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By Ye Chen, Jianhua Chen, Xianhao Long, Qingxia Liu, Zhenghe Xu

"It is crucial to understand the mechanism of the collector interacting with the mineral surface in the presence of water molecules, which could influence the relaxation and electronic properties of sulphide mineral surface due to the proximity effect for narrow band gap of semiconductors. The adsorptions of three typical collector molecules (xanthate, dithiocarbamate and dithiophosphate) on the sulphide mineral surfaces in the absence and presence of water molecule have been simulated by density-functional theory (DFT). The calculated results show that the adsorptions of collectors on clean mineral surface in vacuum are not in agreement with the observed flotation behaviours. The presence of water molecules has a great influence on the adsorption of collectors. The analysis of density of states of the mineral surface atom suggests that the adsorption of water molecules could influence the electronic properties of mineral surface and consequently influence the adsorption between the surface and the collector molecule.INTRODUCTIONIn the separation of multi-metal sulphide ores, the selectivity of a collector is a key factor for the efficient recovery of the aimed mineral. Xanthate, dithiocarbamate (DTC) and dithiophosphate (DTP) are the most common collectors used in the flotation of sulfide minerals. Generally, xanthate exhibits powerful collecting property but lack of selectivity. While dithiophosphate and dithiocarbamate show the good selectivity in the lead and copper sulphide mineral flotation. The mechanisms of these collectors interacting with the sulphide mineral had been attracted many attentions and several mechanism based on experimental results had been reported (Chander & Fuerstenau, 1974; Fuerstenau, 1990; Raju & Forsling, 1991; Crozier, 1991; Bradshaw, Cruywagen & O’Connor, 1995; Guler, Hicyilmaz, Gokagac & Emekci, 2006). However, the micro-mechanisms of the selectivity of these three thiol collectors on different sulphide mineral surfaces are not fully understood."

Jan 1, 2016

By J. A. Cole

This paper discusses the modification of the cyanide tailings treatment method from ferrous sulfate to Caro's acid (peroxymonosulfuric acid). An examination of the operating parameters, costs, and chemistry describes how the decision was made to switch to this treatment method. Plant data collected from the last several months will be used, along with considerations from an operator's viewpoint.

Jan 1, 1996

By F. S. Crawford

Although it may be impracticable to adopt standard methods of safe working in all branches of mining, and although it may be impossible to establish a standard for each class of work at each mine, some of the iron-mining companies in the Lake Superior district have found that by adopting certain standard ways of performing certain of their operations they insure both more efficient and safer working conditions. Many companies have adopted the idea that the safe way of doing things is also the most efficient and economical way, and, through the medium of their safety conferences they are trying to find the safest way, and the most efficient way, of performing practically every operation about the mines. This activity will, undoubtedly, be continued at every operation which uses this method of doing safety work, because in the advance of industry changes must be made in the results required from time to time. A review of the safety standards and safety suggestions which have been arrived at by some of the companies in this the greatest iron-mining district in the world, will be of value to companies who are interested in improving the safety of their working conditions. So that attention may be directed to the methods in use, rather than to individual companies, all names have been omitted and companies are referred to only by letter.

Aug 1, 1931

By H. D. Dahl

In January, 1969, the Central Research Division of Continental Oil Company initiated a research program on roof control. The purpose of the research was to improve roof stability. Toward this end, it was necessary to determine which of the many geological and geometrical variables have a significant effect on roof stability. The isolation of these significant variables would allow research effort to be concentrated where it would be most effective in improving roof control. The research effort was directed toward two major objectives. One was to de-fine the geological and/or geometrical parameters that affect the severity of roof conditions in any particular area of the mine. This study was concerned with roof fall intensity. The second was to define why roof falls in Humphrey No. mine (and in northern West Virginia-south-western Pennsylvania coal mining areas) are oriented so that they occur primarily in north-south rooms or entries. This study was concerned with roof fall orientation. To provide a reference framework for further discussion, a geological description of the area is presented in Part II. In Parts III and IV, the procedures, methods, and 'results of the research applied toward the afore-mentioned major objectives are presented. Part V contains the conclusions and recommendations for-warded by this study.

