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By A. M. Engelbrecht

Paper written on project work carried out in partial fulfilment of B Eng. (Chemical) Membrane processes are vital to a diverse range of technical and biological systems, which also feature in mineral processing applications such as the treatment of mine effluent and extraction of metals. In this study, the use of cellular automata to model a semi-permeable membrane that separates two compartments is considered. Cellular automata are simple models that enable the analyst to represent well-understood local effects, such as the chemical or steric interaction between molecules themselves and between molecules or particles and their environment, which can lead to very complex behaviour on a macroscopic scale. Various physical phenomena, including reverse osmosis, were simulated. Initial results for the effect of temperature, membrane structure and chemical properties of the solutes on the performance of the membrane appear promising. Keywords: cellular automata, dynamic modelling, filtration, membrane fouling, osmosis.

Jan 1, 2007

By K. W. Lee, C. Pound, J. Carmody, L. Petersen, C. Nelson, J. G. Cai

The feasibility of developing the Underground Science City below the Kent Ridge Park has been investigated. The primary aim of the study has been to explore the possibility of creating underground space to house a new community of research laboratories and offices. The investigation represents the first such study undertaken in Singapore for a non-military underground facility. The paper describes the geology of the Underground Science City site and illustrates the layout and plan of the Underground Science City. The geology and rock mass below the Kent Ridge Park is generally favorable for the development of an underground cavern complex. Underground Science City can be potentially developed housed in a cavern complex. Several potential development schemes are studied; with various combination of deep/shallow mined caverns of different span sizes and access options. The preferred scheme is shallow, mined room-and-pillar caverns with large spans and shaft accesses at both existing surface Science Park 1 and Science Park 2. The scheme can be potentially expanded laterally to create more underground space for new Underground Science Cities at Kent Ridge area.

Jan 1, 2001

By Martin B. Hudson, Daniel Brescia, Zhangwei Ning

Due to the complexity and sensitivity of surrounding environments, instrumentation and monitoring (I&M) is critical for many urban deep excavations. The objects to be monitored include shoring bulkheads, retained embankments, adjacent buildings and roads as well as underground utilities. However, there are also plenty of constraints on the implementation of I&M such as: congested site space, difficult access to instruments, coordination among multiple contractors, and installation permits for private or public properties. Because of these constraints, sometimes the implementation of the initially planned I&M is delayed, its scope is reduced, and/or the continuity of monitoring is interrupted. For these reasons, it is important to implement the I&M with robust and redundant capabilities while providing minimal interference to the project construction and schedule. This paper describes state-of-the-art I&M technologies including automatic motorized total station (AMTS) with camera and automatic leveling device, reflectorless AMTS and IoT- based wireless sensors based on a case study of an on-going deep excavation project. INTRODUCTION In urban environments, deep excavations requiring the construction of temporary shoring bulkheads are becoming increasingly common, with the associated need to provide protection of the surrounding built environment during construction. Protection of the surrounding environment requires planning, engineering, construction, monitoring, and excessive shoring movement mitigation. The I&M is a vital component of the deep shoring implementation. In public projects, geotechnical I&M is often placed within the general contractor’s scope, whereas the majority of deep excavations are privately undertaken. For those private developments, sometimes the developer contracts the geotechnical I&M directly with the project geotechnical engineer or by a geotechnical I&M specialist hired by the project geotechnical engineer. In either the public project or private development case, the effective deployment of the I&M system relies heavily on coordination and collaboration with the project contractor.

