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By ROBERT R. ROUGH, FRANK L. BACON, John Dasher

(being shipped as bailast in ocean freighters). Within the last 10 years it has become more economical to use local sands, and there has been a general shift from the Belgian sand. Deposits of purer sand were treated and used for 'some time: but the suprly became limited, and means were sought to beneficiate the more bountiful subpay-f impure beach sands. These sands are composed of, 50 percent feldspar and 50 percent quartz, with small amounts of iron- bearing minerals, The most objectionable impurities in these West coast sands are the oxides of iron and aluminum. The Del Monte (Calif.) beach sand contains about 0.13 percent FeqQg and about 11.0 percent Aig03 (the latter being furnished by the large amount of feldspar present.) For the manufacture of feldspar present.) For the manufacture of flint-glass containers the maximuni quantities of these two impurities permitted in the sand are 0.05 percent F20 and 6 to 8 percent A1203.. The Fe0g occurs in the sand as follows: Traces of iron-bearing minerais resistant to weathering, ferruginous clay stains on the sand grains, and iron minerais not visible and possibly in solid solution or as colloidal incisions in the grains of feidspar or quartz. A good part of the iron in the sand is present in the traces of iron-bearing minerals, biotite, ilmenite, garnet, monazite; and hornblende. Biotite is present in larger quantities than the others. Samples of quartz, were freed of iron-bearing minerais by the use of heavy liquid (sp.gr. 2.70), leached with boiling HCI and SnCl2. Under a microscope a few apparently clean quartz grains were selected, and Fe203 was determined spectrographically to be 0.03 percent. The technique is similar to that described by Gabriel and Slavin. 4/

Dec 1, 1943

By H. L. Burmeister

This report describes the mining and milling practices used by the Eastern Magnesia Talc Co. at its Johnson, Vt., operation. The report also contains a description of the local geology and all available information on cost and performance data. Since 1925 the mine has produced continuously at an average annual rate of 54,000 tons, and the ratio of ore hoisted to finished product is roughly 2 to 1. Ore is stoped by a combination of shrinkage and sublevel methods. In any 24-hour period the mill produces an average total of 14 grades of finished talc product, 9 by dry grinding and air classification and 5 by wet grinding and flotation methods. The mine operates one shift per day, 5 days per week and the mill operates on a 3-shift, 5-1/2-day-per-week basis. Operating costs for 1958, on a percentage basis, were mining, 22.34; milling, 54.77; ore haulage, 2.89; and all other, 20.00 percent.

Jan 1, 1963

By E. L. Singleton

This Bureau of Mines investigation was initiated to study and establish some of the chemical and physical characteristics of the condensed Mno-Si02 system. To prevent oxidation of the manganous ion, I atmosphere of purified helium was used in the furnaces. Solidus-liquidus curves and invariant points were established from melting-point determinations and were supplemented from data obtained by the static-quenching method. Experimental findings and data are for the intermediate compounds of tephroite and rhodonite with their respective eutectics represented at 25.5 and 37.2 weight-percent silica. Tephroite melts congruently at 1,347° C., and rhodonite melts incongruently at 1,286° 8.. A metastable transformation was determined to exist at the 1,347° C. isotherm, the congruent melting point of tephroite. A composite X-ray-diffraction pattern was formulated for synthetic rhodonite. This investigation contributes fundamental data leading toward a better understanding of the more complex slag systems.

Jan 1, 1962

By R. A. Pimentel

Many longwall operators experience difficulty complying with the federal regulation limiting average dust exposure. Others are currently in compliance, but the dust exposure limit keeps then from increasing their production. Spray water is a major means of dust control. Excess water can cause problems in the transportation system and the cleaning plant, and reduces the Btu value of the run of mine coal. Thus, the dust exposure reduction per unit of water sprayed must be maximized. This paper discusses underground tests recently completed as part of a Bureau of Mines research program to determine the effects of variations in spray water flow rate, pressure, proportioning and spray orientation on longwall shearers.

