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By Peter Hayes, Evgueni Jak, Ata Fallah Mehrjardi

Modern analytical tools, such as electron probe X-ray microanalysis (EPMA), are used in experimental characterization of phase equilibria and microstructures of complex slags. Integrated thermodynamic computer packages, such as FactSage, are used to provide more accurate descriptions of complex slag systems. These advanced methodologies have been applied to characterize dynamic steady state freeze linings in slag systems using submerged cold finger probes at controlled laboratory conditions, establishing the effects of bath chemistry, temperature, heat extraction rate and bulk fluid flow. It has been found that stationary freeze lining deposit interface temperatures at steady state conditions can be lower than the bulk slag liquidus temperature, and that stable operation below the liquidus is possible. A conceptual framework has been developed to explain the phenomenon and the range of interface temperatures that can be obtained in dynamic steady state conditions. These findings have important implications for the design of freeze linings and possible improvements to high-temperature metallurgical operations.

Jan 1, 2014

By John O. Marsden

"This article is an attempt to capture a presentation given at the 2016 SME Mineral & Metallurgical Processing Division (MPD) Luncheon held on Feb. 24, 2016, in Phoenix, AZ. It was presented as a tongue-in-cheek, lighthearted view of several of the issues facing our industry, while identifying some of the challenges and opportunities available to new engineers entering the industry today.Disclaimer• What you are about to read includes personal preferences, biases and occasionally arbitrary opinions.• Some readers may have dissimilar opinions on the contents and/or the rank order of the lists.There are eight top ten lists offered in this article: (1) Industry realities (2) Things a metallurgical or mineral process engineering graduate should do (3) Books every metallurgist should have on their shelf (4) Things I wish I had known (5) Legends of metallurgy (posthumous, with highlights) (6) Things we’ve forgotten (7) Mineral processing innovations of the past 20 years and, finally, (8) The future? For some items, additional context or clarification is provided after the item, while for other items no further explanation is warranted and none is offered. Top 10 industry realities1. Metal price cycles.2. Bigger is better (except when it isn’t).3. Ore grades declining across the board of metals/commodities.4. Ores becoming more complex.5. Three-fold increase in capital costs between 2004 and 2015.6. Three-fold increase in operating costs between 2004 and 2015.7. Less capital availability/challenging financial markets.8. Environmental constraints increasing.9. Socio-political constraints increasing.10. The mine manager is always impossible to work with.As Table 1 shows, there was more than a three-fold increase in gold operating costs between 2004 and 2014. The increases for copper, iron ore and other commodities were similar."

Aug 1, 2016

By James J. Brady, Kenneth L. Faught, Chadi El Mohtar, Chaoshi Hu

"During construction of a 9.5-ft. diameter sanitary sewer tunnel, the City of Edmonton encountered a large pocket of flowing sand that flooded their TBM and caused significant surface subsidence, stopping further tunneling by the TBM through this zone. A unique collaborative effort ensued between the authors representing the city, consulting engineers and academic researchers to develop the optimal strategy for grouting the problematic soils. The site has a layer of very find sand between 20 and 30 ft. in depth with fines contents ranging from 5% to more than 40%. The collaboration extended from requesting additional site investigation efforts to shipping samples to the UT-Austin laboratories for grout testing plus ground and grouting characterization tests resulting in field recommendations for a full scale ground improvement program. New research information on the grouting of fine sands along with a collaborative framework for the design of in-situ grouting projects are the key topics presented. INTRODUCTION Encountering a large unexpected pocket of flowing sand with an open-faced TBM while excavating a tunnel below the groundwater table is never a good thing. This was certainly true for the City of Edmonton when one of their Lovat TBM’s became inundated by flowing sand while excavating the 9.5-ft. diameter Millwoods Double Barrel Replacement Tunnel in September 2013. However, since the City of Edmonton self-performed this work, a rare situation existed where the site could be investigated objectively, without the prejudice of contending parties selectively influencing how information was gathered and presented, to accurately examine site conditions with a goal of identifying the best remediation measures."

