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By Beatriz Dogliani, Elisabeth Williams, Maria Berenice Sandobal, Carina Bertino

The environmental management of steel mill slag should be understood as a management philosophy, observing technical, economic and environmental criteria associated with their generation, storage and final destination. The slag can be considered as a synthetic mineral resource and become a very useful co-product in different areas. The Argentinean steel industry prioritizes the efficient environmental management of its waste, thus contributing to its own survival taking into account the sustainable development. In the world, the slag produced by the steel industry has been used as steel aggregate for road bases, railway ballast and filling material among others. Any factor that influences the economy of the country affects all branches of society, mainly public agencies, whose financial resources are increasingly scarce to deal with all public works. It is necessary to join efforts of private and public initiative in the adoption of alternative materials that replace the use of finite natural resources. This presentation aims to show the work done by private companies together with public bodies and universities to obtain a regulatory document for the management of slag as steel aggregates for three different uses, namely: road use, railway use and general use.

Nov 5, 2019

By Jack Thibodeau

During the past six years, most states have promulgated water quality regulations which contain numerical aquatic life standards for heavy metals. In addition, the Environmental Protection Agency (EPA) promulgated national water quality standards in 1992 which also include numerical aquatic life criteria for heavy metals. Numerous wastewater discharge permits have been issued by the states and EPA to industrial facilities which include low microgram per liter heavy metal limitations. In many instances, the limitations are below detection limits or treatability limits using state-of-the-art analytical methods or treatment technologies. This paper will discuss options for conducting studies, including the use of water-effect ratios, metal partitioning coefficients, and recalculation procedures to develop site-specific metals criteria and higher permit limitations. The installation of expensive metal treatment systems to remove trace metals may be avoided if higher permit limits are indicated by the site-specific studies.

Jan 1, 1996

By Paul Doherty

It is known that the axial capacity of a displacement piles installed in clay varies with time. Consolidation theory suggests that dissipation of porewater pressure set-up during pile installation would lead to increased effective stress and hence higher pile resistance. In recent years a number of case histories have reported time dependent capacity increases for piles installed in sand. Although there is some debate regarding the physical mechanisms controlling this phenomenon, known as ageing, it is unrelated to pore pressure dissipation as piles in sand are installed in primarily drained conditions. A series of field tests designed to investigate ageing effects in soft clay are presented in this paper. Full-scale load tests on 6m long 250 mm square concrete piles, which were driven into soft clay are described. The piles were first tested approximately 100 days after installation, at which stage full equalization of the excess pore pressures had occurred. Static load tests were then performed up to 10 years after pile installation. The piles exhibited significant ageing, with their shaft resistance increasing by up to 66% over a 10 year period. Possible mechanisms for such aging characteristics are explored.

Jan 1, 2011

By Sheldon P. Wimpfen

Back in 1970 Congress passed the National Mining and Minerals policy Act, which had as one of its basic tenets to rely on a strong and stable private minerals industry for the development and production of our mineral resources. Since then, a substantial amount of legislation has been introduced that impacts on the minerals industry. Although most of the bills proposed are not passed into law, each bill affecting minerals and mining is given careful review by the Bureau of Mines. Comment is forwarded with the object of being helpful to legislators by providing our assessment of the probable impact of each bill proposed along with suggestions to improve them. Actually few bills introduced become law. For example, in the 93rd Congress 4,260 bills were introduced in the Senate and 17,690 in the House. In the final accounting there were passed 123 private laws and 649 public, 3 percent of the bills introduced. There would be little merit here in attempting to analyze each mineral-related bill that was proposed. Many are similar and aim at making a certain aspect of our minerals activity fit needs. So, to simplify the task the many bills have been grouped by subjects. Slide 1 shows the principal topics and the number of related bills introduced. Putting it altogether, there are 26 principal subjects and almost 200 bills. And these numbers are probably off somewhat, as this accounting was made early in December.

Jan 1, 1976

During the second quarter of 1983, the economic recovery showed further strength abetted by the performances of consumer spending, residential investment, and the slowing down of inventory reductions. Real gross national product (GNP) increased from the first to second quarter at an annual rate of 9.2 percent, compared with 2.6 percent from the fourth quarter of 1982 to the first quarter of 1983 and an overall 1.9- percent decrease in 1982. Total industrial production increased 1.8 percent in July, and productivity as measured by output per man-hour increased 1.3 percent between 1982 and the first quarter of 1983 (table 1). Especially noteworthy .was the performance of real consumer durable goods expenditures, which increased at an annual rate of 32.0 percent from the first to the second quarter (about half of the increase consisted of automobile sales) and real consumer spending, which increased between these periods at an annual rate of 9.7 percent. Residential investment increased at an annual rate of 76.1 percent between the first and the second quarters,1/ and private housing starts by about 38,000 units in both March and May.

