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By Brian Langdon

The DRIVEN GROUT PILE was developed in 1989 by DeWitt Construction, Incorporated. This piling essentially consists of a cost-in-place concrete piling that reacts on a steel boot that is driven to bearing. This report will describe the driven grout pile, its background and its installation. The advantages and disadvantages of this system are also discussed. Finally, the results of actual field installations are presented and discussed. BACKGROUND The DRIVEN GROUT PILE was developed out of a need for a low-cost high capacity piling (100 ton) that could be installed with ordinary pile driving equipment. This search was motivated by attempting to incorporate the material economy of an auger-cast piling with the "empirical load test" of a driven pile. Typically, the least cost material for piling in the 100 ton range is concrete (grout). A grout shaft with minimal reinforcement can withstand a compressive load of 100 tons for a material cost in the range of $6.00 to $8.00 per lineal foot. A pipe piling with a capacity of 100 tons has a unit material cost ranging to $13.00 per lineal foot. The marriage of these two advantages resulted in the DRIVEN GROUT PILE. A pile that utilizes the economy of a reinforced grout shaft and has the loading confidence of a driven pile.

Jan 1, 1990

By G. R. Speich

The precipitation of the Feab and Fe,Ti Laves phases (MgZn, type, C14) from Fe-Nb and Fe-Ti solid solutions, respectively, has been studied in the temperature range 500" to 800°C using hardness measurements, light and electron microscopy, and X-ray and electron diffraction. The Fe-Nb alloys contained 0.96, 1.67, and 3.80 pct Nb and the Fe-Ti alloys 3.5, 5.8, and 8.8 pct Ti. In both systems only the equilibrium Laves phase is formed, with nucleation occurring at grain boundaries, at dislocations, and in the matrix. No cellular precipitation or transition phases were observed. The precipitation of the Laves phase in a fine dispersion leads to significant hardening in both systems. The hardness of the aged alloys is proportional to the reciprocal of the square root of the interparticle spacing. The maximum solid solubility of titanium in a! iron is 9.0 pct Ti at 1280°C. THE precipitation of the FezNb and FezTi Laves phases (MgZn2 type, C 14) from Fe-Nb and Fe-Ti solid solutions, respectively, has been investigated as part of a continuing study of the mechanisms of precipitation from ferritic binary iron-base alloys. The iron-rich portions of the Fe-Nb and Fe-Ti phase diagrams are shown in Fig. l(a) and l(b). The Fe-Nb diagram is essentially that given by ansen' with the more recent work of Hume-Rothery and Gibson2 added. Goldschmidt3 indicates that the FezNb Laves phase has a solubility extending from 32 to 55 wt pct Nb. The Fe-Ti diagram is also essentially that reported by Hansen.l The recent results of Nishimura and kamei, Murakami, Kimura, and Nishimura,' indicate that the FezTi Laves phase has a solubility extending from 22.5 to 30.5 wt pct Ti. The L/6 + FezTi eutectic temperature of 1298°C indicated by Kornilov and oriskina' has been adopted. The addition of niobium or titanium to iron lowers the 6 — y transformation temperature and raises the y — a! transformation temperature. This results in a closed y field in the Fe-Ti system, but the lower solubility of niobium in a! (6) iron results in a eutec-toid, 6 — y + FezNb, at 1200°C, and a peritectoid, y + FezNb —-a, at 989°C in the Fe-Nb system. The maximum solubility of niobium is reported to be 4.5 wt pct in 6 iron,' 1.0 wt pct in y iron,7 and 1.8 wt pct in a iron.' Some results from the present work indicate that the maximum solubility in a! iron is actually less than 0.96 wt pct Nb. The maximum solubility of titanium in a! (6) iron is somewhat uncertain since the early work of To faute and Butting-haus indicated a value of 6.0 wt pct while later work of Kornilov and Boriskina6 yielded a value of 14.0 wt pct. The present work indicates that the maximum solubility is actually 9.0 wt pct. In both systems the phase in equilibrium with the iron-base solid solutions is a Laves phase (Mg znztype, C14), FezNb or FezTi. Both of these Laves phases have a wide range of Solubility. The precipitation-hardening behavior of Fe-Nb or Fe-Ti alloys has not been studied extensively. Genders and Harrison' reported that binary Fe-Nb alloys hardened upon aging. Peter and Fisher7 studied the mechanical properties of Fe-Nb and Fe-Ti alloys quenched from different phase fields.

