Search Documents

By Zhuo Sheng

We have designed a high-temperature Raman micro-furnace and cell that is suited for the electrochemical process study of the NO3 − in molten NaNO3– KNO3 (fraction of NaNO3 50 wt%) salt. During the cycle voltammetry and constant potential electrolysis process, the Raman laser beam was focused near the electrode; subsequently, the Raman spectra are obtained and the reduction process of NO3 − is analyzed. In the CV cathodic scan process, the new peak attributed to the ν1 mode of NO2 − emerges, and the peaks assigned to superoxide ions (O2 −) and peroxide ions (O2 2−) are not found. In the constant electrolysis process, the peaks at 1130 and 800 cm−1 appear when the potentials are between −2.0 V and −3.2 V (vs. Pt). The results show that when the NO3 − is reduced in molten the NaNO3–KNO3 mixtures, the reduction product O2− cannot stably exist, and O2− will react with NO3 − to form of superoxide ions (O2 −) and peroxide ions (O2 2−).

By L. A. Ruth

Introduction The US Department of Energy's Office of Fossil Energy has begun a new approach for developing the ultra-clean energy plants. This approach will allow the nation to continue to use low-cost fossil fuel feedstocks during the early decades of the 21st century. The new approach is called Vision 21. The overall goal is to effectively eliminate, at competitive costs, environmental concerns associated with the use of fossil fuels for producing electricity and transportation fuels. Vision 21 is based on the following three premises: •The nation will need to rely on fossil fuels for a major share of our energy needs well into the 21st century. •It makes good sense to rely on a diverse mix of energy resources, including coal, gas,

Jan 1, 2003

By Peter Bates

"HIsmelt has faced and overcome many challenges in the understanding and development of injection technologies that satisfy process and engineering requirements for further scale up to a commercial plant.An overview of the design basis of bottom and top injection systems with plant results are described in this paper.IntroductionAn appropriate way to introduce this paper is to initially reflect on the genesis of the HIsmelt Process.It is appropriate that Professor Womer is the one we are honouring as it can be claimed that by the involvement of CRA in the WORCRA process that the concepts for irijection systems in iron and steel pyrometallurgical processes achieved significant attention by the company. The development of water cooled injection lances and their application injecting solids and gases with success was certainly a pre-cursor to the development of other injection systems commonly used today in arc furnaces and for top injection at HIsmelt.HistOrically it was the work of Savard and Lee in Canada with shrouded tuyeres and the subsequent commercialisation of this technology at the Maxhiitte Steelworks spawning the suite of bottom oxygen blown process as known as QBOP; OBM and the subsequent combined blowing process such as KOBM that first commercially succeeded in injecting solids under a molten metal bath. The next progressive step from the injection of calcined lime in the technology development was the injection of coal for coal gasification as developed by Klöckner technologies being called KG, KSG and KMS and also the injection of coal for increased scrap melting.A paradigm shift in thought process to leap from steelmaking and coal gasification to direct smelting by injecting coal and iron ore into a molten metal bath in the correct stoichiometric ratio to maintain the bath at a constant temperature and carbon level was the true genesis .of HIsmelt.A good overview of the state of the art of tuyere type injection technology is given in Ref. 1."

Jan 1, 1996

By Maria Carolina Andrade Teles

Uma fibra natural apresenta características interfaciais com matrizes poliméricas que favorecem a absorção de alta energia de impacto da estrutura compósita . Este trabalho procura avaliar a resistência ao impacto deste tipo de matriz de poliéster com reforço de fibras naturais. As fibras de Fique foram misturadas com resina de poliéster sob pressão em um molde metálico, e curada à temperatura ambiente durante 24 horas . Amostras padrões foram preparadas até 30% em volume de fibras Fique alinhadas ao longo de todo o seu comprimento, estas amostras foram então testadas com ensaio de impacto Izod do pêndulo e as superfícies de fratura examinadas por microscopia eletrônica de varredura, MEV. A resistência ao impacto aumenta substancialmente com a quantidade relativa de fibra de Fique como reforço do compósito . Isto pode ser atribuído a uma descolagem preferencial da interface fibra / matriz , o que contribui para uma elevada energia absorvida.

