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By R Chandramohan

Comminution is the science of size reduction of brittle materials. It is integral to mineral extraction and is one of the most energy intensive processes in the mining industry. There are a number of tests used to quantify the strength of ore, which are then used to size the AG / SAG mill in circuit design. The calculated energy utilized for breakage in these devices is based on the assumptions that the materials treated are of average shape and that the processing equipment is designed to break the ore as efficiently as possible under the given operating conditions. In drop weight tests, it was found that shape significantly influences the measured rock strength. Controlled experiments with variations in blends of rock shape show that mill throughput increases with the addition of weaker shaped rocks.

Jan 1, 2012

By Hillary W. Clair

An equation is derived for the rate of reaction of a sphere of metal oxide in a restricted enclosure through which a reducing gas is flowing . The equation takes into consideration the reaction rate coefficient , transport through the gas and through the porous shell of reduced oxide , the rate of gas flow , and the volume of the enclosure . The equation serves as a model for predicting the course of reduction of a particle of metal oxide in a shaft furnace .

Jan 1, 1964

By Vince Saporito

Miners work in dangerous terrain, around the clock, with heavy equipment. Is there room for improvement in safety and standardization in the mining industry? Recent history would suggest there is a need for action. At a 2011 Spring Thaw conference in Denver CO, one speaker commented, ?We are having a number of incidents with workers getting ?pulled? into rollers or ?trapped? at transfer points when trying to manually clean (it) while the conveyor is still in motion.? It?s a troubling thought. These actions are specifically prohibited under U.S. Mine Safety and Health Administration (MSHA) regulation 57.14202. Another official from MSHA earlier this year indicated with today?s technology and policies presently in place, ?we should not be repeating the same incidents and violations year after year as we currently do.? But we are doing exactly that.

Jan 1, 2012

By L. K. Smith

Flotation work conducted by CSIRO on both single minerals and high-arsenic copper ores from a number of sources, has shown it is possible to produce separate low-arsenic copper concentrates and high-arsenic copper concentrates from high-arsenic copper ores. The procedure involves controlled separations at high or low pulp potential regions exploiting subtle differences in the flotation behavior of the arsenic-bearing and non-arsenic-bearing copper minerals. An overview of several case studies investigating the applicability of the controlled potential flotation approach to the separation of copper and arsenic from sulfide copper ores is presented. It highlights the variables which influence the efficiency of the separation which include mineralogy, liberation and reagent selection. The procedure can produce a saleable low-arsenic copper concentrate, which can be directly smelted without penalty, and a high-arsenic low copper concentrate, which will require further processing. Keywords: flotation, copper, arsenic, controlled-potential flotation

Sep 1, 2012

By H. H. Law

Large amounts of waste material in the form of flue dust are generated in the operation of copper smelter furnaces. As a result of increasingly stringent disposal, it has become important to develop methods for treating such metallurgical wastes to extract metals and convert them into salable products. A two-step closed-loop hydrometallurgical process, has been developed: (1) extraction with sulfuric acid removes about 90% of zinc and decreases the dust volume by 50%; (2) extraction with hydrochloric acid dissolves the lead and further decrease the dust volume by 75%. A process scheme for generating salable products is proposed.