Jan 1, 1971

By Antonio Huerta

The effects of potassium ethyl xanthate collector and potassium dichromate used as a depressor on a PbS mineral were studied by high frequency impedance technique. Measurements of complex permittivity, at 100 MHz suggested that is possible to obtain from isotherm adsorption the adequate industrial collector concentration being this in the range of lE-3 to 5E-3M of KEX. The e' values (320-420) in the PbS-KEX system was increased as the KEX concentration was lowered). In the other hand the PbS- K2Cr2O7 system showed higher values of e' (420-510) as the K2Cr2O7 concentration was increased. The PbS-KEX-K2Cr2O7 system was evaluated.

Jan 1, 1997

By D. R. BUDINSKI

Clinton Creek Mine in west-central Yukon produced 0.94 million tonnes of fibre from 15 million tonnes of asbestos ore between 1968 and 1978. The mine closed in 1978. The deposit lies along the margin of a medium sized ultramafic pluton that intrudes schistose and gneissic rocks of the Yukon Metamorphic Complex. Country rocks are metamorphic equivalents of a mixed sedimentary and volcanic assemblage deposited during Precambrian or early Paleozaic time. Movement along the north west-trending Tintina Fault System probably caused the fairly high meromorphic grade that altered the original rocks to schists and gneisses. The ultramafic pluton hosting Clinton Creek Mine is one of several bodies that were emplaced along a deep seated imbricate fault system parallel to the Tintina Trench. Most of rhe intrusions were hydrothermally altered to serpentinite, bur apparently only the one at Clinton Creek contains commercial quantities of asbestos. The Clinton Creek pluton was probably injecred slowly at relatively low temperatures into the crustal rocks as a "mush" that cooled gradually, allowing sufficient time for serpentinization and chrysotile fibre crystallizarion.

Jan 1, 1984

By John A. Franklin, Tom C. Palangio, Norbert H. Maerz

No blast evaluation is complete without fragmentation measurements which until now were inaccurate, costly, time consuming and created delays in production. “WipFrag.s”is a fully automated PC based fragmentation analysis system that uses digital photo analysis techniques to measure broken rock. Fragmentation can be measured in minutes using compact videocameras for image acquisition. Even subtle changes in rack quality can be detected providing the information necessary for pattern optimization, explosives evaluation, timing selection, benchmarking and blast model validation.

Jan 1, 1995

By N. S. Dalal, X. Shi

"This study reports a new property of the important NAD(P)H-dependent flavoenzymes, glutathione reductase, lipoyl dehydrogenase and ferredoxin- NADP oxidoreductase, that can catalyze a one electron reduction of metal ions such as chromium(VI) and vanadium(V). During the enzymatic reduction process, molecular oxygen is reduced to H2O 2 , which reacts with the reduced metal complexes to generate hydroxyl radicals. Since the hydroxyl radicals have been suggested to play an important role in Cr(VI) toxicity, this study provides a basis for a recent observation that Cr(VI) mutagenesis is strongly oxygen dependent. These results also point to an enzymatic pathway for the metabolism of some metal ions and concomitant generation of hydroxyl radicals. l. INTRODUCTIONThe purpose of this communication is to report that some important NAD(P)H-dependent flavoenzymes (glutathione reductase, lipoyl dehydrogenase and ferredoxin-NADP+ oxidoreductase) can catalyze one electron reduction of metal ions such as chromium(VI) and vanadium(V) and simultaneously reduce molecular oxygen to generate Hi02 and, eventually, the ""OH radical. This finding is significant because (i) the known substrates for the flavoenzymes are organic species and not metal ions, and (ii) the report on the enzymatic formation of the ""OH radical provides a new pathway for understanding the mechanism of genotoxicity of some non-ferrous metal ions. For example, it has been suggested that OH radical is likely to be the major species responsible for Cr(VI) genotoxicity [1-5). The 'OH radical is generated through the reaction of Cr(V) complexes with cellular Hi02 [4,5]. Cr(V) itself is known to be generated from Cr(VI) in various biological systems, in particular, microsomes [ 6), mitochondria [7] and mitochondrial electron transfer chain complexes [8]. However, no specific enzyme responsible for the Cr(V) generation has been identified except possibly glutathione reductase [4]. In this study we have used ESR and spin trapping techniques to show that the flavoenzymes can generate Cr(V) and provide a catalytic redox cycle for 'OH formation in such reactions. Herein we present our results on Cr(VI) and summarize those on other systems. Correspondence address: N.S."

