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By I. Benning

Since the dismal performance of the Rand Mines management was called to account by its shareholders in 1994, the waves of change have continued to ripple across the South African mining industry .The number of listings on the gold board of the Johannesburg Stock Exchange, that once numbered 40 or 50-odd, have now dwindled to no more than a handful as unprecedented restructuring has taken place. The redefining of the industry has not been limited to the gold sector, but across the base metal, coal, diamond, platinum and industrial mineral sectors as well. At the same time the Mining Houses began to reconsider their funding strategies. Originally established in the early part of the century to ensure the long-term sustainability of their group mining operations by providing substantial financial muscle and technical support, the Mining Houses were faced with a rapidly changing political environment, which proved to be a critical catalyst in giving momentum to the change. Furthermore, the significant development costs and increasing risk profile for new projects, coupled with pressure from shareholders demanding respectable returns, opened the door to opportunities for banks to begin providing external debt by the way of project finance. However, the provision of long-term debt to the South African mining industry had generally not been common since mining companies had financed new projects with equity, or with the cash flows from existing operations. Those banks that had the appetite for exposure to the perceived high risks of the mining sector rapidly built up specialist resource banking divisions capable of addressing the increasing demands of the industry. The application of project finance, the principles of which were developed in the 1970s specifically for infrastructure projects and privatization, is now commonly applied in the financing of greenfield and brownfield mining projects. This paper outlines the approach that lending banks would typically adopt when arranging or providing mining project finance, their usual areas of concern and the way in which the finance is structured to mitigate the many inherent risks.

Jan 1, 2000

By J L. Mauk

Gladstone Hill, a volcanic-hosted low-sulfidation epithermal prospect in the Coromandel Peninsula, is less than 1 km from the world-class Martha Hill Au-Ag deposit. Gold-silver-bearing quartz veins occur in Late Miocene andesitic volcanic rocks of the Waipupu Formation that are extensively altered. The occurrence, spatial distribution and temporal relationships of hydrothermal minerals have been determined along two cross sections that transect the Amaranth, Gladstone, Cowshed and Moonlight veins. Quartz and pyrite are ubiquitous along these sections. Adularia and chlorite are widespread, but both are scarce in wall rocks adjacent to the Moonlight and Cowshed veins. By contrast, rare hydrothermal albite and epidote are restricted to wall rocks surrounding the Amaranth vein. Illite, which replaces adularia, is widespread and grades laterally eastwards into a zone of interstratified illite-smectite that envelops the Moonlight and Cowshed veins. During late-stage hydrothermal activity, rare calcite formed at depth and uncommon kaolinite and alunite formed at shallow levels. The overall clay mineral zonation with illite grading eastward into interstratified illite-smectite reflects paleothermal gradients of >220¦C to -170¦C towards the margin. The alteration assemblage of quartz, adularia, chlorite, albite, epidote, illite, interstratified illite-smectite and pyrite reflects formation from a near-neutral to weakly alkaline pH chloride water that contained low concentrations of CO2, Late calcite formed from very local descending steam-heated CO2rich water, whereas the rare assemblage of kaolinite and alunite formed from shallow steam-heated acid-sulfate water. Analysis of the available data indicates that the Martha Hill deposit and the Gladstone Hill area formed within a single large geothermal system. We infer that the Martha Hill deposit formed in the main upflow zone, whereas the Gladstone Hill area may have formed adjacent to this upflow zone.

Jan 1, 2001

By F. Habashi

"The rare earths industry started in Austria in 1887 by Carl Auer von Welsbach (1858-1929) Professor of Chemistry at the University of Vienna. The process was based on monazite sand transported from Brazil as shipping ballast free of charge. This made possible producing thorium, cerium, and other rare earths at a low cost, thus permitting the growth of the industry. However, once the Brazilian authorities realized the strategic importance of the sand, shipping was stopped. Brazil then started its own processing of the sand in 1949. The background for Auer’s work, the role of Robert Bunsen in Heidelberg, and the invention of the spectroscope will be presented. INTRODUCTIONHeidelberg on the Neckar (Figure 1) was the meeting place for chemistry students from all over Europe in the nineteenth century. Her university founded in 1386 had already a famous professor of chemistry and medecine in the Faculty of Medicine by the name Leopold Gmelin whose three - volume Handbuch der theoretischen Chemie appeared in 1817-1819, that became later a multi-volume monumental work. As successor to Gmelin came Robert Bunsen (Figure 2) in 1852 who made this university town the Mecca of chemistry students. One of his students, the English Henry Roscoe (1833-1915) who became later a distinguished professor in Manchester, described him as follows: ""As an investigator he was great, as a teacher he was greater, as a man and a friend he was greatest""."