Jan 1, 2016

By G. Riveros

A new, continuous fire refining process for copper has been developed and tested at the 5 tph pilot scale. During oxidation, the blister copper flows through a packed bed of crushed refractory bricks counter-current to a hot oxygen containing gas. The resulting desulphurized copper flows then directly into a packed bed of charcoal for deoxidation. By controlling the air to natural gas ratio, both temperature and reducing conditions can be controlled. Based on extensive laboratory scale measurements of the rate of copper oxidation and reduction, the process concept was developed aided by process modeling and simulation. The industrial-pilot scale installation built at the ENAMI Paipote smelter in Chile, consists of two cylindrical, compact reactors, operating in line, with a designed capacity of 5 t/h of blister copper. The results of the industrial-pilot tests confirmed the feasibility of the new process. The blister copper processing capacity was increased to 10 t/h with satisfactory sulphur removal. The degree of oxidation as well the copper temperature was controlled with relative ease. The specially designed siphon block allowed for smooth tapping of the oxidized copper and separation of refining slag. The reduction of oxidized copper in the packed bed of charcoal appeared to be very effective while control of the degree of reduction according to the height of the bed ensured control of the oxygen content in the refined copper at the required level.

Jan 1, 2007

By David Morrison

"The history of the mining industry is littered with in-pit crushing and conveying (IPCC), which should not be confused with the International Protocol for Carbon Capture, projects that failed. The failure is not the technical one of “did it achieve the desired tonnage rate for a longish test period” but, rather, the far more important one of “did it provide return on the investment in the manner that was promised?” While quite a few can claim the former, very few system installations can claim the latter.The reasons for the many failures are numerous, but they are all characterized by a combination of an element of engineering optimism in any, or all of the production rates, the productivity, or the operating and maintenance costs and in predicting the continuity of operating conditions. In these days of big data, propagating such a situation is rapidly becoming unforgivable.In this article, the three most common scenarios put to the corporate board for approval, and the logic as to why they were selected, are examined (with the irony included intentionally).• Fully mobile crusher, fed by a shovel and conveyed out of the pit to a waste dump / process plant.• Semimobile crusher (much more expensive than a fixed crushing station but which apparently allows trucks to short haul inside the pit and improve productivity), which moves when the face moves.• Relocatable crusher (more expensive than a fixed crushing station but which gets relocated at great expense after all the fixed infrastructure impeding relocation is demolished) fed by trucks that don’t leave the pit mostly.This paper will also consider the truth about their operational performance and associate costs."

Dec 1, 2016

By P. Nelson

Extending the campaign life of the Mitsubishi furnaces at Xstrata Copper's Kidd Metallurgical Division Copper Smelter has been a major focus of attention for many years. One aspect of this effort is real time monitoring to detect abnormal conditions and safely shut the furnaces down before significant damage occurs. Traditional real time methods of monitoring the integrity of refractory furnaces containing molten metal include alarms on individual temperatures of the refractory or cooling water. The need to set alarm limits which are not exceeded across the range of normal operating conditions leads to a system that only provides a limited warning, if any, before a failure occurs. Integrity monitoring systems that look at many different signals and alarm only changes in the relationships between the signals have been implemented on the smelting and converting furnaces. The systems are based on principle components analysis (PCA) models and implemented with the monitorMV software package. These provide much more sensitive and selective alarms so that changes in integrity are alarmed well in advance of any event. At a critical alarm level, the converting furnace is set to automatically shut down so that operating and technical personnel can review the situation. The configuration of the systems and operating experience with them will be discussed.

Jan 1, 2007

By K Nakashima, K Aya, T Sumita, N Saito

Electro slag remelting (ESR) is one of the methods used to produce high-cleanliness steel. In the ESR method, the product steel electrode is immersed in flux, and the electrode is melted by the Joule heat of the flux generated by high current. CaF2-based melts are mainly used as fluxes, but the electrical conductivity of CaF2-based melts varies widely among researchers and measurement methods. Therefore, this experiment aims to measure the electrical conductivity of CaF2-based melts based on the van der Pauw-Ohta method, which does not require the cell constant that is a fundamental error factor in electrical conductivity measurement at high temperatures. The measurement temperature was set at 1450–1600°C, and dehydrated Ar flowed through the furnace at 200 mL/min. Electrodes were fabricated by Pt-30mass per cent Rh alloy, and the electrodes were connected to an impedance analyser using a four-terminal probe. The electrodes were immersed in the melt, and the impedance and phase angle were measured by AC frequency sweep (50 Hz to 200 kHz). The electrical conductivity was then calculated by utilising the impedance’s real part values when the impedance’s imaginary component was zero. The electrical conductivity showed a positive temperature dependence. The electrical conductivity of 60(CaO⋅Al2O3)-40CaF2 melt increased with increasing temperature but was found to be roughly one-third of those of the previous studies. In the conductivity measurement of 60(CaO⋅Al2O3)-40CaF2 melt, the AC frequency with a phase angle of 0° was found to be different depending on the temperature and immersion depth. By sweeping the frequency, the impedance at the phase angle of 0° can be obtained, which enables us to measure the electrical conductivity more accurately.

