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By L. L. Oden

The Bureau of Mines has studied a number of processes to remove Cu from molten steel scrap with the objective of determining if any of the laboratory methods studied warranted in depth research investigations. Experimental approaches included oxidizing Cu from steel containing other metals that form stable mixed oxides with Cu (AI, Cr, Fe, Mn, Mo, and V), injecting the same metals as oxides to simplify the mechanism of complex oxide formation, partitioning Cu into alkali or alkaline earth silicate slags or oxide-moderated sulfides, and coremoving Cu and S by injecting active compounds of Ca and Mg. The most promising tests, producing nearly 0.3 pct Cu in the slag, used Ar injection of K20-moderated Na2S-FeS below the surface of molten steel containing about 0.6 pct Cu and protected by a CaO-SiOz slag; however, in depth research investigations currently are not felt to be warranted.

Jan 1, 1987

By T. Thuy Minh Nguyen, Sathish K. Lageshetty, Paul Bernazzani

The addition of nanoparticles to epoxy resins often results in changes in the physical properties of the material particularly when dealing with thin coatings. By characterizing the mechanism of interactions between nanoparticles and polymer chains the material could be tailored for specific applications or properties such as enhanced biodegradability. This study compared the characteristics of common DGEBA resin coated on a silicon substrate and embedded with nanoparticles of TiO2 and Fe2O3. Specifically, we investigated the rate of curing, and the thermal stability of these nanocomposites. Results show changes in the stability for compounds containing TiO2, while Fe2O3 significantly enhanced the curing rates of the nanocomposites while maintaining similar physical properties.

Mar 1, 2017

By S B. Richardson, D Mead, N T. Moxon

The use of air-decks to reduce explosive costs has become very topical in recent years. The majority of the research in this area has been arried out between the Soviet Union where reductions in explosive consumption of between 10-30% have been claimed with apparent benefits being gained in both fragmentation and movement. Work carried out by the University of Maryland using thick plexiglass blocks has supported these findings and indicated that air-decks in measetbe duration of action of the shock wave on the surrounding material by a factor of 2 to 5 (see Figure 1). Although the fracture network resulting from this mechanism is not as intense as that produced adjacent to the explosive charge it does appear to act over a larger volume of material. Although the mechanism attributed to air-decking has been studied in some detail the effect of this mechanism on the size distribution of material produced during a blast does not appear tot have attracted much attention.

Jan 1, 1991

By I. Filippova, L. Filippov

"The by-product potential of light rare-earth elements (LREE, La, Ce, Nd) and rare-metals (W, Nb, Sn) within the St Austell kaolin deposits (UK) is related to the kaolinisation process, which liberates the accessory heavy minerals of the host granite in the clay matrix and allows their separation in the waste streams. As a consequence these minerals are pre-concentrated in the micaceous residue which displays relatively high LREE content (around 170 ppm) hosted by monazite which is mainly distributed (up to 95%) in the -100 µm fraction. A combined gravity/flotation concentration flowsheet, starting with classification of the residue into 3 size fractions (+150 µm, 150-53 µm and -53µm) was developed. This study presents the results of the clay-rich -53 µm size fraction beneficiation by flotation using sodium oleate and hydroxamate as collectors.The effect of dispersant addition during de-sliming operations on flotation efficiency was also investigated. The LREE grade in the floated product obtained with sodium oleate increased from 3370 ppm to 5350 ppm and recovery from 30% to 80% with dispersant which is attributed to clay coating. Comparison of flotation performance and Falcon Ultra-Fine (UF) concentration of monazite to previous results obtained with Falcon Semi-Batch (SB) gravity concentrator on the unscreened raw residue clearly shows that flotation of the fine residue is more efficient than Falcon UF and Falcon SB. Indeed Falcon UF produced high recoveries (87-95%) but with almost no enrichment (1.3-1.4 ratios) whereas Falcon SB concentration of unscreened residue produced higher grades (up to 0.6 % LREE) but with low recoveries (17-22 %). These preliminary results show that LREE can be pre-concentrated suggesting that the micaceous residue stream (and the associated tailings dams) could be considered as a potential resource for these metals."

Jan 1, 2016

By D. Seo, P. Au, S. Yandt, N. Tsuno, A. Sato

Nickel-base single-crystal superalloys are used for gas turbine airfoil applications due to their excellent high temperature properties. A good understanding of the mechanical response of these alloys under different temperature and loading conditions is essential for modeling their behavior. In this study, the low cycle fatigue behavior of CMSX 2 oriented with the loading axis along [001] was investigated under zero-compression strain-controlled loading at 1100°C. The experiments were performed with or without a two-minute dwell (hold) in compression. The microstructure before and after testing was analyzed to understand the deformation characteristics including the effect of dwell.