Jan 1, 1983

By M. A. Schimmelpfennig, A. D. S. Gillies

Loss of visibility due to the occurrence of atmospheric fogging in underground mine airways can lead to longer travel times and loss of production efficiency, an increase in the frequency of vehicular and foot traffic accidents and difficulty in checking rock surfaces for instability and loose material. Where hot and humid surface air meets colder underground air, conditions for fog formation may be present. Further, suspended particulate matter from diesel exhausts or stoping operations together with slow movement of air along passageways may contribute to formation. This study describes an investigation being undertaken with the cooperation of Kennecott's Ozark Lead Co. to identify causes of the problem.

Jan 1, 1984

By A. Idegami, M. Imamura, S. Heguri, Y. Ozaki

"Nickel powder can be produced by the reduction of a nickel ammine complex solution by hydrogen at high temperature and pressure. To minimize the deposition of fine nickel on the surface of the reactor and other equipment, seed crystals are added to the initial solution to promote nucleation of the nickel powder. Such seed crystals catalyze the precipitation of the nickel particles on the surface of the seed and enhance grain growth. In this study, nickel nuclei were precipitated by the addition of a polymer to the nickel ammine complex solution, resulting in the production of nickel powder. Thus, we herein propose a model that explains the effect of the polymer in the precipitation of nickel nuclei.INTRODUCTIONNickel powder is commonly produced via a hydrometallurgical process from the hydrogen reduction of a solution containing a nickel ammine complex at high temperatures and pressures, and this process was commercialized in the 1950s by Sherritt Gordon (Sherritt International, Canada, Benson & Colvin,1973; The Staff, Research and Development Division, Sherritt Gordon Mines, Ltd., 1958).In the above transformation, upon the injection of hydrogen gas into the solution, nickel is reduced as outlined in Equation(1), ultimately resulting in the production of nickel powder.Ni(NH3)nSO4+ H2?Ni+ (NH4)2SO4+ (n-2)NH3(n:2–6)(1)In this process, seed crystals are added to the reactor to suppress the precipitation of fine nickel (scaling) and to enhance nickel reduction (Benson & Colvin, 1973; Mackiw, Lin & Kunda, 1957). More specifically, iron sulfate and a small amount of dispersant polymer are added, which leads to the formation of nuclei. Upon subsequent hydrogen reduction, the reduced nickel can then be deposited on the nuclei, allowing nickel particle growth to take place. However, this results in iron contamination in the final nickel product, and so the use of pure nickel as a seed crystal is desirable to produce high quality nickel powders."

Jan 1, 2017

By ELLSIVOKTH DAGGETT

THE Berlin gold quartz mine is situated in Nye county, Nevada, on the west flank of the Shoshone range, about 40 miles south and 30 miles west from the town of Austin, the county-seat of Lander county. The distance from Austin is about 60 miles by stage-road. The outcrop of the vein, at the top of the incline-shaft, is situated just at the base of the mountain proper, almost exactly at the intersection of the mountain-side with the gravelly bench that slopes for about three-quarters of a mile to the flatter sage-brush plain, or desert valley, below. The -vein itself consists almost entirely of quartz, with perhaps 2 per cent. of sulphide of iron, copper, lead, zinc and antimony, and perhaps a trace of some of the compounds of tellurium with gold and silver, although none of the latter have been as yet positively identified. The relative proportion, by weight, of silver and gold in the ores, varies in different parts of the vein, from 12 silver for 1 of gold, to 7 silver for 1 of gold. The quartz vein-filling is usually frozen fast to the walls, and is very hard and compact, seldom showing the friable, fissured, or shelly structure often to be found in quartz veins. Comparatively little evidence of relative motion of one wall of the vein upon the other is to be found-a fact indicating that during the formation of the vein, and prior to the extensive movements herein described, little disturbance had taken place. No evidence whatever of metasomatic origin has been observed. On the other hand, occasional occurrences of comby structure, in which the axes of the quartz crystals are at right angles to the plane of the vein, rather indicate deposition from solution in a pre-existing fissure. Spurs, or branches, and small parallel veins, while not en-\