Jan 1, 1992

By D. L. Cluff

Ventilation Air Methane (VAM) is a high volume low concentration methane source. The capture or use of methane from VAM is challenging, which results in the routine discharge of methane into the atmosphere. Mitigating VAM has the benefits of providing an energy source and reducing the atmospheric Greenhouse Gas (GHG) burden. The GHG radiative forcing effect of methane is 17?23 times as potent as carbon dioxide on a 100-year time horizon. Thus, any reduction in atmospheric methane would be beneficial. The calorific value of methane is 55.5 MJ/Kg; therefore, a 100 m3/s flow with VAM concentrations from 0.1?1% can provide 3.8?38 MW of exploitable power. Strategies to mitigate VAM such as: Thermal Flow Reverse Reactors (TFRR), Catalytic Flow Reverse Reactors (CFRR), Lean Burn and Catalytic Gas Turbines, Biothermica Vamox®, Megtec VOCSIDIZER©, and Vamcat? are briefly reviewed. The review of VAM mitigation technologies reveals disadvantages such as the need to maintain a minimum internal heat capable of oxidizing the methane. This requirement uses all of the available methane up to the point of reaction sustainability and up to half at the highest methane concentration in VAM. Some systems may introduce a pressure drop to the ventilation system, which would impinge on the existing ventilation system design. These impediments necessitate the development of a more amenable technology. In the proposed system, gas turbines (GT), coupled to a combustion chamber with an external fuel supply, assist the combustion of the VAM. The combustion-chamber coupled system provides electricity, while the heat contained in the GT exhaust gases increases the temperature of the VAM, encouraging the development of a flame inside a combustion chamber. The flow from the combustion chamber streams through a primary air/fluid heat exchanger capable of producing steam of a high enough quality to generate electricity using conventional steam turbines. The residual heat after primary extraction, directed through other equipment, provides additional heat based products such as industrial scale dry air, chilling by an absorption chiller or hot water. The overall design of the system is scalable for low to high VAM flows or variations in concentrations and is capable of providing the company or community with heating, chilling, hot water, electricity or motive force as needed by the particular site or community. The Multi-generation system uses heat from three sources to provide clean efficient energy while mitigating the atmospheric emissions of methane. These sources are heat from the GT, often considered waste heat, heat from fuel injected into the igniters and heat from the VAM. The opportunity to collect carbon credits may improve the economics. In order to design a system with this capacity, a detailed analysis of the combustion characteristics of three separate flows is required. VAM is the main airflow, having the highest volumetric effect, while the GT exhaust and the additional fuel added to the hot exhaust flow of the gas turbine are lower flows, but have a higher velocity and temperature. The aim of the modeling undertaken in this work is to establish the combustion dynamics, degree of pre-heating required and the geometry essential to the design of combustion based VAM mitigation multi-generation systems.

Aug 1, 2013

By C. Turek, R. Henderson

Mine planning is the foundation of value for a mining company. Good mine planning requires solid understanding of the ore body, rigorous standards and processes, robust and useful information technology and skilled people. Life of mine planning is key to identifying strategic direction for any mine and short range mine planning is key to delivering forecast and budget expectations. Mine planning at Kinross has been identified as a critical success factor and initiatives are being prepared to improve the quality of our plans and to build bench strength in our teams. The Kinross Way for Mine Planning (KWMP) has been developed and implemented to establish the standards to ensure a strong business foundation. This paper briefly describes the process used to develop the KWMP and presents a selection of mine planning best practice initiatives at Kinross mines.

Jan 1, 2011

By G. R. Lane

A large opencast gold mining company in Africa had just completed a feasibility study for the expansion of the operations. A traditional net present value project valuation methodology had been used that showed a very positive net present value (NPV). The project team had conducted a qualitative risk assessment that identified and logged all potential project risks and had subjectively incorporated ?risk? via the discount rate and other assumption contingencies around gold price expectations, operating parameters etc. Management requested that an independent quantitative risk modelling approach be adopted to obtain a better understanding of the impact of risk on the overall project valuation and confidence level in the final valuation. A detailed project valuation model was configured in the Carbon Modelling Technology and the stochastic modelling module used to perform the Monte Carlo simulations. Analysis of historical operational performance data relating to actual achievements versus planned and budget determined the historical variability of the underlying parameters as well as variance to budget. This was done at a detailed level for mining rates and costs, processing rate, costs and recovery, and other operational efficiency measures. External market assumptions relating to gold price, exchange rate, and inflation were modelled and the dependency between them modelled using a copula. This case study will demonstrate the approach taken to building and populating the quantitative risk model and the overall results of the Monte Carlo simulation. The final valuation demonstrated that the project had a 44 percent probability of an NPV less than zero i.e. 44 percent chance of project finance loss.

