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By S. W. Chang, James R. Hein, S-R. Lee, A. Zondervan, H. Choi

"Nine Fe-Mn nodules from the extensive nodule field in the east of Campbell Plateau of southwest Pacific Ocean beneath the Deep Western Boundary Current (DWBC) and Antarctic Circumpolar Current (ACC) were analyzed for the 10Be/9Be dating by AMS (Accelerator Mass Spectroscopy) at IGNS, New Zealand.Several types of nodule morphology were identified including distinctive discoidal forms with overgrowths resulting possibly from overcrowding and partial sediment burial. Five principal nodule facies were also recognized by location and occurrence (Fig. 1) (Wright et al., 2005). Fe-Mn nodules show various concentric internal growth textures, such as, cuspates, large parabolic cuspates, pseudo-columnar, columnar, globular, and laminated, which vary even in a nodule with hydrogenetic, early diagenetic, or mixed origin. Each texture shows micro-textural varieties and different mineralogy and/or chemistry. The genesis of each internal texture was indicated by the REE patterns, the mineralogy of Mnoxides, and the Mn/Fe ratios."

Jan 1, 2017

By R. Thorpe, M. Dosbaba, A. Kopriva, A. Niiranen, J. Ruokanen

"Automated Mineralogy (AM) is an important diagnostic tool in flotation plants as it adds ore and particle mineralogical properties to traditional mass and chemical data. AM is used in project development, for future ore studies and for diagnosing concentrator operations. With the exception of operations who own central laboratory or on-site systems, the use of AM is often limited to the analysis of a comparatively small set of samples. Metrix Plant Technologies has partnered with TESCAN to integrate TIMA AM technology into the implementation of Performance Assessment Campaigns (PAC). Routine daily composite samples from the mill are analysed mineralogically on a size-by-size basis over several weeks. All the relevant metallurgical, process control and mineralogical data is combined into a single large database for mass balancing and interactive examination. This paper describes the implementation and results of a PAC at the Agnico Eagle Kittilä gold mine in Finland. Although challenging, the addition of mineralogical data as dependent variables in multivariate analysis leads to a much deeper understanding of the root cause effect of events driving the flotation performance. INTRODUCTION TO STUDY The Kittilä mine, owned by Agnico Eagle, is Europe’s largest primary gold mine, with annual production of approximately 180,000 Oz. The operation is located in Lapland in northern Finland, and is currently expected to operate until 2035. The location of the operation is shown in Figure 1. Historically, the mine was an open pit, although in recent years ore is sourced solely from underground operations. The processing plant features crushing and grinding, followed by carbon flotation and sulphide flotation. Carbon concentrate is a waste stream, and sulphide concentrate reports to pressure oxidation (autoclave) and CIL circuits for gold extraction. The final flowsheet is shown in Figure 2. Following commissioning in late 2008, the operation achieved commercial production on May 1st 2009. Gold recovery in flotation gradually increased to a 92-96% range at a throughput of ~3500-4000 tonnes per day. In late 2014, the operation commissioned a plant expansion to ~5000 tonnes per day. Following a commissioning period, the operation stabilised with recoveries in a 90-94% range, which over any given period was determined to be ~2% lower with statistical significance. The trends from start-up of gold recovery in flotation and throughput are shown as follows in Figure 3. In early 2016, Agnico Eagle Kittilä mine, along with Agnico Eagle Technical Services (AETS) partnered with Metrix Plant Technologies and TESCAN, to perform a Performance Assessment Campaign (PAC) at Kittilä, involving automated mineralogy on five key streams at Kittilä on 40 days selected from a 50 day period between February 15th and April 4th 2016, when plant operations were stable. In addition to the mineralogical data, metallurgical and operational data were pooled into a single, powerful database to explore opportunities for the operation to improve recovery in a sustained manner, ideally to the levels pre-expansion."

Jan 1, 2017

By Josh B. Taggart

Some twenty to twenty-five years ago we saw the beginning of mechanization in our coal mines, It has now progressed to the point Chat as instruments of production the pick and shovel are things of the past, They had to give way to better and more efficient methods--so mechanization, followed by and combined with automation, has become common-place in our mines. Our coal could not keep its competitive position without this progress Without it our industry could not look to the future with any degress of confidence. Today we lock back and see cases of regained and salvaged markets. We see better coal products being produced at decreasing costs. We see better utilization of manpower and a stronger, more confident industry, Our hats arc off to those mining men, equipment manufacturers, labor leaders, and others who had the foresight to work toward these ends and the ability to bring them about.