Jun 19, 2024

By B. T. Brady

Rock mechanics, like all engineering disciplines, must have a theoretical foundation. The subject of this chapter is the formulation of analytical methods that may aid in the rational design and determination of the stability of engineering structures in competent brittle rock materials. By an engineering structure in rock, we mean any (1) excavated sub- surface opening, (2) open surface structure, or (3) system of openings in rock that is virtually self-supporting-that is, not requiring artificial systems to carry structural stresses.

Jan 1, 1970

By R. J. Sweigard

One possible alternative for disposal of flue gas desulfurization (FGD) by-products is use as backfilling support material in highwall mine adits. The finite element method was used to analyze the variation of stresses and displacements within and around a highwall adit backfilled with FGD materials. The engineering properties of the rock material and the optimum mix proportioning of the FGD materials were obtained from laboratory tests. Finite element analyses show that, for the case in question, the roof displacement would decrease about 48 percent and the peak stress could be decreased about 58 percent. The study indicates that fairly weak FGD materials can eventually lead to stability of backfilled highwall adits.

Jan 1, 1996

By G. L. Zhu, Y. F. Wu, H. Nagaumi

A novel eutectic-type alloy Al12Si-HTC with high thermal conductivity has been developed by strict chemical composition control and heat treatment. The thermal conductivity of the alloy is about 30 % higher than that of current commercial Al12Si alloy. The Al12Si-HTC alloy has a silicon content of 10~12 wt.%, which provides excellent castability. Trace element strontium or calcium is added to modify eutectic silicon, and contents of transition elements such as copper, manganese are controlled in a low level. By appropriate heat treatment, thermal conductivity of the castings increases by 7.5 % and finally reaches 172 W/(m·K). It is found that eutectic silicon modification which makes average particle size finer than 2µm plays a dominant role in improving thermal conductivity, as well as further spheroidization of eutectic silicon and reduction of lattice defects in a-Al microstructure in subsequent heat treatment process. The alloy is successfully applied to produce a certain communication enclosure with complex finned structure by die casting process in industrial scale. The results of numerical simulation and thermal analysis experiments show that when manufactured by Al12Si-HTC alloy, the surface temperature of chips in the enclosure is reduced by 2.0~4.5 ? and the temperature distribution is more homogeneous compared with traditional Al12Si alloy.

Jan 1, 2015

By Jilai Xue, Jun Zhu, Liang Liu

"Separation removal of fluorite and calcite from scheelite is a difficult technical operation in current industrial practice with a heating process causing large energy consumption and high production costs. In this work, the floatation separation at room temperature were carried out using two types of skarn scheelite ores. The results showed that CaO and Na203 are better than NaOH as a regulator in pH value. In the rough floatation and first cleaning floatation, CaO (500g/t), Na203 (3000g/t) were used as a pH regulator, waterglass (4000g/t) was as a gangue depressant, oleic acid or sodium oleate were used as a collector. The degree of the obtained W03 concentrate was more than 65% (commercial product).IntroductionThe mainly gangue in scheelite are quartz, calcite, barite and some rare metal ores. There are three main types of scheelite for floatation: scheelite--quartz (silicate minerals) type, scheelite-calcite/ fluorite type, scheelite--calcite/fluorite/barite type. Generally speaking, scheelite--quartz type is separated easily, and others are difficult, on the contrary. The last two kinds of scheelite are always called scheelite--calcite/fluorite (barite) type, because there are similar floatation ability and floatation process between them. Scheelite, calcite and fluorite have same cation - Ca2+, it makes them have close floatation property [1]. Separation removal of fluorite and calcite from scheelite is a difficult technical operation in current industrial practice.The traditional separation method is a heating floatation process (Petrov's process) [2]. It can deal with many kinds of scheelite, and can be obtained stable quality ofW03 concentrate. On the other hand Petrov's process causes large energy consumption, high production costs and bad operational environments. Since 1980s, scheelite ambient temperature floatation has become the mainstream of study [3]. Nowadays more and more studies on scheelite floatation focus on complex reagent system [4, 5], rigid operating rules and at the same time development new regulator [1, 5]. Some research show there are new regulators can concentrate scheelite efficiently, but it may cause high costs, potential pollution and difficulty to spread. Oleic acid and sodium oleate used as collector have high adsorption capacity to scheelite, but same to calcite and fluorite[6]. So, it would not get ideal effect for separation of scheelite. In this work, the floatation separation at room temperature were carried out using two kinds of skarn scheelite ores. Calcium oxide and sodium carbonate was used as a pH value regulator, waterglass was used as a depressant and Oleic acid/sodium oleate was used as a collector. The result of experiment showed that the degree of the obtained W03 concentrate was more than 65% by one time ambient temperature roughing floatation, several times ambient temperature cleaning process."