Jan 1, 1984

By L. Gutierrez, S. Gering, C. Calderon-Arteaga

"Drill and blast represent the most important, and sometimes the costliest processes in the mine. The cost of drilling and blasting operations greatly contributes to the “high cost trends of the overall mining operations” (Afum and Temeng, 2015). The use of available information to improve the drill and blast processes can be the difference between a wasteful process and one that is optimized for costs, safety and desired fragmentation. Mining operations have access to several types of data sets that include a variety of different systems. This information can be used to improve, evaluate and apply processes for drilling and blasting. This may include different types of data from the different stages of the process (before, during and after the drilling and blasting operations), such as hole locations (planned and actual), penetration rates, drill operators, fragmentation (expected and resulting), explosive (design and usage), geology, vibration and others. This information can be used on its own or combined for further analysis to reduce costs, improve safety and evaluate results. Fortunately, due to advances in mining software, drill and blast engineers can exploit this data and create reports to evaluate results and improve the drill and blast process. However, as users start combining information from multiple datasets and establishing standard operating procedures for reporting across multiple sites, it becomes valuable to create auditable, automated and sustainable workflows for handling the information.In some cases, the task of aggregating and standardizing the data formats has already been completed and is available to consumers via the Enterprise Data Warehouse (EDW). A data warehouse team extracts data from the source systems and transforms it so that it is meaningful for decision support (Wixom, Watson, 2007). The author’s initial implementation plan for the drill and blast solution included using data stored at the sites on local servers. However, we learned early in the process that much of the work for aggregating and supplying the required data was already completed and was available in the EDW ready for use. This saved time, reduced risk and added value to the system.The goal for this case study is two-fold: to show how information can be used to make decisions and improve processes, especially highlighting the value of using an EDW for managing drill blast information; and to discuss how technical challenges encountered during the implementations were resolved. This article targets users that want to better manage their drill and blast data or try to set up standardized workflows for using this information.This case study will discuss the process of implementing a drill-and-blast workflow at multiple sites within Freeport-McMoRan (FMI) using both data at the sites and information available from the EDW."

Jan 5, 2017

By Francisco Morganti

Weight reduction is the main target of all carmakers, which results in a continuous development of new steel grades. Latest 3rdgeneration advanced high-strength steel grades (AHSS) are complex materials with special chemical compositions and multiphase microstructures. The pickling, annealing and galvanizing processes of these grades aresomewhatdifferent due to the changed chemical compositions and microstructures. Therefore, these innovative steel grades place new demands on the plant technology of pickling, annealing and galvanizing lines. The most significant challenges for the pickling process are sludge occurrence during pickling, varying pickling times, weld ability of the materials, changed visual appearance and required high surface qualities. The most important topic concerning annealing line is a precisely controlled and very flexible heating and cooling process in the furnace.One of the new requirements in galvanizing linesis the prevention of surface faults caused by bare spots, which can occur since these materials feature a higher content of alloying elements like silicon or manganese. Prevention is possible with the special pre-oxidation technologies.Due to the higher strength of the material also the mechanical equipment has to be designed differently in these lines. This paper describes the influences of the changed chemical composition and material characteristics of modern steel grades on the pickling, annealing and galvanizing process and gives an overview about the technical solutions.

Oct 30, 2017

By M. A. Mahtab

This paper presents the results of a parametric study of the influence of natural features (stress field, rock strength, and strength and orientation of fractures) as well as the influence of induced features (undercut span, boundary slot, and other boundary-weakening measures) on the cavability of an undercut block of ore in mining by the block-caving method. The two-dimensional finite element analysis technique was used for this study. A coarse "mesh," along with linear homogeneous assumptions for rock properties, was used to model the problem of initiation of caving in a block of ore. Interpretation of the test results suggests that weakening the "abutments" of the block as well as certain orientations of natural fractures exercise significant influence on cavability. These findings hold promise for immediate application to known situations in block-caving mines.

Jan 1, 1975

By E. Kenneth Siroky

The concept of ultrasonic measurement was originally applied to marine operations. Sonar . . . standing for Sounding, Navigation and Ranging, was developed for military uses. Today Sonar has become very important to the fishing fleets and marine construction industries where its applications cover a wide range of uses our company, in addition to the inair ultrasonic equipment as discussed in this paper, is also deeply involved in marine sonar and works primarily with oceanographic research and fishing industries. Ultrasonics, by simple definition, are sound waves beyond the audible range of the human ear and are generally accepted to be waves over 20,000 cycles per second. When applied to level measurement, the principles of ultrasonics are basically quite simple. A sound pulse is initiated at a point in time and the time interval for the echo from that pulse to return can be interpolated into distance. The speed of sound in air under standard conditions is approximately 1,100 feet per second, or if converted into more meaningful information as related to distance measurement, the time required for sound to travel one foot round trip is 1.78 milliseconds. An early application for ultrasonic level monitoring equipment was in large grain elevators. Prior to ultrasonics, the common practice of inventory measurement was to have an employee walk around the top of these large grain elevators, which are often over 100 feet above ground level, and drop a weighted rope or chain down into the silo to determine the level of the grain. Needless to say, this was a slow process and could be extremely unsafe, especially during windy and snowy weather conditions. An alternate