Aug 17, 2017

By Jan M. Peter

Many of the Pb-Zn massive sulfide deposits of the Bathurst area in northern New Brunswick, Canada, are intimately associated with laterally continuous iron formation (IF) (Figure 1). This IF is a fossil laminated, exhalative, chemical sediment. Together, the IF and the Brunswick #12, Brunswick #6, and Austin Brook deposits (rightmost discontinuous horizon on Figure 1) are collectively referred to as the "Brunswick Belt". To date we have only studied the Brunswick Belt and have not examined the horizon along which the QSR, CNE and Flat Landing Brook deposits lie. The Bathurst area is underlain by the Tetagouche Group (Figure 2), a Cambro(?)-Ordovician sequence of metasedimentary and bimodal metavolcanic rocks that was intruded by mafic to felsic plutons and subsequently deformed during the Taconic Orogeny. The stratigraphic sequence consists of shales and greywackes that are overlain by carbonaceous shales and felsic volcanic and volcaniclastic rocks; these are in turn overlain by mafic volcanic and sedimentary rocks. The massive sulfide deposits and IF occur within the upper portions of the felsic volcanic rocks in close association with carbnaceous metasedimentary footwall rocks (Figure 2).

Jan 1, 1993

By W. P. Yant, G. W. Jones

During the testing of porcelain insulators with a " 60 - cycle flash - over apparatus " , gases are liberated having an odor greatly resembling that of ozone . Since the two main constituents of normal air are nitrogen and oxygen , and high voltages (approximately 90,000 volts ) are used during the tests , the conditions are favorable for the production of ozone or oxides of nitrogen , and perhaps both simultaneously . The presence of these gases is only noticeable during the testing period . They soon disappear after the test is over . No fatalities have ever resulted from these gases at the plant visited nor are there any records of any of the men who worked on the tests being confined to their homes from this cause . New employees sometimes complain of a depressed feeling and shortness of breath , which is most noticeable after leaving work and getting into fresh air , but they som become accustomed to it and no ill effects are noticed . In view of previous work*** which the Bureau of Mines has done on oxides of nitrogen in connection with mine gases and problems in gas analysis , tests were made at the plant of the Westinghouse High Voltage Insulator Company at Derry , Pa . to determine the kind and amount of gases liberated .

Jun 1, 1923

By L. Filippov

"Nickel is an important metal with the total global consumption of about 2 million tons per year. It is sourced from both sulfide and laterite ore, but currently laterites are becoming more attractive for nickel production due to the depletion of high grade nickel sulfide ores. Laterites are generally processed by hydro or pyro-metallurgy and therefore, pre-concentration of nickel before such processes is very important. In this paper the effect different physical methods (including flotation) on the pre-concentration of nickel in laterite ores will be discussed. The ore used in this study was a laterite from South East Asia. Nickel was upgraded using different methods such as magnetic separation, flotation and sizing. The effect of ore mineralogy on choosing the best strategy to upgrade nickel will be discussed. The findings of this project will help to unlock a substantial volume of nickel with significant value from laterite ores.INTRODUCTION Nickel is an important metal with the total global consumption of about million tons per year which has grown rapidly during last decades (Mackey, 2011). Nickel is sourced from two different types of ores, sulfide and laterite. The majority (about 70%) of the world’s nickel resources occur as laterite ores which are often complex, and low grade, and therefore expensive to treat using conventional methods (Xu et al., 2013). Today, nickel laterites are more attractive for production of nickel as the amount of high grade nickel sulfide ores has diminished (Janwong, 2012). Therefore more economic processes to recover nickel from these resources should be developed.It should be noted that nickel laterite mineralogy is complex, and nickel often presents as ultrafine inclusions in a number of mineral phases. Because of the low nickel concentration and variable distribution in these phases, effective upgrading by physical separation processes would be challenging. Researchers have tried to improve nickel laterite flotation recovery by using a number of feed preparation techniques. A summary of the nickel grades obtained using flotation and magnetic separation as reported in the literature is presented in Table 1. It can be seen that only minor nickel upgrades have been reported. Quast et al. (2015) have concluded that the complex mineralogy of nickel laterite ores makes it difficult to achieve any significant nickel upgrading by physical techniques, including flotation. They achieved 40% increase in the nickel content (from 1.0% to 1.4%) at a nickel recovery of 43% (Quast et al., 2015). Various attempts in USA, New Caledonia, India and Australia, to upgrade nickel in laterite using magnetic separation have not been successful (Quast et al., 2015). A recent comprehensive review on topics influencing nickel laterite flotation has shown that further investigations in the flotation of laterite ores are undoubtedly warranted (Farrokhpay & Filippov, 2016)."

Jan 1, 2018

By T. W. Camm

One function of the U.S. Bureau of Mines is assessing potential economic impacts of federal land withdrawal policies. This often requires performing economic ana1ysls for an area with limited geologic information available. Input to the economic decision process relies heavily on estimates of mine and mill costs for the potential resources in the area being considered. A methodology for performing these cost estimates was needed to address this situation.