Jan 1, 2012

By Zhanjing Yu

In this paper, an equation is developed to characterize the relationship between the UBC and plate size using a boundary integral approach. The equation was validated by the results from mo& than seventy (70) plate loading tests of different sizes conducted in various underground coal mines throughout the Illinois Coal Basin. The equation indicates that the UBC decreases as the plate size increases. The fundamental solution for this boundary integral problems is the Boussinesq equation. The load exerted by the plate on the floor surface is assumed to be uniformly distributed. Both normal and tangential loads are considered. It is also assumed that the floor fails in shear in a plate loading test. The equation may provide the mine operators with a useful tool to obtain from a plate load test of any plate size the UBC value required by the regulations.

Jan 1, 1993

By S. Behera, K. Dey

This paper presents a methodology for finite element (FE) modelling to analyse the total deformation of rockmass under blast-load, with a focus on predicting backbreak that may occur during surface blasting operations. Backbreak can result from improper use of explosive energy, leading to damage beyond the excavation zone and jeopardizing operational safety and productivity. The paper highlights the impacts of backbreak on bench stability, excavator operation, drilling operation, flyrock generation, and improper fragmentation and boulder formation in surface blasting. However, prior estimation of extent of rock breakage zone can provide an idea to formulate the blast design to control the backbreak. While vibration-based prediction models are commonly used to estimate backbreak, they require physical blasting experimentation. To overcome this limitation, the paper describes the development of a FE model using ANSYS Explicit dynamics, which simulates rock blasting and calculates the total deformation of the rockmass. The rockmass deformation is modelled using Drucker-Prager (D-P) strength model with the Jones-Wilkins-Lee (JWL) equation of state for the explosives. The accuracy of the FE model is evaluated through physical experiments, and the results are compared with the vibration models. The FE model demonstrates close proximity to physical observations as well as vibration model result in predicting backbreak, thereby offering a promising alternative to vibration-based prediction models. The primary objective of the study is to predict the response of the insitu rockmass to explosive blast loading and determine the effective rock breakage zone.

Jan 1, 2024

By He De-wen

The influence of wastewater containing benzene from chemical industry by technology combined blow-off with Fenton reagent oxidation was experimentally studied. The present results suggest that the technology combined blow-off with Fenton reagent oxidation can effectively remove benzene pollutant in wastewater. The main factors that influence the removal benzene such as temperature and blowing time and volume, pH and reagent dosage of H2O2 and Fe2+ are studied and the optimal experimental conditions are as follows: time 20min, temperature 40i, air-blowing volume 0.4L/min, pH value 5, and H2O2 and Fe2+ dosage 2mL/L and 200mg/L respectively. Under the above conditions, benzene pollutant can be removed up to 97%. Compared to other removal ways of wastewater containing benzene, the technology combined blow-off with Fenton reagent oxidation is more effective and has the advantage of high speed.

Jan 1, 2009

By E. W. Murbach

The oxidation of uranium carbide by oxygen at various pressures, and by air, has been investigated at temperatures up to 600°C. Arc-melted and cast uranium carbide displays oxidation behavior that appears to be dependent on its treatment after melting. ccReactive" uranium carbide, which results from exposure of freshly melted material to laboratory air, ignites in oxygen at about 275° to 350°C depending on pressure, and in air at about 350°C. The product of the initial oxidation appears to be UO2+.. Continued heating produces U30,. The initial oxidation rate is poportional, roughly, to the square root of the oxygen pressure. The activation energy determined for the initial oxidation reaction is 7.1 kcal, from 400° to 600°C in 10 mm of oxygen. AN investigation of low-decontamination methods for reprocessing uranium carbide reactor fuels is being carried out at Atomics International. One of the reprocessing cycles includes oxidation of the fuel at relatively low temperature (300° to 500°C) and reaction of the product oxide with carbon at elevated temperatures (above 1500°C) to produce uranium carbide. A number of small-scale experiments have been carried out in which uranium carbide was oxidized in air and oxygen at various pressures to measure reaction rates and to obtain other information concerning the oxidation process. In initial experiments with arc-melted UC, ignition was observed at about 275°C in oxygen or 350°C in air. However, similar experiments by Neymark' at 426°C in air showed no ignition. It was soon determined that the difference in oxidation behavior was due to the treatment of the UC following arc-melting. Neymark's experiments were carried out with freshly melted UC while those reported in the