Jan 1, 2010

By A. Vien

MOCCA is a Multivariable Optimal Constrained Control Algorithm developed specifically for non-square industrial control applications with practical difficulties such as interactions, time delays, constraints, modelling development, etc. MOCCA consists of an off-line simulation/translation module, for tuning the control parameters, and an on-line module that implements the designed control law. This paper describes an evaluation of MOCCA on the Hemlo grinding circuit which comprises one open circuit ball mill and two closed circuit ball mills in series. In this case a 4x4 unconstrained control problem was considered. The manipulated variables included the fresh ore feed rate and three pump box water additions. The controlled variables were the grinding circuit product particle size and three pump box levels. In this application soft constraints were implemented through control action and control error weighting. The feedforward capability of MOCCA was used to compensate for a measured water flow disturbance to one of the pump boxes. MOCCA performed very well during plant evaluations when compared to the original classical multi-loop control strategy and proved to be quite robust. Perhaps most importantly, the process engineers and plant operators have a high level of comfort both in understanding MOCCA's general operating principles, and with its demonstrated performance.

Jan 1, 1991

By Michael Clar

Total suspended solids (TSS), generally referred to simply as sediment, is one of the four major parameters of water pollution associated with surface mining activities. The other three para¬meters are iron, manganese and pH. Currently the Environmental Protection Agency (EPA) is in the process of developing and implement¬ing effluent limitations for these pollutants pursuant to section 301 of the Federal Water Pollution Control Act Amendments of 1972, 33 USC 1811.1 To date, effluent guidelines for existing point sources have been published, and guidelines for new sources are forthcoming. The effluent limits which have already been developed for TSS have been subjected to some controversy.1 Some industry spokesmen have indicated that they may be unable to meet these effluent limitation guidelines for TSS. The industry claims that in certain areas the suggested limit is unattainable since high suspended solid loads already exist in streams due to numerous and various sources of nonpoint pollution which include agriculture, silviculture and urban construction for which no TSS effluent limits have been set. An opposite viewpoint asserts that the TSS limitations are too lenient since permit data from the Regions (U.S. EPA Regions) indicates present compliance for several companies under more stringent TSS limits. The experience at the Centralia mine in Washington is one example.2

Jan 1, 1977

By F. E. Joyce

The Bureau of Mines studied copper-nickel minerals (mainly sulfides) of the Duluth Gabbro Complex in north-eastern Minnesota to determine their response to selective high-temperature sulfatization techniques. The gabbro, containing 0.44 percent copper and 0.13 percent nickel, was ground to minus 325 mesh and sulfatized in a heated, rotating, stainless steel bench-scale retort. Tests demonstrated that over 95 percent of the copper and 80 percent of the nickel can be converted to water-soluble sulfates, depending upon the roasting conditions employed. Yield equations were developed using regression analysis for predicting the extraction of copper and nickel between the temperature limits of 520° to 670° C, the roasting time limits of 3 to 7 hours, and S02 limits of 10 to 40 percent in S02-air mixtures.

Jan 1, 1971

By Xiqing Wu, Liang Dai, Tao Yue, Longsheng Yi, Ruifang Wang

Magnetic seeding flotation (MSF), i.e. adding magnetic seeds and pre-magnetization-flotation, is a new flotation technology especially for fine particles, which improves the flotation performance by enlarging the apparent size of the particles in a way of magnetic agglomeration. Both the fine coal slimes with a size of 66.68% –38µm and the pyrite slimes with a size of 73.95% –23 µm were investigated by the MSF, respectively. Flotation tests with variable of dosages of magnetic seeds and polyacrylamide were conducted, and some measurements, such as laser diffraction size analysis, magnetic susceptibility by vibrating sample magnetometer (VSM) and infrared spectroscopy (IRS), were also applied in order to probe the mechanism of the MSF. Based on the tests, measurements and calculations it was found that both the recovery of coal and the flotation kinetics of pyrite slimes increased with the additions of the magnetic seeds, and in the presence of polyacrylamide the coal flotation was further strengthened due to a synergetic effect of magnetic seeds and polyacrylamide on the flotation and a relatively larger apparent size of slimes after additions of magnetic seeds and polyacrylamide. The reason for the MSF lies in fact that the presence of the polyacrylamide intensified the adsorption of magnetic seeds on the coal particles and increased the coverage of the magnetic seeds on the coal surface from 0.2 to 1.3 wt%, resulting in increased magnetic susceptibility of coal particles from 9.13×10-9 to 22.17×10-9 m3/kg and thus a low magnetic field strength of pre-magnetization needed for the magnetic agglomeration among the coal particles from 602 to 24 mT prior to proper flotation. IRS shows that polyacrylamide chemisorbed on the surfaces of both coal particles and magnetic seeds, thus acting as the bridging media between particles and seeds.