Jan 1, 1990

By V. Adamek

The specific lithological conditions over the Pittsburgh coalbed, highly resistive limestone and sandstone units with relatively shallow overburden, prevent the use of any predictive method as developed for European conditions. This paper describes the development of a subsidence precalculation methodology suitable to the mining-geological conditions in the Northern Appalachian Coal Field. It has been found that due to lithological conditions over the Pittsburgh coalbed the subsidence coefficient varies within the area of the subsidence trough. This is different from the European conditions where the subsidence coefficient is considered to be a constant. The effects of lithology, in-the form of a variable subsidence coefficient, have been separated for each test site by introducing a correlation between hypothetically homogeneous overburden and existing lithological conditions, while providing for different mining conditions. Field data from eleven Bureau longwall panel studies were used in the regression analysis. For each panel the characteristics of the variability of the subsidence coefficient along individual profile lines were defined. Regression analysis of the subsidence coefficients from all test sites on the location relative to the edge of the panel has yielded a third degree polynomial equation with a coefficient of correlation of 0.9999. All sensitivity tests have shown good results.

Jan 1, 1985

By G. A. Irdi

An automated method of microscopy for determining the pyrite size distribution on two base coals that were crushed to 28 mesh x 0 has been developed. Polished epoxy-bound coal pellets were prepared and examined by a Zeiss IBAS image analyzer utilizing a program developed from provided software. Pyrite size distribution determination is considered a necessary first step in pyrite characterization that could lead to successful predictions, by microscopy, of a coal's theoretical pyritic sulfur removal. Our research efforts to date have indicated that the IBP-S can be a reliable instrument for determining pyrite size distribution in crushed coal. A program was also developed to convert pyrite size data to a weight basis for comparisons to the results from chemical analyses. The problems encountered in our research and their solutions will be presented in the discussion.

Jan 1, 1986

By Yong Liu, Peng Qian, Shu-Feng Ye, Shao-Jun Chu, Pei-Wei Han

"Chromite with a low mass ratio of Cr to Fe (Cr/Fe ratio) was treated by the carbochlorination method using solid chlorinating agent (MgCl2 and CaCl2) and carbon in the present paper. The results showed that iron could be selective removed mainly in the form of FeCl2. The removal of iron was indirectly, which consisted of the decomposition of solid chlorinating agent to release Cl2/HCl and the carbochlorination of FeO•Cr2O3 by Cl2/HCl and C. The Cr/Fe ratio increased as increasing temperature from 700 ? to 900 ? in air atmosphere, while the tendency was opposite in N2 atmosphere. The removal efficiency of iron by CaCl2 was better than that by MgCl2. At last, a new pelletizing process was proposed to treat fine chromite with a low Cr/Fe ratio based on carbochlorination method, which could produce the high quality roasted chromite pellets with higher Cr/Fe ratio and compressive strength. INTRODUCTION Chromite is mainly used for the production of ferrochromium. A high Cr/Fe ratio (>2) of chromite is usually required to meet the technical specification of ferrochromium.(Gasik, 2013) Attentions have been attracted to the economic and efficient methods for the recovery of chromium from lower-grade ores as the higher-grade ores become depleted. However, the Cr/Fe ratio is difficult to improve through the conventional beneficiation methods (such as gravity concentration, flotation) due to the spinel composition, although beneficiation methods could increase the metal content of chromite ores by removing gangues.(Nafziger, 1982) The main industrial mineral of chromite is (Fe,Mg)O•(Cr,Al,Fe)2O3, which belongs to spinel magnetite.(Liu, 2013) Iron should be selectively removed through the structural dissociation of spinel to increase Cr/Fe ratio.(Nafziger, 1982)"

