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By Kuiting Wang, Jinshan Liu, Ninglei Sun, Aiguo Dong, Yeda Lu

"Eliminating the environmental threat caused by waste effluent containing magnesium sulfate derived from the process of nickel laterite sulfuric acid leaching and subsequent nickel precipitation is always a focus in the metallurgy field. A new flowsheet whose procedures include vaporization, crystallization, two stages precipitation of magnesium, causticizing treatment of filtrate and ammonia recycle was investigated. Both the details of the flowsheet and its application are described in this article. It is confirmed to be an effective and economical method to prevent the pollution by the waste effluent, simultaneity, a series of magnesium products recovered during the process own good economic returns.IntroductionSulfuric acid leaching is the conventional procedure of extraction valuable metals from ores in hydrometallurgy field. During the process of nickel laterite sulfuric acid leaching, several metals, including Ni, Co, Al Mn, Fe, Mg etc., migrate into the leachate in the form of soluble metal sulfate. After subsequent procedure of purification, precipitation of Ni and Co and neutralization, an enormous stream of waste effluent which contains a concentration of approx. 15-40g/L Mg is exhausted. Such solution containing magnesium sulfate is toxic, which causes diarrhea for both human and animals. On the other hand, large amount of sulfate acid was consumed during the process of leaching by the compound of Mg, which increases cost of a hydro nickel plant.In arid areas, the waste effluent mentioned above is treated via evaporate pond owning large acreage, which needs not only the appropriate meteorologic condition, but occupies much land. In coastal areas, it is directly discharged to the sea, which probably deteriorates ecological system of offshore strip. The most widespread method to treat with the waste effluent is neutralization by lime cream, the residues of which containing magnesium hydroxide and gypsum are transported to residues pool. Neutralization is a simple process, but it never recycles the Mg and sulfate anion into new application, meanwhile, the residues are potential threat to the environment."

Jan 1, 2012

By A. G. Scobie

THE research laboratory of this Company was recently faced with the problem of determining trace amounts of tungsten in a series of classifier sands. A spectrographie survey revealed the feasibility of using this instrument in the final evaluation, but a check of the common methods in use for the isolation of tungsten (3, 4) showed these methods to give incomplete separation for trace amounts. An investigation into the possibility of modifying these procedures, or developing others, was thus indicated. ASSAY PROCEDURE Weigh 10 grams of 200-mesh ore or concentrate into a 400-ml. beaker, wet the sample well with about 20 ml. of water, and add 100 ml. of hydrochloric acid. Cover, digest at 60° to 70° C. for about 1 hour, and then boil down to approximately 25 ml. Cool, add 25 ml. of hydrochloric acid and 10 ml. of nitric acid, and again boil to former volume. Add 20-ml. portions of nitric acid with successive boiling clown until chemical action is complete. Then add 20-ml. portions of hydrochloric acid until all nitric acid is removed. Take nearly to dryness on a law-temperature hot plate, but do not bake. Take up in 10 ml. of hydrochloric acid and 20 ml. of water and heat on a law-temperature hot plate until all iron goes into solution. Dilute to 200 ml. and heat to just below boiling. Stir in pulp of about half of a No. 41 Whatman filter paper (12.5-cm.) and continue digestion on plate with occasional stirring for 15 to 20 minutes.

Jan 1, 1943

By Ivo André

Sorption of copper ions from aqueous solutions by dried biomass of the aquatic plant Potamogeton luscens was studied at laboratory scale. The aquatic plant was collected in water resources in Brazil, washed, dried at 60°C and ground in a bladed mixer. Sorption experiments were conducted in agitated flasks and in a packed bed column. Maximum copper removal was obtained between pH 5.0 and 6.6 when copper was present in the ionic form Cu'. Sorption followed the Langmuir isotherm with saturation attained at 35 mg/g. Free energy of sorption was found, to be of the order of -25 kJ/mol. Sorption kinetics data were better described by a second order reaction and rate constants were calculated in 0.030 1/(min.mg) for - 4.0 mm particles and 0.081 1/(min.mg) for - 0.59 mm particles. Removal of metal ions in a packed bed column showed that Potamogeton luscens biomass can be used in several sorption/dessorption cycles. After sorbent saturation, copper ions can be recovered from the loaded biomass by elution-with H2SO4, solution. Main mechanism responsible for heavy metal uptake was found to be ion exchange. Results are discussed in terms of the surface properties of the biomaterial, solution chemistry of copper ions and thermodynamics parameters.