Jan 1, 2014

By D. F. Doerr, E. Blalock, D. R. Bush, K. D. Cohen

"INTRODUCTION The design, development, fabrication, and test of cryogenic breathing apparatus is part of a much larger effort funded by the National Institute for Occupational Safety and Health (NIOSH) and managed through a Space Act Agreement with the National Aeronautics and Space Administration (NASA) at the Kennedy Space Center (KSC) in Florida. This effort is designed to create cryogenically based life support equipment that is responsive to the needs of miners as required by the Miner Act of 2006. Our goal was to design and build a liquid air based self-contained breathing apparatus (SCBA) that lasted 2 hours and would be used for the egress of miners during a mining accident and be refillable while worn. Therefore, the current report describes tests of an Advanced Cryogenic Breathing Apparatus (termed the ACryoBA) designed to provide miners egressing an emergency situation with a two-hour open-circuit SCBA. The ACryoBA utilizes low pressure cryogenic liquid air instead of high pressure compressed air commonly used in most commercially available SCBA. The ACryoBA can also be self-filled from strategically placed Cryogenic Air Supply and Fill Stations (CryoASFS) initially, and thereafter on the egress route approximately every 1 hour and 30 minutes with a 30 minute air reserve. The ACryoBA evolved originally from a one hour Liquid Air Pack (LAP) developed in the 1980’s for Space Shuttle Rescue forces allowing for longer duration and cool air (Figure 1). It was used successfully for many years, through the end of the Space Shuttle Program. The first attempt at a mine egress pack was the Cryogenic Breathing Apparatus (Figure 2). It was to have a low profile, two hours of breathing, attitude independence, and a simple rapid refill while in use. The CryoBA met the two hour criteria, but with difficulty due to excessive heat leakage caused by the dual 4 liter Dewar design. Much of the stored air was lost as it vaporized faster than it could be used. However, the pack was successful in demonstrating both attitude independence and a simple rapid refill capability. The ACryoBA project was designed to continue the progression and address the deficiencies in the CryoBA. The ACryoBA pack was designed to last 2 hours. It minimizes the heat leakage with a single Dewar and thereby requires less liquid air. The single Dewar design also minimizes weight, making it much more manageable by the user (Figure 3). The ACryoBA complies with 42 CFR part 84 NIOSH certification test requirements. One critical requirement for the ACryoBA is operation in positions other than vertical for periods up to 1/4 (i.e. 30 minutes) of the rated service life of 2 hours; this was accomplished by use of new technology called the “attitude independent pickup” which is abbreviated “AIP.” The AIP, developed by BCS Life Support LLC (patent #8,899,226), has a tube going from the top flange down through the center of the Dewar. At the end it has a flexible bellows and a weighted end. Due to the flexible nature of the bellows, the pickup at the end is free to rotate and follow the liquid level around within +/- 90o of vertical."