Jan 1, 2012

By V. Panayotov, M. Panayotova

"Wastewater from ores processing is often polluted by molybdate and sulfate (SO42-) ions. Sorption is one of suitable methods for removing those pollutants when presenting in low concentrations. This work reports results on adsorption of sulfate and molybdate ions on metal modified (with barium - Ba and lead - Pb) and organic reagent modified (with Hexadecyl-trimethyl-ammonium bromide - HDTMA) clinoptilolite. Zeolite’s modification with Pb, Ba and HDTMA increases its uptake capacity with respect to Mo(VI) at pH 3, with the uptake capacity decreasing in the order CL-Pb > CL-HDTMA > CL-Ba. Lead-modified clinoptilolite shows high uptake with respect to Mo(VI) in acidic, neutral and slightly alkaline conditions. The presence of SO42- in concentrations twice higher than the amount of Mo(VI) do not interfere with the Mo(VI) removal by CL-Pb. Zeolite’s modification with Ba and Pb renders it able to immobilize SO42- from water in the pH range 3-9. Kinetics of the uptake process is best described by the pseudo-first order kinetic equation. Increasing the initial concentrations of Mo(VI) and SO42- increases the removed amount of pollutants. INTRODUCTION Wastewater from copper-molybdenum ores processing is often polluted by molybdate and sulfate ions. Molybdenum (Mo) migrates easily in water and consequently the Mo polluted areas could extend for hundreds and thousands of meters (Ryzhenko, 2010). Molybdate anion is the only Mo(VI) species in natural water, i.e. at pH > 6.0. Its median freshwater hazardous concentration affecting 5% of the species (HC 5.50%) is 38.2 mg Mo/L (De-Schamphelaere et al., 2010). The marine water chronic toxicity (HC 5.50%) is assessed at 5.74 mg Mo/L (Heijerick et al., 2012). The predicted no-effect concentrations (PNEC) are 12.7 mg Mo/L and 1.92 mg Mo/L correspondingly for freshwater and marine water (Heijerick et al., 2012a). When sulfates present in drinking water in excess of 250 mg/L they cause a cathartic action (especially in children) in the presence of sodium and magnesium, and when the concentration exceeds 600 mg/L, diarrhea. When sulfate-rich effluents are discharged into the environment, they may increase the acidity of water bodies and soils (Guimarães and Leão, 2014). Because of the adverse effects to human health and the environment, limits are set for SO42- concentrations in waters and wastewaters in the range of 250 / 500 mg/L."

Jan 1, 2018

By Ali Behrad Vakylabad, Esmaeel Darezereshki, Babak Koohestani

As a by-product of the steelmaking industry rich in iron and zinc, electric arc furnace dust (EAFD) landfill disposal is restricted in many countries due to the metal lixiviation risks. Several approaches have been examined to recycle or reuse EAFD. Hydrometallurgical methods mainly include the preparation of pregnant acid leached solution (PLS) using inorganic acids followed by selective metal recovery using different methods. We herein proposed a hydrometallurgical process initiated by acid leaching and finalized by thermal treatment to produce nano-ZnO from EAFD. At the condition of this study, only 67% of zinc was leached by sulfuric acid from EAFD into PLS while 98% of surplus leached iron was removed through precipitation by sodium hydroxide. Additional purification of iron removed PLS was accomplished using di-2 ethylhexyl phosphoric acid to extract Zn+2. The addition of ammonium hydroxide to purified PLS provided (Zn(OH)2)3(ZnSO4)(H2O)5 as the final precursor for nano-ZnO that ultimately transformed to nano-ZnO (60 ± 6 nm particle size) at 850 °C. The achieved results were scrutinized through various tests and analyses including TEM, XRD, SEM, EDS, FTIR, and TGA.