Jan 1, 1992

By Jamey Rosen, Georgette Hlepas

Verticality data collected from panel and pile elements of seepage barrier walls describe the shape and position of those elements in three dimensions. These data are used to determine if a barrier wall is constructed as designed and if it meets the owner specifications with respect to tolerance (i.e., if each element is sufficiently close to vertical) and overlap (i.e., do adjacent elements overlap sufficiently to prevent leakage). Contractors use verticality data to confirm that their work matches the design, and owners use verticality data to verify the contractor’s work and confirm that specified criteria were met. Project Information Management Systems (PIMS) technology has been applied to the management, visualization, and analysis of verticality data. This paper will provide examples of how contractors and owners have used a PIMS to compile and synthesize data collected during excavations (e.g., from Cutter Soil Mixer and Hydromill drill rig telemetry), and from measurements of completed excavations (e.g., using the Koden ultrasonic tool), and used those data to model excavation geometry. We will present case studies of using these models to estimate backfill placement volumes, and to evaluate the verticality tolerance and overlap between elements.

Sep 8, 2021

By Hongli Wen, Guangkun Shen, Qiong Deng, Xuling Chen, Min Gan, Xiaohui Fan

"In this research, pyrite cinder which contains 53.51% Fe and 0.54% Pb was processed by magnetic roasting separation to obtain a concentrate with 64.62% Fe and 0.56% Pb. The concentrate was then leached with hydrochloric acid to remove lead. Several technological parameters which may influence the removal efficiency were investigated: the mass fraction of hydrochloric acid, pulp density, the leaching time and temperature. On the conditions that the mass fraction of hydrochloric acid of 5%, pulp density of 30%, the leaching time of 30 minutes and leaching temperature of20°C, the lead content in the concentrate was reduced to 0.19%. The product was suitable for agglomeration and pelletization. Through the analysis of the lead distribution and phase change during the whole process, the mechanism of lead separation from pyrite cinder was analyzed.IntroductionPyrite cinder is rich in iron, which defines its most extensive and effective use as raw materials for iron making. However, some pyrite cinders contain much non-ferrous metals, which is detrimental for the iron making process. Lead, one of the harmful elements, will destroy the blast furnace lining. Besides, it causes pollution of the environment[1]. Therefore it is necessary to remove excessive lead before entering the blast furnace. To separate the lead from pyrite cinder, much research was done, including flotation, high temperature evaporation and leaching. High temperature evaporation consumed too much energy. The flotation was difficult to obtain high- grade iron ore concentrate[2]. Majority of the leaching was direct leaching of pyrite cinder, which was also difficult to get high-grade iron ore concentrate[3]. This article explored the magnetic roasting method to get high-grade iron ore concentrate, acid leaching method of the concentrate to remove excessive lead, providing guidance for the efficient utilization of pyrite cinder."

Jan 1, 2013

By Carlos Neto

Traceability is the capacity to recover background, application or localization of an item, through a single, standard and registered identification. It is the identification process necessary to follow all events, occurrences, handlings and movements of a product. Generally speaking, companies and governments in the world are seeking ways for tracing the distribution of controlled products, such as food, medicines, firearms and explosives, within the supply chain as to increase safety of its consumers and the environment (ISO 14000).

Jan 1, 2007

By Kinross Paracatu, Victor Morais, Luis Marinho, Rolando Fuentes, Lucas Steffen, Leopoldo Muñoz, Washington Vilas

Nowadays, mining operations close to communities face increasingly challenges, especially in their drilling and blasting operations. One of the critical effects are the ground vibrations produced in its surroundings. The impact on the community must be minimized to guarantee the license to operate and, on the other hand, costs must be optimized, and an adequate fragmentation must be achieved to ensure the efficiency of subsequent processes and, consequently, to give sustainability to the business. In this regard, it is necessary that some controlled blasting technique to be performed and the utilization of advanced vibrations models. Currently, it is common in the industry either use of the double decking technique, where very low explosive charges are applied, making it necessary to use smaller drill patterns in order to keep powder factor as per design, which strongly increases the demand for drilling and a consequent impact negative on costs.