Jan 1, 2016

By Kevin M. Connor, Malcolm J. McPhersqn

Examples are presented in which Time Domain Reflectometry (TDR) was employed to locate deformation of rock masses induced by mining. The first example involved motoring the propagation of overburden fractures above a longwall coal panel and the second example involved the we of a)R to monitor rock mass deformation in the vicinity of a strip mine highwall. Bock mass deformation, strata separation and large block movement generated strains and failure along coaxial cables which were installed in drill holes and the TDR reflections generated by these strains and failures were monitored. Analysis of field data and a preliminary laboratory test indicate that it may be possible not only to locate rock mass movements but also to quantify these movements with TDR data.

Jan 1, 1984

By S. Paul Singh

"The long-term viability of seismically active and/or deep mining operations hinges upon the industry's ability to maintain profitability in a climate of increasingly difficult conditions, escalating operating costs and fluctuating metal prices. Within this context, it is prudent to explore mining techniques that could provide means for safer and more profitable extraction of seismically active and/or deep seated deposits that are vital to the long term survival of the industry.The first step was to examine Penetrating Cone Fracture (PCF) and other relevant concepts with the objective of semi-continuous mining in deep underground hard rock mines. This was followed by an assessment of the current conventional drilling and blasting practice. Thirteen blasts were monitored in five different seismically active workings of an operating deep mine. The main concerns during the current drill and blast practice were identified.On the basis of the literature review, three short round blasting techniques were short listed for further review. These techniques were evaluated based upon the available literature and discussions with the persons associated with their applications. Justification, requirements and major challenges for the application of short round blasting have been discussed in this paper. Suggestions for improving the current drilling and blasting practice have also been outlined.INTRODUCTIONRock fragmentation is the key to mineral excavation and production. Increasing working depths, environmental concerns and trends towards continuous mining necessitate the development of new and improved rock breakage methods.The excavation of hard rocks is still dominated by the sequential routine of face preparation, drilling, charging explosives, blasting, ventilating for fume and dust removal, mucking and roof support. Worse still, drilling and mucking require specialized equipment that fills the end of the heading so that no other operation can be performed and the equipment must be removed from the face to protect it from fly rock."

Jan 1, 2010

By Yajie Wang

Traditionally, roof falls are usually attributed to bad roof strata and high vertical stress related to the overburden depth. However, roof falls under shallow overburden depth are oflen caused by a high horizontal stress field. Recent studies have proven that the high horizontal stress field, if existing, plays a major role in roof stability. Also the roof conditions are related to the entry diredions under a horizontal stress field. Questions are: How to orient the entry to a favorable direction to prevent the roof falls? If the entry cannot be oriented, how to support it? Through a case study in mine A, this paper analyzes the horizontal stress effect on roof stability. The guideline for the entry orientation is given based on the results of analysis. Additionally, suggestions are made for those entries that cannot be oriented to a favorable direction.

Jan 1, 1998

By John D. Corrick

The environmental and nutritional characteristics necessary for maximum copper extraction from a low-grade ore by Ferrobacillus ferrooxidans have been explored as have many of the limiting parameters. Criteria considered were oxygen consumption, copper extracted, soluble copper concentration, temperature, pH, particle size, nutrients, and other inorganic salt concentrations. A set of environmental and nutritional conditions were developed for E. ferrooxidans Which supported cell reproduction and maximum microbial oxidation of a low-grade copper sulfide ore. Percolator tests conducted under these optimum conditions resulted in an 18 percent increase in the quantity of copper microbially extracted over that extracted under conditions considered to be standard. Manometric tests determined those extremes of environmental conditions and nutritional factors Which were detrimental to the extraction of copper by E. ferrooxidans.

