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By R. Mensah-Biney

The kinetics of gold-bromide loading onto activated carbon has been investigated in a batch stirred reactor. The amount of gold adsorbed by the carbon was correlated with time based on a second-order equation. The rate constant for gold-bromide species onto activated carbon ranged from 0.27 to 1.2 x 10-3 (kg/t)-l(min)-l from a solution containing 25 ppm of Au, with 0.8 g carbon per liter of solution at 30° C. The equilibrium saturation capacity (Q.) was 36±3.0 kg/t from the same system. The rate of loading increased with decreasing particle size, decreasing pH, increasing temperature, and decreasing concentration of gold in solution. The calculated activation energy E. was 8.8 kcal/mole, significantly higher than those reported for physical adsorption. The equilibrium saturation capacity (Q.) increased with increasing concentration of gold in solution, but was independent of other variables such as temperature, agitation speed, particle size and pH. These rate constants and equilibrium saturation capacity for the gold-bromide species are higher than those reported for the gold-cyanide systems.

Jan 1, 1996

By Ata Akcil, Z. B. Karshigina, Ye. G. Bochevskaya, E. A. Sargelova, Z. S. Abisheva

Phosphorus slag is one of the most large-tonnage of yellow phosphorus production waste, which for decades stored in the slag disposal, by polluting the environment and creating environmental problems in the regions. Phosphorus slags from the processing of Karatau phosphorites are a very promising source of raw materials not only for silicon compounds but also rare earth metals (REM). Among the REM, yttrium, neodymium, europium and lutetium predominate, which are relevant to high-tech industries. The report presents technological scheme of complex processing of slags of phosphoric production with obtaining of REM concentrate and precipitated silicon dioxide ("white soot"). The regime parameters of the main operations of the technology are determined: I stage- leaching of slag with nitric acid solution; extraction of the REM-containing solution with tributyl phosphate and stripping of the REM with water; settling of solution of salts of oxalic acid, calcining the precipitate to obtain a concentrate S REM oxides and II stage of leaching silicon cake to obtain "white soot". Recovery of S REM from slags of phosphoric production on various redistribution has made, %: leaching – 95.0; extraction - 90.2; extraction on the average ~ 93.2; the production of a concentrate of REM oxide is 93.9. A concentrate containing 17.3 % of REM oxides was obtained. According to X-ray analysis it contains the following phases: calcium oxide, portlandite2, gadolinium oxide and yttrium, gadolinium oxide, gadolinium oxide and cerium, neodymium oxide, neodymium oxide and cerium. Thus, the concentrate can serve as a raw material for the production of individual rare-earth metals like gadolinium, cerium, yttrium and neodymium. After performing the II stage of leaching siliceous cake with nitric acid the samples of "white soot" were obtained. Its chemical composition corresponds to the state standard and has a specific surface area equal to 180 - 200 m2/g. The technology has been tested in a large-scale laboratory scale and will solve the problem of complex processing of phosphorus raw materials and import substitution in Kazakhstan. The end-to-end recovery of S REM oxides and silicon into concentrate and product from their initial content in slags is ~ 75.0 and 98.0 %, respectively.

