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By Jeffrey D. Smith, William G. Fahrenholtz, Jose M. Soto

Interactions between A356 aluminum (Al-Si alloy) and dense fused silica (FS) riser tubes used for low-pressure casting of aluminum alloys were evaluated using a sessile drop approach. The tubes have a short service life, but cost and thermal shock resistance make them an effective solution. The main problem encountered during use is the reaction of aluminum with silica to form alumina and silicon, which causes failure. Tests have been conducted on as-fired (uncoated) and modified (coated) tubes. Experiments were carried out in a horizontal furnace at 1225°C under argon to minimize the effect of the aluminum oxide on the interactions at the alloy-silica interface. Images of the drop were acquired and contact angle values were estimated for uncoated and coated samples, but no significant differences in the contact angles were observed. Scanning electron microscopy revealed the presence of cracks at the interface between the reaction zone and the unreacted silica. The presence of reaction products (silicon in the reacting alloy and aluminum in a reaction zone between the alloy and the unaffected silica) has been confirmed using energy dispersive spectroscopy. A two layer coating system was found to be effective in reducing penetration of the aluminum alloy.

Jan 1, 2004

By M. Di Tommaso

Acid Mine Drainage (AMD) is a quite diffuse environmental problem in dismissed sulphur mine districts. AMD is related to sulphur oxidation of abandoned tailings, generating heavy metal-bearing streams with high iron and sulphate contents and low pH. Treatments of AMD aim firstly to increase the pH to reduce its leaching power causing the further release and mobilization of heavy metals through soil solution and groundwaters. Increasing the pH also allows the precipitation of iron (III) (involved in sulphur oxidation and then in AMD generation) and the partial removal of other toxic components such as arsenic. pH adjustment and the reduction of the high concentration of iron are also necessary for the successive biological treatment in permeable reactive barriers (PRB) with sulphate reducing bacteria (SRB) (II step, biologically mediated precipitaton/biosorption) to avoid the rapid plugging of the barrier (for the large amounts of iron precipitates) and to ensure neutral pH conditions for SRB growth. In this work the first step (chemical precipitation) of a combined chemical and biological treatment of AMD is presented. Experimental data from column tests using carbonate stones to remove iron and increase pH were reported. Toxicity tests have been carried out on the treated wastewaters by Lepidium sativum.

Jan 1, 2006

By Keith G. Wallace, K. M. (Chris) Chmura, Kirk H. McDaniel

The Waste Isolation Pilot Plant (WIPP) performed a feasibility analysis for the purpose of either modifying, supplementing, or replacing its two main mine fans. The WIPP, located near Carlsbad, New Mexico, is a U.S. Department of Energy (DOE) fa¬cility designed to demonstrate the permanent, safe disposal of U.S. defense-generated transuranic waste in a deep bedded salt deposit. Since the centrifugal fans were installed in 1988, multiple op¬erational and performance concerns have been identified. A com¬prehensive engineering study was conducted in 1995 to: 1) Qualify and quantify operational concerns, 2) Evaluate possible alternatives, and 3) Recommend an optimum solution. Multiple system modification and/or replacement scenarios were evaluated with associated cost estimates developed. The study considered replacement with either centrifugal or axial fans. Multiple fan duties are required at the WIPP. Therefore, Variable Frequency Drives and Inlet Vane Controls (IVC) were investigated for centrifugal fans. In-flight adjustable blades were investigated for axial fans. The study indicated that replacing the existing system with two double-width, double-inlet centrifugal fans equipped with IVCs was the best choice. This alternative provided the most desirable combination of: 1) ensuring the required operational readiness, and 2) improving system performance. The WIPP is currently planning to replace the first fan in 1997.