Jan 1, 2018

By Delio Amorim

Industry 4.0 concepts is the new biggest challenge on the industry nowadays and every company in every industry in every part of the globe is looking to implement this somehow on their factories and machines. To do that on the newest long rolling mills, that brings already onboard state-of-the-art technologies, is for sure a challenge of machinery builder industry, but how to become the long rolling mills built on 70’s, 80’s or 90’s part of this innovation process and connected to the new trends? This is the main mission here, to show some examples of applications that goes in this direction.

Oct 1, 2019

By R. K. Filip

"Steel bearing piles have long been used to carry high compressive, tensile and lateral loads. Such piles are most commonly tubular or ""H"" profile and are typically installed using percussive techniques. The noise and vibration associated with such installation techniques tends to preclude the use of steel bearing piles in urban and other sensitive areas.This paper describes the design and construction of an innovative new road bridge in Milton Keynes, UK. The steel bearing piles were required to continue out of the ground to form the bridge columns and abutments and then be cast directly into the soffit of the reinforced concrete bridge deck. This project was to be the first time in the UK, that this form of bridge design had been used.The paper shows how new installation techniques allowed the designers to use these high capacity steel elements in a sensitive urban environment without the use of percussive or vibratory installation techniques. Finally the paper shows how these quiet and vibration-less installation techniques can be extended to other applications.A UNIQUE BRIDGE SUPPORTED ON ""BOXED SHEET PILES""CONCEPT HISTORYThere are over 700 bridges in Milton Keynes. Concrete is the dominant construction material, most are single span with massive parallel wing wall retaining abutments. All have a certain uniformity of aesthetic design. Pell Frischmann Consultants Ltd (PFC) proposed to the client, English Partnerships (EP), that an ""integral bridge"" with a slender open appearance would be an appropriate aesthetic form for a new highways bridge, within the district of Westcroft (figure 1). The concept required that the bearing piles be continued up out of the ground to form the bridge columns and abutments. Four rows with four piles in each row were suggested. Each would then be cast directly into the reinforced concrete bridge deck forming a moment connection (figure 2). This concept meant that a single continuous steel structural member would replace traditional reinforced concrete bored piles, pile caps and piers. This member would carry vertical and lateral loads. The conceptual design was intended to meet the following client requirements:"

Jan 1, 2005

By Liping Li

A comprehensive three-dimensional two-phase mathematical model was developed to represent a channel type reactor with intense bottom gas agitation. Tracer dispersion and particle tracing methods were used to conduct the analysis based on the solution of the Navier-Stokes equations. Different operational parameters, such is gas volume flow rate. bubbler separation aspect ratios and liquid Input flow rates, were investigated for the purpose of reactor optimization. The numerical calculations were compared with experimental results obtained at the University of Missouri and a good general agreement was observed. Relatively low longitudinal mixing was observed characterizing the system as a "plug-flow" type reactor, in contrast to the intense vertical mixing, under the conditions investigated. Some general mixing characteristics are also discussed In connection to the behavior of other metallurgical reactors.