Jan 1, 1971

By S F. Wang, J J. Yin

Dust pollution poses a persistent challenge within mining processes, giving rise to a spectrum of concerns, including occupational diseases, mechanical degradation, diminished visibility, and the potential for dust explosion incidents. Existing dust detection and monitoring methodologies face limitations, including insufficient measurement accuracy and intricate processing procedures. Consequently, a comprehensive identification and evaluation system rooted in image processing technology is proposed to facilitate real-time measurements of dust pollution in mining worksites. The study primarily employs grey scale average and fractal dimensions to characterise particle features evident in collected dust images. As a result, the data processing platform can dynamically process data and present dust pollution conditions. Notably, this research integrates the monitoring and assessment of dust pollution with the systematic adjustment of mining parameters, ventilation parameters, and strategies for dust reduction. Through statistical analysis of dust concentration and particle size during mining processes, rock properties such as components and cuttability can inform mining parameters. This information, in turn, guides detailed excavation strategies, including cutterhead speeds, torque, and excavation speed. Similarly, analysing dust characteristics derived from images is a valuable resource for gaining deeper insights into the efficacy of implemented ventilation strategies. By harnessing vision-based information detailing dust concentration and distribution, a wealth of direct guidance becomes available for refining ventilation parameters. This encompasses crucial aspects such as the selection of appropriate ventilation systems tailored to the specific mining environment and the optimisation of operational conditions for ventilation fans. Additionally, the detailed information derived from the visual data allows for strategic decisions on factors like the spatial arrangement of ventilation outlets and the calibration of airflow rates. Moreover, precise choices for dust reduction measures and parameters can be made based on the prevailing dust conditions. Upon real-time monitoring of dust pollution using the proposed method, corresponding measures such as spraying and foaming can be promptly implemented. Crucial parameters, such as spray angles and volume, are integral to these application processes. In essence, the proposed method assumes a pivotal role in not only dust monitoring but also the formulation of preventative and control measures within mining processes.

Sep 1, 2024

By A. W. F. Smith, P. B. Prangnell, D. N. Crowther, P. J. Apps

It is well known that the refinement of grain size in metals leads to a significant improvement in important mechanical properties. As part of a European collaborative project, processing schedules have been investigated aimed at producing a homogeneous ultra-fine ferrite and spheroidised carbide aggregate microstructure structure in high carbon (CMn) steels (0.6-1.2wt%C), via conventional 'warm' rolling and innovative Equal Channel Angular Extrusion (ECAE). Suitable deformation schedules were determined from dilatometry and thermo-mechanical Gleeble simulations. Evidence of an ultra-fine ferrite and carbide aggregate microstructure following 'warm' rolling is given. A significant improvement in tensile strength, particularly proof stress (0.2%) was also noted in comparison to material deformed at higher temperatures. Concurrent Equal Channel Angular Extrusion (ECAE) experiments investigated microstructural evolution with incremental strain. Extensive analysis was carried out using various techniques, including high resolution Electron Back Scattered Diffraction (EBSD). Evidence of ferrite grain refinement was noted in a eutectoid composition steel. A sub-micron ferrite structure was observed following high strains (E-3.33) and the mechanical properties exhibit a marked increase in tensile strength.

Jan 1, 2004

By H. Kamarudin

The behaviour of cassiterite-sulphosuccinamate flotation system was examined in the light of zeta potentials measured by micro-electrophoresis method. It was observed that sulphosuccinamate substantially affects the zeta potentials of cassiterite, lowering its i.e.p. to pH 2.5 and indicating a specific adsorption and/or chemical interaction. The optimum concentration for flotation, as seen in micro-flotation tests, was found to be associated with the most effective lowering of the zeta potentials, the optimum pH being 3.0. The effect of cations in the pulp was examined for the presence of ferrous, ferric, aluminium and lead ions. The ions ferric and aluminium were observed to create an intense effect of increasing the potentials to positive side, possibly due to adsorption of cation hydroxy complexes, as indicated by their respective species distribution diagrams.