Jan 1, 2018

By Charolett Hayes, A. L. Russell, Anthony J. Bednar, Jared Smith, Valentine A. Nzengung, Stephen L. Pilcher

The manufacture of Energetics Materials (EM), including maintenance and demilitarization of munitions causes dangerously high levels of explosives residues to be harbored in building features. The two commonly approved methods of decontaminating energetics contaminated equipment and building features are thermal treatment and steam washing. The current regulatory environment is generally becoming more stringent and unfavorable to thermal and steam decontamination because of their adverse impact on air, soil, and water and their ineffectiveness to completely remove accumulated energetics from foundation cracks, internal and external piping, voids in walls and ventilation systems, and internal cavities of fixed equipment. However, chemical destruction of energetics, especially high explosives, is gaining acceptance as a safer, cost-effective and environmental friendly alternative to thermal and steam decontamination. Organic explosives, including nitramines and nitrate esters are oxidized organic compounds that are susceptible to chemical oxidation and reduction reactions. Under suitable conditions, a chemical reagent consisting of sulfur-based bulk reductants (neutralent) commercialized as MuniRem generates highly reactive free radicals that very rapidly degrade many energetic compounds to innocuous end products while stabilizing metals as the insoluble metal sulfides.

Jan 1, 2016

By O. E. Traubert, E. G. Meiter

"The daily sulphur dioxide content of the air at the Pittsburgh Experiment Station of the Bureau of Mines was determined by the bureau at the request of Committee D-14 on Screen Wire Cloth of the American Society for Testing Materials. The purpose of the investigation was to obtain data for use in interpreting screen-corrosion tests, which were conducted simultaneously and jointly by the committee4 and the Bureau of Mines.The plan of this investigation was to vale a single daily determination, except on Sundays and holidays, of the SO2 content of the atmosphere at the exposed test screens, for a period of one year. No attempt was made to determine the variation during the day, except on the morning of October 15, 1927, when the atmosphere was unusually foggy and smoky. Several successive determinations were made on that date to ascertain changes in the SO2 as the morning haze disappeared. The SO2 determinations were begun on August 11, 1927, and continued until August 11, 1923.The Pittsburgh Experiment Station of the Bureau of Mines is in a residential section about 3 miles east of the central or main business district of Pittsburgh. The air samples were taken on the roof above the auditorium, or the center rear of the building. This was also the place where the pieces of screen were placed for corrosion tests. The height was about 40 feet above ground level. Several sources of considerable smoke and SO2 are in the immediate vicinity. On the west side of the building is a double-track railroad. At this point the line runs through a cat below the level of the building. The horizontal distance between the air-sampling position and the railroad tracks is about 400 feet, and the vertical distance about 70 feet. The power plant for the Bureau of Mines building is about 250 feet south of the sampling position. About 1000 feet farther to the south are the engineering building and power plant of Carnegie Institute of Technology, and 1/4 mile to the southwest is the power and heating plant for the Carnegie Library and Museum. About 1 to 2 miles farther south and also southwest"

Jun 1, 1930

By R. Zivojinovic, S. Vujic, T. Tanaskovic

The problem of determining the optimum exploitation life of machinery, namely the optimum time for machinery and equipment replacement, represents a complex and highly responsible engineering task. Taking into consideration the situation prevailing at coal pit mines in Yugoslavia, the tasks of this class are very complex and difficult. To make a decision on replacement of capital equipment and machinery, such as bucket wheel excavators within the mentioned systems, understands a management task of utmost responsibility. It requires high professional and analytical knowledge as well as the reliable arguments, based on multidisciplinary professional approach. In this paper, the authors present their views on the problem of establishing the optimum exploitation life of bucket wheel excavators, offering an algorithm, based on dynamic programming, as a solution. Keywords: Bucket wheel excavators, exploitation life of machinery, optimization, operations research, theory of replacement, dynamic programming

Jan 1, 2003

By Karen M. Kessen

The isotopic variations of lead from Mississippi Valley galenas have long been used to place constraints on the sources of the lead, and on the residence the of the lead in crustal reservoirs prior to its emplacement in the Mississippi Valley province. Similar studies based on strontium isotope variations in gangue minerals associated with the lead-zinc sulphides have been neglected until Haden's (1) study of such minerals from several localities in northwestern Ohio. His work revealed two things about the mineralization. Firstly, it shoved that the average isotope composition of lead from galenas from northwestern Ohio lies on the anamalous lead line characterizing Mississippi Valley-type leads, albeit at the least radiogenic end of the entire data array. This confirm earlier assignments of the Ohio mineralization as Mississippi Valley-type (Hey1 and others (2)). Secondly, Haden (I) showed that the strontium in the calcite, strontianite and fluorite is broadly similar in isotopic composition to the strontium in the host Silurian to Devonian marine carbonates within which these minerals arc emplaced. He concluded that the mineral strontium my have been very locally derived, from the carbonate hosts.

