effect of some organic additives on the diamond drilling of quartzite was recently investigated in the laboratory by personnel of the U. S. Bureau of Mines. In these tests, the penetration rate and bit life were found to increase with the use of additives. In addition, an economic analysis of a hypothetical 1000-ft hole showed that additives can reduce drilling costs by 30%. Wetting Agents Improve Drilling Efficiency Much of the interest in the use of wetting agents to improve drilling efficiency is the result of an observation made by Rehbinder, Shreiner, and Zhigach.1 These investigators postulated that drilling creates a region of increased crack formation directly below the bit and that a circulating medium that wets the rock will also penetrate the micro- cracks of the predestruction zone. Increasing the molecular affiinity (wetting ability) of these circulating media for the surface of the rock helps the deformation and destruction by softening the rock in the zone of increased crack formation. In this manner, the hardness or strength of the rock is decreased as the medium wets the rock in the predestruction zone. This is known as the "Rehbinder effect." Rehbinder&apos;s work has prompted many investigators to examine the relationship between the use of additives and the mechanical destruction of rock. Engelmann, Terichow and Selim reported that the maximum penetration of the rock by a diamond point in a solution environment was at the isoelectric point of the mineral and solution interface.2 Improvement in rock breakage with the use of additives was observed by Frangiskos and Smith.3 Joris and McLaren suggest that additives having a lower surface tension than water will also be more efficient in cooling the diamonds.4 Additives help remove fine cuttings from the face of the bit and improve efficiency. The latter two authors also report an improvement in impregnated bit life and penetration rates with the use of soluble oil additives. All of these investigations were initiated in the hope of discovering what economic benefits will accrue with the use of additives.

Jan 10, 1969

By P. Taskinen, D. Lindberg, H. Viitala

The formation of copper chlorides in flue dust or deposits in heat recovery boiler of copper smelters or waste-fired boilers may lead to formation of corrosive partially molten deposits on walls and heat exchangers of the boilers. These deposits can contain various other metals, such as alkalis, Fe, Zn, Pb together with oxides and sulfates. In the present study, a thermodynamic model for copper-containing binary and ternary metal chloride systems within multicomponent CuCl-CuCl2-FeCl2-FeCl3- PbCl2-ZnCl2 system has been assessed and optimized based on own experimental phase equilibrium data, as well as literature data. The thermodynamic properties of the liquid phase was modelled using the quasichemical quadruplet model and a thermodynamic database was optimized to predict all available experimental data within the experimental error limits. The thermodynamic database allows for more accurate predictions of potential corrosion-related issues in various heat recovery boilers and waste-fired boilers due to formation of copper chlorides. INTRODUCTION In the copper flash smelting, flue dust can cause severe problems in the gas train, used for separating dust from the SO2-rich off gas, by forming corroding accretions on the walls of the heat recovery boiler. Formation of dust build-ups in the boiler need to be cleaned regularly and potential corrosion damage checked, requiring costly and unscheduled shutdowns of the flash smelting process. Compounds of copper and zinc among other elements having high vapour pressures may volatilize during the smelting of the copper concentrate, forming dust when the process gas cools down. Also, particles of solid or liquid iron oxides originating from the ore get transported with process gas to the heat recovery boiler as a result of entrainment in the flue gas (Miettinen, 2008) The dust deposit build-ups on the boiler walls are formed partly by direct impact of particles and partly by vapour condensation on the boiler walls. The initial deposition takes place by the condensation of vapours that contain zinc, lead, arsenic and other metals having high vapour pressures. Also, low melting point eutectic components of alkali salts such as chlorides and sulphates can act as sticky cohesive particles attaching to the boiler walls. The fine particles landing on the surface of the porous dust deposit layer react in the SO2-rich atmosphere of the boiler to sulphates. The process gas within the boiler contains SO2, O2, SO3, H2O and N2 that diffuse into the porous accretions to form a stagnant gas layer within the dust deposit structure. The composition of this gas layer may differ greatly from the composition of the process gas that is flowing on the surface of the accretion layer. Locally HCl and H2SO4 are formed and even a reducing atmosphere may exist within the dust deposit layer, allowing new reactions to take place. The local micro-atmosphere may enable metal sulphates to be reduced to secondary sulphides and even metallic components. Within the accretion layer, components may be formed that would not be stable in the gas atmosphere inside the boiler (Miettinen, 2008). This may be the mechanism by which for instance chlorides of Cu, Fe and Zn are formed within the deposit layer.