Jan 1, 1962

By Rodney L. Stone

As part of an overall laboratory and plant test program to determine mixing and other techniques relating to the more economic use of bentonite as an iron ore pellet binder, a settling test was developed for measuring the bentonite content within a pellet or within a batch of pellets. Between pellet batches, each containing a different level of bentonite, the dry fracture load is directly proportional to the bentonite content between pellets of the same batch, however, the fracture load is inversely proportional to the bentonite level; this is explained by a negative correlation between a pellet's size and its bentonite content and the fact that larger pellets can withstand a higher fracture load than the smaller.

Jan 1, 1968

By J. M. Hollicky

The economical processing of wet and sour natural gas presents a problem due to the seasonal demand for natural gas. The plants must be sized to handle the peak loads but may only operate at half capacity on the average, in which case the sales value of sulphur and hydro-carbon liquid by-products cannot support the operating and capital costs of the plant. This must result in an increased price for the gas. This problem was solved by Pacific Petroleums and Westcoast Transmission in the design of their pipeline and plant facilities now operating in the Peace River area, where there are both wet and dry gas fields. By .building a plant to process sufficient wet gas to pro-vide the base load requirement, and by drawing on the dry gas fields for peak loads, an optimum economic operation was ?possible. The sulphur, L.P.G., and gasoline produced not only are able to support the operating and capital costs of the pro-cessing plant, but were instrumental in the sharp drop in retail prices of these commodities in the area. The sour gas and condensate is gathered from the fields in the area and transmitted in a two-phase gathering system to the gas processing plant at Taylor, B.C. The condenrnte is knocked out in inlet scrubbers. Hydrogen sulphide and carbon dioxide are removed in an amine scrubbing unit. The hydrogen sulphide is stripped from the amine and is sent to the Jefferson Lake Sulphur Company's plant which produces sulphur by the partial oxidation of the hydrogen sulphide. The natural gas, now sweet, is processed in an absorption unit to recover additional liquids, before being de-hydrated to remove water. It is then sent to Westcoast's main c8mpression station. The condensate recovered in the inlet scrubbers and the liquid re-covered in the absorption unit are fractionated to remove fuel gas, used in the plant, and to produce pro-pane, butane, and naphtha. The pro-pane and butane are scrubbed with caustic soda to remove hydrogen sulphide. The naphtha is treated with hydrogen in a unifiner unit to re-move sulphur compounds completely, and is split into a light and heavy naphtha. The heavy naphtha is .catalytically reformed to produce a high-octane blending-component. These fractions are blended with components produced from crude oil at the Dawson Creek refinery to produce a high-quality balanced gasoline with special attention being paid to volatility for ease of starting, warm up, and engine cleanliness, and octane for power and ?performance.

Jan 1, 1958

By H. E. Cook

The Ising model for the internal energy of a binary alloy has been used to obtain a general equation for the critical resolved shear stress of partially ordered crystals. The equation expresses the stress in terms of the Warren "alphas " and can be used to estimate the variation in strength with order without the assumption, present in the original formulation of this problem in terms of domain size, that order is complete within each domain and that the domains are of ungorm size and shape. In addition, it is the general equation, according to the Ising model, for strengthening by short-range order. Two applications of the equation are considered: One is an estimate of the variation in strength of CkAu with long-range order. The other is an estimate of the variation in strength of FeCo with quench temperature. Reasonable agreement is found with the variations reported in the literature. When the internal energy of an alloy crystal depends upon the distribution of solute, the strength of the crystal will also depend upon it because a portion of the applied stress for plastic deformation will be: where V is the volume of the crystal and E(E) is the energy change associated with the solute redistribution caused by the plastic strain, E. We expect T to equal zero for a crystal having a random arrangement of solute because the arrangement would remain random after plastic deformation. Likewise, we expect it to equal zero when the crystal is perfectly ordered because the motion of paired dislocations found in such crystals does not disrupt order. However, when short-range order exists or when long-range order is incomplete, plastic deformation will decrease the amount of order and additional work, proportional to the ordering energy, will be expended. Fisher' estimated T for crystals having short-range order by assuming an interaction energy between neighboring atoms and estimating the change in the number of unlike neighbors as a dislocation moved through the crystal. (His analysis was limited and several workers2"6 have since given more complete ones.) Fisher minimized the importance of a strengthening mechanism of this type for paired dislocations in a structure having long-range order. ~ottrell,' however, pointed out that T could be appreciable for ordered crystals having antiphase domains. He attributed the strengthening to the increase in surface energy of the domains as they were cut by paired dislocations. Ardley,' in his test of Cottrell's theory, found that r for Cu3Au crystals obeyed the equation: for 1 > t where 1 is the domain size, t is the domain wall thickness, and y is the surface energy of an antiphase boundary. His experiments represent the classic confirmation of the strengthening mechanism proposed by Cottrell. However, the assumptions involved in using Cottrell's theory are valid only for large domain size in CU~AU,~"~ i.e., when Eq. [2] reduces to: For small domains, ~linn~ has questioned Ardley's assumption that order was complete, and, indeed, Stoloff and ~avies" fpnd it incomplete until a size of approximately lOOA was reached. Even when the order within a domain is complete, it is not obvious how one determines the appropriate value for I in a structure where domains vary in size and are irregularly shaped. The purpose of this paper is to estimate T without restrictions upon the degree of order and domain shape. Our major assumption will be the use of a generalization of the model proposed by Bethe" (the Ising model) for the internal energy. This will in fact allow us to combine the theories for strengthening by short-range order and by antiphase domains into a single, general formalism. We will use the results to estimate the variation in strength of Cu3Au crystals with long-range order8 and the variation in flow stress of FeCo crystals with quench temperature.12'13 INTERNAL ENERGY For simplicity, we restrict our considerations to those binary solid solutions which can be described as an arrangement of atoms on a Bravais lattice. An atom site will be indexed by three numbers (PI, pz, p3) determined by the vector: from the origin fixed at atom (0, 0, 0) to the atom site where a', an, and a, are the lattice translation vectors. We write: For the energy of the crystal where pi(p) is the probability (either zero or one) of finding an atom of type i (i = 1, 2) at site (p), which is shorthand for (pl, pz, p3) and pj(p + r) is that for an atom of type j (j = 1, 2) at the site (p + r), which is shorthand for (pl + rl, The coupling parameter, resents the energy associated with the pair Pi(p), Pj(p + r). The crystal is assumed large enough so that surface effects can be neglected; therefore, trans-lational and inversion symmetry require the coupling parameters to obey the relations