Mar 1, 1907

By A. Galvan

High rate compressible media filter (CMF) tests produced exceptional total suspended solids (TSS) removal at hydraulic loading rates ranging from 97.8 to 122.2 m/h. The compressible media is manufactured from a robust resin fiber that can withstand low pH and temperatures up to 149 °C. The media porosity can be varied by applying compression onto the media. At 40% compression, the CMF can remove particles greater than 4 μ. Three synthetic test-samples were generated by Hazen Research Inc., (Golden, Colorado) to simulate the copper Pregnant Leach Solution (PLS), Raffinate and Electrolyte solutions used for the testwork conducted at their facility. The preliminary results showed that the CMF was very effective in removing TSS without the use of chemical conditioning from the above test-solutions with efficiencies of 98%, 97%, and 96%, respectively. Given the remarkably high hydraulic loading rates, the industrial equipment footprint would be minimized appreciably over conventional clarification and alternative filtration systems.

By Hao Deng, Hongmin Zhu, Jichao Li, Kai Huang

"Silicon and silicon carbide mixing micropowders obtained from the saw cutting industry of polycrystalline silicon ingot is separated by a simple sequential sedimentation. The Zeta potentials of the powders in the aqueous suspension are adjusted by varying the pHs with dilute acid or alkaline reagents. The dispersion and aggregation content of the microparticles is significantly influenced by pHs, and so their settlement velocity in the same hydraulic conditions are quite different, and silicon powders tend to suspend in the upper section of the suspension for its finer size and smaller density under the stronger Zeta potential repulsion force. The original content of the cutting powders with 30%wt silicon are separated into the Si-rich and SiC-rich powder respectively, and 62%wt Si-rich powder can be obtained after 4 times of sedimentation under pH = 8.0, showing the great potential for Si and SiC powder separation and recovery in a cost-effective way.IntroductionWith the fast development of photovoltaic (PV) technology these years, the market demand for the solar-grade high pure silicon material significantly increased, making the silicon recycling and recovery from the wire sawing slurry profitable and attractive[1]. Waste silicon slurry was produced in the multi-wire sawing process of a silicon ingot by using an ethylene glycol-based solution and silicon carbide abrasives as the slicing system. During this slicing process, about 30% of the silicon ingot will become the waste as the fine particles suspended in the slurry, which mainly consists of silicon kerf-loss particles, SiC fragmental particles, tiny iron fragments from the worn sawing wire and ethylene glycol-based solution [2]. The separation of above individual component is usually easy except for Si and SiC fine particles for their quite similar properties. So the biggest challenge for the effective recovery and recycling of silicon particles from the wire sawing slurry actually lies in the mutual separation of silicon and silicon carbide particles."

Jan 1, 2012

By Shoji Taniguchi, Lifeng Zhang, Kaike Cai

"In the present paper, based on the two-phase (Eulerian-Eulerian) model, the 3D fluid flows in gas-stirred systems, i.e., air-stirred water vessel and argon-stirred liquid steel ladle, are simulated. In the Eulerian-Eulerian two-phase model, gas and liquid are considered to be two different continuous fields. The phases are assumed to share space in proportion to their volume fractions. The exchange between the phases is represented by source terms in conversation equations. Turbulence simulated by the k- e model is assumed to be the property of the liquid phase. The following effects of mathematical treatments and operational factors on the fluid flow are discussed, such as interphase drag force, turbulent model, the size of bubble, and gas injection mode.Some interesting results are derived. Except the interphase drag force, the interphase lift force should be taken into accounted in order to exactly simulate the fluid flow in gas-stirred systems. Suitable turbulent model and drag coefficient have effect on the mathematical simulation. Injecting small bubbles can realize a well mixing flow condition. The distance between the two gas-injection nozzles has effect on the fluid flow."

Jan 1, 2000

By J. Armanet

THREE MINING colleges are maintained in France; the École Nationale Supérieure des Mines, of Paris; École Nationale Supérieure des Mines, of Saint Etienne; and the École Supérieure de la Metallurgie et des Mines at Nancy. Besides graduates of these schools, a few graduates of the École Centrale des Arts et MIanufactures and of the École Polytechnique are employed as ]nine managers or engineers; however, most of the latter have taken a graduate course at one of the mining schools.