Jan 1, 1997

By J. J. Bikerman

In a recent study' of the martensitic transformation of Cu-Zn ß-phase alloys, it was noted that the MS temperature at the surface was raised due to the loss of zinc by volatilization. It seems likely, therefore, that the MS temperature may serve as a guide for the measurement of composition. From a knowledge of the dependence of the transformation temperature on composition, 2 it should be possible to detect variations in zinc content which are less than 0.1 at. pct by measuring the MS temperature throughout the sample. It is unlikely that an electron microprobe analysis could detect accurately such small zinc losses because the presently accepted limits of accuracy of the micro-probe analysis in simple ternary systems are of the order of 2 to 5 pct of the amount present.3 In the present study, a composition gradient was produced by precipitating the a primary solid solution, and reheating for a very short time within the 0-phase field. The nominal composition, in atomic percent, of the ternary ß-phase alloy used, 64.2 Cu, 34 Zn, 1.8 Si, was selected because it had an MS temperature of +4°C, thereby simplifying the experi-

Jan 1, 1968

By R. Fraher

The control of mine roof is of vital interest in underground coal mining not only for reasons of safety, but also to avoid the high costs of cleanup, resupport and production losses that can result from roof falls. The difficulty in determining roof stability mine-wide is due in large part to the broad variation of geologic and structural conditions that typically exist throughout a mining area. To ensure a stable roof over the entire mine, support systems must be selected to minimize the possibility of failure. The magnitude and cost of the support selected is a trade off against the cost of the number of falls that can still occur after it is installed. Because of the large number of variables involved in analyzing and optimizing roof stability versus support, a digital computer simulation was selected to find a cost effective solution to roof support design. A total cost approach is used which includes the actual cost of the roof support as well as the cost of the roof fall in terms of resupport and loss of production (Fraher 1990a). A Monte Carlo simulation program called ROCSIM (Roof control Optimization Cost SIMulation) has been developed for determining the optimum roof control system and design layout for underground room-and-pillar mining.

Jan 1, 1992

In the hierarchy of performing mine planning tasks, production scheduling is naturally at the bottom. Yet good production scheduling is probably the most demanding and difficult task to achieve for various reasons. Being the last task in the mine planning hierarchy, a proper production schedule must not only conform to both the long-range and the short- range mine plans but also satisfy many practical details that are unique to day-to-day operations. For example, the averages which were good enough for both long-range and short- range mine planning are no longer good enough for production scheduling. Instead, the variations become the overriding concern. The answer must also be obtained quickly and on time, thus adding another dimension to the overall problem. Because of these considerations, many production scheduling problems have been begging for solution during the past decade. Many attempts were made to solve the production scheduling problems in the past using computers and the available operations research (OR) techniques, particularly among academic groups. However, it is probably true that, compared with the current full-time computer usage in long-range and short-range mine planning, very little computer usage is being made in production scheduling to date.

Jan 1, 1979

By Bruce W. Cavender, Brian L. Granger

The leaching characteristics of non-homogeneous ores have traditionally been difficult to assess in laboratory tests. A result of the large sample size necessary to ensure representativity, this difficulty is most acute for ores containing nuggets or other irregular occurrences of precious minerals. Consequently, small-scale leaching tests are often regarded as indicative rather than conclusive. The predictive nature of leaching tests can be improved by applying the experimental design concepts of blocking and randomization. In the case of column leaching, experimental 'blocks" are constructed with the same number of columns as there are separate test conditions. These blocks are treated identically throughout the test, with differences between columns within each block being the variables of interest. To maximize the uniformity of the blocks, randomization procedures are employed in the preparation of the sample and conduct of the test. The initial ore sample is screened and individual column charges composited from randomly selected increments from each size fraction. The leaching order, daily solution analyses, and processing of leach residues are similarly randomized. The observed differences in leaching performance between the columns in each block are compared to determine the over-all outcome of the test. A statistical analysis using t distributions gives a quantitative measure of the reproducibility of the outcome.

Jan 1, 1995

By A. M. Gaudin, T. P. Meloy

Based on the equation for single fracture, a formula has been obtained for repeated fracture. Solution of this equation is obtainable analytically for a few examples and numerically for all others. Graphs of the size distribution equations have been obtained; they agree broadly with the experiments of others. In another paper1 we have considered a model and a comminution distribution equation for single fracture of brittle materials. Most comminuting devices, however, depend on the occurrence of repeated fracture. This is especially true of continuous cylindrical mills of the ball, tube, or rod type. But even in primary crushers there is some repetition of the breaking process, so that this paper should be of interest in connection with all comminuting devices. HALF LIFE AND PROBABILITY OF FRACTURE To facilitate the study of fracture it is useful to introduce the concept of the half life of a particle, In the ball mill, for example, we may start with 10,000 feed particles. The time, 7, by which one half of these particles have been broken is the half life of the feed under the prevailing experimental conditions. The probability of breakage bears an inverse relationship to the half life. In a ball mill, for instance, it can be shown that the