Jan 1, 1962

By A. Mukhopadhyay

Gas stirring, simultaneous arcing, chemical additions are some basic steps in the secondary steel making. From tap to team however, there are enough uncertainties and several in-situ decision making required to match the fmal composition and temperature in the given amount of processing time. Currently available control algorithms rely on overall material and heat balance coupled with a self-learning regression based tuning of model constants. In this paper we demonstrate the capabilities of Computational Fluid Dynamics (CFD) in modeling and analyzing the thermo-chemical aspects of secondary Steelmaking. These models take advantage of scientific and engineering advances in computational tools and provide almost real time speed of analysis. This can be a very effective tool for operator training, process debugging and improvement as well as new innovations. Keywords: Argon purging, Secondary steelmaking, Arcing, Ladle Furnace, Process Control.

Jan 1, 2003

By J. D. Meakin, H. G. F. Wilsdorf

An etching technique.has been used to investigate the dislocation structure of deformed @-brass single crystals. Isolated single ended pileups have been observed, and it is shown that, in certain cases, the configurations of such pileups agree with theoretical predictions. Many discrete pileups within heavily deformed regions have also been detected and the influence of surrounding dislocations on these groups are reported and discussed. Divergences between the experimental and theoretical spacings in the isolated pileups and the origin of the stress maintaining the pileups are discussed. THE spatial configuration of a linear array of identical dislocations has been evaluated theoretically by Eshelby, Frank, and Nabarro.' Of particular interest is the equilibrium spacing of a series of dislocations under a uniform shear sti-ess when the leading dislocation is held fixed in the lattice; such an array is termed a single ended pileup. Eshelby, Frank, and Nabarro' found that an explicit analytical solution to the problem of n dislocations in a pileup is not possible, but they were able to derive approximate formulae applicable under various limiting conditions. An alternative method of determining the equilibrium configuration was proposed by Leibfried and Leibfried and Haasen in which the discrete dislocations are replaced by a continuous dislocation density. This technique was used by Head and Louat to solve in first approximation, a number of problems of particular interest, eg., single and double ended pileups. Head has also solved numerically a number of specific configurations involving up to six dislocations. Recently Kuhlmann-Wilsdorf has obtained numerical solutions for single-ended pileups containing between three and seventy dislocations, thus making possible a comparison between appropriate experimental results and accurate theoretical values. The considerable use of the pileup concept in theories of plastic flow has stimulated a number of attempts to observe such arrays experimentally. There is of course considerable intrinsic value in revealing an isolated pileup because a direct check on the elastic theory of dislocations then becomes possible. The only technique generally applicable for studying pileups in bulk metal specimens is selective etching of the point of emergence of individual dislocations. Confining our attention to etching studies which have revealed pileups, the earliest reported work

Jan 1, 1961

By Aureo D. V. Machado

An experimental study to obtain zirconia powders (ZrOz) from carboxylate zirconium solutions followed by hydrogen peroxide stripping and precipitation, has been carried out. Zirconium carboxylate was prepared by solvent extraction from a chloride aqueous phase using magnesium carboxylate as organic phase. The variables examined in the precipitation reaction were: Temperature: 25 - 90 ?C ? H202= concentration: 0.3 - 5% wt/wt - pH: 1 ? 9 Organic/Aqueous ratio (1/1) and reaction time (30 minutes) were maintained at constant levels. The optimum results (98% precipitation) were achieved at 25 °C, 5 % wt/wt H202=, and pH = 5. The precipitates were composed of large amorphous aggregates (<I00 micrometers). After calcination for 1 hour at 1000 OC, monoclinic ZrO2 with a large variation in particle size (1 -100 micrometers) was obtained.