Jan 1, 1969

By W. F. Kieschnick, C. C. Miller, E. R. Brownscombe

The possibility has been mentioned that large pressure gradients in a solution gas driven field caused by high production rates might lead to a reduction in the ultimate recovery obtainable compared to that which would be obtained by a very slow rate of production. In the present study the reservoir conditions accompanying a high rate of production and the corresponding ultimate recovery were compared with those obtained if the reservoir were produced at some marginal rate throughout its entire life. The method of calculation involved the application of fluid flow - material balance analysis to a series of successive steady state conditions in the reservoir. In the case studied very little difference in recovery was obtained at the abandonment pressure. An analysis of the basic factors involved indicates that the sane results would hold for considerable variation in properties of reservoir fluids, permeability of the formation or well spacing. Even if the reservoir has a water drive it appears that no harm will be done by- open flow production if the rate is cut back before any appreciable free gas is produced. However, any condition which leads to disproportionate withdrawal rates and which causes large pressure differences over large areas might result in substantial loss in ultimate recovery. INTRODUCTION When the pressure declines in a reservoir, gas is evolved from solution causing a shrinkage in the reservoir oil so that a stock tank barrel of oil with its residual dissolved gas occupies a smaller volume than originally. For a given reservoir oil saturation, therefore. stock tank oil content will be higher at the lower pressure. At the same time the evolved gas which remains in the reservoir reduces the reservoir oil saturation, and this would be expected perhaps to cause a reduction in stock tank oil content. However, around the well the shrinkage occurs so rapidly that stock tank oil may actually accumulate in this region in spite of the simultaneous reduction in reservoir oil saturation. If this accumulation should continue, spreading into a larger zone, the loss might be appreciable and because larger pressure gradients accompany higher rates the accumulation might possibly be large if wells are produced at too high a rate. It is the purpose of this paper to determine the effect of rate of flow on ultimate recovery by solution gas drive. The problem under consideration involves the unsteady state flow of oil in a closed radial system from which oil is produced by the evolution of gas as a finite drawdown is estalllished and the reservoir pressure declines. A somewhat similar unsteady state production problem dealing, however, with a linear system has been considered by Muskat and Meres, but these authors do not discuss the effects which rate may have on recovery. Other methods have been reported for estimaling recovery as a function of pressure decline when producing at an infinitesimal rate, and Muskat and Taylor' have shown the effect of fluid and reservoir characteristics on recovery under these conditions. Assuming steady state to exist, Babson has given a procedure for computing the decline in well productivity as the field is depleted, and Moyer has combined these methods to estimate abandonment conditions and the resulting ultimate recovery. These latter approaches to the problem either do not consider the effect of rate or assume steady state can be established. In detail this paper presents the behavior of the reservoir producing under unsteady state conditions and considers the effect of production rate during this unsteady state flow on the recovery attained. The analysis also shows that there will exist at abandonment a type of steady state, and on this basis a method has been clevelopetl for rapid calculation of abandonment conditions.