Jan 1, 2018

By Kikuo Okuyama, I. Wuled Lenggoro, Manabu Shimada

"Aerosol processing of materials such as (i) gas-to-particle conversion process (e.g., Chemical Vapor Deposition (CVD) method) and (ii) liquid (or droplet)-to-particle conversion process (e.g., spray pyrolysis) has become of major interest to produce novel submicron- or nanometer-sized particulate material used in electronic and chemical industries. After reviewing recent theoretical and experimental researches on the evaluation of properties and morphology of fine particles by the CVD and spray pyrolysis methods, the importance of the process engineering approach· for aerosol processing of materials and the use of advanced aerosol measurement technology have been pointed out.IntroductionMaterial synthesis via aerosol processing offers a route to producing nanometer-sized and submicrometer-sized particles of high purity with specifically tailored chemical and physical properties. Especially, single nanometer-sized particles (nanoparticle materials) are considered to play an important role in the synthesis of nanostructured materials as well as in nanotechnology in 21st century due to their quantum effect and so on.However, the transformation of gaseous or liquid precursors to the final functional particulate matters consists of various complex chemical and physical processes. In order to control the size distribution and morphology of produced particles, it is important to analyze and model various phenomena, such as gas-phase or liquid-phase chemical reaction, nucleation, condensation, agglomeration and sintering that occur simultaneously in aerosol material processing. By introducing the Aerosol Science and Materials Science, the authors have been trying to model the changes in particle properties and morphology by gas-to-particle conversion and droplet-to-particle conversion processes. The authors have also been trying to obtain the experimental data on the particles properties as accurate as possible."

Jan 1, 2000

Jan 1, 2002

By Juan L. Yarmuch, Gonzalo Sepulveda

Medium- and short-term mine planning holds immense significance in optimizing production and resource utilization. It serves as a vital link between the long-term strategic plans and the day-to-day operational activities of a mine. In this context, a mathematical formulation is proposed to incorporate mining width constraints into the production scheduling process, aiming to maximize the net present value (NPV) of the schedule while ensuring enough room for the operation of mining equipment.

Jul 1, 2024

By M. J. Collins

A hydrometallurgical process has been tested at the Sherritt Research Centre for separation of zinc, lead, copper and precious metal values from the zinc oxide fume leach residue stockpiled at the HBM&S operations in Flin Flon, Manitoba. Zinc is found primarily as zinc femte and sphalerite in the residue, lead as lead sulphate and jarosite, and copper as sulphide and jarositic compounds. Gypsum and siliceous gangue are significant diluents. The separation process includes hot acid, atmospheric and reducing (sulphur dioxide) leaching; zinc, copper and lead flotation; and atmospheric iron removal steps. Zinc is recovered to a high strength zinc sulphate solution and to a zinc sulphide concentrate suitable for feed to a roaster or to a zinc pressure leach plant; lead to a high grade lead sulphate concentrate suitable for feed to a lead smelter, and copper to a high grade copper sulphide concentrate suitable for feed to a copper smelter. Precious metals are divided between the zinc, lead and copper concentrates.

Jan 1, 1993

By R. Perlo

"INTRODUCTION Peoples’ and operators’ safety in construction are tightly linked to the engineering choices, as much as the necessity of reducing time and costs of realization. Therefore, it is of paramount importance to address them properly from the earliest stage of the design, identifying the risks connected to the work and the variability of such during the different phases of the project. Risk is often measured as the expected value of an undesirable outcome. Regarding to occupational safety and health, the risk is the likelihood that a person may be harmed of suffers adverse health effects if exposed to a hazard. This combines the probabilities of various possible events and the assessment of the corresponding harm into a single value. However, the actual occurrences are often more complex than a single binary possibility case. In a real case scenario, with several possible accidents, the total risk is the sum of the risks for each different accident, provided that the outcomes are comparable. The semi-automatic tunnel support system along with its erector machine proved to be a solution with improved structural performance, able to reduce the time and yet to deliver an enhanced, quality-aware and safer working environment for the operators. The implementation of the system provides the engineers, the contractors and the owners with an effective alternative option shortlisted in 2015 for the ITA Award for the Safety Innovation of the Year. In a market industry driven by safety and time constrains the efficiency shall be the ultimate goal, in order to provide solutions able to negotiate with the most challenging ground conditions. In this paper, the authors describe the recent developments on regard of this whole new tunnel support system, including design approach and presenting related case histories OFFSETTING THE RISKS Considering the above factors, from the manufacturers’ point of view, an effective way to limit the construction risks is to focus on the material and technological characteristics, their application and the risks related to them including any residual risks. Finally addressing the construction needs also involves time and cost-effective solutions. The path to follow is an integrated approach where the efficient management of the risk is supported by a flexible, user-friendly, and time effective product that is able to provide a safe, reliable and viable solution to address the construction requirements. Therefore, in a market sector driven by safety and time constraints, the efficiency is a key goal, in order to avoid redundancy and yet to deliver a safe working environment able to meet the construction schedule. The safety of all the parties involved is given by stable working conditions, either for the workers, or the operators and eventually the public. Therefore, the solutions provided should ‘strengthen’ the overall condition and such “to limit or to reduce the deformations within acceptable designed limits and to prevent [the tunnel] to collapse” [1: Clause 207.1.4]."