Jan 1, 1962

By S. Atak, G. Bulut

The xanthate adsorption mechanism on pyrite was investigated with an emphasis on solubility studies. Additionally, adsorption studies, Eh and infrared spectrophotometer measurements were performed. Pyrite floats at pH levels between 3 and 6 using ethyl and amyl xanthates with a maximum at pH 4. The solubility of pyrite in the absence and presence of xanthate was investigated in detail with respect to pH and conditioning time. Experimental results showed that the solubility of pyrite increases from 60 to 120 ppm (10-3 to 2x10-3 mol/ L) in the presence of xanthate at pH 3. Fourier transform infrared (FTIR) spectra of ferric xanthate, dixanthogen and pyrite conditioned with xanthate indicated that dixanthogen is the only species that can be determined on the pyrite surface. Adsorption tests showed that the highest level of xanthate adsorption was in the acidic range; yet higher adsorption densities were detected in neutral solutions compared to alkaline conditions. Electrochemical data suggest that the doubling of the iron concentration is due to the reduction of ferric ion to ferrous by xanthate while xanthate is oxidized to dixanthogen. Dixanthogen formation together with the hydrophobic iron hydroxy-xanthate complex on the surface is proposed to be responsible for pyrite flotation. Key words: Flotation, Pyrite, Adsorption, Xanthate, Dixanthogen

Jan 1, 2003

By A. M. Gaudin, Olav Mellgren, P. L. De Bruyn

In commonly used to prepare the surface of the mineral to be floated so that attachment to air takes place. The quantity of agent required to make the mineral hydrophobic is usually very small, of the order of 0.1 to 0.25 lb per ton of mineral. Details of the mechanism of pyrite collection are for the most part unsettled. Adsorption of collector has long been believed to involve an ion exchange mechanism as demonstrated for galena' and for chalcocite. In the work on chalcocite it was also demonstrated that a film of xanthate radicals unleachable in solvents that dissolve alkali xanthates, copper xanthate, or dixanthogen was formed at the surface of the mineral. The unleachable product increased with increasing addition of xanthate up to a maximum corresponding to an oriented monolayer of xanthate radicals. Pyrite is extremely floatable with xanthate if its surface is fresh,,' but the floatability decreases rapidly as oxide coatings increase in abundance. Pyrite shows zero contact angle when in contact with ethyl xanthate solution at pH higher than about 10.5; at neutrality. a contact angle of 60° is obtained at a reagent concentration of 25 mg per liter. Alkali sulfides and cyanides are pyrite depressants.

Jan 1, 1956

By Pollard D. M

The BHAS copper-lead matte leach process, developed in Port Pirie, South Australia, has been in operation on a commercial scale since 1984. This process is one of many developed in the past decade to recover copper via the hydrometallurgical route. In essence, the process involves a single stage agitative leach of 100% -75um matte in an acid chloride-sulphate lixiviant with gaseous oxygen as oxidant. The leach temperature is controlled at 85¦C to assist with reaction kinetics. After leaching, divalent copper is recovered from solution via a conventional solvent extraction/electrowinning circuit to yield cathode copper for sale The BHAS matte leach process has several unique characteristics cf. other commercial oxidative acid leach processes. These include i) the use of gaseous 02 as oxidant ii) H2SO4 addition as make up acid iii) Relatively low chloride ion addition (30 g/1) For this reason, extensive work was carried out into the optimization of leaching by Meadows (1985). Variables investigated included ò Oxygen flow-rate ò Agitation intensity ò Leach temperature ò Free acidity ò Chloride ion concentration ò Matte particle size The current work was conducted to determine the effect of cooling rate, and hence mineralogy, on the leaching characteristics.

Jan 1, 1989

By C. H. Lee, F. Concha, L. G. Austin, P. T. Luckie

The Concha-Almendra batch-settling treatment for concentrated suspensions of single-diameter spheres has been modified. This modified version is used in the differential equations of simple batch settling of a particle size range of different density materials. The equations have been programmed for a finite difference solution, and a number of test cases have been analyzed. By cutting the settling column at a fixed fractional height, the material below this height can be treated as underflow and the material above as overflow. The predicted partition curves obtained from treating the settling in this way have Sharpness Indices in the range of 0.5 to 0.6, in the absence of dispersion effects. The Sharpness Indices decrease as dispersion increases. When the feed size distributions are of the Rosin-Rammler form, the partition curves (corrected for the bypass fraction) fit the Rosin-Rammler equation with reasonable accuracy. The predicted Sharpness Index of a component of a mixture of two materials of different densities was unchanged from that of the same materials settled alone. However, for the same, feed size distribution and volume fraction of solids in the feed, the heavier material settled faster, and the lighter settled slower, than when settled alone.