Jan 1, 1979

By K Lee, L Mann, J Bygrave, G Sheldon

Ausmelt is supplying commercial quantities of an alkyl hydroxamate flotation collector AM28 for flotation of oxide and supergene base metal ores and tailings. AM28 is a non-hazardous product used as a ten per cent to 50 per cent solution in dilute potassium hydroxide. It is a selective flotation collector for oxide or oxidised base metal minerals and replaces conventional sulfidisation for oxide mineral flotation. At Radio Hill, the AM28 is used in conjunction with traditional sulfide collectors, which allows simultaneous flotation of oxide and sulfide copper minerals. The Fox Resources Radio Hill copper concentrator near Karratha, Western Australia, is currently configured to treat supergene copper ore sourced from the West Whundo open pit. This Archean VMS type copper deposit has been deformed and remobilised with uplift, erosion and weathering to form a significant supergene zone. The sulfide copper minerals present in the upper zone are digenite and chalcocite with lesser chalcopyrite and covellite. Oxide copper minerals present include cuprite, with lesser malachite and azurite. Gangue minerals include quartz, talc and chlorite. Plant trials at Radio Hill are reported for supergene West Whundo ore, where the AM28 was stage added into the circuit at nominally 80 g/t. Plant data over three months shows the copper recovery increased consistently from around 50 - 60 per cent to above 70 per cent when AM28 was added. This has been proven statistically. The grade of the concentrate was consistent with and without AM28, at nominally 22 - 24 per cent copper.

Jan 1, 2007

By Brian Isherwood, Tara Brown, Paul Kreycir, Jenny Earle

"The Shangri-La hotel and luxury condominium tower, recently opened on University Avenue in downtown Toronto, required eight levels of underground structure, four extending into the shale bedrock.Isherwood Geostructural Engineers was retained in 2007 by Anchor Shoring Limited to provide an alternative design-build solution to better address serious foundation risks. The site, bounded on three sides by City streets, abuts an existing 1957 14-storey building with five underground levels to the north. Sitting on the rock surface along the east perimeter under University Avenue runs the existing Toronto Transit Commission’s University Subway Line built by cut-and-cover in the 1950’s and which was believed to lie very near the property boundary at the southeast corner of the site.The bedrock under Toronto is known to contain very high locked-in horizontal stresses, much higher than can be resisted by shoring techniques, which result in inevitable wall movement when excavating deep into the rock. The strategy adopted to control the risk to the Subway, adjacent building, and major utilities is described in the paper, along with the comprehensive monitoring of movements, and their comparison to predictions.The ProjectThe 66-storey Shangri-La hotel and luxury condominium tower, recently constructed on University Avenue in downtown Toronto, houses 222 hotel rooms in floors 1-17; 287 residences on floors 18-49; and private estates including two 2-storey penthouses on floors 50-66. These comprise 873,000 square feet of development. Eight levels of underground basement are required to provide parking and other amenities, the lower four extending into the shale bedrock."

