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By George C. Branner

This circular is concerned with eight nonferrous scrap metals as they generated, collected, prepared, and consumed in California. Brief reference also is included with respect to Nevada and Hawaii. Four of these scrap metals - copper, lead, aluminum, and zinc - are of major importance and make up about 95 percent of the total value, whereas the remaining four - antimony, magnesium, nickel, and tin - make up the remaining 5 percent. For convenience, the subject matter is divided into three parts, (1) Data with respect to the collection, preparation, and marketing practices that are common activities to all the nonferrous scrap metals; (2) separate discussions and statistical data with respect to each of the eight nonferrous scrap metals in California; and (3) data with respect to Nevada and Hawaii.

Jan 1, 1962

By Nickolas J. Themelis

Nearly thirty two million tons of municipal solid wastes (MSW) are combusted annually in over one hundred U.S. Waste-to-Energy (WTE) power plants, thus reducing the use of fuel oil by about 1.6 billion gallons of fuel oil One of the advanced WTE processes is the 0.9-million ton/y SEMASS facility at Rochester, Mass. Most of the combustion in the three giant combustion chambers occurs while the injected shredded wastes are in suspension, i.e., in flash combustion mode. The velocity, temperature, and concentration profiles in the SEMASS combustion chamber were simulated by representing the combustible fraction of MSW by the simplified formula C6HIO04 and using the CFD program Fluent to solve the turbulent energy and mass transport equations. After validation against plant data, this model will be used to examine options for increasing the productivity of WTE combustion chambers, such as optimum distribution of primary and secondary air and oxygen enrichment.

Jan 1, 2003

By Nickolas J. Themelis

Nearly thirty two million tons of municipal solid wastes (MSW) are combusted annually in over one hundred U.S. Waste-to-Energy (WTE) power plants, thus reducing the use of fuel oil by about 1.6 billion gallons of fuel oil. One of the advanced WTE processes is the 0.9-million ton/y SEMASS facility at Rochester. Mass. Most of the combustion in the three giant combustion chambers occurs while the injected shredded wastes are in suspension, i.e .? in flash combustion mode. The velocity. temperature, and concentration profiles in the SEMASS combustion chamber were simulated by representing the combustible fraction of MSW by the simplified formula C6HIO04 and using the CFD program Fluent to solve the turbulent energy and mass transport equations. After validation against plant data. this model will be used to examine options for increasing the productivity of WTE combustion chambers, such as optimum distribution of primary and secondary air and oxygen enrichment.

Jan 1, 2003

By L. Munsamy, B. J. Madden

OpenRisk, an open cast risk rating system, takes into account relative differences in the importance of hazards, as experienced on each mine as a result of different combinations of geotechnical factors and mining conditions. The system is based on critical geotechnical and operational parameters that have been identified by mining personnel and rock engineers. The primary advantage of this risk rating system is that all the strip mines would use an identical system, which enables the user to compare their risk to the risk at neighbouring mines and/or other open cast mines. The system can be adjusted to meet local, mine specific requirements. This system has been made practical and easy to use. Therefore, this tool can be used by personnel from other disciplines not directly related to rock engineering. OpenRisk system has been in operation at nine Anglo Coal and other open cast mines. It adequately detects areas of high risk and generates adequate remedial solutions to reduce the risks. Awareness of the personnel has been higher at the sites that use OpenRisk. The proactive approach of OpenRisk ensures that all personnel are aware of risks in the pits and how to deal with potential risky areas.