Jan 1, 1963

By X Ma

Kaolinite is of very fine particle size in nature and thus its dispersion plays a key role in the successful removal of kaolinite in iron ore flotation and selective flocculation processes. As the most widely used dispersant in the world, sodium silicate has been used as a standard dispersant for kaolinite in the iron ore industry. However, the actual effect of sodium silicate on the colloid stability of kaolinite particles and its dispersion mechanism remain unknown in the literature. In this work, the dispersion effect and dispersion mechanisms of some common inorganic and organic dispersants, including sodium silicate, polyphosphate and a low molecular weight polyacrylic acid, on kaolinite particles were systematically investigated through electrophoretic mobility and colloidal stability studies over a wide pH range. It was found that sodium silicate-kaolinite interactions only take place in the neutral and acidic pH range, while polyacrylic acid and polyphosphate interact with kaolinite from pH 3 to 10.5. Consequently, sodium silicate only disperses kaolinite at neutral and acidic pH. In contrast, polyacrylic acid and polyphosphate disperse kaolinite from pH 3 to 10.5, with strong dispersion effect observed at neutral and acidic pH. In the iron ore industry, selective fl occulation and reverse cationic fl otation, the most widely used flotation route, are both conducted at pH 10 to 10.5. The results of the present study show that, at such high pH, polyacrylic acid and polyphosphate are more effective dispersants of kaolinite, in comparison with sodium silicate.

Jul 11, 2011

By B. Qiu, Y. Luo

The design of the predriven recovery room is not an easy task, because the stress distribution in the barrier pillar, standing supports, fender pillar and the immediate roof is changing as the longwall face approaches the predriven recovery room. An analytical approach is proposed to determine the stress distribution in the barrier pillars, fender pillars, standing supports and immediate roof of the recovery room based on the fracture mechanics approach. Based on the developed mathematical model, a stand-alone computer program has been developed to facilitate the required computations. The parameters such as overburden depth, recovery room width, mining height, shield and standing support capacities are incorporated into this program to access the feasibilities of predriven recovery room designs. Compared to the finite element method previously employed, this analytical approach offers the same, if not better, accuracy without requiring expensive computer hardware and software or specialized expertise.

Jan 1, 2012

By Sidney Katell

This report covers the period January 1963 through December 1963; it is a continuation of the series that began with the publication of Information Circular 7516 in October 1949. Also, it is the fifth in a series of reports prepared under a cooperative agreement between the Bureau of Mines and the American Association of Cost Engineers. The agreement provides for the publication of an annual cost bibliography with the work load involved in the preparation shared equally. The abstracted articles, concerned with all facets of cost engineering in the field of chemical and petroleum plants and related subjects, are from the following sources:

Jan 1, 1964

By Yan Fu, Chuanlin Fan, Xiujing Zhai, Yongfeng Chang, Binchuan Li

"The mechanism of the selective chlorination of nickel and cobalt in reduced limonitic laterite was investigated. Reduced ores were obtained from the reduction roasting of a limonitic nickel laterite. The thermal decomposition of related chlorides and the selective chlorination of the reduced ore were carefully studied using Differential Thermal analysis - Thermogravimetry (DTA-TG), X-Ray Diffraction and chemical leaching methods. In the temperature range of 300 - 500 °C, aluminum chloride hexahydrate was chosen as chloride agent. During the selective chlorination, reduced ore was partly chlorinated by hydrogen chloride generated from the thermal decomposition of chloride agent. Then the oxydrolysis of ferrous chloride re-generated hydrogen chloride was used to further the chlorination. Finally, iron was mostly rejected as hematite, while nickel and cobalt were selectively chlorinated. More than 91 %Ni , 90%Co and about 4%Fe in the chlorinated ore was extracted using a water leaching method.IntroductionLimonitic nickel laterite is an important nickel reserve, which is rich in iron in the form of goethite and has low contents of magnesium, aluminum, silicon, and other elements. Goethite is the main nickel-bearing mineral in the laterite [1]. Nickel is generally present in goethite in three modes: (a) associated with amorphous or poorly crystalline goethite, (b) weakly adsorbed to the crystalline goethite surface, and ( c) as lattice substituents [2]. In addition, cobalt in limonite was found to be associated with a manganese phase rich also in nickel [3]. These results indicate that the extractions of nickel and cobalt are highly dependent upon the degree of the decomposition of the nickel, cobalt-bearing minerals.For the selective extraction of nickel and cobalt from limonitic laterite, the ore is usually processed by hydrometallurgical methods, including high pressure acid leaching (HPAL) [4] or reductive roasting - ammonia leaching (Caron process). However, there are still some disadvantages in these processes, such as the expense of autoclaves and scaling problems in HP AL [ 4, 5], and relatively low overall metal recovery, large energy and reagent requirements for the Caron process."

Jan 1, 2011

By I Elias, E Moya, S Chaffer

This paper is based on a case study from a mine site that operates two gyratory primary crushers. These crushers were encountering problems, which included inconsistent P80, reduced liner life tonnage and, on some occasions, catastrophic failure of the liners.As part of an evaluation process, both crushers were ‘mapped’ using a technology for condition monitoring and modelling of the crusher’s wear components. The technology provides comprehensive coverage of the crusher’s concaves and mantle at 100 mm intervals. It also automatically assesses wear rate between inspections and determines the highest wear areas. Outcomes include projected optimum reline dates at target replacement thicknesses, the identification of asymmetrical wear patterns, and the accurate measurement of open and closed (OSS/CSS) side settings.A comprehensive study was performed to optimise the performance of both these crushers at site. Over a period of seven liner service lives, the strategies to improved performance included liner analysis (concaves and mantle profile analysis), tonnes per day (t/d) and tonnes per hour (t/h) analysis, mantle reutilisation, detection and control of loose concaves, and detection and control of uneven wear and hot spots.These strategies resulted in the improved mechanical and operational performance of both crushers through concave and mantle redesign, OSS/CSS control, accurate wear forecasting plus other initiatives.As a result of these initiatives, the site now experiences benefits which include consistent product size, increased tonnes per hour (t/h) for both crushers and the liner life tonnage has doubled. Additionally, further benefits include less downtime for crusher liner maintenance and the reduced cost of inventories by mantle reutilisation.CITATION:Elias, I, Chaffer, S and Moya, E, 2015. Improvements in service life and cost reduction for gyratory primary crushers through mantle and concaves optimisation – a case study, in Proceedings Iron Ore 2015, pp 115–128 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By Sidney Katell

This report covers the period January 1963 through December 1963; it is a continuation of the series that began with the publication of Information Circular 7516 in October 1949. Also, it is the fifth in a series of reports prepared under a cooperative agreement between the Bureau of Mines and the American Association of Cost Engineers. The agreement provides for the publication of an annual cost bibliography with the work load involved in the preparation shared equally. The abstracted articles, concerned with all facets of cost engineering in the field of chemical and petroleum plants and related subjects, are from the following sources: 1. American Association of Cost Engineers Bulletin. 2. Bureau of Mines Information Circulars. 3. Bureau of Mines Reports of Investigations. 4. Chemical Engineering. 5. Chemical Engineering Progress. 6. Chemical Week. 7. Coal Age. 8. Coal--Today and Tomorrow. 9. Coal Utilization. 3/ 10. Cost Engineering. 11. Hydrocarbon Processing and Petroleum Refiner. 12. Industrial and Engineering Chemistry. 13. Nucleonics. 14. Oil and Gas Journal. 15. Petroleum Management. 16. World Oil.