Feb 6, 2023

By T. Asahina, M. Nakamura, M. Mabuchi, I. Shigematsu, M. Nakanishi, G. Yamauchi

"Commercial stainless steels (SUS304L and SUS430) were subjected to equal channel angular extrusion (ECAE) at room temperature to a total strain of 2.3 to 9.2. For each type of stainless steel, it was shown that the sample processed by ECAE showed higher room temperature strength than the as-quenched sample. This is probably due to the heavily worked structure. On the other hand, both strength and elongation of the ECAE processed SUS430 were increased by annealing at 773K. It is likely that higher strength is attributed to both the heavily worked structure and fine substructures. It is also likely that higher elongation is attributed to the fine substructures. It is concluded that ECAE is available for improving the room temperature strength of commercial stainless steels.INTRODUCTIONEqual channel angular extrusion ( ECAE ) is a technique that provides the repetitive deformation and allows to high intensity of deformation. With this procedure, a sample is pressed through a channel that has an equal cross section but bent at an angle of ?> [1-2]. Shear strain is introduced when a sample passes through the bending point of the channel. Repetitive processing is feasible because the cross-sectional dimension of a sample has no change during processing. To date, many reports have described that ECAE is available for the fabrication of fine-grained materials [3-14]. On the other hand, an ECAE processed sample can achieve high intensity of deformation through repetitive deformation. According to the equation given by Segal [ 2 ], a strain of about 1 is introduced in each pass through die if the angle ? is 90 deg.It is well known that high tensile strength can be achieved in metallic materials through work hardening [15]. It is also known that metallic materials with fine grain size show high strength [16]. Hence, it is expected that ECAE is available for strengthening method in metallic materials. In the present paper, we will report the mechanical properties of stainless steels processed by ECAE. As samples, SUS304L austenite stainless steel and SUS430 ferritic stainless steel were chosen. Each alloy has a single-phase structure (fee or bee) and shows no phase transformation, so that transformation strengthening cannot be applied. Hence, a heavy cold work such as ECAE may be effective for strengthening of this stainless steel. Annealing was conducted for the ECAE processed SUS430 to vary its microstructure. Then, the effect of annealing on the strength of the ECAE processed SUS430 was also investigated."

Jan 1, 2000

By Richard D. Begley

This paper summarizes the development of a mechanistic model to predict longwall mining induced surface subsidence. The model was originally developed from data acquired from a recent field study conducted in Northern West Virginia. Additional data has been collected from published sources and used to refine the model. The original model utilizes a negative exponential equation to predict the subsidence profile after the maximum possible subsidence is predicted based on the following input parameters: mine geometry, angle of draw and expansion factors for the deformation zones that have been identified above a longwall excavation. The model refinement involved the development of relationships between physical properties of the overburden strata and angle of draw in addition to the expansion or bulking factors. Therefore the refined model now requires only mine geometry and a typical geologic column from the site to predict the subsidence profile. This paper provides the methodology that enables the model to determine the angle of draw and expansion factors breed on physical properties of the site geology i. e. percent of strong rock and Rock Quality Designation of the overburden strata. In addition :comparisons of predicted results with measured data for over H) different sites with various geological and geometrical parameters located throughout the United States will be presented.

Jan 1, 1989

By Y. Rama Murthy

Around 90% of the chromite resources of India are concentrated in the Boula-Nuasahi Sukinda belt of Orissa state. In order to conserve these valuable ore resources strategically, several companies established chrome ore beneficiation plants in this region. The general beneficiation process in these plants consists of gravity unit operations such as Floatex density separator, spiral, wet shaking table etc. Most of these gravity circuits suffer huge losses of valuable minerals in the tailing. Any attempt towards decreasing these losses would not only increase the limited reserves in India but also make the economics of the operations more attractive. Apart from the liberation phenomena, in many of the operating plants considerable quantity of values are lost in the tailings, due to inconsistent feed quality, inappropriate selection of operating and design parameters. Mineral engineers in this regard have to play a proactive and continuous role to improve the performance of all separating units by modifying even small changes based on tests conducted in laboratory under controlled conditions followed by attempts to make necessary changes in the plant. For such improvements, accurate data collection and proper data interpretation followed by making necessary change which is implementable in an operating plant play a very critical role in performance of the circuit. Databank collected over a period of time under various conditions would also help in overcoming the future problems related to either variation in the feed characteristics or specific demand by metallurgical industries. The above concept was adopted in one of the operating chromite beneficiation plant at Sukinda. The approach adopted and practical problems encountered during the study were reported in this paper. The result of trial campaign has shown that, an overall product assaying 30.2% Cr2O3 from the feed (18% Cr2O3 ) can be produced to in single stage. The final discards of the process contain 12% Cr2O3. Keywords: chromite, chromite beneficiation, chromite losses, gravity concentration techniques, plant operating data bank