Jan 1, 1995

By Moto Goto

Today, Pierce-Smith converters, coupled together with various types of smelting units, are used in most of the world's smelters. However, due to the "batch" processing nature, and problems associated with fugitive emissions during the transfer of melt and blowing stages, this arrangement will unlikely be adopted in future smelters. Modern day alternative processes include the Mitsubishi Process, Outokumpu Flash Smelting and Flash Converting Process, the Noranda Process, and the Ausmelt Process, but only the Mitsubishi Process is a "truly continuous" smelting and converting operation, producing a constant flow of blister without tapping, and is economically proven by long term commercial operations. This paper reviews recent advances in modern continuous converting technologies, with a special section devoted to operation of the "first standalone Mitsubishi C-furnace" coupled together with a Noranda Reactor, at Port Kembla Copper Pty. Ltd. in Australia.

Jan 1, 2003

By Moto Goto

Today, Pierce-Smith converters, coupled together with various types of smelting units, are used in most of the world's smelters, However, due to the "batch" processing nature, and problems associated with fugitive emissions during the transfer of melt and blowing stages, this arrangement will unlikely be adopted in future smelters. Modern day alternative processes include the Mitsubishi Process, Outokumpu Flash Smelting and Flash Converting Process, the Noranda Process, and the Ausmelt Process, but only the Mitsubishi Process is a "truly continuous" smelting and converting operation, producing a constant flow of blister without tapping, and is economically proven by long term commercial operations. This paper reviews recent advances in modern continuous converting technologies, with a special section devoted to operation of the "first standalone Mitsubishi C-furnace" coupled together with a Noranda Reactor, at Port Kembla Copper Pty, Ltd. in Australia.

Jan 1, 2003

By J M. Galvin

History attests to the catastrophic consequences that fire, explosion and contaminated, noxious andirrespirable atmospheres can have for workplace health and safety in underground coal mining. It also confirms that fires and explosions present the greatest risk of partial or total loss of underground mines and equipment and that this risk continues to materialise. The design, implementation, operation and maintenance of the mine ventilation system are core controls for managing the hazards associated with these risks, both for preventing them from materialising and for mitigating their consequences if they do materialise. These are most effective when embedded in a risk management approach.

Oct 12, 2022

By J. E. Dutrizac

Mercury balances have been obtained for the flotation circuits at Pamour Porcupine Mines, Timmins, Ontario, and at Brunswick Mining and Smelting Corporation, Bathurst, New Brunswick. The mineral form of mercury in both deposits has been ascertained. At Pamour Porcupine, the mercury is approximately evenly divided among sphalerite, native silverelectrum and tetrahedrite-tennantite; at Brunswick Mining, this element is contained mostly in the sphalerite, although tetrahedrite (and possibly pyrite) also contains minor quantities.

Jan 1, 1979

By C. A. Pickles

Microwave processing is a relatively new technology that has been successfully applied in a number of industries. However, in the field of metal extraction, there is a paucity of success, despite considerable hype in the early years. Increased reaction rates, lowered reaction temperatures and higher energy efficiencies were some of the advantages claimed. Even with over almost two decades of research and some pilot plant studies, microwave metal extraction remains essentially a laboratory technique. In this paper, the research performed over the last few decades will be reviewed and some reasons for the lack of success in developing microwave metal extraction processes will be discussed. Based on the knowledge gained from these experiences, a more informed view of microwave heating can lead to the realization that there is still some untapped potential for this heating technique in metal extraction processes.