Jan 1, 1993

By Sh. Arshadnejad

Stress analysis in a rock medium is essential to determine the stress concentration between two consecutive circular holes and prediction of fracture behaviour. When two consecutive circular holes in a hard rock medium such as granite are loaded internally by the pressure of non-explosive expansion material (NEEM), stress concentration occurs between the holes which then causes the rock to fracture. In this work, finite element (FE) analysis using Phase2 code was employed to study the stress concentration between two consecutive circular holes under internal pressure induced by NEEM. Effects of different hole diameters and spacings, rock properties and NEEM pressures have been analysed. The data gained from the numerical analysis and analytical solutions were then used to develop two models. These models were then modified by using the FE data and polynomial regression analysis. The developed analytical models showed to be in a very good agreement with the FE analysis. Hence, the developed models can be used with confidence to determine stress distribution and concentration factors around two consecutive circular holes in a hard and brittle rock which are loaded internally by the pressure induced from the NEEM. Keywords Finite element method, non-explosive, quarry mining, stress concentration..

Jan 1, 2011

By Horace Pops, Jorge E. Kittl

In a recent study' of the martensitic transformation of Cu-Zn ß-phase alloys, it was noted that the MS temperature at the surface was raised due to the loss of zinc by volatilization. It seems likely, therefore, that the MS temperature may serve as a guide for the measurement of composition. From a knowledge of the dependence of the transformation temperature on composition, 2 it should be possible to detect variations in zinc content which are less than 0.1 at. pct by measuring the MS temperature throughout the sample. It is unlikely that an electron microprobe analysis could detect accurately such small zinc losses because the presently accepted limits of accuracy of the micro-probe analysis in simple ternary systems are of the order of 2 to 5 pct of the amount present.3 In the present study, a composition gradient was produced by precipitating the a primary solid solution, and reheating for a very short time within the ß-phase field. The nominal composition, in atomic percent, of the ternary ß-phase alloy used, 64.2 Cu, 34 Zn, 1.8 Si, was selected because it had an MS temperature of +4°C, thereby simplifying the experi-

Jan 1, 1968

By N. J. Grant, Masao Adachi

A number of Cu-SiO, and Cu-A1203 alloys of low oxide content, produced by internal oxidation of copper-silicon and copper-aluminum dilute solid solutions, were exposed at temperatures up to 1050°C for fairly long times to bring about partial or total re crystallization. The creep-rupture properties of these re crystallized alloys were compared to those in the as-extruded condition at 450° C. Some of the alloys were cold worked after re crystallization to note changes in creep-rupture properties, also at 450OC. SINCE the introduction of the SAP alloy in 1949,~ many studies have been carried out on similar oxide and intermetallic dispersion hardened alloys to determine properties and to establish the mechanisms involved in the strengthening process which led to stable, high-temperature behavior.'-' To date, it has been indicated that, however achieved, the structure should be composed of a continuous ductile metal matrix in which is dispersed a fine, submicron size, hard, insoluble second phase (or at least, essentially insoluble at temperatures very near the melting point), with a submicron or near submicron interparticle spacing. Stored energy, obtained by a high strain rate deformation process appears desirable, as an additional strengthening means beyond pure dispersion.=

Jan 1, 1961

By Artmont G. J, Palmer K

Alluvial gold is an ideal exploration tracer to bedrock source and indicator of bedrock mineralisation style because (i) gold occurs in a wide range of deposit types, (ii) primary composition is sensitive to style of mineralisation, and (iii) it is a heavy resistate mineral that is readily preserved and easily sampled. In regional exploration of the Central Ranges of Irian Jaya, alluvial gold mineralogy has been applied to maximise the information return from panned concentrate sampling and to focus exploration effort. Primary gold is a solid solution of Au+Ag¦Cu¦Hg, ¦ trace Pd, Te, and Sb. In general Ag¦Hg increase and Cu decreases with inferred decreasing temperature of formation, and gold from particular mineralisation styles has signature compositions that can be used as indicators of bedrock mineralisation type. Furthermore, the abundance of alluvial gold is an indicator of the economic potential of a catchment. The convergent continental-oceanic plate geology of the Central Ranges is conducive to a wide range of mineralisation styles. Mineralogy of gold in ophiolite, skarn, porphyry, mesothermal vein and possible VHMS environments is characterised from alluvial and bedrock samples, and the use of gold mineralogy in prospecting at regional scale through prospect definition to drilling is demonstrated.