Mar 10, 2021

By A. Noble

"In coal and mineral processing, several numeric parameters are used to quantify the separation performance of unit operations. For density-based separations, the partition curve is used as the starting point for many stages of diagnostic analyses. The curve is often quantified by its midpoint slope sharpness, and this single value is subsequently used for technical evaluation, benchmarking, and comparison. While this analytical approach does depict misplacement by relative density class, it inherently prioritizes middling separation and does not consider process economics or the micro-price value of individual classes. An alternative parameter, the organic efficiency, does indirectly consider process economics, but it does not reveal information on the root cause of lost revenue or misplacement. In this paper, a new analytical approach, the partition moment of inertia, is introduced. This parameter reconciles the technical misplacement data derived from the partition curve with the economic data derived from micro-pricing. The result is a new analytical procedure that promises better use of performance data. IntroductionPartition curves are commonly used in the characterization, evaluation and simulation of various physical separators. In mineral processing, partition curve analysis is routinely applied to hydrocyclones, screens, density separators and other beneficiation technologies that are based on intensive physical properties. Graphically, the partition curve depicts the recovery of particles as a function of the physical property on which the separation is based, such as particle density, size or magnetic susceptibility. Given the probabilistic nature of many real separators, the partition curve often exhibits a characteristic S shape (Fig. 1), similar to a cumulative normal distribution. Other geometric features of the curve are also depicted in Fig. 1, including the high and low closeout, or bypass, values; the midpoint slope; and the separation cut point, defined as the property value with 50 percent recovery.Partition curve analysis was originally proposed to evaluate coal washability (Tromp, 1937). Given the limited computational resources at the time, the analytical methods relied heavily on graphical construction and interpretation of the curve. Owing to the simplicity of calculation and interpretation, many of these graphical approaches are still widely used for performance analysis today. The most common calculations are based on the slope of the partition curve at the midpoint. Increased slopes correspond to enhanced separation performance, as a perfect separation exhibits a stepwise transition from 0 to 1 at the desired cut point, that is, an infinitely large slope. One common formulation of this slope, the Ecart Probable, Ep, is derived by evaluating the slope between the 25 and 75 percent recovery points:"

Jan 1, 2016

By S. M. Copley, M. Yankova, E. Y. Yankov, J. A. Todd

"Nanophased coupled growth structures, with spacings of -10 nm, have been observed in banded microstructures produced by laser melting hypoeutectic Ag-Cu alloys. These coupled growth structures comprised a Cu-rich phase of width - 1 nm and a Ag-rich phase of width - 9 nm. In this paper, microstructural observations of nanophased coupled growth structures in hypo eutectic AgCu alloys are presented. Laser beam velocities for the transition from banded to microsegregation free microstructures are modelled and compared with experimental values. Models are presented to show that, at a critical undercooling, initial growth of a Ag-rich, metastable, extended solid solution is rapid but slows to a halt as copper is partitioned into the liquid at the solid/liquid interface. Following nucleation, the coupled growth structure then grows until the partitioned copper is consumed, at which point growth of the Ag-rich solid solution is again accelerated. This cycle then repeats resulting in banded microstructures comprised of 750 nm of the Ag-rich extended, metastable solid solution, followed by 250 nm of the coupled growth structure.1. Structural Studies of Laser Melted and Resolidified TrailsPresented here are observations of laser melted and resolidified trails in Ag-Cu alloys obtained at beam velocities ranging from 0.7 to 34 cm S·I. When the laser beam is scanned along the surface (positive x-direction) with a velocity Vb a melt pool with the shape given in Fig. 1a moves with the beam. The isotherms move with the velocity, Vi,. = Vb cos.p. Calculations employing the thermal analysis of Kou, Hsu and Mehrabian [1] for the beam velocities of this investigation and for the thermal properties of AgCu alloys, indicated that, .p, the angle between the isotherm velocity and beam velocity should be small at the surface where microstructural studies were made. This prediction was supported by observations of trail cross-sections. Based on these observations, and the calculations which include latent heat effects, the isotherm velocity for observations near the surface in our investigation was taken to be 27 cm S-I."