By Bowen Li, Matthew D. Andriese, Jiann-Yang Hwang, Zhiwei Peng

"Magnetic iron sulfide ore particles heat rapidly by microwave (MW) irradiation generating plasma during oxidation of surfaces. The high temperatures produced by the exothermic event decompose local portions of samples forming a differentiated flux of partially melted silicate (si-mt) with entrained metal-sulfide (sul-mt) droplets. The si-mt forms crystals of olivine (01) in Ca-rich pyroxene (Cpx) melt that resorbs a portion of iron sulfide (Po). The immiscible sul-mt droplets of (Fe,Ni,Cu)1-xS contain magnetic subsolidus Ni-pyrrhotite (Ni-Po) with Cr-bearing ferrospinel (Mag). Sub-micron sized flecks of Au are found on the surface of a sul-mt droplet with scanning electron microscope (SEM).IntroductionSulfide ore deposits supply the world's mineral resource in the production of non-ferrous metals. Particularly, Cu-Ni deposits are chemically enriched in metals from high sulfur saturation during magmatic formation that creates the proper geochemical environment for metals enrichment [1, 2]. The sulfur and oxygen fugacity control redox conditions of a differentiated silicate/sulfur magmatic melt with the concentration of iron playing a dominate role in the chemical partitioning of metals in sulfide liquid [3, 4]. The initial magnetic crystallization of (Fe,Ni)i-xS monosulfide solution (mss) from metal-sulfide liquid has an exclusive effect on the fractionation of mineral assemblages (zoning) [5].Phase equilibria of sulfide melt (sul-mt) components are related by a miscibility gap with mss forming Ni-rich pyrrhotite (Ni-Po) followed by the crystallization of (Fe,Cu)1-xS intermediate sulfide solution (iss) [6]. Precious metals form stable chacogenides and are retained in solution until the final liquid solidifies. The redistribution of metals now occurs by subsolidus cooling of mss and iss that exsolve low-temperature Fe-Cu-Ni bearing mineral assemblages [7]. The proper interpretation of ore genesis increases processing capabilities by isolating chemically enriched zones during extraction and should be used to aid in sustainable mine site development [8-11]."

Jan 1, 2013

By T. C. Holmes

Introduction The Dome mine, in the Porcupine mining camp of northern Ontario, is one of the important gold mines of the country, having produced over 139 million dollars worth of gold from the commencement of production in '1910 to the end of 1944. The geology of the mine is complex and a number of types of ore are known, each occurring under particular conditions. The mine workings are very extensive and by far the greater part of them have been geologically mapped only in reconnaissance fashion. By 1940, when the writer joined the mine staff, the orebodies in the sedimentary trough and the 'nose' orebodies, the first types to be developed, were almost worked out and many workings were inaccessible, so the descriptions of these types are based largely on study of the plans and records. The same applies to a lesser extent to some other types. At various places in this paper, statements are made as to the mineralogical or chemical composition of the rocks. Most of these determinations are based on examinations made with a hand lens and cannot, therefore, be regarded as very reliable. General Geology As there are several types of ore in the mine, occurring under quite diverse conditions, a brief outline of the geology is given here, sufficient to provide a general picture into which the fuller descriptions given with each type of ore can be fitted.