Jan 1, 1991

By Hanlu Xie, Liang Yu, Ping Wang, Yuanchi Dong

"The leaching process is the first step when recycling BF slag as raw material for some other products. While studying the kinetics of the BF slag leaching process, a fractal phenomenon was found, which indicated some interesting mechanism in the process. The result suggested a new understanding of the leaching process in detail which useful for the industrial applicationIntroductionTypical composition (wt. %) of blast furnace slag varied in a pretty wide range: SiO2 30–40, Al2O3 10–20, CaO 30–40, MgO 5–10.The ground granulated slag is commonly used as base of roadway (mixed with natural inert for paving, soil stabilization, etc.) or one of the resources of Portland cements because of its good hydraulic activity [1]. To recycle the slag economically, the selective recovery of some components of the slag may be considered. As main components exist in the slag, silica [2, 3 and 4] and alumina [4] recovery was first considered.While recovering of silica from the slag, silica gels are recovered selectively from the leaching solution deriving from the treatment of the slag with waste sulfuric acid. After separation of the exhausted solid of leaching, the silica gel is precipitated from the solution at pH 3.2. Although the silica gels obtained by this procedure contain many impurities and need some more work afterward, it is the first and important step for the process.In the prior work [5], silica extraction using blast furnace slag had been investigated, focused on the pH value of selectively silica extraction. In the present work, kinetics of the leaching process was focused. It is important to design an economical process.ExperimentalThe composition of the slag and the calcined gels has been determined by a LINK860 (Oxford Instruments, Oak Ridge, TN) energy dispersive spectrometer (EDS) in conjunction with a CAMBRIDGE S250-M2 (Cambridge Instrument Ltd., Cambridge, U.K.) scanning electron microscope(SEM). The leaching of slag and the precipitation of silica gels have been conducted at atmospheric pressure in a stirred reactor placed at temperature controlled by a heated water bath."

Jan 1, 2008

By Alvin Schallis

Of all the uses for dolomite that depend on its magnesia content, perhaps the most important is its use in basic refractories. The quantities of dolomite (including both that used as crude and that calcined before use) sold or used for refractory purposes by producers in the United States for 1920-41, inclusive, are shown in figure 1. As can be seen from the chart, the utilization of dolomite as a basic refractory is far from new; it was, in fact, the first basic refractory used extensively in open-hearth steel furnaces. After large deposits of magnesite were opened in Austria-Hungary, the use of dolomite in the open hearth declined somewhat, only to be actively revived during the World War of 1914 to 1918, when supplies from Austria were shut off. The use of dolomite as a refractory in the steel industry again declined slightly for a brief period after the Armistice, but subsequently its use has tended steadily to increase, latest statistics indicating that more dead-burned dolomite is used per ton of open-hearth steel now than during the World War of 1914 to 1918. Despite fluctuations in consumption, dolomite has continued to be by far the most widely used basic refractory material. The following table, showing the quantities of basic refractories consumed in the manufacture of steel, the principal outlet, indicates the relative importance of dolomite. The chief reason for the widespread use of dolomite as a basic refractory is its relatively low cost. Its abundance and the proximity of the deposits to the steel industry (see fig. 2) afford every incentive to enhance the desirable physical properties of dolomite refractories and to ameliorate certain of their less desirable characteristics. The present emergency, with its huge demands upon the steel industry, has lent further impetus to the work of improving dolomite refractories.

Jan 1, 1942

By Fredy A. Elorrieta Agramonte, Gabriel von Rickenbach, Roberto Luis Fonseca, David Córdova Rojas, Rolando Romero, Rico Brändle

The mine’s economic life is dynamic by nature. Some factors that create this scenario are the need to recognize new exploitation areas, the evolution of the mineral prices and the development of new technologies to access them. The dynamics of mining development, especially in the underground environment, changes significantly as the stages unfold. In many cases the final solution differs greatly with the initial. The frequent presence of new conditions and factors often cause the mine to develop in a quasi-permanent transition stage, which could be characterized by the generation of dynamic micro-seismic events that could cause rockburst damage in some specific areas. Although they may be infrequent, these dynamic events can have an important adverse impact on mine safety and causes serious losses. Also, changes in the production schedule during exploitation could be a big issue if the problem is not effectively addressed. When the transition of the mine to an active micro-seismic environment begins as an unforeseen scenario, it is frequent to use static ground support systems as they are readily available. Traditionally, the support systems used are reinforced shotcrete with a middle layer of Welded Standard Wire Mesh (WSWM) and Chain Link Standard Wire Mesh (CSWM) of reduced gauges, i.e. wires less or equal than 4 mm in diameter. Although, this support system is used to control static instability problems, there is no good reference of its energy absorption capacity under dynamic load conditions, creating uncertainty in the effectiveness of controlling rockburst events. These support systems are analyzed at the present paper, testing the reinforced shotcrete layer with 4 mm diameter of WSWM and CSWN under dynamic load. Additionally, the influence of the use of high tensile strength steel wire in the meshes (HSWM) compared to the previous ones, is analyzed to assess the scope in controlling rockburst events and keeping the safety of underground environment.