Jan 1, 1949

By C. C. Miller, W. F. Kieschnick, E. R. Brownscombe

The possibility has been mentioned that large pressure gradients in a solution gas driven field caused by high production rates might lead to a reduction in the ultimate recovery obtainable compared to that which would be obtained by a very slow rate of production. In the present study the reservoir conditions accompanying a high rate of production and the corresponding ultimate recovery were compared with those obtained if the reservoir were produced at some marginal rate throughout its entire life. The method of calculation involved the application of fluid flow - material balance analysis to a series of successive steady state conditions in the reservoir. In the case studied very little difference in recovery was obtained at the abandonment pressure. An analysis of the basic factors involved indicates that the sane results would hold for considerable variation in properties of reservoir fluids, permeability of the formation or well spacing. Even if the reservoir has a water drive it appears that no harm will be done by- open flow production if the rate is cut back before any appreciable free gas is produced. However, any condition which leads to disproportionate withdrawal rates and which causes large pressure differences over large areas might result in substantial loss in ultimate recovery. INTRODUCTION When the pressure declines in a reservoir, gas is evolved from solution causing a shrinkage in the reservoir oil so that a stock tank barrel of oil with its residual dissolved gas occupies a smaller volume than originally. For a given reservoir oil saturation, therefore. stock tank oil content will be higher at the lower pressure. At the same time the evolved gas which remains in the reservoir reduces the reservoir oil saturation, and this would be expected perhaps to cause a reduction in stock tank oil content. However, around the well the shrinkage occurs so rapidly that stock tank oil may actually accumulate in this region in spite of the simultaneous reduction in reservoir oil saturation. If this accumulation should continue, spreading into a larger zone, the loss might be appreciable and because larger pressure gradients accompany higher rates the accumulation might possibly be large if wells are produced at too high a rate. It is the purpose of this paper to determine the effect of rate of flow on ultimate recovery by solution gas drive. The problem under consideration involves the unsteady state flow of oil in a closed radial system from which oil is produced by the evolution of gas as a finite drawdown is estalllished and the reservoir pressure declines. A somewhat similar unsteady state production problem dealing, however, with a linear system has been considered by Muskat and Meres, but these authors do not discuss the effects which rate may have on recovery. Other methods have been reported for estimaling recovery as a function of pressure decline when producing at an infinitesimal rate, and Muskat and Taylor' have shown the effect of fluid and reservoir characteristics on recovery under these conditions. Assuming steady state to exist, Babson has given a procedure for computing the decline in well productivity as the field is depleted, and Moyer has combined these methods to estimate abandonment conditions and the resulting ultimate recovery. These latter approaches to the problem either do not consider the effect of rate or assume steady state can be established. In detail this paper presents the behavior of the reservoir producing under unsteady state conditions and considers the effect of production rate during this unsteady state flow on the recovery attained. The analysis also shows that there will exist at abandonment a type of steady state, and on this basis a method has been clevelopetl for rapid calculation of abandonment conditions.

Jan 1, 1949

By S. E. Stallibrass, A. M. McNamara, J. P. Panchal, Leonardo M. LaLicata

Urban development in congested cities requires a better exploitation of the available surface, leading to taller structures. These buildings are usually founded on piles that have to be increased in dimension to accommodate the larger loads. Consequently, both the cost and the carbon footprint of the pile foundations rises. An alternative option is to improve pile performance by enhancing shaft capacity, which is commonly the most important factor in determining the ultimate capacity of a pile constructed in a clay soil subjected to axial load. For piles in stiff clays, such as London Clay, the soil/pile friction may be increased by profiling the side walls of a bored cast in situ pile with small discrete “impressions” such that the latter form nodules on the shaft of the concreted pile. The results from centrifuge and full scale field tests showed that the impression pile represents a viable technology to enhance the shaft capacity as they provide an increase in capacity of 40%. Alternatively, reduced length impression pile can be used. This paper explores the implications of the impression pile technology on the potential carbon saving.