Jan 1, 1947

By T. A. Rickard

Slovenliness is as reprehensible in words as in clothes. Much writing that we recognize as poor in style is merely sloppy. Just as some students postpone the necessary shave or forget to change their collars, so young engineers in writing drop their articles, definite and indefinite, or omit prepositions where they are required, possibly to compensate for these they use unnecessarily The work will begin [on] Saturday. The work will begin [on] Saturday. `Influenza seriously affected many mines [during] the last three months. Flotation in America [during] the last two years has made tremendous strides. Construction of the mill started [on] August 12, 1915, at which time 75% of the excavation was completed. The idea I wish to convey is [that] there are mineral deposits to which the present law applies badly. For this reason, if there was [for] no other, the ownership of the ore below and [of] the surface above should go together. When a unit of mapping is furnished, be the unit a claim or [a] group of claims, it is necessary .. . A fully stocked store was started in Park City and all employees [were] sold merchandise on a strictly cost basis. The word "merchandise" is left without government or agreement. I suggest: ". . . and merchandise] was sold to all the employees on a strictly cash basis.". The verb `be' is serving concurrently both as a principal and as an auxiliary in the following: At first the work was interesting and [was] liked by most of the men. The sulphide ore was more complex or [was] milled at an increased cost. The failure to repeat tie auxiliary verb in successive clauses is a common error, as in The filter is filled with liquid allowed to empty, and then ignited.

Jan 1, 1931

By Gregory A. Stephan

A case history of design, prediction, instrumented static load tests on probe piles, installation monitoring, and integrity testing of production piles is presented. Based upon project-specific subsoil conditions, as obtained from several 60 to 80 ft (18.3 to 24.4 m) deep test borings, deep foundation system alternatives included driven concrete and steel pipe piles as well as augered cast-in-place (ACIP) piles. High structural loads, site-specific constraints, and the production time frame mandated by the project owner led to the selection of an ACIP pile foundation system that was designed for a pile capacity of 75 tons (667 kN) in compression and 35 tons (309 kN) in tension. Site-specific concerns were raised about the highly porous nature of fragmented and decomposed sandy limestone as well as the high grout intake during construction that could result in increased foundation cost as well as interconnecting of the piles in the rock layer. Consequentially, a multi-phase ACIP pile evaluation program consisting of instrumented compression pile load tests, in conjunction with single-hole ultrasonic pile testing, pile echo testing (sonic testing), as well as full-time production pile monitoring by an experienced geotechnician was specified. As a result of this testing and evaluation program, while grout usage was determined to be within an acceptable range, the instrumented compression load tests yielded data that allowed use of 55 ft (16.8 m) long ACIP piles in lieu of the original plans to use 70 ft (21.3 m) long precast concrete piles. This information was effectively utilized as part of the overall quality control program to install a total of 268, 14 in. (356 mm) diameter ACIP piles within the building footprint to depths of 55 ft (16.8 m) below the pile cut-off elevation as part of the foundation support system. Information recorded during installation included rate of insertion/extraction of the auger, grout pump strokes and pressure, total grout volume, and grout factors, as well as quality and strength of grout. Additionally, many pre-selected installed piles were tested for integrity with a Pile Integrity Sonic Analyzer (PISA) using both sonic and ultrasonic methods. This engineered, monitored, and tested foundation solution provided an effective and quality intensive basis for completion and approval of the foundation work for the building that resulted in cost savings over other foundation alternatives for the owner.