Jan 1, 1964

By Stanley Davidson

"The ore deposit mined by Falconbridge Nickel Mines, Limited, is one of the numerous nickel-copper sulphide bodies marginal to the large oystershaped mass of differentiated norite in the Sudbury district, famous as the world's most important nickel producing field. The unique character of the ore deposits of the district has resulted in its intensive geological study over a period of more than 50 years. The results of these studies have given rise to a voluminous geological literature and to a great deal of controversy as to the genesis of the ores. This description of the structural geology at the Falconbridge mine is presented in the hope that it may form a small part of the chain of evidence leading to a reasonably satisfactory explanation of the ore genesis.The mine, named after Falconbridge township in which the deposit occurs, lies along the southeast margin of the norite mass, which, however, is h::re concealed beneath a deep mantle of glacial sands and gravels averaging over 100 feet in thickness. As a consequence, the deposit was not discovered by the early prospectors, and it was not until 1916-17 that E. J. Longyear, of Minneapolis, located the ore by drilling(ll). The discovery was foreshadowed in 1899 by the work of Thomas A. Edison, who found indications of the deposit by what is believed to have been a combination of magnetic and electrical geophysical surveys. He sank a prospect shaft over what has to date proved to be the largest and richest ore section in the mine. A wet quicksand layer at the rock surface proved impenetrable, however, and the 'Edison' shaft never reached bed-rock.The Falconbridge property was acquired by the Lindsley interests in 1928, and ore output, since its inception in 1929, has gradually risen from a modest beginning to the present 2,000 tons and more daily. Total production in this period is 7,500,000 tons of ore averaging 1.72 per cent nickel and 0.89 per cent copper, together with a small but valuable content of precious metals, principally of the platinum group."

Jan 1, 1954

By R. Hogg, J. M. Mutmansky, E. Kaya

"Characterization of the size, shape, chemical composition, and mineralogical content of mine airborne dusts generally requires a larger mass of dust particles than is typically collected using traditional sampling devices. In this paper, the general design of a passive dust collector is described and the field results are presented. The collector was constructed of galvanized sheet metal duct with a resin-coated honeycomb to provide an elutriation-type system for particle collection. Several versions of the collector were used in the field portions of the research.The dust samples collected from underground coal mines were found to possess angular particle shapes, relatively consistent size distributions, and elemental compositions that showed relatively little variation, at least for the more prevalent elements. In addition, the distributions of particles sizes obtained from the passive dust collector appear to be similar to those of samples collected at the same time in a conventional personal sampler except that the passive device seems to collect a larger quantity of coarse, nonrespirable particles. Conclusions on the suitability of this dust collector for collecting characterization samples are presented. In addition, the potential for using such a dust collection system for supplying dusts for biomedical research is discussed.INTRODUCTIONRecently, a considerable amount of research effort has been directed toward better understanding of the characteristics of the coal dust generated during the mining process. It is generally believed that dust characteristics play a significant role in the development of Coal Workers' Pneumoconiosis (CWP). In order to effectively protect coal workers from coal dust, it is important to understand the properties of dust, the mechanisms of generation and dust-lung reaction. Conducting research on dust characterization, dust control and the biomedical aspects of dust toxicology generally requires a large sample of airborne coal dust. Unfortunately, current dust sampling instruments are not able to meet this demand because only a few milligrams of dust are collected."

Nov 1, 1995

By Luis W. Pommier

The wastes of the plating industry are generated in the process of rinsing the plated objects and during the cleaning of the plating shops. High volumes of hazardous waters are neutralized on site producing recyclable water, generating a metal rich, hazardous, filter cake. Occasionally, a complete plating bath has to be discarded which increases the metal content of the filter cakes. These filter cakes are discarded as hazardous at a cost of over $ 250 per ton. The metals found in the cakes are generally copper, nickel and chromium or zinc, lead and cadmium, assaying from 2% to 15% or even higher content of each metal The metals and their contents are highly variable. Some plating shops discard their products directly to hazardous waste sites, others, have them collected by companies which consolidate wastes from several producers prior to discarding. These wastes, richer in metal content than mine ores, need neither mining nor crushing and grinding for concentration. The commonly found impurities in the mine ores, i.e.: pyrites, arsenic, and valuable metals which are present in minute quantities, are absent in the filter cakes. The processes available to selectively recover the metals from the filter cakes, are discussed based on their technical and economic merits. The flow-sheets include leaching, solvent extraction when required, and electrolytic refining. Examples, showing the separation of copper, nickel and chromium and also of zinc and lead in pilot plants, show the technical and economic viability of the processes.