Jan 1, 1995

By M. K. Elmouttie, G. V. Poropat

Mapping of exposed rock walls provides data on geological features such as joints, bedding planes, faults etc critical to the economics and the safety of mine operations. Traditional, manual methods of mapping can be time consuming, error prone and limited in their coverage. New methods have been developed to map exposed faces remotely and safely however the benefits of these methods are only fully realised when exposed structures can be quickly and easily mapped using automated methods. This paper describes the application of an automated method of analysis of 3D images that provides users with the capacity to map exposed structures automatically. The method is based on the use of vector classification methods used in some neural network systems and provides rapid and reliable identification of exposed planes. CSIRO Exploration and Mining is applying these methods to 3D images for a range of applications from pit mapping to machine automation.

Jan 1, 2006

By Alcides Eloy Cano

Los recursos minerales de un depósito está en función de las dimensiones de la geometría del cuerpo mineral, así como sus reservas minables permiten saber el verdadero valor económico de su contenido. En este sentido, la Geotecnia es una herramienta que define las condiciones de los esfuerzos in situ, predice el comportamiento alrededor de excavaciones subterráneas e interactúa con las labores próximas, así como también la distribución de esfuerzos. Por ello, el presente trabajo señala la aplicación de esta herramienta a una mina subterránea de Oro localizada en el Perú, donde se tiene bloques de mineral económicos, así como señala su accesibilidad con leyes encima del Cut-Off. De forma que se recupera el mineral económico a través de las rutas críticas de carguío, en función de la viabilidad de autosostenimiento.

Sep 12, 2011

By Y. M. Zhao

The separating performance of a pilot dry beneficiation system using a gas-solid fluidized bed was investigated with coal from South Africa. The coal used for the study has a low inherent moisture content, a moderate ash content, a moderate volatile content, a low sulphur content and a high calorific value. Its washability is moderate. Experimental results show that the separating quality of the fluidized bed drops gradually as the feed-coal particle size decreases. The probable error, E, values for 50?25mm, 25?13 mm and 13?6 mm coals were 0.04 g/cm3, 0.06 g/cm3 and 0.09 g/cm3, respectively. The cause of the differences in separating characteristics was analysed by particle dynamics and numerical modelling. Furthermore, the pilot fluidized bed was employed to separate 50-6mm coal. In this experiment the coal ash content was reduced from 23.74% to 11.79%, with a probable error, E, value of 0.07 g/cm3and a recovery efficiency of 98.26%. This indicates that the fluidized bed is applicable to the separation of coal from South Africa and has good separating performance and wide applicability. Keywords: feed-coal particle size; gas-solid fluidized bed; dry coal beneficiation; numerical simulation.

Jan 1, 2010

Paper 1: Risk of gastrointestinal cancers from inhalation and ingestion of asbestos, John F. Gamble Selikoff suggested the hypothesis that asbestos exposure is causally associated with increased risk of gastrointestinal (GI) cancers in an early study of insulation workers. In this paper, John Gamble reports on his extensive review and reanalysis studies that address the relationship between asbestos exposure and GI cancers. The purpose of the review was to evaluate the association between asbestos exposure and risks of stomach, colorectal, colon, and rectal cancers separately. Gamble evaluated exposure?response (E?R) relationships using surrogate exposure methods ??because few individual studies of GI cancer have reported exposure? response analyses.?? The principal asbestos exposure surrogates are: (1) the rate ratio (RR) for lung cancer; and (2) the percent of mesothelioma among exposed workers. Analyzing SMRs for GI cancers from individual studies versus the risk of lung cancer and mesothelioma provides crude estimates of E?Rs for asbestos exposure and GI cancer. Briefly, Gamble justifies the surrogate approach as follows:

Jan 1, 2007