Jan 1, 2015

By J. A. Theron

"This paper provides guidelines on performing mass and energy balance modelling involving coal and coal derivatives. Usually, the inputs to a pyrometallurgical process would be specified in terms of elements and compounds. Reliable thermochemical data is more widely available for species involving uniquely defined, relatively smaller molecules. However, in the case of coal, the molecules are extremely large and not uniquely defined. Consequently, modelling processes involving coal and its derivatives involve several potential pitfalls. These are outlined in the present paper.It was found that coal proximate analysis should not be regarded as absolute; it could vary with several parameters, including heating rate. For modelling, the use of ultimate analyses should be considered a preferable option to proximate analyses, where ‘fixed carbon’ and ‘volatiles’ are not defined in terms of chemical composition. Significant errors could be incurred if the larger molecules are neglected during calculation of the calorific value (CV) of coal gas (the gas liberated when coal is heated in the absence of oxygen).For elemental analysis determination, the oxygen content (which is calculated by balance) should be checked to ensure it is within the expected range. For representation of sulphur in coal, one should avoid doublecounting due to SO3 in the ash analysis.Potentially, oxygen in coal could be represented as O2, H2O, CO, or CO2.However, use of some of these species without considering the experimentally determined gross CV leads to significant errors in the energy balance. If coal enthalpy is calculated from elemental analyses without correction, representation of coal oxygen as H2O(l) gives reasonable accuracy. Coal volatiles could be represented by a complex mixture of compounds, even using different oxygen-containing species than these four, provided the enthalpy is corrected.It is recommended that an ‘enthalpy correction value’ be incorporated in energy balances involving combustion, devolatilization, or conversion of coal and coal derivatives, e.g. coke, char, or tar. That would imply that proximate analysis, elemental analysis, as well as the gross CV would be required for all solid or liquid coal-derived substances being modelled. No other correction due to carbon being present in a form other than graphite should be used, as that would imply double-counting some effects."

Jan 1, 2015

By W. H. Fluker

Until recently, the universal practice in New Zealand was dry-crushing and direct cyaniding. With ores containing no mineral sulphides, and little or no coarse gold, 'this method, in spite of its many disadvantages, gave excellent results, and was by far the best one available, pending the solution of the slimes-problem. But the situation has now been changed. The successful treatment of the slimes, enabling the mines not only to do away with dry-crushing, but also to deal with the mineralized ores of the lower levels, which are, for obvious reasons, quite unsuited to that method of treatment, has made wetcrushing universal; and this may be taken as satisfactory proof of its superiority over the former practice. In the lack of accurate information from plants operating successfully, particulars of experimental trials carried out on a working-scale at the Waitekauri Extended mine, Maratoto,

Jan 1, 1903

By R. Haecker, S. Gupta, P. Somasundaran

Rock disintegration processes are usually inefficient and costly operations in mineral beneficiation, mine development and oil well preparations. Thus, there is a strong need for improving the energy efficiency of unit operations such as drilling and comminution. The effects of selected cations and anions on drilling efficiency in a hard rock formation (Dakota Sandstone) were studied. The zeta potentials and the tensile strengths of the drilled samples were measured under similar chemical conditions. The chemicals tested included MgCl2, Na2CO3, AlCl3, NaCl and Dodecylammonium chloride. The results indicated that drilling rates can be enhanced or retarded depending on chemical conditions such as the solution pH and the type and concentration of reagents. Drilling data are correlated with mechanical (tensile strength) and interfacial (zeta potential) properties of the rock formation. The mechanisms involved are discussed in light of Rehbinder's and Westwood's theories.

Jan 1, 2000

By Josh Swank

Albert Einstein once said, ?the important thing is not to stop questioning.? In the mining industry, a lack of inquisitiveness may lead to a blissful ignorance but it certainly will not increase efficiencies. While one may claim necessity is the mother of invention, questioning and analyzing how methods and systems can be improved is the catalyst to discovering necessities. Understandably, when working in the middle of Canada?s oil sands, where trucks operate around the clock every day of the year, it is nearly impossible to pull the nose from the grindstone long enough to provide thorough analysis. But, fortunately, some manufacturers/inventors have assisted by examining the process and the ensuing headaches within this application.