Jan 1, 2018

Due to complex mineralogical and chemical interactions of the value and gangue mineral phases present in uranium-containing lateritic ores, deleterious pulp gelation which impacts on value metal recovery sometimes occur during atmospheric leaching. In this study, the leaching behavior and particle interactions of selected oxide (hematite, quartz) and clay minerals (muscovite, chlorite), which constitute predominant host gangue phases of typical lateritic uranium ores are investigated to provide basic, mechanistic understanding of temporal pulp gelation phenomenon. Isothermal, batch leaching with H2SO4 was carried out on concentrated dispersions (30 ? 57 wt.%) of single minerals at pH 1 and 25 or 70 °C and their concomitant solution, speciation and rheology (shear yield stress, viscosity) were characterized. It is clearly shown that despite the high oxide content of lateritic ores, the pulp chemistry and rheology is largely affected by the incongruent leaching behavior of more reactive, acid-consuming aluminosilicate clays. Furthermore, time- and temperature-dependent alumino-silicate species polycondensation interfacial reactions are shown to be responsible for the enhanced particle interactions, reflecting strong pulp rheology in agitation and pumping. If not properly mitigated, high pulp shear yield stress and viscosity have a striking impact on processability and hence, value metal recovery.

Sep 1, 2012

By QUANWEN PU, Yonggang Wei, Bo Li

With the advancement of industrial science and technology, more and more catalysts are used. The spent catalysts produced are solid waste products, which cause environmental pollution if they are not treated. At the same time, the spent catalysts contain some precious metals such as platinum in concentrations that are often higher than in their ore resources. Therefore, the recovery of valuable metals in spent catalysts is a hot research topic at present. However, due to the complex structure of the spent catalysts, dealing with them is a lengthy process. The first step of recovery, enrichment of the spent catalyst, becomes particularly important. In this paper, a pressure solution method is investigated for this purpose, in which the alumina carrier is dissolved and platinum is enriched in the leaching residue.

By Zhucheng Huang, Lingyun Yi, Bin Chai, Tao Jiang

"A high iron content manganese ore was reduced at 900~1200°C and followed by a magnetic separation process. SEM and EDS analyzes were employed to examine the transformation of microstructure and phase in reduced sample and the mechanism was revealed. Results showed that elements enriched during reduction. Iron existed in the metal iron phase and most of oxygen formed compound with manganese. Consequently a clear distinguish between iron phase and manganese minerals formed, which was beneficial to the separation of iron and manganese. But the iron phase can not be monomer dissociation in grinding process and manganese compounds turned into magnetic product as package and mechanic inclusion due to the isomorphism of iron and manganese and the small particle size. And MnO could be found partially in iron phase, which hindered the further separation of manganese and iron.IntroductionManganese is widely used in industry. The amount of manganese used in steel industry is very huge and 90% manganese is used in steel industry. Manganese ore resources are rich in China, yet with fewer rich ore but more low-grade ore which accounts for 93.6% and fine refractory ore. The constitution of the ore is very complex and more than 73% of all the manganese ore contains iron[l,2]. With the increasing of consumption of steel, the demand for manganese is becoming larger and larger and the imported ore accounts for more than 50%. Therefore, how to use the manganese ore efficiently has very significant meaning. The main method is manganese residual, which is simple and stable. However, the development of the method is limited by the quality of manganese ore, the huge amount of manganese residual, the technology of blast furnace process and economics[3,4]. Chemical benefication which may pollute environment and is difficult to recover iron is still being researched[5,6]. The paper investigated the process in which anthracite coal was the reducing agent for coal-based direct reduction and magnetic separation of the ore, and SEM with EDS measurements were employed to examine the transformation of phase in reduced sample and the mechanism was revealed[7,8]."