Jan 1, 1994

By Leo Brewer, Kazuyoshi Shimakage, Mamoru Mitomo, Toshiyuki Nishimura, Yoichiro Uemura, Shinji Hirai

"In the synthesis process of ß -La2S3 via the sulfurization of La2O3 powder using CS2 gas, La2O2S was formed. This occurred at an initial stage of the reaction for sulfurization temperatures below 973K, and ß -La2S3 was also formed at a shorter period for higher sulfurization temperatures. It was found that the oxygen content in ß -La2S3 powders decreased gradually with an increase in sulfurization temperature. On the other hand, the carbon content in these powders increased gradually with an increase in the sulfurization temperature. Though it has been reported that ß -La2S3 was transformed to Y -La2S3 at 1723K± 50K, the sintered compact of double-phase Y -La2S3 and ß. -La2S3 was formed at a rather higher temperature of 1973K when the synthetic powder of ß -La2S3 containing a high amount of oxygen was used. However, phase transformation of -La2S3 to Y -La2S3 progressed preferentially with a decrease in the oxygen content of synthetic ß -La2S3 powder. The Seebeck coefficient of the sintered double-phase Y -La2S3 and -La2S3 was higher than that of the single-phase Y -La2S3, reported previously.Introduction La2S3 exists in three polymorphic forms that are similar to a series of Ce2S3, Pr2S3 and Nd2S3: a, ß , and Y'. The a -La2S3, which is stable at low temperature, is irreversibly transformed to ß -La2S3 of various compositions in the solid-solution range between La2S3 and La3S4, at 923 ± 50K. The -La2S3 may also be an oxysulfide of La10S14O2. Moreover, the ß .-La2S3 phase is transformed to Y -La2S3 ,which has a Th3P4 structure, at 1573 ± 100K. The melting point of Y -La2S3 is 2398 ± 30K where this temperature is similar to those of common refractory materials such as silica and alumina. Therefore, it can be predicted that y -La2S3 which has a high melting point and a thermodynamic stability due to the strong affinity of La for S, would have &high refractory character and chemical inertness in many molten metals. The y -La2S3, colored vivid faint yellow is stable up to 623K in air, where oxidation starts. y -La2S3 is frequently used as pigments for plastics and paints3. Furthermore, Y -La2S3 which is a semiconductor, is considered to be useful as a thermoelectric conversion materials, because it has a high Seebeck coefficient."

Jan 1, 2000

By D. M. Rippley

THE St. Lawrence Seaway Project ranks with the greatest engineering undertakings of all time. A summary of major materials going into the construction of this project, shown in Table I, will assist in an appreciation -of this fact. These data relate to Seaway construction only, and it should be remembered that two large-scale power projects are in the construction stage on the St. Lawrence river concurrently with construction of the Seaway. A project of such magnitude as the Seaway would attract widespread interest even if it were being constructed in a remote area. The fact that it is located in a heavily populated and developed section of both Canada and the United States has done much to enhance this interest, and in many ways complicates the problems confronting the engineer in the design and construction phases. Many consider the St. Lawrence Seaway to be a new idea that has developed within the past decade - such is far from the fact, because the St. Lawrence River canal systems have existed for more than a century, and the Seaway Project is but a new, larger, and more efficient version of a continually expanding facility.

Jan 1, 1957

By A Maier, M Goldner, C Gimber

Given the ongoing global crises of climate change and nature loss, with the World Economic Forum (WEF) identifying them as the top risks to global economies in terms of both likelihood and impact in the coming ten years (WEF, 2022), there is increasing, pressing demand for companies to demonstrate they understand their climate and nature related risks and look toward contributing genuine beneficial environmental outcomes. Within the mining industry, mine closure is the obvious field in which climate and nature positive strategy can be linked with operations. To do so, there is a need to challenge long-held assumptions around closure in the mining and regulatory context; particularly, to shift the focus from closing individual mines to considering regional opportunity generation and value creation.