Jan 1, 1965

By B. T. Lusk, J. M. Hoffman, J. Silva Castro

Blast vibration induces sounds within neighboring residences. A housewide vibration and sound monitoring system was installed in a West Virginia home subjected to blasts from various distances and directions. Eighty-nine blast events were monitored and analyzed. Fifteen channels of data were collected, including data from three triaxial geophones, one airblast microphone, one uniaxial geophone mounted on the wall of the house (response channel) and four microphones that recorded CD-quality sound waves inside the house. Each of these channels was recorded on the same time scale. The response channel signal was easily separated into ground vibration and airblast-induced movement, due to differences in the time of arrival. This response channel was then compared to the sounds recorded to determine which component of blast vibration induced the maximum sound response. Blasts at distances less than 762 meters (2,500 feet) had maximum sound responses from both ground vibration and airblast, while for blasts beyond 762 meters (2,500 feet), the maximum sound response was caused by ground vibration without exception. When airblast was identified as the dominant sound generator, the peak amplitude of the sound was directly related to the amplitude of airblast. When ground vibration was identified as the dominant sound generator, the peak amplitude of sound was not related to the amplitude of ground vibration. Findings from frequency analysis showed that the frequency content of sounds inside the house was not related to the frequency content of airblast or ground vibration, regardless of source. This finding suggests that residents will have difficulty determining the source of blast-induced noise in their homes. The proposed airblast response factor (ABRF) can aid blasting operations to determine the dominant source of sounds inside a complainant’s house based on the time-of-arrival relationships. With this site-specific information, public relations responses can be developed accordingly.

Jan 1, 2010

By R Sterk, B Reid

The Konongo Gold Project is located on the western margin of the 125 Moz Ashanti Gold Belt in Ghana, West Africa. It is situated 60 km along strike of the world-class mineral system at Obuasi and is interpreted to lie on the same controlling regional shear system.The project is operated by Signature Metals, a subsidiary of the Liongold Corporation, and is managed and funded by the Liongold Corporation.Historic underground operations at Konongo produced 1.6 Moz Au at a head grade of 11.8 g/t Au, from eight operations spread along 16 km of the shear system. Mining focused almost exclusively on free-milling gold in quartz, ignoring the gold-bearing sulfide mineralisation associated with the quartz veins. Underground mining ceased in 1986.In 2013, Signature Metals re-focused the program at Konongo to assess the viability of mining the sulfide ore sustainably. This led to the first campaign review of the historic underground data and resource potential since mine closure. The Obenemase mine was the first of the eight operations to be assessed as part of this campaign.Large amounts of legacy data have survived for Obenemase and several historic resource estimations have been completed based on these data. The data typically consisted of hand-drawn sections and plans, and ledgers of commonly incomplete drilling and sampling data. Some drill core have been lost over time, but a large amount of quarter-core and half-core as well as pulps and rejects are still available. Previous resource estimates had a low confidence value because all the available assay and geological data were integrated effectively with the estimates, resulting in a lack of understanding of both grade and geological continuity.This project built a new geological model for Obenemase that greatly enhances the understanding of the controls on mineralisation using a thorough approach of re-surveying, re-cataloguing and re-logging. This model led to an increased degree of confidence and a subsequent upgrade of resource classification, and created several previously unrecognised strong exploration targets. The resulting resource estimates increased the value of the project by 100 per cent.This paper emphasises and highlights the importance of a well-understood geological model on the confidence of a resource estimate and how this may directly impact on the project’s ‘bottom line’.CITATION:Sterk, R and Reid, B, 2014. The Konongo Gold Project, Ghana – an example of how geology makes all the difference to a resource estimate, in Proceedings Ninth International Mining Geology Conference 2014 , pp 467–476 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 18, 2014

By P. C. M. Knops, K. Rijnsburger, R. M. Santos

To overcome the challenges of mineral CO2 sequestration, this work utilizes a unique proprietary Gravity Pressure Vessel (GPV) reactor technology, and focuses on reaction products of high economic value. The GPV provides intense process conditions through hydrostatic pressurization and heat exchange integration that harvests exothermic reaction energy. Here, laboratory-scale tests of the envisioned process was performed in tubular and continuously stirred tank reactor (CSTR) autoclave reactors. The mineral used was Olivine (~Mg1.6Fe2+0.4(SiO4) + ppm Ni/Cr), although asbestos, steel slags and oil shale residues are also under investigation. The effect of several process parameters on reaction extent and product properties was tested: CO2 pressure, temperature, residence time, additives (buffers, lixiviants, chelators, oxidizers), solids loading, and mixing rate. The products (carbonates, amorphous silica and Chromite) were physically separated (based on size, density and magnetic properties), characterized (for chemistry, mineralogy and morphology) and tested in intended applications (e.g. as pozzolanic carbon-negative building material). Economically, it is found that product value is the main driver for mineral carbonation, rather than, or in addition to, the sequestered CO2. The approach of using a GPV and focusing on valuable reaction products could thus make CO2 mineralization a feasible and sustainable hydrometallurgical process.