Jan 1, 2016

By Jun Xiao, Xiaodong Li, Chunming He, Daixiong Chen

"Benzohydroxamic acid with double dentate can react with copper to form cyclic hydroxyl oxime acid copper chelate, indicating a good selectivity for copper oxide minerals flotation, especially for malachite. The flotation results of the pure malachite mineral show a strong synergistic collecting effect between hydroximic acid and xanthate at a ratio of 3.5:1, achieving a malachite recovery of 95.5% when certain sodium sulphide is used as a sulphidizing agent in the optimal pH range. Thanks to the synergistic collecting effect, the flotation recovery of malachite of a real refractory ore flotation ,can reach over 92% under the optimum condition, a 12% higher than the recovery achieved with the conventional collectors. In industrial application, the flotation of the copper oxide minerals is improved , leading to a high efficiency utilization of copper oxide resources.INTRODUCTIONBeneficiation of copper oxide ore is one of the recognized challenges in mineral processing industry. Copper oxide ore is a vital component of copper resource in the world, which has abundant reserves. Majority of sulphide deposits has oxidized zone on the top, and some deposits are oxidized to become the large and medium-sized oxide deposits (Willam & Chavez, 2001). Most copper oxide ores have problems in processing such as high slime consumption, poor floatability, complex ore property and low flotation recovery, so it is of great significance in beneficiation of copper oxide ores to develop an efficient collector, especially for malachite (Fu & Gu, 1997; Wen, 2010; Riet, Kier & Elford, 1980). At present, sulphidization-xanthate flotation is the most important method for treating copper oxide ore. In recent years, due to the decreasing ore grade, the utilization of refractory copper oxide ore draws more and more attention (Zhou, 2003), except for sulphidization-xanthate method, chelating flotation method (Lu, 2009), chemical beneficiation method (Lenormed, Salman & Yoon, 1979), microwave radiation flotation method, hydrothermal sulphidization-flotation method (Mao, Wen & Fang, 2014) and ammonia leaching of sulphide precipitation-flotation method (Lekang, Stevik & Bomo, 2003) have occurred."

Jan 1, 2016

By Dennis Greene

Real-time GPS position monitoring of mining equipment is becoming more and more commonplace. Digital mining plans can now be used onboard properly equipped earthmoving equipment and excavation status is available in real-time via high bandwidth data radio systems. These systems provide a closely integrated link between operations and planning. No longer must operations wait for or be hindered by insufficient survey marks, nor is engineering delayed by lack of timely mine status information. Unprecedented efficiency gains become feasible -from the engineering office, to drilling and mucking, to reclamation, as well as in mine construction projects. Direct economic benefits of these systems will be explored as will the less tangible, but very significant, indirect operational efficiency gains.

Jan 1, 1998

By Carlton D. Hulin

ARE we a "have" or a "have-not" nation in our domestic supply of metals and minerals? Impinging on the ears of a people weary of war and faced with the problems of reconversion to peace, the import of this question has built up with the momentum of an avalanche. Stemming from statistics cited by Pehrson and accelerated by the pessimistic and possibly biased statements of Ickes, hardly an issue of any technical periodical dealing with mining has appeared during the past year but within whose pages was to be found some comment, some discussion of the question: Are we a "have" or a "have-not" nation? We have proved commercial reserves of high-grade iron ore in the Lake Superior region sufficient for 22 years, based upon the prewar rate of consumption; commercial copper reserves to last only 34 years, one fourth being inferred ore; zinc sufficient for nineteen years, over half being inferred; lead for twelve years, two thirds of which is inferred; mercury for only three years. So read the figures. Although admitting that these figures may be extended by new discoveries, by the use of marginal and submarginal ore, and by further technological advances, are we nevertheless to assume complete pessimism in the acceptance of the meaning of these statistics; are we to expect a rapidly increasing dependence upon foreign sources of mineral supply; are we to believe that we are at or near the peak of the "metal age" as has been held by Theodore J. Hoover? Or is some more optimistic viewpoint possible?

Jan 1, 1947

By Thomas L. McVay

Laboratory batch and pilot plant flotation tests were made to determine the feasibility of recovering commercial grade kyanite from a quartzite- kyanite rock from the Graves Mountain, Ga., deposit. Best results in laboratory and continuous tests were obtained using sodium carbonate for pH control, citric acid for quartz depression, and oleic acid as the kyanite collector. Over 80 percent of the kyanite was recovered in a concentrate analyzing 56.8 percent Al203 and 3.8 percent hydrochloric acid soluble Fe203. Subsequent treatment of the flotation concentrate by magnetic separation reduced the acid soluble Fe2O3 to 0.6 percent and increased the alumina content to 59.2 percent. Acid leaching of the concentrate gave a product analyzing 59.7 percent Al203 and about 0.1 percent Fe203. As a result of the beneficiation research, a commercial kyanite flotation plant was completed in September 1962 by private industry.