Jan 1, 1996

By William A. Fuchs

A study of carbonaceous ore at the Santa Fe mine (Corona Gold Inc.) shows that there is no quantitative relationship between organic carbon content and preg rob, although much of this material preg robs. However, there is a relation between K20 and preg rob. Preg rob generally occurs only in those samples with greater than 2% K20. X-ray diffraction and chemical . studies show that the critical factor is the illite content of mixed (possibly interstratified) illite-smectite. Apparently illite, at a certain threshold, "geo-activates" the carbon. The potential for easily monitoring preg rob using a gamma ray spectrometer is discussed.

Jan 1, 1990

By Jeff Wachendorf

As the title "Cast Blasting Around Town" implies, this paper details the starting of a cast blasting program in and around the town of Colstrip, Montana. As strip ratios have increased, the need to adapt and find solutions to provide coal at a reasonable cost to the captive power plants has risen. Colstrip, Montana has a long history of coal mining which dates back to the early 1920's when Foley Brothers began supplying coal strictly for powering locomotive engines. Early mining days starting in the 1920's and the progression up through the 1970's when mine mouth power plants were built will be discussed. To accomplish the desired results, early mining techniques included steam and electric powered equipment as well as a lot of actual horse power.

Jan 1, 2009

By R. J. Rice, K. F. Denning

Effect of iron on the removal of arsenic, mercury and selenium from gold mining effluents. Arsenic, mercury and selenium are common trace elements in gold tailing effluents that require removal before the water is either recycled or returned to a receiving body. One of the better methods of removal of these elements is the use of iron salts whereby, the metal is trapped on the freshly precipitated hydrolyzed iron oxides either by adsorption or enmeshment of the fine particulate and hence, removed from solution. The metal removal is effected by iron to metal ratio, pH, temperature etc. Pilot plant tests have shown that mercury can be reduced to < 5 ppb Hg, while full scale tests on arsenic and selenium have achieved levels of < 50 ppb As and < 10 ppb Se in well controlled systems.

Jan 1, 1993

The feasibility of exploiting a mineral deposit by developing a surface mine is closely related to the environmental protection and land reclamation costs. This issue has utmost importance for West Macedonia Lignite Centre (WMLC) of Greece, where there is still a lot of interest for opening of new mines and for further development of the existing open-pits. The decision-making process in these cases can be based on a decision tree that takes into consideration the various cost components of environmental management, the alternative solutions, the environmental permits and the cost reports of environmental management actions carried out so far. Moreover, the mine planning procedure is affected indirectly by numerous uncertain environmental and socioeconomic parameters, such as the delays caused by the bureaucratic procedures and the settlement of arguments in the Court.

Jan 1, 2006

By Tang Chaobo

Employing manganese carbonate ore and zinc oxide dust as material, Mn-Zn compound oxide powder for soft magnetic ferrite was prepared by a serial methods, as follows: leaching by using sulfuric acid, removing aluminium and silicon by neutralization and flocculation method, using ammonium bicarbonate to co-precipitating Mn and Zn, calcinations and washing to removing impurity content. The optimal technical condition was obtained by experiments. The difficulty of removing impurity such as Si, Al, Ca, Mg, from leaching solution was solved. The impurity content in the production meets with the preparation standard of high quality soft magnetic ferrite. The compound oxide powder obtained in the experiment was made into lower power loss magnetic ferrite, the quality of magnetic ferrite meet the standard of PC40 which was established by TDK corporation.

Jan 1, 2006

By John A. Johnson

Conclusions regarding the use or omission of stemming in blasting have not peen reached, pending completion of all aspects of this investigation. The results from the dust phase of this study on six classes of stemming prove that the kind of stemming affects the amount of dust produced from blasting. In previous work at the Mount Weather testing adit it was demonstrated that blasting produces the highest dust concentrations of any of the mining processes.5/ Under the conditions prevailing at the Mount Weather testing adit, the average of all rounds having a break of at least 95 percent showed that the least amount of dust was produced when no stemming was used.

Jan 1, 1940