Jan 1, 2013

By John W. Buch

Safety and cost in mining coal beds under the extreme pressures found at depth, full extraction to conserve resources, and even surface subsidence to minimize damage of improved areas have directed much well-deserved attention, in the United Kingdom; to roof-control methods. Because the effects of pressure will be felt intensely as our Pennsylvania anthracite mines grow deeper, the senior author took advantage of an opportunity afforded by a mission to Europe3/ to observe, to a limited extent, the effects of pressures found in deep mines and the manner in which they are con trolled. Organized research relating to strata control has been carried on in Great Britain for nearly 25 years. These activities have been ably outlined by Dr. D. W. Phillips.4/ Physical properties of coal-measure rocks, movements of roof and floor, and types of face and roadway supports have been investigated. Same of the forces induced by the extraction of coal have been measured. The results of this research have been publicized and openly discussed, and much progress has been made in establishing a better factual understanding of roof-control problems and their solution.

Jan 1, 1951

By Mike Broczkowski, Laura Dewhirst, Kieran Large, Angelo R. Fernando, Heather Daigneault, Jim Johnson, Randy Wiens

The radioactive isotope radium 226 is a contaminant of potential concern in effluent waters from metal mining operations in Canada. Acceptable release levels of radium 226 are governed by Metal and Diamond Mining Effluent Regulations. Since radium is invariably present as a companion element in uranium ore, monitoring and controlling of radium 226 is a must for uranium mining operations. Measurement of radium 226 is traditionally carried out through a radiochemical technique involving selective co-precipitation of radium with barium sulphate followed by alpha spectroscopy for quantification. As of 2010, Cameco has also been using an ICP-MS based radium analysis method developed in collaboration with a research team at Trent University, Peterborough, Ontario. This method, which is highly automated and requires significantly less sample handling, with improved turn-around-times, is being used by Cameco site laboratories at the McArthur River and Cigar Lake mines as well as the Port Hope Conversion Facility. This paper compares the benefits and drawbacks of this new method, compared to the traditional alpha counting procedure drawing from almost ten years of field experience.

Jan 1, 2020

By A S. Fogliata, L Bengochea, G Mas, J E. Lazarte

The Culampajß auriferous district is located in the northern sector of the eastern edge of the homonymous hill, Catamarca Province, Argentina. Tajo Largo mine is situated in the southern flank of Las Minas gulch at an approximate height of 3.600 m above sea level. In the studied area main outcrops are orthogneiss rocks of Chango Real Formation. The ore mineral is native gold with a lesser amount of pyrite, chalcopyrite, haematite, limonite, malachite, azurite and covellite. These ore mineral assemblages are disseminated in quartz veins filling tension fractures in the host orthogneiss.Several types of inclusions have been recognised, including three phase H2O-CO2liq-CO2vap inclusions, polyphase inclusions with H2O-CO2 and one or more solid phases, and two phase aqueous inclusions. In the three phase H2O-CO2liq-CO2vap inclusions the Tmclath is about 1¦C and the CO2 liquid-vapour homogenisation occurs at 26 - 28¦C, to liquid phase. The homogenisation temperature of H2O-CO2 occurs at 365 - 380¦C in the aqueous phase. This set of data defined a solution with a salinity of 14, 4 wt per cent NaCl equivalent and a density of 0.84 g/cm3. In the two phase aqueous inclusions the melting temperature (Tm) of -5.4¦C and the eutectic point (Te) in -38¦C indicates a salinity of about 7.5 wt per cent NaCl equivalent, with the probable presence of Ca2+. Density of fluid is about 0.83 g/cm3. Homogenisation temperature ranges between 260¦ and 280¦C. The pressure, temperature and salinity of fluids in the polyphase inclusions suggest an early fluid of high density and high salinity. The three-phase fluid inclusions may be the result of an unmixing-phase separation of post magmatic hydrothermal fluid due to pressure decrease along fractures. It is suggested that the deposit was formed during the late magmatic hydrothermal stage genetically linked to granitic rocks and can be comparable with the intrusion-related gold system of Baker (2003).