Aug 2, 2023

By J. C. Wynn

J.R. Hillebrand From the abstract, "A realistic ore deposition model to serve as a conceptual framework." Further, on page 246, "The first area of study was the Josephine peridotite, now identified as an ophiolite terrane, located in northern California and south-western Oregon (Fig. 3). Here, it was felt that we could test the models shown in Figs. 1 and 2 and, if successful, expand the model and test it in other chromite districts in the US and around the world." My comments refer only to chromite deposits in Europe and the Middle East. First, I question that may chromite deposits occur in the idealized ophiolite section shown in Fig. 1. Second, although some podiform deposits (referring to morphology) have been important (Guleman, Turkey, for example), the stratiform deposits are of greater importance in tonnage and frequently grade. Examples include Nada, Yugoslavia; Bulqiza, Albania; Xerolivado, Greece; Saranovsk, Russia; and Abdasht, Iran. Reply by J.C. Wynn Mr. Hillebrand raises two issues that deserve a serious response. One issue is basically subjective and the other is ultimately political. First, the question of where (and how many) podiform chromite deposits are found in the idealized ophiolite section of Dickey (1975). The Dickey model is still perhaps somewhat controversial (Panayoutou, 1980), but our experience in the Josephine ophiolite of northern California (Wynn, 1980; and Albers, 1983) shows that the model works well there. Virtually all the chromite is found in dunite lenses in the tectonite peridotite (harzburgite). Since there are few complete ophiolites exposed in the world, the model will probably never satisfy everyone. The degree of acceptance is a function of any individual's subjective experience. Second, it is well known that stratiform chromite contributes more than 95% of the chromite reserves presently known in the world, and it could be reasonably argued that there is no point in exploring for or exploiting podiform deposits further. The title of the paper, however, was in part 'strategic minerals geophysical research'; chromite is considered a strategic and critical mineral of the US and many other industrialized nations. Stratiform deposits in South Africa and Zimbabwe account for most of the chromite reserves in the world. Unfortunately, experience in modern times with substantial price fluctuations and even resource cartels dictates the wisdom of identifying and maintaining a national chromite reserve, irrespective of the cost. An improved exploration methodology is an essential element in this strategic objective. References Albers, J.P., 1983, "Geological and Geophysical Studies of Chromite Deposits in the Josephine peridotite, California and Oregon," US Geological Survey Bulletin 1546 A-D, 118 pp. Dickey, J.S. Jr., 1975, "A Hypothesis of Origin for Podiform Chromite Deposits," Geochimica et Cosmochimica Acta, Vol. 39, pp. 1061.1074. Panayiotou, 1980, Proceedings, International Ophiolite Symposium, Cyprus, 1979, 781 pp. Wynn, J.C., 1980, "Exploration Geophysical Methods and Strategies, and Their use to Locate and Assess Small Mineral Deposits," Chapter 12 of Meyer and Carmen, eds., The Future of Small Scale Mining, McGraw-Hill, New York, pp. 75-83.

Jan 12, 1983

By SHANTAE LEE, ELAHEH TALEBI, Frank A. Drews, ROGERS W. PRATT

Fatigue is a relatively well-investigated topic in the surface transportation industry with a research focus on sleep deprivation and disruption. This paper examines fatigue in mining operations. While mine operators are using or currently introducing technology to monitor fatigue, there is little work that focuses on the operators’ experience of fatigue and the acceptance of fatigue-monitoring technology. Focus groups were conducted to investigate these topics. The results of this research suggest that current fatigue-monitoring systems lack validity, reliability and user acceptance. Overall, these results emphasize the importance of a socio-technical systems perspective to guide interventions aiming at improving miner health and safety.