May 1, 2022

By E. Vesely, A. Saxena

"SAG mill liners are designed for protecting the mill shell and providing lifting power for ore charge and grinding media. Due to the impacts from the charge and the grinding media, the liner experiences dimple, plastic deformation, strain hardening, fatigue, peening and final failure. Because of the collisional environment directly measuring such dynamical loads is extremely difficult if not impossible. In this study we tried to evaluate the liner failure risk by simulating the collisions of solid particles with mill liner using Discrete Element Method (DEM). DEM simulation has been proved to be a very useful tool in evaluation of granular flow and its impacts on the solid structure. But there are certain limits in DEM coherently, such as the number of solid elements, the computer runtime, etc. Here we first present the general feature of the particle-liner collision in terms of impact force and collision energy. Then the effects of parameter selection is discussed. Our simulations show the fatal collisional event of huge impact force is very rare and the collisional events of low impact is much more frequent. The fatal event may contribute most to the liner failure. The rarity of the fatal events may be missed in a short runtime simulation. This technical challenge combined with lacking of criterion to evaluate varying impact loads in fatigue problems may further complicate the evaluation. Should we use the largest impact force alone or we should use the more frequent events is an open question and requires more effort. In order to evaluate the quality of liner design, we proposed a relative comparison method. In the end we show the implication and application of this method in liner optimization by a work example. In particular, the effects of the charge level of grinding balls and their size on the operation performance is presented.INTRODUCTION Grinding is one of the most important and expensive steps of mineral processing. A variety of grinding mills such as rod mills, ball mills, semi-autogenous (SAG) mills and autogenous (AG) mills are being utilized for comminution of mineral ores (Gupta & Yan, 2016). Up to today, SAG mills and AG mills have been widely used to reduce operation costs and increase throughput. In an AG mill, a rotating drum throws larger rocks of ore in a cascading motion which causes impact breakage of larger rocks and compressive grinding of finer particles. Unlike AG mills, SAG mills use steel grinding balls to break ores of size quite small such that they cannot be easily broken in AG mill. SAG mill liners are designed for protecting the mill shell and providing lifting power for ore charge and grinding media. Due to the impacts from the charge and the grinding media, the liner experiences dimple, plastic deformation, strain hardening, fatigue, peening and final failure. Quality and performance of SAG mill liners play a fundamental role to enhance efficiency of grinding mills, because failure of liners is the major cause for unexpected breakdown (Banisi, Hadizadeh, Mahmoudabadi, & Eilkhany, 2006)."

Jan 1, 2019

By Kenneth Gavin

Design practice for piles installed in Irish glacial till has developed in an ad-hoc manner, based on the results of un-instrumented load tests. This had led to designers using similar design parameters for both CFA and displacement piles. To address the concerns of industry a series of instrumented pile tests were performed by two Irish Universities. These tests summarized herein, revealed that CFA piles develop higher shaft resistance than piles driven in glacial till. However, they exhibit low base stiffness and the end bearing resistance that can be mobilized at acceptable pile settlement is low. The use of simple non-linear elastic design approaches to predict the load-displacement response is considered. The methods are used to predict the capacity of two large diameter CFA piles installed in glacial till. While the predictions were reasonably accurate at predicting the initial load-displacement of the piles, significant creep settlement developed at higher load levels. The cause of the creep settlement was investigated through the use of plate load tests and the consequences for pile design are discussed.

Jan 1, 2009

By Emad Iskander

The seepage forces generated around pressurized water tunnels in rock are investigated using the analysis tools of geomechanics. The theoretical background of the two-phase material behavior is explained and the equations of motion and continuity are presented. Applications on two case studies typically occurring in practice deal with the required minimum rock cover for a pressurized tunnel and the separation between two tunnels carrying different heads. The rock mass behavior as described by the Mohr-Coulomb and Hoek-Brown material models is investigated by numerical analyses and the results are compared. The effect of key material parameters on the safety factors and the associated modes of failure is discussed.

Jan 1, 2008

By R. R. Klimpel

In this first report, we present a preliminary model based on the simple binary sys¬tem of component B occluded in a matrix of compo¬nent A, for the case where fracture planes can pass with equal ease through A or B. By assuming that the volume fraction of B in AB in the overall matrix is small, which is realistic for many prac¬tical systems, the problem is reduced to a one-¬dimensional treatment which is conceptually easy to understand. The model was programmed for Monte Carlo simulation, and an analytical solution also developed based on the assumption of zero or one mineral fragment per particle. Preliminary ex¬perimental confirmation using a synthetic "mineral¬-host matrix" of known amount and size of B in AB is presented.