Apr 26, 2022

By Y. A. Topkaya

The placer gold occurrences at Sart Çayl, Manisa, Turkey, the legendary River Pactolus of King Croessus, were evaluated in this study to determine if this deposit contains sufficient recoverable value to justify development and exploitation. The gold occurs both in the upper Neogene conglomerates and the alluvium derived from these conglomerates. The total reserve in the whole region is estimated to be 500 million cubic metres. Samples were taken of the upper conglomerate and in the alluvium in an attempt to determine the amount and the physical nature of the gold. The gold in samples was recovered by screening out barren oversize followed by washing the sand and gravel through riffled sluices. The resulting sluice concentrate was later panned and amalgamated at site. Laboratory cyanidation testing of some samples for control purposes was also done. The average calculated free gold was found to be about 90-100mg/m3 and the size of gold flakes found was quite small. The field as well as laboratory testing of the samples of Sart Çay1 indicated that the potential reserves in this region could only be developed as a sand and gravel operation and the gold could be recovered together with the heavy minerals as a byproduct.

Jan 1, 1984

By Jodie Robertson, Isabel Barton, Cristian Caro

Prior to mining, all rocks contained in a mineral deposit must be placed in one of several categories known as ore types. Each ore type describes a different way that the rock will behave in processing. The ore type determines which process stream a particular mined unit will be sent to, sets expectations for process engineers and metallurgists, and forms the basis for recovery predictions and production estimates. At first, ore types are assigned mainly by geologists based on visible geological criteria (dominant ore mineralogy, estimated grade, rock type, alteration type). As metallurgical tests are carried out and process data accumulate, the resulting criteria may be factored into the ore typing process, typically as assays and recoverable metal using the relevant process(es). Other variables may also be incorporated into ore typing at operations if they are particularly important, such as grindability, preg-robbing, gangue reagent consumption, and the presence of especially deleterious minerals such as talc or smectite. The mine operation department may also redefine ore types and/or process destinations based on economic criteria. A “best” ore type is designated that (in theory) best describes how the rock will behave in processing. Codes representing this ore type are entered into the drill hole database, then interpreted on cross sections and level plans, and finally added to the block model. Ore types are iteratively reexamined and adjusted over the life of a project. Major difficulties in effective ore typing are (1) lack of communication between geologists and metallurgists, (2) the imprecision inherent in imposing clean categories on messy natural systems without discrete divisions, (3) the need for ore types to provide useful information for a wide range of processes, (4) difficulties in scaling up laboratory test results to mine production, and (5) conflict among geological, metallurgical, and economic criteria for ore typing.

Nov 8, 2023

By P Cesare, S Munro, D Wandel, R A. Bearman

Consideration of the processing plant operational envelope is a key factor in production scheduling,and therefore mine planning, for any mining operation. In many cases hard-wired or regressionbased tonnage-grade-recovery relationships are used as mine planning constraints and as a means of valuing the system output. In extensions of this type of approach, various regressions can be used to describe throughput limits, based on a number of global metallurgical parameters.The ultimate position for the optimisation of a mine plan and production schedule is to have a full process plant model running as an integrated part of the mine planning exercise. A plant model suitable for this needs to have all the required sensitivities to input parameters such asfragmentation, grade, mineralogy, strength and hardness. The model then needs to convert these to performance measures for the plant, which include recovery, throughput, product size distributions, energy consumption, water use and operating cost.In this paper an approach is outlined that takes this view and then goes beyond it to provide a full, time-based bottleneck identifi cation and valuation tool.Using such an approach it becomes possible to run mine plans and production schedules in windows of days, weeks, months and over the life-of-mine with a time-enabled process model acting as the active constraint. In this way virtual bottlenecks can be identifi ed for various mine plans and schedules well ahead of time. The value of de-bottlenecking can be defi ned, not just at a plant scale, but in terms of the overall mining operation, and the data can be used as the basis for capital investment decisions.CITATION:Bearman, R A, Cesare, P, Munro, S and Wandel, D, 2014. Incorporation of a full process plant model as an active constraint for mine planning and production scheduling, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014 , pp 121–128 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 24, 2014