Jan 1, 2015

By Michael Wieland

The work principle from thermodynamics is used to model the shock and heave for explosives shot in rock or under water, with the latter compared to reported results. The work principle utilizes restrictions and constraints to yield a representative fit to the irreversible (natural) shooting process. The reduction of the internal energy of the reaction-zone yields the total expansion work (TXW), the resultant sum of the rock/water shock and heave. The restoration technique of forming a closed thermodynamic loop yields the reversible mechanical work (RMW) or the rock/water heave. The residual work that remains when RMW is subtracted from TXW yields the irreversible disorder work (IDW) or the un-dissipated (without loss) shock in the surrounding rock or water. The work principle renders an unequivocal relationship for the shock-loss factor, rather than the traditional roundabout formula for correcting the underwater gauge-shock of un-modeled explosives. There’s a novel heave-ratio factor that unquestionably rates the fit of results under comparison. Rock-shots are more complex in nature than underwater shots due to rock fracture and stratum rupture, though numerical resolution is worthwhile. The proposed rock-water-jelly (RWJ) model yields rough estimates, with rock-type results not wholly different from their underwater counterparts. Though reported underwater shots reveal shock and heave trends with respect to charge formulation ingredients, there are no such rock-shot results for comparison, since the relevant test measurements in rock remain difficult, if not intractable.

Jan 1, 2007

By P. A. Mingione

AEROPHINE® 3418A is a unique sulfide mineral promoter produced by Cyanamid, based on phosphine (PH3) chemistry. It has proven effective as a collector for the sulfide minerals of copper and particularly lead (galena), as well as for secondary gold and silver values. AEROPHINE 3418A has widest application as a Cu and/or Pb collector for complex ores of Cu-Zn and Pb-Zn, which frequently have significant quantities of associated precious metal values. Advantages shown in the use of AEROPHINE 3418A are improved selectivities against Zn-and Fe-sulfides, increased precious metals recoveries, reduced total collector consumptions for Cu and/or Pb flotation, and increased flotation kinetics leading to higher recoveries of these values. Operating plant, pilot plant and laboratory test data from treat-ing different ores are presented, demonstrating the advantages in use and preferred application of AEROPHINE 3418A.

Jan 1, 1991

By A. Kotze, D. Messina, E. Nagels, Y. Cryns, S. Arnout

The FlashPhos process aims to recover white phosphorus (P4) from sewage sludge by drying, flash combustion/gasification, and carbothermic refining steps. This study evaluates the material behaviour of sewage sludge ash melting and reduction in a refining furnace for the novel FlashPhos process. Thermodynamic modelling in FactSage 8.2 is combined with experiments from a tube furnace to determine the possible phosphorus recovery and minor element behaviour. For the two studied sludges, a yield of 40% and 75% white phosphorus is achieved after 1 hour at 1600°C, corresponding with a 60% and 25% loss to the metal phase. This is slightly above the calculated equilibrium yield of 28%–73%, which depends mainly on the Fe/P ratio of the sludge. Temperature is found to have a significant influence on the final phosphorus yield when leading to incomplete melting of the ash. A clean slag is produced in the process free of heavy metals making it suitable to be used as a cement-like binder material. The main heavy metals that co-evaporate with the phosphorus are Zn, Pb, As, Sb, and Sn. Additional processing steps will be required to remove these to produce a pure P4 product. The metal alloy consists of mostly Fe and P with smaller amounts of other components such as Mo, Cr, Cu, Mn, Sn, Sb, and V. The final slag consists of CaO, SiO2, MgO, and Al2O3 with virtually complete removal of P and heavy metals.

Oct 2, 2025

By Volker Vogt, Wolfgang Sand, Eberhard Gock

"It was discovered that the selective activity of bacteria during the extraction of raw material concentrates by means of flotation could also be achieved with extracellular polymeric substances (EPS) excreted by bacteria. EPS, which is extracted by means of centrifuging bacterial cultures, can help to significantly reduce the use of cyanides, approximately 200,000 t/a of which are used for ore dressing today.The bacterium used was Acidithiobacillus ferrooxidans. In order to identify the bandwidth of the oxidation activity, 20 bacterial strains of the strain collection of the University of Hamburg were attracted to iron(II) sulfate and pyrite under defined conditions. All strains oxidized iron(II) sulfate ten times faster than pyrite.EPS has so far been derived from four strains. In general, EPS extracts are divided into a hydrophilic and a hydrophobic fraction. The hydrophilic fraction is composed of e.g. fucose, rhamnose and glucose; fatty acids such as dodecanoic acid, hexadecanoic acid, octadecanoic acid and nonadecanoic acid were found in the hydrophobic fraction.Pure mineral phases and mineral mixtures were used for the flotation tests. As opposed to current knowledge, the results were reproducible with technical flotation machines."

Jan 1, 2003