Jan 1, 2006

By Deborah McCombe

-Canadian Regulators -Qualified Person -Professional Association -Resources & Reserves -Foreign Codes -Disclosure of Historical Resources -Issues in Application of Resources & Reserves -Industry Best Practices developed by CIM -Technical Report and Reserves and Resources -Summary

Jan 1, 2003

By Paul C. Schmall, Kevin Clarke, Paul J. Lewis, John M. Stanbury

"The $200M rehabilitation of the more than 100-year-old Gowanus Flushing Tunnel and pumping station located on the Gowanus Canal in Brooklyn, NY required deep excavations in an extremely congested urban environment. The environment posed significant challenges, including: support of excavation for protection of existing structures, excavation through man-made fill while eliminating groundwater inflow due to potentially contaminated groundwater chemistry; discharge and disposal impacts; and potential settlement of surrounding structures. This paper will present the design and construction challenges associated with the construction of a new combined sewer overflow (CSO) chamberwhich included a jet grout bottom seal, to mitigate groundwater inflow during excavation. The foundation for the finished structure also included a unique system incorporating the jet grout bottom seal elements with deep jet grout columns (piles) acting as the foundation system for the final structure. Design and construction challenges included highly variable soil conditions such as man-made fill, obstructions from previous construction, presence of an organic stratum, and conflicts with existing timber foundation piles. The jet grout bottom seal was constructed in loose sands with the deeper jet grout foundation elements extending to bear on a dense sand stratum. Challenges associated with the bottom seal included grid spacing and construction sequencing. Wet in wet sequencing was used to mitigate potential windows in the bottom seal further complicated by shadowing from existing timber foundation piles.Introduction And BackgroundModernization of the Gowanus Tunnel Pumping System required deep excavations in the extremely congested urban environment of Brooklyn, NY. The project location is shown on Fig. 1 and 2. The focus of this paper is to present the design and construction challenges associated with the support of excavation, control of groundwater, and ultimate foundation support for the combined sewer overflow (CSO) bypass chamber extension. The project site was tightly constrained by adjacent, active roadways and underground utilities, as well as residential and industrial structures. Therefore, excavation support was required to limit ground movement and maintain the integrity of the surrounding facilities. Excavation depths to as much as 16 ft below ground level, 8 ft below groundwater, required that seepage and groundwater be controlled so as to minimize pumping and disposal of groundwater and maintain the surrounding groundwater levels to avoid potential settlement of adjacent roadways, utilities, and structures. In addition, the subsurface conditions required that the proposed CSO bypass chamber extension be supported on a deep foundation to avoid differential and total settlements that may be detrimental to the existing and expanded structure. A plan view of the existing CSO bypass chamber and the proposed extension is shown on Fig. 3."

Jan 1, 2016

By Joseph A. Meyers, Michael D. Stokes

This paper will focus on the use of Deflagrating Cartridges for tunnel excavation in Midtown Manhattan at Grand Central and 42nd Street Station, where the excavation has challenges due to the proximity of existing underground infrastructure and a contract blasting restriction. Skanska and FDNY’s collaborative teamwork successfully used deflagrating cartridges and gathered vibration data to properly predict ground vibrations on nearby infrastructure. In cities like Manhattan, conventional blasting excavation methods can be constrained or restricted entirely by the risk of damage to nearby structures, utilities, and disruption to everyday life on the streets. The introduction of Deflagrating Cartridges to the project offered a promising solution to mechanical excavation being used by providing controlled, precise, and deflagrating rock breaking capabilities that minimized disturbance to the above items. This technology minimizes the risk of vibration damage to preexisting infrastructure due to its reduced velocity of deflagration, making it useful for the location of our project. The team's approach involved numerous test shots to help determine the appropriate loading and timing sequence, as well as to collect data to properly be able to predict vibration on the adjacent structures. The successful application of deflagrating cartridges in the Grand Central area demonstrates their usefulness in logistically challenging underground excavation projects in urban cities. Through careful coordination and innovative use of this technology, the team was able to navigate the complexities of working near existing infrastructure while maintaining high levels of safety and productivity. Overall, our paper will speak to the importance of new technologies like deflagrating cartridges for usage in urban environments while minimizing disruption to the world above and below, the technology of these products, and the outcomes of our vibration data collection. By embracing these advancements, construction teams, owners, and other agencies can effectively address the unique challenges posed by projects in densely populated areas, while maintaining safety and productivity.