By D. F. Malan

This paper gives an overview of the difficulties associated with determining the strength of hard-rock pillars. Although a number of pillar design tools are available, pillar collapses still occur. Recent examples of large-scale pillar collapses in South Africa suggest that these were caused by weak partings that traversed the pillars. Currently two different methods are used to determine the strength of pillars, namely, empirical equations derived from back analyses of failed and stable cases, and numerical modelling tools using appropriate failure criteria. The paper illustrates that both techniques have their limitations and additional work is required to obtain a better understanding of pillar strength. Empirical methods based on observations of pillar behaviour in a given geotechnical setting are popular and easy to use, but care should be exercised that the results are not inappropriately extrapolated beyond the environment in which they are established. An example is the Hedley and Grant formula (derived for the Canadian uranium mines), which has been used for many years in the South African platinum and chrome mines (albeit with some adaptation of the K-value). Very few collapses have been reported in South Africa for layouts designed using this formula, suggesting that in some cases it might yield estimates of pillar strength that are too conservative. As an alternative, some engineers strongly advocate the use of numerical techniques to determine pillar strength. A close examination unfortunately reveals that these techniques also rely on many assumptions. An area where numerical modelling is invaluable, however, is in determining pillar stresses accurately and for studying specific pillar failure mechanisms, such as the influence of weak partings on pillar strength. In conclusion, it appears that neither empirical techniques nor numerical modelling can be used solely to provide a solid basis for conducting pillar design. It is therefore recommended that both these techniques should be utilized to obtain the best possible insight into a given design problem. Owing to the uncertainties regarding pillar strength and loading stiffness, monitoring in trial mining sections and in established mining areas is also an essential tool to test the stability of pillar layouts in particular geotechnical areas.

Jan 1, 2011

By K. Huang, L. Pan

"Darcy’s law has been used extensively to model cake filtration. It is a macroscopic model, in which particle size dominates the kinetics and cake moisture. In the present work, a capillary flow model has been developed from first principles to study the effects of microscopic parameters such as capillary radius, boundary layer slip, disjoining pressure, and surface tension that may be important for dewatering ultrafine particles. Laboratory-scale pressure filtration tests show that dewatering kinetics is strongly dependent on capillary radius, which in turn is influenced by surface hydrophobicity, surface charge, and length scales of particles. The model parameters determined from laboratory-scale filtration tests show that use of a hydrophobizing reagent can greatly improve fine particle filtration due to increased slip and decreased capillary pressure. The kinetics of dewatering kaolin clay is fastest at a pH where the layer-structured particles coagulate with a face-to-edge orientation. The capillary flow model developed in the present work may be useful for designing filters and optimizing operating conditions.INTRODUCTIONIn 2014, Canada produced 2.2 million barrels per day of crude oil from the oil sands resources in Alberta, which is expected to grow to 3.2–4.0 million barrels per day by 2030 (CAPP, 2013). One of the challenges to meeting these projections is the tailings management. At present, the industry uses ?77 km2 of the lands to construct tailings ponds. Significant amounts of the tailings disposed to the ponds are silts and clays that are slow to settle and consolidate, creating problems for reclamation. It is, therefore, the objective of the present work to develop a filtration model that may be useful for developing advanced dewatering technologies that can address the tailings management issues.Darcy’s equation is the governing law for filtration. It was derived as an empirical model by H. Darcy in 1856 while he was studying fluid flow in sand filters (Hall, 1956). Since then, many investigators derived it from first principles. It relates superficial fluid velocity to the pressure drop across a porous medium of known permeability. In filtration, the latter can be related empirically to particle size using the Kozney equation (Yoon, 2005)."