Jan 1, 1963

By Uday B. Pal

In the electrochemical vapor deposition (EVD) process, gaseous cation precursors are passed over one side of a porous substrate, and oxygen is passed on the other side of the substrate. The gases diffuse and react within the porous substrate, and the pores get filled with the desired solid oxide. Subsequent solid state electrochemical transport through the solid oxide in the pores continues the reaction, and the film grows over the porous substrate. The EVD process has been used to deposit lanthanum chromite interconnection films and yttria stabilized zirconia electrolyte films over porous air electrodes. The EVD growth of these solid oxide films is found to be parabolic in nature, which indicates that the solid state transport (diffusion) of ions through the film controls the growth. This solid state transport can be analyzed using Wagner's treatment of the electrochemical transport. Conductivity measurements and the information on the defect structure of the oxide can be combined with the EVD growth rate measurements to calculate the solid state transport properties (transport numbers and partial conductivities) of the rate-controlling minority species in the oxide. Using this approach, the EVD growth of other electronic, mixed conducting and ionic solid oxide films can also be analyzed.

Jan 1, 1992

By Ballard H. Clemmons

THE future of the steelmaking industry of the Birmingham, Ala., district is closely related to and, in a large measure, dependent on the development of workable, economic processes of ore concentration. Operations thus far in the area have been possible only because of the fortuitous occurrence of iron ore, fluxing stone, and coking coal-all the primary iron-making materials- within a 25-mile radius of the blast furnaces. Commercial ore of the district consists mainly of a 10 to 20-ft hematite-calcite-silica bed locally known as the "Big Seam," a component of the Clinton formation of Silurian Age. At present mining rates, this ore will be available for a number of years. It is largely mined under 1000 to 2000 ft of cover and transported on 15 to 20" slopes that, in some instances, are as much as 10,000 ft long. Under these conditions, particularly with increasing distances from face to portal, mining costs are gradually becoming disproportionately high. Although not a major factor thus far, it should also be noted that the average annual ore output of the district is gradually be- coming more siliceous.

Jan 1, 1950

By R. L. Grayson

Compliance standards for respirable dust which are reduced because of high quartz concentrations have become an industry-wide problem. Research on the physical and chemical character of quartz-classified particles in respirable coal mine dusts indicates that they may exist in intermixed layers or may be coated by clay or coal material. The relative amount of intermixing varies with the coal seam being mined. If most of the quartz particles of a mine dust are "pure," then the dust may have a high fibrogenic risk potential because of truly free silica and the compliance standard should be lowered. If, however, the quartz is locked inside another material matrix, or coated, a reduced compliance standard may not be appropriate.

Jan 1, 1990

By T. Tumidajski

The purpose of the separation processes in coal processing is obtaining products of certain ash contents. In the most of cases it is assumed that the separation process is described by one, selected parameter, which usually is grain size or material density. The separation may be described by means of statistical distributions of random variables, what allows forecasting the separation results of certain enrichment method. There are very well known the applications of approximations of Tromp separation curves or distribution functions of Erasmus, Meloy or Weibull. It is necessary to say that if the fitness of the approximation more suitable, then the characteristics of the process itself is also better. In purpose of obtaining more appropriate results, these methods were modified by application the mathematical functions, as i.e. hyperbolic tangens function. Furthermore, on the basis of empirical data, so-called interpolations may be performed in purpose of getting more appropriate results of approximation. One of the most known techniques of interpolation is Hughes method. This method for interpolating standard data involves breaking down each interval into a number of smaller sub-intervals. The results of such one-dimensional approach not always contain the full in-formation of the searched distribution. It happens because such interpretation of the problem is not completely correct. In practice, the separation process depends not only on the one parameter (i.e. grain size), but also on many other features characterizing certain material (i.e. its density). It seems then that in some cases the application of multidimensional grain characteristics distributions will be more appropriate. In this paper, the technique of joining the distributions of grain size and density by means of so-called Morgenstern distributions is shown. The general form of these distributions is as following:

Jan 1, 2014