Jan 21, 2025

By Jogeshwar P. Singh, Mohamed Ashour

The Soil-Foundation-Structure-Interaction (SFSI) problem involves Kinematic Soil- Foundation Interaction occurring during large (cyclic and permanent) ground deformations as well as Inertial Foundation-Structure Interaction occurring during shaking all of which take place while the soil and possibly structural properties degrade with time. The design of the deep foundations for liquefaction induced lateral spread loads include estimation of passive pressure applied by the liquefied material as well as the amount of anticipated displacement. Coupled analyses for SFSI problems that account for liquefaction induced lateral spread and their interaction with the deep foundation system can be performed using sophisticated numerical modeling techniques based on finite element and/or finite difference methods using computer programs such as FLAC or OPENSEES. Such complete SFSI analyses are very tedious and expensive and not feasible for most projects. In 2011, California Department of Transportation (Caltrans) released guidelines for foundation loading and deformation due to liquefaction induced lateral spreading. This simpler prescriptive approach combines empirical and analytical methods through decoupled analyses using computer programs such as LPILE and SLOPE-W together with liquefaction induced lateral spread estimates based on published empirical equations. Pile group effects and pile caps are accounted for using a concept of super-pile. In this paper, we discuss the solution of the same lateral spreading related SFSI problem using computer program CGI-DFSAP (CGI-Deep Foundation System Analysis Program) based on the strain wedge theory that can account for liquefaction, lateral spreading, pile groups, pile caps and nonlinear behavior of piles in a more coupled manner to analyze the foundation system under the lateral spread loadings. CGI-DFSAP can be used to analyze piles in sloping ground conditions as well as piles beneath the abutments near a free-face slope. We have included Strain Wedge Model (SWM) solutions using CGI-DFSAP of several field and laboratory case studies of lateral spreading related to pile foundations. Finally, we have also included the SWM solution of one of the Caltrans (2011) example problems.

Jan 1, 2015

By Nigel Marx

In order to understand (and ultimately to predict) the friction reduction resulting from the use of polymer solutions, the rheological properties of model polymer solutions have been measured over a wide range of shear rates. Both temporary and permanent shear thinning have been observed. By using base fluids of different viscosities it has been shown that permanent shear thinning depends more closely on the shear stress experienced by the fluid than on the strain rate. Hydrodynamic measurements have been made on the polymer solutions using a compliant ball on flat lubricated contact that operates in isoviscous-elastic conditions. The measured friction values can only be predicted with reasonable accuracy if the measured shear thinning properties of the lubricant are taken into account in the hydrodynamic model.

Jul 31, 2018

By Dmitri Nassyrov, In-ho Jung

"All relevant thermodynamic and phase diagram data in the CaO-Fe10-CaF2 system were critically reviewed. One set of model parameters describing the Gibbs energy of all phases has been obtained as a result of critical evaluation of the available data and optimization of the model parameters. The Modified Quasichemical Model was used to describe the interactions in the liquid phase. All calculations were performed using the FactSage thermochemical software.IntroductionSlags contaimng CaF2 are of significant interest to the steelmaking community. Notable examples of slags containing significant amounts of CaF2 include Electro-slag Remelting (ESR) slags [1] and mould flux for continuous casting [2]. The role of these slags is, among other things, to refine steel by absorbing inclusions and dissolved impurities. During slag-steel interaction, some iron from the steel will inevitably get oxidized and form iron oxides which will dissolve into the slag. With this in mind, it is important to understand the interaction between CaF2 and Fe,0 for accurate prediction of slag composition and process optimization. A thermodynamic optimization of the CaO-FetO-CaF2 was thus undertaken."

Jan 1, 2013

By Xiang Sun

Microwave heating has been used in numerous industrial processes due to its great advantages when compared with conventional heating methods. However, microwave heated products can be affected by non-uniform temperature distribution resulting from the mechanisms of microwave heating. To overcome this problem, a critical step is to have a temperature-time profile. In order to characterize and evaluate microwave heating effects, an accurate temperature measurement is needed. This paper discusses the possibility of applying several temperature measurement techniques in microwave processing. Both contact and non-contact methods are introduced and compared.