Jan 1, 2016

By Eckl, Martin, Stefan Lemke, Martin Londschien

"Tunnels are built with a design life expectancy of over 100 years. One key component of such a design is the waterproofing system, which must reliably fulfil its function during the whole service lifetime of the tunnel structure. This paper deals with the determination of test criteria for the durability assessment of geosynthetic products in tunnel sealing systems. Hereby the understanding of the individual aging processes is crucial along with the long-term experience with these materials to ensure the transfer of the laboratory results and performance to site practice (test calibration) and vice versa. To verify the results of the new test procedure the material properties of geosynthetic products samples removed from older tunnels are investigated. Based on the presented results of the still ongoing research programs some preliminary conclusion regarding the updating of regulations for tunnel sealing systems are given. INTRODUCTION Watertightness is directly related to the durability and serviceability of the concrete lining. Therefore, modern traffic tunnels and shafts (Figure 1) are generally protected against mountain/ground water and water penetrating through rock fissures by a sealing system, for example with a loose-laid polymeric sheet membrane. Hereby the waterproofing sealing systems must be reliably fulfilling their function during the whole service life of the tunnel structure, regularly of more than 100 years. In consequence, the quality and lifetime performance of the waterproofing materials—beside the correct professional and careful installation in a tunnel infrastructure, is of great importance. The challenge for the industry, owners, operators and designers is ultimately the development of qualification testing and requirements (acceptance criteria) for products to ensure the design lifetime performance. Hereby the qualification procedure is seen as a routine integrated in standards, norms or guidelines, wherein test procedures should cover typical environments for the specific application fields. Polymeric synthetic raw materials are increasingly used in products with long service lifetimes (e.g. in injections, gaskets, waterbars, spray-applied and sheet waterproofing membranes). During service they are subjected to chemical (e.g. oxidation processes) and physical (e.g. changes in morphology) influences from the environment, which affect their mechanical properties—and they age. Hereby organic materials are more affected than inorganic materials. Also, polymers show strongly temperature-dependent properties compared with other construction materials. However, their long-term aging behavior is not given per se and has to be explored extensively by suitable tests, which simulate—under accelerated processes—real exposures and loads. Hereby the understanding of the individual aging processes is crucial along with the long-term experience with these materials to ensure the transfer of the laboratory results and performance to site practice (test calibration) and vice versa."

Jan 1, 2016

By R. E. Heithecker

The separation of enormous quantities of water produced with the oil in some West Texas fields necessitated the use of special equipment other than the regular lease tanks. Several methods were used with varying degrees of success. They include the water-trap, hay tank and gun barrel, gun barrel and settling tank, chemical and electrical-dehydration methods. The water trap which has been used extensively in the Hendricks field, and in some instances has been installed in the Yates field separates the water and. oil under high pressure before tile liquid and gas pass through the flow beam. The first trap was constructed and installed by the Southern Crude Oil Purchasing Co. in July, 1928. By July, 1929, approximately 300 traps were in use. Treating cut oil by running it through a hay tank was done quite extensively in the Roberts-Settles field, Howard and Glasscock Counties, Tex., and later the method was used in the Hendricks field. In July, 1931, there were 37 hay tanks in the Roberts-Settles field, treating the oil from 123 wells. The cut oil frequently was made acceptable to the pipe-line company by running it through the hay tank. In some instances, however, it was necessary to heat the oil, and occasionally both heat and chemicals were used before complete separation of the oil and water was obtained.

Jan 1, 1932

By B. McFadzean, P. E. Ngoepe, P. P. Mkhonto, J. Taguta

The adsorption of heterocyclic collectors such 2-mercaptobenzothiazole (MBT), 2-mercaptobenzoxazole (MBO), 2-mercaptobenzimidazole (MBI) and their derivatives on pyrite form a basis in understanding the flotation reactivity that may be applicable in a wide range of sulphide minerals. This study uses a computational and experimental approach to determine the heat of adsorption of MBT, MBO, MBI and modified MBT collectors onto pyrite surfaces. Computational calculations found that the adsorption energies were in the order: MBO > MBI > MBT. The heterocyclic collectors were adsorbed in their thiolate form on the surface. In the case of the pyrite (100) surface, the MBT adsorbed through the exocyclic sulphur atom, while MBO and MBI adsorbed through the exocyclic sulphur and N atoms onto the 5-coordinated Fe atom. The (111) surface was found to be more reactive and different adsorption mechanisms were predicted, where the MBT exocyclic sulphur atom bridged on the 5- coordinated Fe and surface 2-coordinated sulphur atoms, while the N atom adsorbed on the 5-coordinated Fe atom. In the case of MBO and MBI, dissociation of the exocyclic sulphur atom from the collector occurred with subsequent interaction with the surface 5-cordinated Fe and 2-coordinated S atoms. This resulted in the collector carbon atom adsorbing on the surface 2-coordinated S atom, while the N atom adsorbed on the 5-coordinated Fe atom. The adsorption of the modified MBT was found to be more exothermic than the MBT, which showed that introduction of a –CS2 group on the exocyclic sulphur atom improved the affinity of MBT on the surface, and was thus a better flotation collector. The computational results were supported by experimental enthalpy of adsorption measurements and microflotation tests. The chemistry of the heterocyclic thioamides is complicated by the fact that they can exist in a number of tautomeric and ionic forms at different pH’s. This is discussed in relation to the flotation and calorimetric data.

