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By M. Cala

Underground coal gasification is technology which enables energy to be extracted from coal beds where mining by means of classical methods is either impossible or uneconomical. The process of coal gasification itself is a complex phenomenon which includes chemical and physical processes: thermal, hydrological and mechanical. Additionally, the analysis of underground coal gasification is difficult to carry out for environment reasons, this being due to the local characteristics of the areas where it is carried out. This paper deals with interaction of geo-reactor with surrounding rock mass, it omits the chemical processes inside geo-reactor itself. Due to the complexity of the processes proceeding and during underground coal gasification coupled with minimal practical experience in using this technology, it is difficult to estimate its influence on the surrounding rock mass. Within this scope, the use of numerical programs can be useful. This paper presents a trial of modeling the processes accompanying underground coal gasification. The processes proceeding and during the underground coal gasification are characterized, and the significant, specific phenomena are discussed, with respect to the influence on the surrounding rock mass. For the chosen processes, examples of numerical calculations are presented. These enabled conclusions to be drawn and also provided directions for the modeling of the underground coal gasification processes.

Aug 1, 2013

By Harald Ulrik Sverdrup, Anna Hulda Olafsdottir

The long-term supply of nickel to society was assessed with theWORLD7 model for the global nickel cycle, using new estimates of nickel reserves and resources, indicating that the best estimate of the ultimately recoverable resources for nickel is in the range of 650–720 million ton. This is significantly larger than earlier estimates. The extractable amounts were stratified by extraction cost and ore grade in the model, making them extractable only after price increases and cost reductions. The model simulated extraction, supply, ore grades, and market prices. The assessment predicts future scarcity and supply problems after 2100 for nickel. The model reconstructs observed extraction, supply and market prices for the period 1850–2020, and is used to simulate development for the period 2020–2200. The quality of nickel ore has decreased significantly from 1850 to 2020 and will continue to do so in the future according to the simulated predictions from the WORLD7 model. For nickel, extraction rates are suggested to reach their maximum value in 2050, and that most primary nickel resources will have been exhausted by 2130. After 2100, the supply per capita for nickel will decline towards exhaustion if business-as-usual is continuing. This will be manifested as reduced supply and increased prices. The peak year can be delayed by a maximum of 100 years if recycling rates are improved significantly and long before scarcity is visible.

Jan 26, 2021

The principle activities of the Explosives Research Laboratory from July 1, 1961 to June 30, 1962, are described briefly in part 1. Part 2 gives short abstracts of publications that appeared during fiscal year 1962; in general, the research reported in these publications antedates the report period. Part 3 gives the results of an investigation which, although too limited to warrant separate publication, merits presentation in some detail because of current interest in ammonium nitrate-fuel oil compositions.

Jan 1, 1964

The principle activities of the Explosives Research Laboratory from July 1, 1961 to June 30, 1962, are described briefly in part 1. Part 2 gives short abstracts of publications that appeared during fiscal year 1962; in general, the research reported in these publications antedates the report period. Part 3 gives the results of an investigation which, although too limited to warrant separate publication, merits presentation in some detail because of current interest in ammonium nitrate-fuel oil compositions.

Jan 1, 1964

By Mingfei He, Jianhua Chen, Yingchao Liu, Yuqiong Li

Pyrite is one of the most common sulfide minerals on earth, which is usually grown with chalcopyrite and other sulfide minerals. In flotation practice, pyrite from different mines or different sections in a same mine may have different flotation behaviors. This is because the pyrite crystal contains lattice defect, including ionic vacancy and lattice impurity. The present work investigates the effects of three typical 3d transition metal (Co, Ni, and Fe) on the adsorption of CH3OCS2 −, OH−, and CN− on pyrite surface by density functional theory (DFT) calculations. Calculated results show that Co impurity reduces the adsorption energies of CH3OCS2 − and CN− on the surface of pyrite, while Ni and Cu impurities significantly increase the adsorption energies of CH3OCS2 − and CN− on the surface of pyrite. Co impurity has small influence on the adsorption of OH−, but Ni and Cu impurities significantly increase the adsorption energies. Calculations on Mulliken charge population of Co2+, Ni2+, and Cu2+ indicate that the Mulliken charges of Co2+, Ni2+, and Cu2+ after OH− adsorption are more than those after CN− adsorption. This suggests that the ionic property of the M-OH- coordination bond is greater than that of M-CN- coordination bond, while covalent bonding of M-CN- coordination bond is greater than that of M-OH- coordination bond. The adsorption results are discussed based on coordination field theory (CFT).