Jan 1, 2006

By F. Leclerc, V. Rebeyrolle, M. Revil-Baudard, A. Jardy, M. Založnik, H. Combeau

"Since the quality of Vacuum Arc Remelted ingots is linked to their chemical homogeneity and metallurgical structure, a modeling study of the solidification during VAR has been undertaken. It is based on the solution of the coupled transient heat, momentum and solute transport equations during the remelting of a cylindrical ingot. Solidification mechanisms implemented in the model include a full coupling between energy and solute transport in the mushy zone, and accounting for nucleation and finite diffusion of solutes at the microscopic scale, in both solid and liquid phases. This modeling can be applied to actual multi-component alloys. In this paper, the macrosegregation in Zircaloy 4 ingots is investigated. To validate the model, one single melt of a homogeneous electrode has been specifically performed. The comparison between the predicted macrosegregation and the experimental results shows the importance of accounting for solutal convection to forecast properly the macrosegregation in remelted ingots.IntroductionVacuum Arc Remelting of zirconium alloy ingots is a key step in the manufacturing process of fuel assembly components in nuclear reactors. The control of the chemical homogeneity is indeed fundamental to ensure the quality and the in-reactor performance of the final products. Despite the use of electromagnetic stirring to homogenize the liquid melt composition, chemical heterogeneities develop in the mushy zone during the solidification stage. One of the main challenges for zirconium producers, as well as titanium producers, is to master the VAR process in order to control the macrosegregation in remelted ingots. Macrosegregation results from the association of microsegregation and transport phenomena. The latter are primarily due to the flow in the liquid and mushy parts. It is now well established [1-4] that the hydrodynamics of the melt pool in a VAR ingot depends on the combined action of the followings: thermal and solutal buoyancy, self-induced electromagnetic force and the periodic centrifugal force caused by the angular movement generated by the stirring. However, for zirconium alloy ingots, the effects of thermal and solutal buoyancy forces on macrosegregation through their influence on the flow in the mushy zone have not been clearly identified."

Jan 1, 2012

By L. Burris, C. H. Stockman, I. G. Dillion

Zone melting is a purification process in which separation of impurities is effected by slowly moving a narrow melted zone through a bar of solid material. Equations are presented which 1—predict the concentration profiles after successive passes of the zone and 2—give the limiting distribution of solute along the bar after an infinite number of passes of the molten zone. These equations take into account the effect of normal freezing in the last zone length. These equations were solved numerically using an electronic computer, and the concentration profiles are presented as a function of the solute distribution coefficient and the ratio of molten zone to total bar length. ZONE MELTING is a purification process in which separation of impurities is effected by slowly moving a narrow melted zone through a bar of solid material. Separation occurs if the solid freezing from a solution at any moment has a composition different from that of the liquid from which it is freezing. Solutes which lower the freezing point will tend to remain in solution and will be moved in the direction of zone travel. Solutes which raise the freezing point will preferentially freeze out, and they will be moved in a direction opposite to that of zone travel. After repeated unidirectional passage of a molten zone through a bar of material, impurities will be concentrated in the ends of the bar. A limiting concentration gradient will be reached in the bar after a large number of passes of the molten zone. Both the magnitude of this limiting concentration gradient and the rate of movement of solute in any pass depend on the zone length and on the equilibrium concentrations of solute in the liquid and solid phases. The basic theory of zone melting was thoroughly covered by Pfann.1 The purpose of this paper is to extend the theory of zone melting by presenting 1—equations which relate the concentration profiles in successive passes of the zone and 2—equations which give the limiting distribution of solute along the bar after an infinite number of passes of the molten zone. These equations take into account the effect of normal freezing* in the last zone length concentration of a given solute in the solid to the concentration of the same solute in the liquid. Analytical methods for determining the concentration profiles after any pass have been developed by Lord2 and Reiss. The method developed by Lord does not take into account normal freezing in the last zone and also becomes very complicated when the number of passes becomes large. The method developed by Reiss enables the direct calculation of the complete concentration profiles (including that in the last zone) after any pass for values of k close to unity (0.9 < k < 1.1). Both methods are useful and provide valuable insight into the zone melting process. The equations given in this article are based on the same assumptions used by Pfann. These are: 1—uniform composition in the liquid, 2—negligible diffusion in the solid, 3—constant distribution coefficient, 4—constant length of the liquid zone (except at the ends), and 5—solubility of the solute in the melt is not exceeded at any point. Equations for Concentrations in Successive Passes For a melted zone of length 1 at the left-hand end of a bar of uniform unit cross-section, the amount of solute in the liquid is J0Cn-1(x) dx [1] where the subscript is the number of the pass. Cn-1(x) represents the concentration (expressed as weight per unit volume) obtained in the previous