Jan 1, 1994

By J. R. Thoenen

The objective of this circular is threefold: First, to describe briefly the various modes of occurrence of sand and gravel. Second, to emphasize the need for adequate prospect¬ ing and exploration prior to the expenditure of funds for development and plant construction. Third, to describe various methods of prospecting and exploration and their application to the several modes of occurrence of sand and gravel. Sand and gravel may be found in nearly every county or township in the United States. Commercial deposits, however, are by no means so widespread. The introduction of concrete and the consequent impetus given to consumption of gravel and sand aggregates has seriously depleted deposits in some congested areas. Increasing re¬ strictions in the specification requirements for marketing sands and gravels have further narrowed the economic areas. On the other hand, the combination of increasing transportation costs and decreasing selling prices has forced the decentralization of gravel production. As a result smaller, intermittently operated, and widely scattered portable or semiportable unit plants have been encroaching on the territory formerly supplied from centrally located pits with large tr.atment plants. Generally speaking, the small portable plant can not produce any great variety of ma¬ terials to as exacting specifications nor as economically as the large permanent plant.

Dec 1, 1932

By DING TANG, JINGHE CHEN, Shuiping Zhong, CHEN KUANG

The Zijinshan gold-copper mine, in spite of the low-grade nature of the ore, has become one of the largest production-scale and most profitable non-ferrous metal mines in China. The successful application of hydrometallurgy as well as proper engineering design are the key factors for large-scale development of the Zijinshan gold-copper mine. In this contribution, the practical experience acquired in the development of the Zijinshan gold and copper mines is summarized. This covers most aspects of the production process including mining, beneficiation, ore stacking, heap (bio)leaching, carbon-in-leach, solvent extraction, electrowinning, wastewater and tailing treatments. The authors believe that this practical experience will not only help to promote the development of hydrometallurgy, but can also serve as a model for other gold and/or copper plants around the world.

Jun 3, 2020

By K. Kryst, K. Elkayar

The increasing need to process lower grade contaminated copper concentrates and simultaneously produce higher purity copper cathodes necessitates a more diligent control in the electrorefining process. Ion exchange processes can be a powerful tool in controlling electrolyte impurities to ensure trouble free operation within the tankhouse and to help maintain cathode purity. In addition, some impurities can be recovered as a value added product. The use of a short bed ion exchange process provides a unique opportunity for impurity management in copper refineries. Several metals are discussed in this paper, including Sb, Bi, As and Ni and their methods of control and recovery within the copper electrolyte circuit. INTRODUCTION To produce a high purity copper product by electro-refining a copper electrolyte, it is important to control the concentration of impurities such as arsenic (As), bismuth (Bi), antimony (Sb), and nickel (Ni). These impurities are introduced into the electrolyte from the copper anode and can affect the copper product and the production operation. The presence of As in the copper product results in a lower electric conductivity and reduced workability of the copper. High levels of Bi in the electrolyte will result in a copper cathode product containing Bi. High Sb concentration will cause undesired floating slimes. A variety of methods have been developed to control the level of these impurities in the copper electrolyte including precipitation, liquid extraction, and ion exchange. These impurities can be recovered and used. This paper discusses novel methods that utilize short bed ion exchange technology to control these impurities. Also, the use of ion exchange to recover acid from the liberator cells bleed for reuse in the tankhouse is reviewed. SHORT BED ION EXCHANGE Short bed ion exchange technology has been employed extensively in the metal finishing industries for over forty years. Unlike conventional ion exchange, short beds are fixed beds without freeboard space. The application of short bed technology results in significant benefits when compared to conventional ion exchange. The resin used in this technology has a significantly smaller diameter than conventional ion exchange resin. As a result of the smaller resin size, exchange kinetics improves dramatically. This facilitates operation at higher flow rates and the use of smaller beds with a small mass transfer zone length. Smaller beds are especially important for applications that use chelating resins due to the high cost of the resin.