Jan 1, 2013

By I R. F MacCulloch

Bacterial oxidation of sulfide minerals is a familiar and commercially available process to enhance gold recovery with problem ores. Pintail Systems, a Colorado, USA based company had developed bio-processes for gold recovery based on natural mineral formation and transformation in a global mineral cycle. The biological recovery of precious metals from ore involves a number of mechanisms that are dependent on the metal-mineralogical association. These processes include: partial bio-oxidation of sulfide ores; oxidation of gangue minerals exposing gold to leaching; surfactant properties of bacteria/nutrient solutions that improve wettability of ores and solution contact with leachable gold and silver; and microbial production and excretion of trace amounts of gold lixiviants, and bio-fracturing or biological alteration of ore minerals. Pintail has demonstrated enhanced recovery of precious metals during cyanide detoxification of spent heaps at the end of mine life. Biological recovery processes also have the potential to be applied to in situ mining technologies. The in situ process application could recover gold from subgrade deposits, small deposits or those ore bodies with uneconomic stripping ratios for conventional mining. In situ biomining can be accomplished at a fraction of the cost of conventional mining and leaching and does not have the environmental liabilities associated with many conventional gold lixiviants.

Jan 1, 2004

By Marco Olper

Zinc bearing materials containing chlorides and fluorides of alkali metals, such as EAF dust, Waelz oxides, galvanizing ashes, zinc & brass foundry fumes and converter fumes are little attractive, both technically and economically for processing in ISF plant or in a conventional zinc sulphate electrolysis works. The Ezinexm Process allows for the recovery of high purity zinc in cathode form, from these materials, regenerating the leaching liquor. The process is based on a new electrochemical system which depolarizes the anode reaction with reduction of the cell voltage, compared with the traditional sulphate electrolysis method. The electrolyte, based on a chloroamrnino complex, allows for the recovery of other valued metals present in the zinc bearing materials such as lead, copper and silver, these being recovered as a metallic cement consequently improving the economics of the process.

Jan 1, 1994

Minerals are a fundamental component of the Nation" material and economic base. Without a continuous supply of minerals to meet growing and changing needs, the basic character of our society would be very different. The importance of minerals to the United States was reemphasized by the Congress in I970 when it enacted the Mining and Minerals Policy Act, which stated that it is the continuing policy of the Federal Government in the national interest to foster and encourage private enterprise in (I) the development of economically sound and stable domestic mining, minerals, metal and mineral reclamation industries, (2) the orderly and economic development of domestic mineral resources, reserves, and reclamation of metals and minerals to help assure satisfaction of industrial, security and environmental needs, (3) mining, mineral, and metallurgical research, including the use and recycling of scrap to promote the wise and efficient use of our natural and reclaimable mineral recources, and (4) the study and development of methods for the disposal, control, and reclamation of mineral waste products, and the reclamation of mined land, so as to lessen any adverse impact of mineral extraction and processing upon the physical environment that may result from mining or mineral activities.,.

Jan 1, 1977

The adsorption of gold onto activated carbon in iodide solutions has been studied. The adsorption rates were determined as a function of temperature, salt concentration and pH as well as activated carbon concentration. A kinetic model was also developed for the adsorption. The adsorption rate was believed to be controlled by a mixed mechanism of film diffusion and pore diffusion, but the film diffusion had a major contribution to the overall rate. Experimental findings were in good agreement with the model developed. The apparent activation energy was found to be 14.9 kJ/mol.