Jan 1, 1956

Antimony ore samples (mean assay 18&#183;7 per cent antimony) from Endeavour Inlet, Marlborough Sounds New Zealand, were tested for upgrading by flotation to a saleable product (60 per cent antimony).The effects of activating agents, collectors, frothers, pH, conditioning time, and particle size on the recovery and grade of a stibnite flotation concentrate were determined using HaIlimond tube and laboratory flotationcell test apparatus. Optimum flotation conditions for the ore were thereby established. A stibnite concentrate grading 63 per cent antimony and an overall recovery of 90 per cent is obtainable in a two-stage process.

Jan 1, 1977

By Chase Palmer

INTRODUCTION. WHILE the reducing action of organic matter, of ferrous sulphate, and of hydrogen sulphide has frequently been invoked to account for the deposition of native gold and silver from ore-forming solutions, the high efficiency in this respect of certain of the metallic minerals which form the ore itself has not been sufficiently recognized. If a little finely powdered chalcocite is placed. in a test-tube and 2 or 3 cc. of a dilute solution of gold chloride are poured over it, two or three shakes of the tube suffice to remove all the gold from the solution. The color of the solution changes from yellow to pale green, showing that copper is dissolved simultaneously with the precipitation of metallic gold. If a piece of chalcocite is hung in a dilute aqueous solution of silver sulphate (1 normal), a coating of silver begins immediately to form on the mineral, and within a few moments a beautiful silver tree has developed, similar to that formed when metallic zinc is immersed in a similar solution.

Jan 5, 1913

By Anand Raman, Steve Dixon

"Industry practice for defining acid consumption is based on column tests. Freeport-McMoRan (FCX) has adopted a practice of leach operation using a defined pH or gpl acid in the raffinate based on the column test program. The acid consumption can be easily calculated using the leach operating parameters of SX-EW efficiency, lift height, bulk density, irrigation rate, primary leach cycle time, acid cure dose and acid concentration in the raffinate. The column leach test results and a column to heap efficiency factor are used to define the copper extraction. The maximum acid consumption will occur when zero acid is contained in the raffinate. The term Net Extracted Value (NEV) is to define the maximum extracted value relative to acid consumed.This paper presents the operating logic and method used to calculate acid consumption based on column tests and operating parameters.INTRODUCTIONIndustry practice for defining acid consumption is based on column tests. This may result in lower economic value if the tests are not designed to account for operating variables. A test program is described to assist in defining lift height and the influence of gangue on solution chemistry. A simple spreadsheet is presented that will use the leach operating parameters of SXEW efficiency, lift height, bulk density, irrigation rate, primary leach cycle time, acid cure dose and acid concentration in the raffinate to calculate the acid consumption for a proposed operation.A review of current leach operations solution chemistry will help to define acid consumption. This is recommended for all current leach operations.DISCUSSIONThe current practice at Freeport-McMoRan (FCX) is the use of column test results to define operating parameters. The monitoring of operational solution chemistry and copper production addresses any changes needed in operational parameters. This practice maximizes the value extracted from each tonne of ore leached."