Jan 1, 1983

By O. Mellgren, A. M. Gaudin, P. L. De Bruyn

The adsorption density of ethyl xanthate on pyrite was determined as a function of xanthate concentration. Surface preparation of the mineral appears to have asafunctionsome effect on the subsequent adsorption process, A monolayer of xanthate on the surface is exceeded only in presence of oxygen. The effect of OH- , HS- (and x and CN- S=)and on the amount of xanthate adsorbed was investigated. Competition between OH- and X- (xanthate) ions for specific adsorption sites is indicated over a wide pH range. IN the flotation of sulfide ores, xanthates are most commonly used to prepare the surface of the mineral to be floated so that attachment to air takes place. The quantity of agent required to make the mineral hydrophobic is usually very small, of the order of 0.1 to 0.25 lb per ton of mineral. Details of the mechanism of pyrite collection are for the most part unsettled. Adsorption of collector has long been believed to involve an ion exchange mechanism as demonstrated for galena' and for chalcocite.2 In the work on chal-cocite it was also demonstrated that a film of xanthate radicals unleachable in solvents that dissolve alkali xanthates, copper xanthate, or dixanthogen was formed at the surface of the mineral. The unleachable product increased with increasing addition of xanthate up to a maximum corresponding to an oriented monolayer of xanthate radicals. Pyrite is extremely floatable with xanthate if its surface is fresh.9 ut the floatability decreases rapidly as oxide coatings increase in abundance. Pyrite shows zero contact angle when in contact with ethyl xanthate solution at pH higher than about 10.5;4 at neutrality, a contact angle of 60" is obtained at a reagent concentration of 25 mg per liter. Alkali sulfides and cyanides are pyrite depressants. In this study of pyrite collection the writers have sought to relate measured xanthate adsorption to the method used in preparing pyrite, to the presence or absence of oxygen, to concentration of hydroxyl, hydrosulfide, sulfide, and cyanide ions. The principal experimental tool has been radioanalysis," " using xanthatcx marked with sulfur 35. Experimental Materials Pyrite: Unlike most sulfides, pyrite is a poly-sulfide. The structure given by Bragg7 resembles that of sodium chloride, the iron atoms corresponding to the position of sodium and pairs of sulfur atoms corresponding to the position of chlorine. The edge of the unit cell in pyrite is 5.40 A and in halite 5.63 A. The S-S distance in pyrite is 2.10 A; the Fe-S distance, 3.50 A: and the Fe-Fe distance, 3.82 A. Natural pyrite from Park City, Utah, was used in this investigation. Pyrite 1 was obtained by hand picking pure crystals. Pyrite 2 and Pyrite 3 were obtained from finer textured crystalline material containing inclusions of silicates. The same cleaning technique was utilized for the preparation of Pyrite 2 and Pyrite 3, whereas a different cleaning technique was used for Pyrite 1. Pyrite 1 was prepared as follows: The crystals were ground in a porcelain ball mill and the 200/400 mesh fraction was separated by wet screening with distilled water, followed by washing for 1 hr with deoxygenated distilled water acidified with sulfuric acid to pH 1.5. The acid was removed by rinsing with deoxygenated distilled water on a filter until a pH of 6.0 was reached in the effluent. This filtration was carried out under nitrogen. The sample was then dried in a desiccator under nitrogen. The period of time for which this pyrite sample was in contact with water containing oxygen was about 4 hr. The specific surface as determined by the BET gas adsorption method was 582 cm2 per g. Final material assayed 53.12 pct sulfur and 46.5 pct iron (theoretical, for FeS,: S, 53.45 pct; Fe, 46.55 pct). After crushing, Pyrite 2 and Pyrite 3 were washed with 1 M HCl. rinsed, and fed to a laboratory shakinq table to remove the small amount of silicates. The concentrate obtained was ground in a laboratory steel ball mill. The 200/400 mesh fraction was separated by classification in a Richards hindered settling tube. This fraction was then given a final wash with 0.1 M HCl and deoxygenated water was filtered through the sample. The final effluent showed a conductivity equivalent to that of a solution having a salt concentration of 0.3 ppm. Aqueous hydrogen sulfide solution was then added to the sampln (about 100 ml saturated H,S solution to about 1000 g pyrite under a few hundred milliliters of water) which was stored wet under nitrogen. The sample stored in this manner showed no indication of formation of iron oxides, whereas iron oxides appeared

Jan 1, 1957

By Taner Kavas

The refractory bricks of a rotary cement furnace containing of alumina and magnesium chromite were studied in order to determine whether they could be used in the concrete production as aggregates. Three mortars were prepared by mixing 1 part cement, 3 part aggregate materials, 0.5 part water by weight and mechanical, chemical, thermomechanical and microstructural characteristics were evaluated. The compressive and bending strength of samples were determined after 2 and 28 days curing. Resistance to chemicals were established by calculating the weight gain of mortars stored in 2 % HCl solution for 1 h and 24 h. Thermomechanical characteristics were determined by measuring the compressive strength of heat treated specimens at temperatures of 400 °C, 600 °C and 800 °C. Consequently, magnesium chromite containing waste brick aggregates have given the best results.

Jan 1, 2006

By V. S. Sastri, M. Elboujdaïni

"Corrosion rates of silicon brasses, highzinc yellow brass, low-zinc yellow brass, leadedtin bronze and silicon bronzes in both permanent-mold and sand-cast conditions were determined in soft water of pH 3, 5 and 8, and hard water of pH 8 at 70°C by electrochemical polarization technique. The alloys in permanent- mold condition showed greater corrosion resistance than sand-cast condition. Corrosion rates obtained from weight loss measurements showed no observable trend of a difference between permanent-mold and sand-cast alloys.The corrosion rates decreased with increasing pH of the medium. Silicon bronze and silicon brass showed high corrosion resistance while leaded-tin bronze showed the least resistance. Addition of small amounts of aluminum improved the corrosion resistance of silicon bronzes and silicon brasses. Alloys in permanent- mold condition showed greater resistance to dezincification than sand-cast alloys when average pit depth parameter is considered."