Sep 1, 2012

By J W Shields

The aim of this paper is to present a concept or model regarding a particular geological environment where gold orebodies occur in the Pine Creek Geosyncline and indeed in many other pans of the world. The name GIGIACS (an acronym for Gold In Greywacke In Anticlinal CrestS) is proposed to label this concept or model. The name Saddle Reefs (which has been in use for many years) is used for gold-bearing quartz veins which often occur in conjunction with Gigiacs. Simple patterns formed by this type of mineralisation at the surface due to different configurations are illustrated. Some examples of Gigiacs and associated saddle reefs are presented from the Pine Creek Geosyncline together with examples from other parts of the world. This concept has been used successfully as an exploration tool and five examples are given. The terms Gicsiacs (for Gold In Carbonaceous Shale In Anticlinal CrestS) and Giliacs (for Gold In Limestone In Anticlinal CrestS) are also used.

Jan 1, 1994

By J J. Van Wijk, A R. Penney

Successful management of geotechnical risk at a mining operation is more than just having a good ground control management plan or using advanced numerical modelling and the latest monitoring technologies. The fundamental requirements for effective geotechnical risk management include identification of potential failure modes, identifying and implementing appropriate controls, and demonstrating the effectiveness of those controls. Effective geotechnical risk management requires an integrated approach by confirming that appropriate risk management systems have been identified and implemented (management plans, procedures etc), and that these systems are executed consistently in the field across all working areas. Development of a thorough integrated auditing process executed by an experienced team of technical subject matter experts with substantial operational knowledge, provides a more complete picture of catastrophic hazard management. Following consistent evaluation criteria allows benchmarking of systems and implementation compliance between the sites being audited, and the results can then be ranked against other operations in an industry database.

Nov 29, 2022

By R. Sullivan, K. Joiner, B. Emery, M. de Vries, F. A. Stober, L. R. Nelson, J. M. A. Geldenhuis

Keywords: Pyrometallurgy, smelting, converting, furnace design, furnace retrofit, high-intensity smelting, copper coolers, plate coolers, waffle coolers, tap-blocks, lower sidewall air-cooling, wall hold-down system, platinum group metals, ferroalloys, ferrochrome, ferrocobalt, ilmenite smelting, ironmaking, operational readiness, operational support The paper describes the development of furnace designs by Hatch in conjunction with the smelting plants in Africa to meet the intense process requirements in certain applications; continued improvement in operating efficiency through increased throughput from existing crucibles; and improvement in campaign life and furnace integrity. The era of Hatch in Africa has seen the doubling of furnace power in retrofit projects using existing crucibles to developing the highest intensity immersed electrode operations in the world. This has resulted in minimized OPEX and CAPEX per unit of production. Through the continued development of its cooling, binding and furnace power supply technologies and working with the experienced and knowledgeable personnel at the smelting facilities in Africa, Hatch has managed to meet the challenges of ever increasing furnace process requirements associated with increased power density and superheats prevalent in the operations. In addition to developing furnace crucible designs, Hatch has also intensified its ?after sales service and support? with the construction, commissioning and start-up technical assistance and operational readiness and operational support for ramp-up to nameplate capacity and beyond. The key areas of furnace risk associated with high superheat molten material tapping has also seen the development of diagnostic systems to mitigate risks and produce early warning signals for the operators.

Jan 1, 2006

By Ayşe Ece Yıldızçelik, Mehmet Buğdaycı, Onuralp Yücel

ZrB2 and TiB2 are significant metal borides. They are being used in various industrial areas from space technology to nuclear industry owing to their physical properties such as high melting point, high thermal/electrical conductivity and low density. Present study was conducted in two main stages: self-propagating high-temperature synthesis (SHS) reactions and leaching. ZrO2, TiO2, B2O3 were used as starting material and Mg was used as a reductant to produce ZrB2-TiB2 powders via SHS. Therefore, it was aimed to determine production parameters, leaching conditions and comprehensive examination of final product features. The samples were characterized by using chemical analysis (AAS), XRD, XRF and SEM/EDS techniques.

Jan 1, 2015

By W. Dolsak

Introduction Alternative bolting injection resin Hollow bars, rebars, and cable bolts Results from an in-house product development project Sept. 2011 to Feb. 2013 Goals Introduction of a newly developed bolting silicate injection resin as alternative to cement grout based injection systems Definition of easy-to-use pumping devices and installation accessories Accomplishment of installation trials and performance evaluation

May 1, 2013