Jan 1, 1939

By FLOYD T. TAYLOR

IN 1833, less than one hundred years ago, Michael Faraday discovered and stated the laws of electrolysis. His discovery formed the foundation of a new use of metals which has now reached a variety of application not ordinarily appreciated. Furthermore, things can be done with electro-deposited coatings which have thus far defied other methods. Some of the uses of electro-deposited coatings are interesting. The tonnage of metals already finding an outlet through such a channel is considerable. In general electro-deposits have two characteristics: ornament plus utility; utility plus ornament. Both these factors are usually found associated in electro- deposits. Ornament plus utility was probably the first use. For example, the silver-plating of tableware, having its real birth in Birmingham, England, about 1844. However, this same ornament plus utility retarded the development of electro-plating, because in the beginning, electro-plated articles were branded with the odium of imitation and shunned accordingly. The gold brick of the swindler may be an exception to this statement.

Jan 1, 1929

By V. A. Feofanov

Technogenic water of ore mining enterprises, nonferrous metals operations, the enterprises of electroplating and instrument making, containing copper in the form of those or other connections can serve as perspective sources on receiving the copper-bearing raw material. Extraction of copper from the given water also solves a problem of water treating from a toxic component that reduces environmental load at evacuation of water in an open basin. The method of case hardening allows extracting copper selectively with reception of a deposit with the content of copper up to 70%. Weakness of the method is its efficiency basically in acid reduction, and also its low degree of copper extraction. On the basis of case hardening the method of galvanic coagulation is devised. It is based on the work of a short-circuited galvanic cell of iron-coke at variable contact of coupled metals components among themselves, cleared by the oxygen of air. The following processes of galvanic coagulation are considered: ? Extraction of copper; ? Formation ferrites of copper; ? Copper sorption on just-aggregated oxide forms of iron. Establishing conditions for passing the given stages provides an opportunity of copper extraction from technogenic water at any value of ??, content of salt and concentration of copper with reception of a compact deposit from which it is possible to extract copper by the known ways of enrichment and metallurgy. Investigations on optimization and intensification of galvanic coagulation with the purpose of reception the maximum rich deposit on copper have shown that the average contents of copper in a solution of 100~200 mg/dm3 the contents of copper in a deposit is 6%~10% at extraction 85%~90%, depending on characteristics of treated technogenic water. Using methods of scanning microscopy it is determined structures, composition and mechanism of phase formation in investigated electro-chemical process. The second stage of galvanic coagulation increases a degree of copper extraction up to 98%~99% that allows returning the cleared waters in circulation for waste recycling or evacuation in an open basin. Nowadays the method of galvanic coagulation is the most acceptable for copper extraction from technogenic water both from the point of view of efficiency and instrument setting that allows applying the method in conditions of the working enterprises.

Jan 1, 2014

By Esam Abraham

A 13.6 mile portion of the 500 kV Tehachapi Renewable Transmission Project crosses the mountains of the Angeles National Forest. Access and environmental constraints precluded road development for most transmission tower foundations, tower erection and conductor stringing operations. Because of the access constraints, helicopter-supported micropile foundation construction was used for this steep and environmentally sensitive portion of the project. The general methodologies incorporated on the project represent innovative implementations of micropile design criteria, preconstruction micropile installation and verification testing, on-site geotechnical characterization, micropile and pile cap installation, and proof load testing. Challenges in constructing the 224 foundations for 56 transmission towers provide lessons learned related to transmission lattice steel tower specific design constraints, construction challenges (environmental and geotechnical), and construction schedule.

Jan 1, 2010

By Boyd Davis, Vladimiros Papangelakis, Joshua LaMarre, Jan de Bakker

"HCl leaching using molten salt hydrates has the potential to improve the extraction of nickel from laterite ores. However, as in other HCl leaching applications, recovery of HCl is key to process economics. Spray pyrohydrolysis, which is used in current chloride-based flowsheets, is associated with a high energy cost. The authors have developed a proposed laterite leach circuit using an alternative HCl recovery route. The leach circuit envisions a leach by concentrated (33%) HCl in an MgCl2 molten salt hydrate (MSH) or brine medium, followed by Ni/Co recovery and iron precipitation. Magnesium and chloride are precipitated from solution as magnesium hydroxychloride; this hydroxychloride is thermally decomposed to produce HCl gas. The proposed flowsheet employs a chloride leach circuit with simpler equipment and lower energy cost than in the conventional practice of pyrohydrolysis. Laboratory work investigated key aspects of the flowsheet, including precipitation of magnesium hydroxychlorides and their composition; magnesium hydroxychloride thermal decomposition; and iron control.Introduction As sulphide nickel ores become harder to mine and more complex to process, laterite ores will increase in importance. Laterite ore deposits can be divided into two main mineralogies. Limonite ores consist mostly of hydrated iron oxide, FeOOH, with 1-3% nickel substituting for the iron. Saprolite ores consist of iron-magnesium silicates, (Fe, Mg)2Si04, again with some nickel substituting for the metal ions. Limonite ores can be treated using the HP AL (High Pressure Acid Leach) process, in which the ore is reacted with sulphuric acid at high temperature in an autoclave. HP AL, however, cannot in general be used to treat saprolite ores because the magnesium enters solution and consumes sulphuric acid, which results in excessive spending on lixiviant. It is therefore desirable to find a hydrometallurgical process specifically for saprolite ores that can provide better results than the treatment options currently available."