Oct 6, 2020

By Shuji Owada, Keisuke Yasukawa

Electrostatic and/or high tension separation has been used for the separation of rare metal bearing minerals, foods, industrial wastes and so on. Since the separation is achieved by the difference mainly in surface conductivity of particles, the efficiency in humid circumstances is very low, and then, the applicability is considerably limited. We applied the following two-stage pretreatment technique to the separation process, which involves (1) adjustment of surface wettability by adsorbing surfactant on the particle surface and (2) control of the surface conductivity by spraying with electrolyte aqueous solution. The addition of this pretreatment technique has been found to have a great advantage over conventional methods. Separation efficiency is achieved even in humid circumstances and selectivity can also be obtained between insulator minerals. The selectivity is very similar to that of flotation in wet process. This separation technique will be applied not only to mineral processing but the processing of industrial waste such as electric and electronic waste materials.

Jan 1, 1995

By W. H. Ode

An investigation of standard methods for determining ash in low-rank* coals showed that generally 60 to 95 percent of the total sulfur in the coal is retained in the ash as SO3. This large sulfur retention causes a positive error in the determined mount of ash of as much as 6 percentage points for the coals examined, although it usually is 2 to 3 percentage points for lignites and about 1 for subbituminous coals. Unless the sulfur content is low or unless a correction is made for the SO3 retained, the fixed carbon and oxygen have an equivalent negative error when determined by difference; also other inaccurate analytical values occur when the data are calculated on an ash- free bas is. No simple modification of the ashing procedure was found that would reduce the sulfur retention to a point where its effect on the ash determination would not be significant, Therefore, for accurate analytical work on law-rank coals, the SO3 should be deducted from the determined ash to obtain a "corrected" ash value.

Jan 1, 1962

By R. G. Gürtunca, J. A. Breslin

This paper briefly describes the progress in mine safety in the United States, with emphasis on recent events that have followed since the explosion at the Sago Mine in January 2006. Legislation following the mine accidents last year and areas of work carried out by the National Institute for Occupational Safety and Health (NIOSH) related to the accidents are discussed. American coal production in 2006 was 1,150 million short tons. Most of this coal is consumed domestically, with annual exports of coal about 50 million tons. One third of annual production is produced at surface mines and the rest from underground. This coal is produced by about 82,000 miners working at 1,400 coal mines. Major improvements in coal mine safety have been made in the US since the Federal Mine Safety and Health Act of 1977. The fatal injury rate in underground coal mines between 1977 and 2004 was reduced by 47.8% to 0.036. The annual number of fatalities dropped from 112 to 14 during that period. Likewise, the non-fatal days-lost injury rate was reduced by 42.6% from 10.87 to 6.24. The improvements in mine safety during this period can be seen in the graph of underground coal mine explosion fatalities and injuries from 1980 to present, which is shown in Figure 1. Between 1984 and 1993 (9 year period) there were 5 explosions and one major mine fire, for a total of 55 fatalities. Over the seven year period from 1993 to 1999 there were no fatalities from coal mine fires and explosions. However, in the six years since 2000 there have been 5 explosions and one fire, which have caused 37 fatalities. [ ]

By Thirumalai, K.

Although the term "spalling" has long been known, Norton l first referred to its usage for the fracture or disintegration of materials subjected to rapid temperature changes. Spalling of ceramic materials at high temperatures has received attention in the past. Removal of the char formed during ablation in re-entry of space vehicles has been referred to as mechanical spalling. The first experiments to evaluate the process of rock fragmentation by thermal spalling were conducted by Stoces using a series of gasoline burners on the quartz veins of the Zinnwald deep mines in Germany. After the development of rocket-jet burners, the principles of 'thermal spalling combined with high fluid momentum found wide practical application in rocks. The well-known jet piercing process for drilling blastholes in taconite and for jet channeling in the quarrying of granite are among the more notable of these application^.

Jan 1, 1970

By George E. Summers

A salt dome appears to provide the basic medium requirements for the excavation of the 315 foot diameter, unsupported spherical cavity at a depth of 2700 feet required by the AEC in a proposed "decoupling" experiment. Tatum Salt Dome was a natural choice for a site because more geological and hydrological information has been accumulated on Tatum than any other salt dome on the Gulf Coast. The Tatum Dome is a mile in diameter, roughly flat topped, nearly cylindrical in shape and has some overhang at the top. The salt stock has nearly vertical layering of alternating bands of salt and anhydrite. In the vicinity of the dome, adequate fresh water for solution mining is available in surface streams and in subsurface aquifers. A saline aquifer is available for brine disposal. A tentative cavity location was selected near the center of the dome which meets the design criteria established by the AEC.