Jan 1, 2008

By Nasri Munfah, Raymond E. Sandiford

"Superstorm Sandy (Sandy) created a storm surge that inundating many of the tunnels that pass beneath the Hudson and East Rivers. The tunnels are vital infrastructure links for the economy of New York City and the northeast region. The sea water, which contains highly reactive salts, caused significant damage to electrical and mechanical systems. In addition, the salt water inundation left corrosive precipitants on the tunnel linings and on and within electrical duck banks. After the salt water was evacuated from the tunnels, condition assessments were performed using a state of the art approach involving high resolution laser scanning, digital imaging, and thermal imaging. These scans were performed prior to hands on inspections. The damage assessment concluded that, although the tunnel structural linings were not damaged, the interior elements of the tunnels needed major rehabilitation to arrest the continual deterioration of the structures. This paper details the state of the art approach used for these tunnel inspections. INTRODUCTION On October 29, 2012 Super Storm Sandy flooded a large number of both transit and vehicular tunnels in the New York Metropolitan area. The region’s transportation network was severely disrupted. The storm damage is estimated to have been in excess of $30 billion, and with the tunnels out of service, the local economy was losing hundreds of millions in economic activity. Restoration of these tunnels was a very high priority and the resulting expedited restoration process did not always provide adequate time for comprehensive condition surveys. This resulted in many of these surveys being conducted after service restoration. Inspecting highly trafficked transit tunnels is challenging and the logistics of working in short night outages led to a rethinking of the conventional inspection approach. Traditionally, visual and tactile methods are first used to inspect tunnels and then quite often followed by LiDAR (Light Detection and Ranging) scanning and perhaps infra-red scanning. For multi-mile tunnels, the time required to visually map tunnel features can be quite extensive. By performing the scanning first and then performing the visual and tactile inspections, one is able to use the scan data to identify the specific areas that need detailed inspections. This approach was used quite successfully for a number of the NYC tunnels."

Jan 1, 2016

By Martha McJunkin, Lawrence Pietrzak

This paper describes and demonstrates the application of systems analysis and mathematical modeling techniques in the planning of actual tunnel projects and research and development to improve tunneling techniques. A recently completed tunnel project located in Utah is used as an example. Although cost estimating computer programs are used in tunnel project planning, the introduction of performance modeling, simulating the time to excavate, has added advantages that are explored here. The performance/cost tunneling model (TM) described herein mathematically simulates on a high-speed digital computer the important activities of a number of tunneling techniques accounting for activity interactions, variable external environments, mechanical failure, and other uncertainties. A cost accounting segment is included to facilitate cost-effectiveness comparisons. It is shown that, when combined with informed judgment and appreciation of limitations, the TM can be a useful tool that may help improve tunneling operations and cost estimation, for example, by achieving more balanced system designs or bounding the performance/cost implications of geologic and other uncertainties. Ultimately, this might lead to more competitive bids and greater profits. The need for systems analysis and modeling in tunneling research and development (R&D) is well recognized and documented.(1-5) In R&D one must seek broadly useful solutions to the basic problems of face fragmentation, materials handling, ground support, and environmental control. These solutions must take account of the interdependence of these elements and, for a variety of ground conditions, the limitations or constraints that any innovation in one element may impose on total system performance and cost. In this regard the structure and logic of the TM has been kept as simple and modular as possible so

Jan 1, 1974

By C. G., Fink

The dissolution of gold by cyanide solutions was studied by determining the time required for the solvents to dissolve gold leaf. Minute traces, even 0.5 ppm, of sulphide ion retard the dissolution of gold, and this behavior cannot be accounted for by the presently accepted hypotheses involving oxygen-depletion or thiocyanate formation. On the other hand, traces of the salts of lead, bismuth, mercury, and thallium considerably accelerate the dissolution. The beneficial effect of lead is dependent upon the pH and cyanide ion concentration of the solution.

Jan 1, 1950

By C. G. Fink, G. L. Putnam

The dissolution of gold by cyanide solutions was studied by determining the time required for the solvents to dissolve gold leaf. Minute traces, even 0.5 ppm, of sulphide ion retard the dissolution of gold, and this behavior cannot be accounted for by the presently accepted hypotheses involving oxygen-depletion or thiocyanate formation. On the other hand, traces of the salts of lead, bismuth, mercury, and thallium considerably accelerate the dissolution. The beneficial effect of lead is dependent upon the pH and cyanide ion concentration of the solution.

Jan 9, 1950