Jan 1, 1996

By E. V. Mezentseva, S. M. Okunev

"In the article there is set forth a development experience of JSC LEBEDINSKY GOK Beneficiation Plant concerning the plan of increase in the production volumes of the iron ore concentrate with Fe content more than 69.5%. There are considered the issues regarding implementation of the updated process scheme of the concentrate beneficiation using fine screening operation, its industrial tests have shown an exploitability of this development direction. There are described the issues relating to the ceramic filters for dehydration of the additionally-beneficiated concentrate, there are given the production and process figures achieved during the exploitation. The methods of the research. In the paper there have been used the following scientific research methods: the methods of system analysis, mathematical statistics, classification, comparison, modelling, observance, experiment. INTRODUCTION JSC LEBEDINSKY GOK is the largest leading enterprise for iron ore beneficiation and the unique RF producer of the merchant hot briquetted sponge iron (HBI) highly demanded by the consumers. Raw materials for hot briquetted iron production are fluxed pellets produced from iron ore concentrate with Fe content more than 69.5% (additionally-beneficiated concentrate). Strategic program of the plant’s development foresees expansion of production of the highly demanded products that imposes a necessity of expending capacity of the enterprise and implementation in production of modern processes and equipment having low resource intensity and ensuring in addition a high efficiency. Construction of the third stage of the HBI Plant became one of directions for the strategic development of JSC LEBEDINSKY GOK implemented in 2017 that caused a demand in the production volumes and filtration of the iron ore concentrate with Fe content more than 69.5%. Purpose of the work – to develop and to provide a rationalization for efficiency of the production process and filtration of the iron ore concentrate with Fe content more than 69.5% ensuring increase of production volumes and its prime cost."

Jan 1, 2018

By Jia Ma, Zhi-Chao Liu, Kang Liu, Chun-Feng Li, Bao-Bin Tang

"The geological environment of the certain uranium-molybdenum deposit is very complicated. While the study of process mineralogy is relatively few, which restricting the processing and leaching effect of ores. According to reaserch on process mineralogy of this mine, the basis of ore processing can be provided. The main contents of research are the uranium occurrence state and the influence of H2O2 in acid leaching. By various methods and experiments, the process of uranium mineralogical characteristics in this deposit are systematically studied. The results show that the uranium is mainly in the form of independent uranium minerals. The structures of these uranium minerals are venous and disseminated in mineral fissures, or microgranular inclusions in quartz and feldspar. It is not appropriate to concentrate the uranium minerals by flotation beneficiation because that the loss rate of target metals via water leaching process is very high. The ores are suitable for being acid leaching directly with 6% – 8% of H2O2, and the maximum leaching rate of uranium can be 96.88%. INTRODUCTION The uranium ores with associated elements have a large proportion in uranium resources (Lei, et al., 2014, Xing, et al., 2006; Ritchy and Wong, 1985). The uranium and molybdenum are easy to be paragenesis in nature enviroment because of their similar chemical properties. Therefor the uranium-molybdenum associated deposits are widely existing, such as the sedimentary sandstone uranium deposit in American with vanadium and molybdenum, the sedimentary sandstone uranium deposits in French with vanadium (Chen, et al., 2014; Lounis, 1997). A certain epithermal porphyry uranium-molybdenum deposit in China is mainly controlled by the subrhyolite- porphyry and the fault zone (Lv, 2012; Rui, 2010; Liu, et al., 2010). The ore properties of this deposit are complex, which include the high alteration degree, and the fine grain size of the target minerals (Ma, et al., 2013). The ore properties and occurrence state are quite different during each mining stage. As a consequence, the consumption of reagent increased and the leaching rate declined as long as the continuously mining. The author explored the best leaching rate of target elements According to the basic research on process mineralogy of present ores, experimental study of water leaching and oxidizing acid leaching on different particle sizes."