Jan 1, 1968

By Gilmar Zacca Batista

The present work is a part of a comprehensive program that aims to evaluate the girth welding procedures for heavy wall API 5L X65 pipes produced for sour service applications. This article describes the results of toughness, strength and sour resistance of girth welds produced with different welding consumables. The methodology applied included girth welds production with GTAW process for root pass using ER70S-6 consumable and FCAW process for filling passes using E71T- 1CJ and E91T1-GM-H4 consumables. Mechanical tests of Charpy, CTOD, tensile, hardness and stress corrosion cracking were also performed. The E71T-1CJ resulted in a girth weld with tensile and yield strength around 7% lower than the pipe. However, according to the papers analyzed at this study, a value up to 10% of undermatching could be acceptable. The CTOD and Charpy tests showed good toughness and weld metal embrittlement was not observed. The hardness and the stress corrosion cracking tests demonstrated that the consumable ER70S-6 is suitable for sour service. All properties evaluated met the requirements specified by the onshore pipeline standards, showing that the consumables ER70S-6, E71T-1CJ and E91T1-GM-H4 are suitable for the welding of heavy wall X65 pipe with sour service and toughness requirements. If an overmatching is required, the E91T1-GMH4 shall be used to assure a strength overmatching and prevent plastic strain concentration at the weld metal. The results provided by this paper can be used for consumable selection and for welding procedure qualification of pipelines construction when heavy wall API 5L X65 are used for sour gas transportation.

Aug 16, 2017

By Xianyang Qiu, Xiuzhi Shi, Chen Xie, Xiaofeng Huo, Yanhai Wang

In upwards medium-deep hole cut blasting, many confinement effects exist due to the small number of free surfaces, which is mainly provided by an empty hole. If the cut blasting effect cannot meet expectations, then subsequent blasting construction will be seriously affected, and large security risks to operators in the stope can be induced. The number of free surfaces is directly related to the layout of the cutting borehole. Therefore, it is necessary to optimize the layout of the first round of cutting boreholes. Theoretical analysis, numerical simulations, and field tests were used to study the formation process of cut blasting and optimize the layout of the first round of cutting boreholes. Based on the blasting parameters in the field, LSDYNA software was used to establish cut blasting models with four kinds of borehole layouts in the first round. The RHT constitutive model was used to simulate the rock-breaking effect. The numerical results show that the cut blasting effect is optimal when Nos. 3, 5, 7, and 9 are charge holes and Nos. 1, 2, 4, 6, and 8 are empty holes. In addition, the greater the number of empty holes, the larger the release space and the better the cut blasting effect. The uniformity of the empty hole distribution, namely, the uniformity of the release space, also affects the cut blasting effect. The field results indicate that a good cut blasting effect can be achieved by optimizing the borehole layout.

Sep 7, 2023

By J. H. Field

Synthesis of hydrocarbons by the Fischer-Tropsch reaction in a hot-gas- recycle system was demonstrated to be technically feasible. This project was undertaken, by the Bureau of Mines, to determine if the system was operable and to ascertain the optimum conditions for the production of gasoline. Carbon steel turnings packed with a void volume from 88 to 90 pct. were satisfactory catalysts, but steel catalysts with greater void volume, either turnings or steel wool, were not as active. Good temperature control with a pressure drop of less than 0.5 pounds per square inch (p.s,i,) per foot of catalyst bed of turnings was obtained by operating with a recycle to fresh feed ratio of 20 and by splitting the total gas flaw and injecting portions into the reactor at different entry ports.

Jan 1, 1961

By Mike Muchard

Augered cast-in-place piles are one of the most cost effective deep foundation options available to designers but have been largely underutilized due to skepticism associated with quality assurance and hence capacity. When installed correctly, unit friction values can rival any other competing foundation system. To this end, many means have been implemented to increase confidence in the competence of the foundation. One such method is load testing via the Statnamic test method. This paper presents an overview of the Statnamic test method, advantages and disadvantages of its use, and several case studies where Statnamic testing of augered cast-in-place piles confirmed quality construction, brought about design changes, or proof tested problematic installations.