Jan 1, 2019

By J. Warner, K. A. Hughes, P. E. R. Blanchard, J. Esslifie-Dughan, J. W. Reid

Tailings management plays an important role in reducing the environmental impact of Orano Canada’s uranium mining operations in Northern Saskatchewan. Uranium ores mined from Northern Saskatchewan are often associated with large amounts (10-20 wt%) of other harmful elements, such as arsenic and nickel. The JEB Tailings Management Facility (TMF) located at McClean Lake, Saskatchewan is designed to prevent potentially harmful water-soluble elements, particularly arsenic, from contaminating the surrounding environment by promoting the formation of water-insoluble minerals. It is therefore important to determine which arsenic-containing mineral species are present in the TMF and how they evolve over time. Researchers at the Canadian Light Source (Saskatoon, Saskatchewan) were successful in identifying the arsenic mineral species present in tailings samples collected from the TMF in 2013 using X-ray absorption near-edge structure (XANES) spectroscopy. XANES analysis verified that the majority of arsenic species in the TMF existed as amorphous and crystalline ferric arsenates with minor amounts of arsenite and arsenide species. Herein, XANES is again used to analyze a new set of tailings samples collected from the TMF in 2018, specifically focusing on the difference in the distribution of arsenic species in old and new tailings.

Jan 1, 2020

By K. G. Wang, M. E. Glicksman, P. Crawford

"We formulate the mathematical solution to late-stage multi particle diffusion in finite systems. The transition from finite system behavior to that for an infinite system is established. Large-scale simulations are reported regarding the dynamics of phase coarsening. Even in the case of a small volume fraction (Vv = 10-4), the particle size distribution is broader than that for the well-known Lifshitz-Slyozov limit at zero volume fraction. We also report the first simulation studies of extremely low volume fraction, for which corresponding experiments, as well as other simulations, do not exist at present for comparison. However, in the case of moderate volume fractions (Vv = 0.1), the fiucutations in the volumetric growth rate of particles are extracted from our simulations. These simulations provide additional insight into the statistical nature of diffusion interactions, including multiparticle stochastics during microstructural evolution.IntroductionPredicting microstructure evolution in alloys remains one of the cornerstones of materials science. Phase coarsening is a common process in microstrucural evolution that leads to a decrease in the excess total interfacial energy of the system. The system typically consists of separate and identifiable units, or domains, such as second-phase particles distributed in a matrix. During phase coarsening, larger particles grow at the expense of small particles. Over time, this ""competition"" results in an increase in the average size of the particle population, and in a concomitant decrease in the number of particles.Particle size and microstructure of many cast alloys depend on similar coarsening processes. Indeed, properties of these materials, such as strength, toughness, ductility, and electrical conductivity, depend on the material's average particle size and particle size distribution (PSD). Understanding and controlling microstructures in two-phase systems are clearly of widespread technological importance."

Jan 1, 2001

By E. Siami-Irdemoosa, S. R. Dindarloo

"Discrete event simulation is a stochastic mathematical modeling tool with applications in queuing systems. Many mining operations, both surface and underground, can be simulated in the context of queuing theory , for example open pit loading and haulage operation, underground level and vertical transportation, and mineral processing circuits. A computer simulation model of the operation is an invaluable tool to study both the system’s dynamics and conducting sensitivity analysis on different effective elements on system performance. In this paper, merits of discrete event simulation in decision making in mining engineering is discussed. Moreover, a stochastic simulation framework for selection and sizing of shovels and dump trucks in surface mining is presented to elaborate one example for applicability of the method in mining operations. INTRODUCTION Mathematical modeling is a valuable tool in design, optimization, and decision making in both surface and underground mining operations. Several researchers have tried to study different aspects of mining operations using a wide range of mathematical techniques such as linear programming[1], analytical hierarchy process [2], non-linear programming[3], genetic algorithms[4-5] ,mixed integer programming [6], machine repair model[7], queuing theory [8], and conventional spreadsheet calculations based on experience and engineering judgments. There are different uncertainties in typical mining operations (e.g. material loading and haulage, drilling, and blasting). For example, in a truck-shovel operation, different governing activities such as loading, haulage, and dumping cycles are stochastic variables. Moreover, analytical modeling of a large truck-shovel operation is very complicated. Thus, application of analytical and/or deterministic techniques cannot guarantee a solution for different problems that are encountered in daily mining operations. Discrete-event system simulation (DES) is a modeling method for such time discrete and probabilistic phenomena [9]. DES has been employed by different researchers in mining engineering through available software and languages such as GPSS, SIMAN- ARENA, and SLAM [10-14]. Most of the studies so far, tried to evaluate some “what-if” scenarios, to understand the possible effects of changing different input variables on overall mine economics. For instance, Baffi and Ataeepur (1996) used Arena to simulate a truck-shovel operation [10]. Also, Sturgul has conducted extensive studies in the application of DES in the mining engineering field [15- 17]. A very good background review of application of this technique in the industry can be found in [15-16]. Previous studies have shown that, different approaches including deterministic, stochastic, and experimental methodologies result in considerable differences in outputs [18]. These techniques lead to different solutions, regardless of the quality of technique/software itself or knowledge of the modeling team. Hence, the first step is to develop a comprehensive simulation framework to obtain nearly the same optimal results for the same input variables, regardless of the employed technique."