Jan 1, 1997

By Bogdan Petkovic, Boban Todorovic

In the early 90's a completely unknown problem was encountered at the converter Department: it was a chronic shortage of the cold copper charge needed for the second operating period. A high temperature operating regime was caused which further provoked a chain of consequences such as a drastic drop of the number of operations in campaigns. The consumption of repair bricks reached the quantity of 8.3955 kg / tonne of anode Cu. In 1994, we won the process of cold material smelting during the "copper" blowing [2]. The number of operations per campaign reached 180-200 again. Also in 1994 we won the process of smelting cold materials to obtain "tin" blowing with the purpose of completing their processing cycle [2]. During the period 1994 – 2007 a total of 107,845 tonnes of cold material were remelted to make copper and 56,794 tonnes were re-smelted to obtain "tin". Upon synthesizing these two processes, a completely new model was achieved in 2005, by Bogdan Petkovic, which entirely utilized all available energy of the Peirce-Smith (PS) converters of the Bor Copper Smelter and now represents the basis of the time cycle. The cold material now enters the converter plant, copper recovery is increased and the method itself is environmentally friendly. 167

Jan 1, 2009

By John S. McCartney, Ismaail Ghaaowd

This study presents the results from centrifuge modeling experiments performed to understand the effects of temperature changes on the pullout capacity of scale-model energy piles embedded in normally- consolidated clay layers. The energy pile under investigation is an aluminum cylinder instrumented with internal strain gages and thermocouples, and its temperature is controlled using an internal electrical resistance heater. The energy pile was first heated until the temperature, pore water pressure, and volume change of the surrounding clay layer stabilized, after which the energy pile was cooled. Pullout tests were then performed on the energy piles heated to different temperatures to understand the effects of the preceding heating-cooling cycle on the pullout capacity. In addition, the clay undrained shear strength profiles were measured using push-pull T-bar penetration tests before and after heating. INTRODUCTION When a heat source such as an energy pile is embedded in a saturated clay layer, temperature changes will result in changes in pore water pressure as the rate of heating is typically faster than the rate of pore water drainage (Campanella & Mitchell 1968, Abuel-Naga et al. 2007, and Ghaaowd et al. 2016). Although all soils will initially expand during undrained heating, normally consolidated soils typically exhibit permanent contraction while overconsolidated soils exhibit expansion after sustained heating when drainage is allowed (Vega & McCartney 2015). Subsequent drained cooling typically leads to elastic contraction. Thermally- induced changes in pore water pressure and volume during transient heating and cooling may affect the soil- structure interaction of energy piles, as well as the ultimate capacity of the energy pile. This study is relevant as relatively few studies have been performed on the behavior of energy piles in soft clay (e.g., Ng et al. 2014), with most focused on the behavior of drilled shaft energy piles in stiff rock or overconsolidated clays (e.g., Laloui et al. 2006; Murphy et al. 2015; Wang et al. 2015; McCartney and Murphy 2017).

Jan 1, 2018

By S. E. Malouf, R. Hinse

"The Mineral possibilities of the Chibougamau area were first recognized by Richardson in 1870 and Low in 1885, both of the Geological Survey of Canada. The first record of interest by the Quebec Bureau of Mines is in 1904, when J. Obalski reported on the discovery of copper and asbestos by Peter McKenzie in the previous year. Reports of 1906 and 1907 covered the McKenzie Gold Mine find and other deposits. In 1908 Prof. Dulieux described the quartz vein on Merrill Island and the mineralized zone on the near-by mainland. In 1910 the Chibougamau Railway Commission, though commenting favourably on the possibilities of the area, concluded that a railway was not then warranted.In spite of this, prospecting in the district continued. The main Campbell Chibougamau deposit, the Blake showing on Merrill Island in Dore Lake, was found in 1920, and other discoveries were made soon after. Between 1927 the work of Mawdsley, Retty, and Norman tor the Geological Survey and the Quebec Bureau of Mines stimulated further interest. In 1934 Consolidated Chibougamau Goldfields Ltd., a subsidiary of Consolidated Mining and Smelting Co. of Canada Ltd., acquired the Merrill Island and Cedar Bay holdings of Chibougamau Prospectors Ltd. They embarked on an aggressive campaign, directed essentially at the gold quartz veins at Cedar Bay. Exploration there included a 522-foot shaft, 4,732 feet of drifts and crosscuts, and about 34,000 feet of surface and underground diamond drilling. Thirteen holes were also drilled on the replacement sulphide lens at Merrill Island. Operations were suspended in 1936, as the occurrence was too low grade for development at the existing metal prices and under difficult operating conditions.The completion of the Quebec Bureau of Mines highway from St. Felicien to Chibougamau in 1950 was followed by a project of detailed geological mapping by the Bureau. It also encouraged Campbell Chibou-gamau Mines to acquire the assets of Consolidated Chibougamau Gold-fields and commence a program of surface exploration. Between August 1950 and April 1951, 41,183 feet of diamond drilling was done on the Cedar Bay and Merrill Island holdings. The Blake showing off the west shore of Merrill Island developed at depth into a major orebody. A lease was obtained on adjacent ground from Merrill Island Corporation, and underground work commenced in November 1951. Development at Merrill Island to June 1st, 1955, included a four-compartment shaft to 1,225 feet, with 8 levels at 150-foot intervals, 5,317 feet of raises, 16,709 feet of drifts and crosscuts, 52,514 feet of surface and 96,593 feet of underground diamond drilling."