Jan 1, 2011

By L. F. Willmott

The Bureau of Nines at Morgantown, W. Va., has been investigating, on a pilot plant scale, various methods of gasifying bituminous coal with oxygen and superheated steam to produce synthesis gas, as part of the broader program of finding new uses for coal. Differences in the pressure gasification methods used have depended on differences in the manner in which the pulverized coal is fed to the gasifier. One of the methods of feeding the coal that was investigated was the continuous, integrated coal-water slurry system. Goal and water were first mixed to produce a slurry; then the slurry was pumped through a heated coil. to evaporate the water fraction; the resulting steam was superheated, and some of it was separated so as to adjust the ratio of the residual steam to the coal fraction and make the resulting mixture suitable for partial combustion with oxygen in a pressure gasifier. Both before and during this reported3 developmental work it was necessary to make an extensive literature search into the technology of aqueous slurries in order to establish design criteria for the pilot plant and to correlate results of various phases of the work with that of other investigators, The pilot work coincided with the commercial development of a long-distance pipe- line for the transportation of coal as a coal-water slurry, and this fact tended to broaden the scope of the pilot plant work and the extent of the literature search. This bibliography is the compilation of the material that was collected.

Jan 1, 1963

By L. F. Willmott

The Bureau of Mines at Morgantown, W. Va., has been investigating, on a pilot plant scale, various methods of gasifying bituminous coal with oxygen and superheated steam to produce synthesis gas, as part of the broader program of finding new uses for coal. Differences in the pressure gasification methods used have depended on differences in the manner in which the pulverized coal is fed to the gasifier. One of the methods of feeding the coal that was investigated was the continuous, integrated coal-water slurry system. Goal and water were first mixed to produce a slurry; then the slurry was pumped through a heated coil. to evaporate the water fraction; the resulting steam was superheated, and some of it was separated so as to adjust the ratio of the residual steam to the coal fraction and make the resulting mixture suitable for partial combustion with oxygen in a pressure gasifier. Both before and during this reported3 developmental work it was necessary to make an extensive literature search into the technology of aqueous slurries in order to establish design criteria for the pilot plant and to correlate results of various phases of the work with that of other investigators, The pilot work coincided with the commercial development of a long-distance pipeline for the transportation of coal as a coal-water slurry, and this fact tended to broaden the scope of the pilot plant work and the extent of the literature search. This bibliography is the compilation of the material that was collected.

Jan 1, 1963

By T. E. Wilson

In conjunction with experiments to improve the particle size preparation of coal bore cores prior to washability testing, discrete-event breakage of coal, shale and homogeneous low-strength concrete cores was studied. Breakage of individual size classes by drop-shatter and by incremental tumbling in an end-over-end hand-driven tumbling cylinder revealed systematic changes in the breakage function, namely, that breakage in any size class diminishes as the number of events increases. The effect of the fines removal enhances the breakage of harder material (having lower grindability indices), but appears to have less effect for softer material.

Jan 1, 1998

By Michelia Alba, Ronaldo S. Sampaio, Davi S. Braga, Mathieu Dubé

Climate change is pressuring industries and governments for decarbonization commitments, research, testing, and use of best practices to achieve the target of global warming below 1.5/2 °C. As it accounts for as much as 7% of all global CO2 emissions and 7% of energy consumption, the steel sector needs to address this issue with extended efforts. This paper provides information on the key potential of renewable biochar as an alternative fuel for pellet production. It also summarizes the successful application of biochar in a pioneering case study as the main fuel for a Grate-kiln pellet plant in Brazil, as well as the study of its use to replace coke and anthracite as an additive for iron ore pellets and other possible applications in the steel industry in COREM's precompetitive research & innovation program. The final discussion reveals the large quantity of biochar required by the Brazilian and Quebec scenarios for reducing CO2 emissions of iron ore pelletizing plants.

Jan 1, 2023