Jan 1, 1999

By Franc R. Joubin, Donald H. James

"The Algoma (or Blind River) uranium district is centred in an area of some 600 square miles on the north shore of Lake Huron, about half way between Sudbury and Sault Ste. Marie, Ontario (Figure 1). Its favourable location, adjoining the main provincial highway and Canadian Pacific Railway line which follow the lake shore, has contributed greatly to its rapid development.By Canadian standards, the district has long attracted geological attention, beginning with the discovery of the Bruce mine in 1846. It has been repeatedly prospected at intervals since then, chiefly for copper and nickel but also for lead, zinc, cobalt, silver, iron, and gold. Numerous discoveries have prompted the suggestion by Yates (13) and others that one metal-logenic province embraces the entire mineralized area from Michigan through Sudbury and Cobalt.Geological mapping was initiated by Murray in 1847, and the area attracted much interest as the type locality of the Huronian, the correlation and stratigraphic position of which are still not entirely agreed on. Subsequent contributors to the geological literature of the area have been very numerous, and the bibliography at the end of this paper includes only some of the more modern reports.The history of uranium in this part of Ontario also dates from 1847, when J. L. LeConte identified as uranium-bearing a pitchblende-like mineral which he named ""coracite"". The specimens came from Theano Point, north of Sault Ste. Marie. In 1948 a search for the source of these specimens led to the discovery of the Camray uranium field. Occurrences in this field consist of numerous small and locally rich pitchblende-bearing fractures, within or along the contacts of diabase dykes cutting Archaean granite and gneiss.None of the showings explored proved large enough to justify production, but they stimulated prospecting of adjoining areas and thus led to the Algoma discoveries.The first find of radioactive conglomerate in place was made in 1949 in Long township, and it was partially staked as the Fisher-Audette-Breton property. Rusty, overgrown rock-cuts indicated that the pyrite-bearing conglomerate had been investigated years before, probably during searches for base metals and gold. Examinations were made at this time by a number of geologists, including the senior author. In spite of high radioactivity, sampling returned only negligible uranium. The claims were allowed to lapse and the showings reverted to obscurity."

Jan 1, 1949

By Jeffrey Hedenquist

The Lepanto and Victoria epithermal deposits contain in excess of 8 Moz Au, associated with massive enargite-cemented breccia and quartz-carbonate-base metal veins, respectively. The two deposits are separated by 500 m, but the latter was not discovered until the former was nearly mined out. The sulfid assemblages of these adjacent deposits are characterized by high- and intermediate-sulfidation states, respectively. However, gold was introduced after enargite at Lepanto, associated with an assemblage that is similar to that of the Victoria ore. An even larger gold resource is present in similar to that of the Victoria ore. An even larger gold resource is present in the Far Southeast porphyry Cu-Au deposit, the top of which lies 200-400 m beneath and adjacent to these two epithermal deposits.

Apr 24, 2001

By A. E. Sobolev

The kinetics of hydrochemical oxidation of antimonite in solutions of nitric acid was studied using the rotating disk method and the factor experiment design. The dependences of the antimonite?s oxidation rate on concentration of nitric acid solutions, temperature, disk rotation frequency, and duration of interaction were determined. The adequate kinetic models allowing calculating the specific oxidation rate at any combination of the values of the influencing factors were obtained. The oxidation process is found to proceed in a mixed mode, close to chemically controlled. Gradually, as the sediments of elemental sulphur and Sb2O5 accumulate on the disk surface, the process becomes controlled by internal diffusion. The observed high (more than second) order of the oxidation rate with respect to the concentration of nitric acid was explained by the autocatalytic action of the acid reduction products. The apparent activation energy depends on the stage of interaction. At the initial stage (in a mixed mode of the process proceeding), it depends on nitric acid concentration and varies from 31.5 kJ?mol?1 (in 2 M HNO3) to 36.1 kJ?mol?1 (in 10 M HNO3). This trend indicates the weakening of diffusion limitations with a nitric acid concentration increase. When the process is controlled by internal diffusion, the apparent activation energy was found to be 14.5 kJ?mol?1. The obtained kinetic characteristics enlarge the database on hydrochemical oxidation kinetics of sulphides and can be used for the elaboration of the recommendations for the effective comprehensive exploitation of antimony-bearing ores and concentrates.

Jan 1, 2014

By José Adilson de Castro

In this paper a new technology for a compact iron ore sintering machine is analyzed. The compact sintering process is based on the massive injection of gaseous fuels and the solid fuel is only agglomerated fine charcoal obtained by biomass. The solid fuel used in this study is obtained by agglomeration of fine charcoal produced from elephant glass which has very short period for production and CO2 capture(less than 6 months in tropical climate). To overcome the lower heat supply into the combustion front of the sintering process the simultaneous injection of oxygen and gaseous fuel is proposed. The proposed methodology is to combine the solid fuel (agglomerated fines charcoal) and steelworks gases in a compact machine to enhance heat and mass transfer with high productivity (about 5 times the conventional large machine). A multiphase mathematical model based on transport equations of momentum, energy and chemical species coupled with chemical reaction rates and phase transformations is used to analyze the inner process parameters. A base case representing a possible actual industrial operation of the sintering machine is used in order to compare different scenarios of practicable operations which represents advanced operations techniques. The model was used to predict six cases of combined operation with biomass and fuel gas utilization with oxygen support.