Jan 1, 2018

By Nils Schneider, Marc Peters, Stefan Frey, Andrea Fluck

Due to the worldwide population growth, the development of sustainable infrastructure and the exploration of renewable energies plays a key role to handle the rising megacity trends and to limit carbon footprint. Herrenknecht AG is a leading manufacturer of Tunnel Boring machines and has constantly endeavored through its extensive Research and Development programs to address limitations faced by the civil engineering industry as regards to construction equipment capabilities. New mechanized technologies, mainly coming from the tunnelling industry, have been developed by Herrenknecht AG as an efficient alternative to conventional civil engineering, where tailor-made concepts are required to comply with restricted conditions onsite. Very often this innovation led technology capability has meant making construction processes safer due to minimal human intervention and also far more productive due to higher performance as compared to other latest or conventional methods of construction. The rising need for even higher building structures and large-capacity bridges involve the development of innovative deep foundation technologies for on- and offshore operation. Conventional methods like bore piles reach their technical and economic limits under certain conditions. For building shafts and foundations, the mechanized Vertical Shaft Sinking Machine technology (VSM) from Herrenknecht AG is a proven innovation and has now been used in various onshore infrastructure projects worldwide to construct a total of 94 circular shafts in depths of up to 115 meters. It operates below the groundwater level, completely remote-controlled from the surface in a diameter range from 4.5 to 18 meters. Subsequently Herrenknecht noted that Offshore foundations, especially in non-drivable ground conditions such as soft and hard rock (e.g. limestone, sandstone, mudstone, granite etc. or soft soil with high density) and shallow continental shelf (water depth approx. 20-60m), presented construction challenges and equally an opportunity for building high performance equipment. The latter construction conditions usually requires drilled installation methods for applications such as harbor enlargements, bridge foundations and foundations for offshore wind turbines. The Offshore Foundation Drilling technology (OFD®) is Herrenknecht’s latest innovation, incorporating our learnings from the VSM and full-face Tunnel Boring machines, and the OFD® enables a rapid and economical offshore installation in such variable ground and rock conditions. This paper will discuss the technology behind the new mechanized technology of VSM and Herrenknecht’s latest innovation of the OFD® along with their respective application fields in foundations construction. The paper will further present in details, their range of benefits to the construction industry.

Nov 1, 2022

By Jürgen Kretschmann

The European climate and energy framework for 2030 is highlighting the reduction of man-made CO2 by increasing the use of renewable energy to mitigate climate change. In this spirit, Germany has decided to erase the coal use as an energy source by 2038 completely. Inevitably, this strategy promises a feasible, responsible, and sustainable post-mining management, because 200 years of coal mining have created numerous challenges necessary to tend to once the mining ends. Thus, the Research Institute for Post- Mining (FZN) at the TH Georg Agricola University in Bochum, Germany, has developed a holistic approach to meet these postmining challenges including further expertise present at our university. Here, the four strategic research pillars are (1) technical geoecology and hydrogeology to avoid and mitigate risks underground, (2) geomonitoring to evaluate and protect the surface, (3) industrial heritage preservation and engineering to secure and reuse brownfields such as mine sites, and (4) economic transformation planning of mining regions to enable a prosper future for generations to come. In all efforts, we aim to achieve the fundamental goals of the UN to deal with the resources of our planet responsibly and sustainably. Furthermore, we are synergizing increasingly with national and international networks in the interest of social, economic, and environmental stakeholders.

Jul 23, 2020

By M. F. El-Demerdash

The activity distribution diagrams for different species in aqueous systems are developed. Computational method may be considered as an extension of the Activity-Term method introduced by the authors to construct EH-pH diagrams. In the Activity-Term method, all activities of different species are evaluated before deciding the most stable one. In the present study, a factor is assumed to allow for the conservation of the element. At any point, the total concentration of all species should contain only the input m moles of the element (elements) considered. This approach is applied to Zn-, 5-, and Zn-S-H2O and activity distribution diagrams are plotted as a function of pH, at different potential levels and at different temperatures.

Jan 1, 1990