By D. H. Pulling

Statistics for copper consumption from various sources show that the importance of production from secondary sources is increasing. This is of particular significance in countries such as the U.K ., which are totally dependent on secondary material for the supply of home-produced copper . A brief survey of the U.K . industry has shown that, in the past, relatively high profit margins have not encouraged high cap ital investment and development of more sophisticated operating techniques, but set against a background of rapidly escalating operating and energy costs , together with an ever-increasing demand for copper , it is anticipated that the industry will see great changes in the near future. With this in mind, an experimental furnace for continuous smelting of copper-bearing scrap has been developed at the University of Birmingham. This furnace has been designed to combine the conventional operations of blast furnace or reverberatory smelting, usually followed by converting, in one unit, and incorporates many of the features of the WORGRA and Noranda processes for continuous primary smelting . It consists of a long, sloping channel, constructed of chrome-magnesite refractory, which: is churned near the top. Smelting is effected lower down the channel, where iron, etc., in the scrap is oxidized and slagged off with silica flux. Provision is made for oil injection to increase oxidation rates. Metal can flow from the bottom of the channel, and slag from the top, so that a counter-current flow is achieved. The approximate molten capacity is 25 kg. Various scrap charges, both synthetically made and as supplied from various industrial smelters, have been successfully smelted. Metal of 83 -95 % Cu has been produced, depending on the original charge composition and the degree of air injection, although air injection was also found to considerably increase the copper loss to slag. Recoveries of other valuable non-ferrous metals in the charge were good.

Jan 1, 1977

By Y. De Gao, C. Gang Zhong, X. Yang Qiu, Li Wan

The chelating reagents are used as effective collectors in wolframite flotation, and certain metal cations need to be added using chelating collectors so as to activate valuable minerals and obtain good flotation indexes. Different metal cations will result in different reactivity with collectors, in order to select the effective activator in BHA flotation of wolframite, the activation effectiveness of different metal cations on wolframite ((Fe,Mn)WO4) flotation were studied using pure minerals. The results showed that the wolframite activation by Pb2+was the best among the selected cations. The maximum flotation recovery of wolframite was found to be 95.58 % under conditions of 100mg/LBHA and 1×10-4mol/L of Pb2+at pH 9. The dosage of Pb2+needs to be controlled in an optimum range. Also, the activation mechanism of Pb2+ on BHA flotation of wolframite was investigated by measurements of contact angle, zeta potential, adsorption capacity and IR spectroscopy. It was found that Pb2+ could chemically adsorb onto the wolframite surface improving the flotability of wolframite and enhancing the adsorption of BHA on wolframite. When the dosages of BHA and Pb2+ were 100 mg/L and 1×10-4 mol/L, the adsorption quantity of BHA on wolframite sharply increased up to 0.30 mg/L at pH 9 compared with wolframite treated with only BHA.

Jan 1, 2014

By Bing Ji Yan, Cui Wang, Ya Peng Zhang, Chuan Hui Li, Hong Wei Guo, Jian Liang Zhang

There are a lot of research of the chlorine element’s influence on blast furnace, and mainly pay close attention to the harm to gas pipes and equipment. There are three kinds of chloride in the blast furnace gas, including HCl, NH4Cl, and NaCl (or KCl, ZnCl, etc.). This paper mainly analyzes all kinds of phenomenon of the chlorine element overflowing blast furnaces in Jinan Steel, and puts forward some different viewpoints, which are that the chloride overflowing out of blast furnace in the types of HCl, NH4Cl, or NaCl (KCl) not only has much to do with raw materials of chlorine load level, at the same time with the blast furnace burden distribution. On this basis, comes up with countermeasures for the different situation, such as adjusting the burden distribution matrix to guarantee the central gas flow smooth and changing the kind of raw materials to reduce the chlorine quantity, which will be helpful to prevent the harmful influence of chlorine element.

Mar 1, 2017

By Ted H. Eyde

Nearly 17 years ago a major producer of synthetic zeolites started an extensive exploration program for natural zeolite deposits which resulted in the discovery of over 170 occurrences in the western United States. A few years later several of the other producers and consumers of synthetic zeolites also started similar exploration programs. Since then, small quantities of natural zeolite minerals have been produced from at least 12 deposits in the United States. Of these the Bowie deposit, about 13 miles north of Bowie, Arizona, is the most important,having produced over 5,000 tons of vitric tuff zeolitically altered to the mineral chabazite and minor amounts of the minerals erionite and clinoptilolite. Mining Districts and Mineral Deposits of Arizona compiled by Charles A. Mardirosian, Consulting Geologist, estimates the value of the total production from the Bowie deposit at a very conservative $2,000,000. Unfortunately, none of the companies responsible for the discovery and the initial production of natural zeolites made any effort to develop the high volume, low cost applications of this unique mineral raw material. Instead, they developed only the high unit value uses to supplement their existing synthetic molecular sieve product lines. With the producers of synthetic zeolites thinking in pounds and not in tons, further development of natural zeolite deposits stagnated for over a decade.

Jan 1, 1974