Jan 1, 2016

By M. W. Bartley

"The Steep Rock iron mine is 141 miles west of Port Arthur, Ontario, and 50 air miles north of the Vermilion iron range in Minnesota. The property lies 27'2 miles north of the village of Atikokan on the south line of the Canadian National railway.The orebodies underlying the bed of Steeprock lake, since de-watered, were known to exist 60 years ago. References to the possibility of iron ore at this location were made in early geological papers and reports. In 1937 the locations of the orebodies were determined by dip-needle surveys, and from 1938 until 1943 diamond and churn drilling were carried on to prove their extent and configuration. It was found that the ore, in addition to being associated with definite types of wall-rock, was controlled by structural features, such as faulting and brecciation. From this geological knowledge the presence of other deposits has been inferred, and these are now being explored and developed.Production at the property commenced in October 1944. During that season 17,000 gross tons of ore was shipped. In 1945, 506,000 gross tons and in 1946, 830,000 gross tons was mined and shipped. In 1946, 164,000 gross tons additional was placed on stockpile for future shipment.TYPES OF 0REBODIES AND MINERALIZATIONThe orebodies at Steep Rock iron mine are tabular. They have an average width of 250 feet, lengths up to 5,000 feet, and persist to known depths of 1,200 feet. They are replacement deposits in brecciated carbonate rock at the contact of underlying pseudo-limestones and overlying volcanics. The ore is composed of hematite and hydrous hematite in the form of goethite, turgite, and limonite. These minerals replaced the brecciated host rocks metasomatically as a result of hydrothermal action. The replacement followed a definite structural pattern along the unconformable contact between the sediments or other rock (now replaced by carbonate) and the volcanics, subsequent to disturbances in the form of minor faulting and shearing. The faulting and shearing provided the channels through which the replacing solutions percolated. It is believed that the late basic intrusions outside the ore zones were genetically responsible for the introduction of the ore-bearing solutions."

Jan 1, 1954

By T. Feldmann, G. P. Demopoulos

The feasibility of chloride leaching processes depends on interfacing them with cost-effective HCl regeneration technologies. This paper summarizes the most important findings of research conducted in the past 3 years concerned with a novel process to regenerate high-strength HCl from concentrated CaCl2 solutions at temperatures below 100°C, via reaction of CaCl2 with H2SO4 resulting in the formation of calcium sulfate phases (gypsum, a-hemihydrate or anhydrite). From constant supersaturation semi-batch experiments in pure solution it was found that the crystal growth rate of hemihydrate, and hence the particle size, was influenced by the rate of reagent (Ca2+, SO4 2-) supply to the reactor. Additionally, growth studies of DH in presence of impurities (K+, Mg2+, Sr2+, Ba2+, Fe2+/3+, Al3+, La3+, Y3+, F- and PO4 3-) showed that specifically Sr2+ and PO4 3- are taken up during crystal growth. Furthermore, it was found that decreasing water activity (via different HCl/CaCl2 concentrations) and increasing temperature reduce the metastable life-time of DH and HH by increasing the phase transformation speed. The DH/HH transformation was identified to be dissolution-precipitation based, while HH to AH is a topochemical process. Finally, continuous experiments on bench scale are underway to confirm the feasibility of the process to obtain super-azeotropic strength HCl with up to 9 mol/L (~30wt.%) from 5 mol/L CaCl2 (~40wt.%) solution.

Jan 1, 2014