Jan 1, 1993

By W. S. Morris

PETROLEUM'S importance in World War II can perhaps be better realized by the recitation of a few facts and figures: Gasoline needs in this war are already eighty times greater than in the last war. It takes nearly three pounds of gasoline to deliver one pound of bombs, filled with petroleum explosives, on an enemy objective. Every American soldier overseas requires an average of more than fifty gallons of petroleum products per week, with the oil used by Navy and supply ships and America's Allies boosting the consumption of oil per soldier to an even higher figure. Every oil well in the United States now must produce each day an average of four barrels of oil for war and combat jobs. More than fifty million gallons of gasoline, fuel oils, lubricants, and other petroleum products are now going directly to the fighting forces every day.

Jan 1, 1945

By James M. Barker

Industrial minerals are critical to most aspects of modern society. They are pervasive in both industry and in everyone's lives (McVey, 1989; Barsotti, 1993). They are also the dominant class of minerals produced in the United States but this fact is little known outside the industry. For example, in 1993 (U.S. Bureau of Mines, 1995, table 1) industrial mineral dollar value was double that of metals ($20.86 billion vs. $10.88 billion) and employment levels were nearly so (74,000 vs. 40,000). A further difference is that transportation tends to dominate production costs (FOB end user) whereas they are much less significant in other mining ventures or other industries. Finally, metal mines are more concentrated west of the Mississippi; industrial mineral operations are more prevalent to the east (U.S. Bureau of Mines, 1995, p. 16-17). The significance of transport cost is discussed in Part 2, which is essentially Barker and Austin, 1995. Part 1 will update and expand portions of Barker and Austin (1995) and provide a more detailed discussion of import/export relationships using a China/United States reference point because of China's dramatic influence on some industrial mineral markets since the mid-1980s (barite, etc.).

Jan 1, 1996

By D. G. Foot

The Bureau of Mines investigated energy-efficient methods for recovering potash values from process and waste brines. Laboratory pan evaporation of four chloride brines produced crude salts containing predominantly sylvite, halite, and carnallite. Six sulfate-chloride brines produced crude salts containing primarily schoenite, kainite, leonite, sylvite, carnallite, and halite. Potash grades ranged from 7.2 to 22.2 pct K20, and recoveries from 84 to 99 pct. Sylvite flotation from chloride evaporites, with amine collector, recovered 90 to 97 pct of the potash in a concentrate containing 54.3 to 60.3 pct K20. Fatty acid flotation of the high-sulfate evaporite recovered 78 pct of the sulfate minerals in a 27.8-pct-K20 concentrate. Flotation of the chloride minerals with amine collector recovered 80 pct of the potash in a 59.7-pct-K20 concentrate. Solar evaporation of 10,000 gal of brine recovered 99 pct of the potash in a crude evaporite containing 24.5 pct schoenite and 20 pct sylvite. Continuous flotation in a 100-lb/h process research unit recovered over 95 pct of the potash in schoenite and sylvite concentrates containing 28.0 and 62.3 pct K20, respectively. An economic evaluation suggested a rate of return of 3 pct for a new facility and 9 pct if. the process is adapted to fit an existing plant.

Jan 1, 1984

By James P. Kimball

Jan 1, 1885

By Robert J. McKay, F. P. Huston, WILLIAM G. HUMPTON

THE manufacture of nickel-clad steel plate and the fabrication of articles from it has progressed far enough to permit a general description of the working methods used. The manufacture of sheets made up of layers of nickel and steel is not new as a sheet of this character was patented in Germany in 1893. Present development differs mainly in the size and finish of the product. The earlier light-gage highly finished products have been limited in their application due to their similarity, in certain respects, to electro-plated and highly finished alloy sheets. The new product is a relatively heavy plate 1/4 or 3/s in. thick and heavier, with one side coated with nickel, the weight of nickel being of the order of 10 per cent of the whole. The finish is that of hot-rolled steel plate.

Jan 1, 1931

This appendix contains the list of equipment, their corresponding number and their specifications with the quotations from the vendors/ manufacturers who can supply this equipment. The listings are arranged by process plant areas.

Jan 1, 1979