Aug 2, 2018

The leaching of gold and silver by ammonium thiosulfate solutions in the presence of copper has been actively studied in recent years. Newmont Gold Company has successfully tested the ammonium thiosulfate for gold extraction following biooxidation pretreatment of low grade refractory carbonaceous/sulfidic ores. In this paper, the chemistry of the copper catalyzed leaching process is reviewed. Factors affecting both the leaching reactions and the stability of the lixiviants are reviewed and discussed from a solution chemistry perspective.

Jan 1, 1996

By Fredrick L. Johnson

In 1987, the U.S. Bureau of Mines began a study of the 4.0 million acre Toiyabe National Forest located in eastern California and western Nevada. This report is a compilation of published, company, and field data for part of the Paradise Range, Nevada. The information is intended to aid the U.S. Forest Service in their long range management of minerals and augment the USBM data base. The Paradise Range study area, located 60 air mi northwest of Tonopah, NV, encompasses about 100,000 acres of which approximately 71,000 are administered by the USFS. The area is in the Basin and Range Province and consists of an east tilted block of sedimentary, metamorphic, and volcanic rocks which have been intruded by granitic rocks. Three major mining districts, the Ellsworth, Gabbs, and Fairplay are in, or extend into the study area. The earliest recorded mining activity occurred in the Ellsworth district in the early 1860's. Commodities produced from the study area include gold, silver, copper, lead, zinc, mercury, tungsten, iron ore, magnesite, and brucite. The Phelps Stokes Iron mine has produced about 1.1 million tons of iron ore, the Baxter-Hancock mine has produced over 10,000 stu WO3, and the Gabbs Brucite-Magnesite mine has produced millions of tons of brucite and magnesite. Numerous other mines have produced, but quantities are relatively small. According to company information the Gabbs mine, currently producing, has brucite-magnesite reserves that will last at least 50 years at current mining rates. One hundred thirty one million tons of identified copper-molybdenum resources exist at the B.C. Springs prospect according to company information, but molybdic oxide (Mo03) prices would need to double or triple from the current $3.00-3.10 per lb before mining of the deposit would be economical. Most company exploration activity in the study area is now focussed on precious metals. Active, or recently active mining claims appear to cover more than one-half of the 100,000 acres studied.

Jan 1, 1991

By A. P. Paiva

The solvent extraction properties exhibited by some /V,N'-tetrasubstituted malonamides to efficiently and selectively recover iron(III) from concentrated chloride leaching solutions can be found in the recent literature. The iron(III) extractive chemistry exhibited by some of these derivatives is revisited, in order to compare their chemistry with that shown by a few of the new malonamide compounds. The generally good extraction efficiency towards Fe(III), from >4 M hydrochloric acid solutions, and the relative ease of Fe(III) stripping by distilled water are remarkable findings that are confirmed for the malonamide derivatives described in this work. Furthermore, additional data regarding their selectivity towards Fe(III) extraction over several base metal ions and their behavior when subjected to successive Fe(III) extraction-stripping tests are also presented and discussed.

Jan 1, 2006

By David Lowell

"The paper point out the cycles of metal prices, and cycles of exploration that tend to lag one year behind metal prices. It appears that mergers and acquisitions are likely to continue in the currentvolatile industry environment, and a two-tier industry will evolve with giantcompanies representing the upper tier and juniors the lower. Strategic alliances will become more common, but irregular and inefficient exploration financing will continue unless the majors make a specific and consistent effort to solve this problem, and also show more discipline in balancing metal prices and production levels. "

Apr 24, 2001