Jan 1, 2000

By Rafael Malagutti Leandro

O objetivo deste trabalho é avaliar a influência do tempo e temperatura de tratamento térmico de solubilização no tamanho de grão e na fração de ferrita de um aço inoxidável dúplex UNS S31803 (SAF 2205). A chapa do aço em estudo foi laminada com 22% de redução de espessura antes de ser solubilizada a 1.000°C, 1.100°C e 1.200°C, por tempos de até 96 h. A fração de ferrita das amostras foi obtida por medidas magnéticas em ferritoscópio e por estereologia quantitativa. Já o tamanho de grão foi determinado por estereologia quantitativa de imagens obtidas por microscopia óptica. Observou-se o aumento da fração de ferrita em função da temperatura de tratamento, como esperado, e foi realizado comparativo entre as duas técnicas de determinação da fração de ferrita com simulações de equilíbrio em Thermo-Calc®. O intercepto médio das amostras solubilizadas a 1.000°C manteve-se praticamente constante em todos os tempos de solubilização estudados, em aproximadamente 9 micrômetros; após 5h de solubilização a 1.100°C, e após 30 min a 1.200°C, contudo, observou-se significativo crescimento de grão nas amostras.

Aug 7, 2018

By Nayara Maron Costa Takahashi

Com o crescente aumento nos preços dos produtos derivados de petróleo no Brasil, o gerenciamento de combustível se torna cada vez mais relevante na tentativa de redução de custos operacionais da planta. Este aspecto envolve, além do controle do combustível movimentado, a detecção de desvios associados a perdas e furto, bem como análises de consumo e desempenho dos veículos e equipamentos abastecidos, e análises de eficiência dos próprios postos de combustível. Neste contexto, um Sistema de Gerenciamento de Combustível contempla a instrumentação necessária para a medição dos volumes transferidos e armazenados nos postos; o sistema de automação utilizado para o processamento, monitoramento e envio dos sinais; e o sistema de gestão de combustíveis. Este trabalho abrange a instrumentação aplicável aos processos de Recebimento, Armazenamento e Abastecimento nos postos de combustível, os tipos de sistemas de controle utilizados neste mercado e as funcionalidades de um sistema de gestão, apresentando uma solução em arquitetura WEB para este sistema

Aug 16, 2017

By V. Angelatou

In the present study, the possibilities of use of natural zeolitic tuffs from the Skaloma area, Rhodope prefecture, Greece, for the removal of Pb and Zn ions from aqueous solutions has been studied. The equilibrium data were examined for different grain sizes, pH?s and initial concentrations. An apparent kinetic study was also carried out for different time intervals at constant temperature and pulp density. For the chemical equilibrium study the Freundlich isotherm was used. The experimental results verified the favored behavior of zeolite on lead ions and the quick kinetic of the process whilst the efficiency of the ion exchange on zinc is rather limited. The grain size of the material did not greatly affect the performance of the process. The removal of metal ions worked better at lower pH. The Freundlich isotherms are in good agreement with the experimental data.

Jan 1, 2006

By A. A. Hejja

The effect of composition on electrical conductivity, viscosity and liquidus temperature of the slags was investigated in the temperature range of 1300" to 1450°C. The synthetic slags containing CaO, MgO, SiO,, A1,0, and FeO were similar to those employed in the electric furnace smelting of sulphide Cu-Ni concentrates containing PGM (Platinum Group Metals) from the Merensky Reef of South Africa. FeO and SiO, were found to affect the viscosity and conductivity the most while liquidus temperature depended on MgO content in addition to these. The activation energy for electrical conduction was found to vary from 67 to 159 kJ/mol and that for viscosity from 125 to 209 kJ/mol. Optimization of the slag composition was attempted on the basis of opposite trend of the viscosity-electrical conductivity relationship with slag composition.

Jan 1, 1994

By R. E. Gertsch

Mechanical mining holds great promise for the mining industry. Realizing this promise depends on giving mine operators the capability to evaluate the higher production, the lower costs, and safety enhancement that comes with mechanical mining. The opportunities for low cost and high production must outset the high capital costs associated with mechanical excavation. Giving the mining industry the tools to effectively evaluate and successfully implement mechanical methods defines the challenges and directions of the mechanical mining industry.

Jan 1, 1994

By Tom Treleaven, Andrew Williams

The town of Greenwich, CT, an exclusive suburb of New York City awarded several contracts for the installation of sanitary sewer in the North Mianus section of town. The Valley Road section was the most challenging from a rock excavation standpoint. The cut was up to 14 ft (4.25m), with adjacent utilities [20 in. (500mm) water, 6 in. (150mm) water and 8 in. (200mm) gas] located to within 5 ft. (1.5m) of the proposed sewer trench. Rock types varied but were ultra metamorphic in nature, ranging from quartzites, granite gneiss and various types of migmatities.

Jan 1, 2004