Jan 1, 2008

By Alejandro Ferrada Vergara

Most blasting techniques that are designed to improve fragmentation and subsequently improve ore work index to downstream comminution processes, apply powder or energy factor increases, either by stretching the drilling pattern (burden/spacing ratio) implementing faster initiation sequences or using more energetic explosives. The new application will move detonation parameters up, making the blasting process riskier for the surrounding boreholes, explosive column or initiation systems functioning.

Jan 1, 2016

By M. Abdollahi, M. R. Khalesi, Y. Kianinia, A. Khodadadi Darban

High cyanide consumption during the processing of gold ores with high sulphide minerals can make the typical cyanidation uneconomic. Also cyanide is a toxic material and environmental concerns of cyanide compounds are serious. Optimization of cyanide consumption requires a methodology to estimate the amount of exposed cyanicides, the kinetic of their dissolution and estimation of formation of cyanide complexes which consume the free cyanide. In this paper, a methodology to estimate cyanide consumption by modeling the minerals and gold leaching kinetic based on a liberation model and speciation of all possible cyanide related species in the solution is presented. The results showed that this methodology could successfully estimate the cyanide consumption based on mineralogical data with very lower number of parameters compared to empirical models present in the literature, while it offers the prediction of formation of all cyanide complexes which could be used for optimization purposes.

Jan 1, 2017

By Michael L. Sorokin

The various methods of converter slag cleaning operation are analysed from the thermodynamk point of view: cleaning using coal, cleaning using combustion products of natural gas and cleaning in presence of matte. All calculations were done, applying the developing computer procedure based on the free energy minimisation algorithm. Three-suffix Margules equations were used to calculate thermodynamic properties of melts; The calculations resulted in recommendations for the practical appliance.

Jan 1, 1995

By I. N. Gridasov, T. V. Ignatova, E. V. Shelepov

"Mikhailovskoye Deposit is comprised of oxidized ferruginous quartzites among other minerals with the former widely spread across the ore field and mined along with unoxidized ferruginous quartzites. PJSC Mikhailovsky GOK strategic development is aimed at iron ore product output expansion. The most critical item of the strategic development road map is process design for separation and concentration of hematite contained in oxidized ferruginous quartzites mined as the by-product in the open pit. Laboratory and semi-industrial tests run to design cost-effective, reliable and environmentally friendly process for Mikhailovskoye deposit oxide quartzites processing included the following processes: - pilot tests of reverse anionic flotation which produced concentrate with Fe60.1-62.9% total iron content and 66-69%Fe recovery rate; - combined magnetic separation and flotation (Marubeni Company, 1982) including slime removal, reverse anionic and cationic flotation and high gradient magnetic separation resulting in 48.9% yield, Fe55-57.5%, up to Fe60.5% hematite concentration ( Fe64.1% being the best result achieved),76.2% recovery. - magnetic separation and flotation, including separation in low gradient (1400 Oe) and high gradient (up to 17000-18000 Oe) magnetic field. The results of these pilots tests were the following: 57-59%Fe concentrate, 70%Fe recovery (Mekhanobrchermet, MGOK, 1982-1988): - magnetic roasting in pilot plant of TSGOK (Krivoy Rog) which produced 61.1%Fe concentrate with 81.5% recovery. Major disadvantage of the method is high generation of dust equal to 20% of the initial feed. Based on third-party studies flotation of oxidized ferruginous quartzites process embracing best processing methods was designed by Metalloinvest Management Company LLC and PJSC Mikhailovsky GOK engineers. This paper discusses analysis of studies aimed at intensification of separation processes with application of mechanical slurry agitation (MSA), addition of alkali (NaOH) and elutriation of initial feed. The paper also provides a design solution to implement a lab-scale MSA plant. It includes feasibility evaluation of MSA inclusion in flotation of oxidized ferruginous quartzites process to enable higher yield and hematite recovery in resultant concentrate. Outcomes of the discussed work have significant value for prospective engineering of OFQ concentration process."

Jan 1, 2018