Jan 1, 2018

Many investigators measured surface forces between hydrophobic macroscopic surfaces using atomic force microscope (AFM). Some investigators observed long-range attractions and attributed them to the presence of hydrophobic forces, while others suggested that they are artifacts of the nano-bubbles and cavities associated with the hydrophobic surfaces. Still others suggested that the long-range attractions are due to the electrostatic interactions between charged patches present on opposing surfaces and hence are unrelated to surface hydrophobicity. In the present work, we have measured long-range attractions between gold- (or silver-) coated surfaces hydrophobized in potassium ethyl xanthate (KEX) solutions at pH 9.2 under controlled potential conditions. The results of our AFM force measurements are consistent with those of the contact angle and voltammetry experiments, indicating that the long-range attractions are hydrophobic forces.

Jan 1, 2012

By Feng Xue, Mi Xujun, Peng Lijun, Yin Xiangqian, Liu Dongmei, Xie Haofeng, Huang Guojie, Yang Zhen

The Age-hardening Cu-Cr alloys are extensively used in integrated circuit lead frame, railway contact wire, resistance welding electrode and continuous casting mold copper plate, owing to having an excellent combination of high electrical or thermal conductivity and high strength. High temperature performance is very important during the service process. Effect of Magnesium and Zirconium on softening behavior of Cr-Cr alloy are investigated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). During the softening process in the Cu-Cr alloy, the recrystallization process, grain growth and Cr precipitates coarsening are observed. The addition of Mg or Zr to the Cu-Cr alloy, the resistance to elevated temperature can be significantly improved, owing to being restrained the growth of the precipitates by segregating along precipitates surface. INTRODUCTION Age-hardening Cu-Cr system alloys can be widely uesed in many fileds such as electrodes for spot welding (Hatakeyama et al., 2008; Cheng, Shen & Yu, 2013; Zhou et al., 2016; Chbihi, Sauvage & Blavette, 2012), intergrated circuit lead frame (Hatakeyama et al., 2008; Cheng, Shen & Yu, 2013; Zhou et al., 2016; Liu et al., 2006; Pang et al., Xia et al., 2012; Wang et al., 2009; Huang et al., 2003; Cheng, Yu & Shen, 2014; Zhang et al., 2016; Li et al., 2007) and railway contact wire (Cheng, Shen & Yu, 2013; Zhou et al., 2016; Chbihi, Sauvage & Blavette, 2012; Liu et al., 2006; Pang et al., Xia et al., 2012; Wang et al., 2009; Huang et al., 2003), because it has high strength, good electrical and thermal conductivity. The precipitation behavior of binary or ternary Cu-Cr alloys had been investigated by many researchers (Chbihi, Sauvage & Blavette, 2012; Peng et al., 2017; Batra et al., 2002). In addition, to obtain additional mechanical properties without much deterioration in electrical conductivity, trace addition of alloying elements like Zr, Ag, rare metals (Y and Ce) and Mg are added into Cu-Cr alloy. The addition Mg to Cu-Cr alloy accelerated the process of precipitates nucleation and restrained the growth of the precipitates by segregating along precipitates surface during aging, which enhanced the stability of the deformation microstructure and improved the mechanical properties of the alloy (Zhao et al., 2018). Additional zirconium in Cu-Cr alloy enhances the strength by the decrease in inter-precipitate spacing of Cr precipitates and the formation of Cu5Zr phase (Chihiro, Ryoichi & Kazue, 2008). Owing to the decrease in inter-precipitation spacing of Cr precipitates and to the Ag-atom-drag effect on dislocation motion, the addition of Ag can increase in strength, stress relaxation resistance and without much deterioration in electrical conductivity (Chihiro, Ryoichi & Kazue, 2008). The enhance in strength and electrical conductivity of the Cu-Cr-Zr alloy by adding Ce and Y elements are attributed to removing oxygen and sulfur from as-cast alloy (Li et al., 2006). However, the effect of Mg or Zr element on microstructure and properties of Cu-Cr alloy during the softening process are not clear. Therefore, Microstructure evolution and properties of a Cu-Cr systems alloy were investigated in detail by OM and TEM. The Relationship between microstructure and properties of Cu-Cr systems alloy was also discussed.

Jan 1, 2019