Jan 1, 2019

By Stephen Iverson

The National Institute for Occupational Safety and Health (NIOSH) is currently performing research to help mine operators minimize the amount of loose or damaged rock surrounding a blasted opening. Improperly designed blast rounds can result in excessive wall rock damage that may reduce the rock mass competency and increase ground support requirements. Unnecessary blast damage can cause many safety and operational concerns including an increased potential for injury from rock falls and other hazards resulting from sub-optimal blast designs. This paper focuses on the ground control and safety implications of blast damage in underground mines. A reduction in rock quality due to blasting can increase the amount of ground support required. Case study data collected by NIOSH in underground metal mines during standard drill and blast production rounds included blast vibration monitoring, detailed three-dimensional laser scanning of the as-built excavation, and geotechnical mapping of development headings.

Jan 1, 2007

By J. C. Willett, J. R. Sanfilipo, P. D. Warwick

The U.S. Geological Survey has conducted an assessment of the Nation’s coal deposits that potentially could be mined during the next 30 or more years. For the Gulf Coastal Plain region, the assessment includes reviews of the stratigraphy, coal quality and resources, and coalbed methane potential of the Cretaceous, Paleocene, and Eocene coal deposits in the region. The results of these efforts are a series of digital maps, text, and tables published in CD-ROM format. Although abundant coal resources are available in the Gulf Coast region, coal quality issues may limit large-scale development in the future. Additional data are required to better evaluate the coalbed methane resource potential for the Gulf Coast region.

Jan 1, 2001

By M. Sengupta

Surface mining in arctic regions is characterized by many unique problems. Continuous and discontinuous permafrost (perennially frozen ground) occurs in most of the arctic and subarctic areas. Permafrost presents special problems of slope stability. Stability of permafrost depends on its temperature, moisture content, and material type. Permafrost slope fails due to solifluction, disturbance of ice-rich slopes, and liquefaction. Drilling and blasting of frozen ground present special problems. Depending on their degree of saturation with water, freezing soils and rocks have a number of important characteristics that affect blasting efficiency. Metals used in mining equipment and mining structures require special selection. At low temperatures, many steels lose most of their normal ductility and toughness (resistance to brittle fracture). This paper discusses engineering solutions to unique problems of arctic mining.

Jan 1, 1988

By Lei Zhang, P. Somasundara

The beneficiation of phosphate is complicated due to its sparingly soluble nature. The surface proper- ties of phosphate and associated minerals are determined, in addition to the ionic composition of the solution, by the dissolution of the lattice ions of the minerals and subsequent complexation, hydrolysis, adsorption, and precipitation of the dissolved species. These, in turn, are influenced by the pretreatment of the mineral. These complex interactions determine the interfacial properties of phosphate and associated minerals and thereby the efficiency of beneficiation processes such as flotation and flocculation. Under- standing of the chemistry involved in such systems is helpful to develop the optimum beneficiation schemes. It is shown that desired selectivity can be achieved by controlling the chemistry of the systems. More important, the need to conduct development tests under plant conditions is clearly demonstrated.

Jan 1, 1999

By Alan DonaldsoN

Plasma Quench production of titanium is the thermal dissociation of titanium tetrachloride into gaseous titanium and chlorine followed by rapid quenching to prevent back reactions. Titanium tetrachloride dissociates into titanium and chlorine atoms at 5000 K. Expansion through a Delaval nozzle accelerates the gas to supersonic speed cooling it very rapidly. Cooling rates are as high as 7exp 1 0 Kelvins per second. Injected hydrogen reacts with condensed titanium particles to form titanium hydride and with the chlorine to form hydrogen chloride. We have produced titanium powder at 20 kglh in a continuous reactor. Costs are projected to be lower than the Kroll Process at large enough scale. Most of the cost reduction would result from elimination of magnesium as a reducing agent and much lower capital costs.

Jan 1, 2001

By K. Morita, N. Sano

Thermodynamic properties of chromium oxides in molten slags are very important for optimization of stainless steel refining processes as well as reduction processes of chromium ores. The solubility of chromite into molten slags has been found to vary considerably with oxygen partial pressure and slag composition in former studies by the authors. In the present study, activity data and redox equilibria of chromium oxides measured under moderately reducing conditions, PO2= 6.95x10–11atm, at 1873 K are summarized. For the CaO-SiO2-CrOXsystem, the activity coefficient of chromium oxide increased with increasing basicity, and the optimized slag composition for stainless steel refining is assessed as that saturated with CaCr2O4and Cr2O3usingthe phase relations determined. On the other hand, the presence of MgO and Al2O3brings about different behaviour of chromium oxide activity and redox equilibiria and the 44 mass per centCaO-39 mass per cent SiO2-11 mass per cent Al2O3-6 mass per cent MgO slag is recommended toreduce the chromium oxidation loss in the practical stainless steel refining process at 1873 K. Keywords: chromium, activity, stainless steel, AOD, VOD, oxidation loss, redox, CaO-SiO2-Al2O3-MgO slag

Jan 1, 2004