Jan 1, 1949

By R. C. Gilmore

Computational fluid dynamics (CFD) has been used to model gas compositions in underground longwall coal mine gobs to study oxygen ingress and the development of potentially explosive methane-air mixtures that may form in the gob. The scenarios studied involve various headgate and tailgate ventilation and inertization schemes and controls. In a project sponsored by the National Institute for Occupational Safety and Health (NIOSH), researchers at Colorado School of Mines have used an innovative meshing approach, allowing easy adaptation of the CFD model to adjust to a variety of bleeder and bleederless mining geometries, with gob porosity and permeability scalable over a wide range. This paper presents the methodology of the meshing and scaling approach along with recommendations for using CFD modeling in longwall gob ventilation applications. The new meshing technique was utilized to evaluate the function of a back return in a progressively sealed gob. The back return was successful in maintaining sufficient oxygen concentrations in the tailgate corner of the longwall face.

Feb 23, 2014

By C. Anderson, B. Schug, C. Cristoffanini, S. Nazari

The Haile Gold Mine in South Carolina is increasing the automation level of their processing plant in order to improve operational stability. One step towards this goal is the application of a Digital Twin concept to provide Virtual Instruments. Haile has engaged ANDRITZ to implement Virtual Instruments at their grinding area hydrocyclones and at their tailing thickener underflow pump. These virtual instruments provide density values in a traditionally difficult location for reliable slurry density measurement. The Digital Twin is a first principles IDEAS1 ™ simulation model, connected in real time to the control system. Results have been promising, with the virtual instrument values matching the physical instrument under normal operating conditions, and showing better prediction under upset conditions. Haile plans to use the virtual instruments as optional process control parameters. INTRODUCTION OceanaGold’s Haile Gold Mine is located near Kershaw, South Carolina, about 50 miles southeast of Charlotte, North Carolina. This location was first mined in 1827, and has produced gold through several operating periods since then, including a heap leaching operation from 1985 through 1992. In October, 2015, OceanaGold acquired Romarco Minerals, the previous owner of the Haile Operation. The current operation began in 2017 as an open pit mine with additional underground resources. The nameplate throughput is 6,350 tpd ore, and 2017 production was 118k oz gold, with 140 to 155k oz gold expected in 2018. Proven and Probable reserves exceed 3 Moz. The process, as shown in Figure 1, includes a primary jaw crusher, comminution with a Semi-Autonomous Grinding (SAG) mill and ball mill circuit, flash flotation, rougher flotation, regrinding, pre-aeration, carbon in leach (CIL) leaching, carbon elution and regeneration, cyanide recovery, electrowinning and refining. The Haile Operation’s inaugural gold pour took place January 20, 2017. Mine life is expected through at least the year 2030. Based partially on prior experience of some key OceanaGold personnel with automation services from ANDRITZ on other projects, OceanaGold decided to include ANDRITZ on the Haile project. The scope of these services for Haile included design and supply of the process control application software, an ANDRITZ dynamic process simulator for operator training, and ANDRITZ Advanced Control Expert (ACE) ®2 systems for the SAG mill, ball mill, and rougher flotation areas. Since startup, ANDRITZ has continued to provide services for the site, particularly related to PLC and HMI equipment, programming and support, ACE system expansion, and the implementation of Virtual Instrumentation. The implementation of this new Virtual Instrumentation technology at Haile is consistent with Haile goals: increased automation, a change in the role of the operator from interactor to monitor, and improved stability by removing human error.

Jan 1, 2019