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By Ingemar Hermansson, Thomas Bjerendal, Mattias Grävare, Carl-John Grävare

"AbstractHigh strain dynamic pile tests (HSDPT) on driven piles have been carried out on a routine basis in Sweden for more than 30 years. The Swedish Commission on Pile research established, in the early 1980s, safety factors based on the percentage of piles tested. The safety factors could then be reduced, creating economic incentives for the contractor to carry out testing.Energy formulas adopted by our neighbour countries, Norway and Denmark, were not accepted in Sweden as a reliable method since the dynamic testing method was considered to be a more scientific and reliable method. It has become almost the only in-situ method used to verify geotechnical bearing capacity on driven piles.The typical Swedish geology of soft soils overlaying very hard strata makes it possible to verify high design loads, typically 20 kN per cm2 of pile cross sectional area for steel piles and 1,5 kN per cm2 for concrete piles.Conventionally a certain percentage of the piles have been tested in Sweden. The EC7, on the other hand states a number of piles to be tested, regardless of the total number of piles. The Swedish NA (National Annex) states a maximum distance between tested piles, which results in better distribution of the test piles over the foundation.For shaft-bearing piles in soft clays, dynamic pile tests have to be correlated by static load tests.Historical backgroundOn a research basis stress-wave measurements have been carried out for a long time in Sweden. One example is a project in the city of Gothenburg, conducted by Fellenius and Pejrud (1964). Strain gauges were glued on the reinforcement bars in 60 m long, precast concrete piles at 3 m and 25 m above the pile tip respectively. Evaluation was done with different methods such as dynamic formulas,stress-wave measurements and in addition compared with static load tests.In the 1975 Building Code in Sweden, driving criteria for concrete piles based on stress-wave theory were introduced, as summarized in Table 1. The driving criteria are intended for 3 and 4 tonne gravity hammers. For hydraulic rigs, which have free-falling hammers, the drop height indicated should be reduced to 80 % of the values in the table. The criteria were considered to include a safety factor of 3,0. For 330 - 450 kN pile load, pile with a standard a cross sectional area of 235 mm x 235 mm was used. For 600 kN load, the standard cross sectional area was 275 mm x 275 mm."

Jan 1, 2014

By W. M. Small

From the one producing well in Austria, 7000 bbl. of heavy oil was produced and sold in 1933. This well, owned by the Raky-Danubia, was completed late in 1932 in the formation called Flysch (Upper Cretaceous or lower Eocene) near Zistersdorf north of Vienna. Two wildcats drilling in the vicinity have not yet reached the producing beds. Near Vienna, the European Gas and Electric Co. drilled five shallow wells for gas, three of which were failures. One gas well was completed for 8 million cu. ft. capacity at 260 meters depth and with a pressure of 570 lb. Another is being tested following blowouts. One gas well and one dry hole were completed in the pool in 1932. In Upper Austria, the same company abandoned one wildcat at 679 m. and is drilling at 280 m. on a second. No gas was sold during the year, but a line is being completed to supply fuel to boilers of the Vienna Electric Works. Hungary No deep drilling was done in 1933. Oil and gas concession was granted by Parliament to the European Gas and Electric Co. on Trans-danubia. Active geological and geophysical investigation is in progress. Czechoslovakia In the Gbely and Hodonin shallow fields, some 26 wells were drilled of which three were reported as failures. The total production of the fields was 111,736 bbl. of oil and 40 million cu. ft. of gas used as fuel in the field. At Vacenovice, where there were already two small gas wells, a third producer was completed at 420 m. This pool markets a small amount of gas, which is compressed and used to light railway carriages. Wildcat wells were reported drilling at about 300 m. depth at both Jasina and Telnice. One 700-ni. wildcat near the Hodonin field was abandoned. Another failure was reported completed and abandoned at 820 m. near Holic.

Jan 1, 1934

By F. S. Crawford

During the course of a study of the safety organizations of the various iron mining companies in the Lake Superior district considerable in¬ formation regarding the methods of safety inspection in use was obtained which may be of value to other companies beginning safety work or contemplat¬ ing changes in their methods. A short description of the safety-inspection methods of eleven of these companies is given in this paper, and in the appendix are illustrated a number of forms used for safety inspections by several of the companies. Most of the companies whose methods are described use few forms for formal inspection. The one long form (10) attached which is used for a general in¬ spection by the safety inspector appears to present a good method for enabling the inspector to check all branches of his inspection and to assure himself that everything has been covered. All names of companies have been deleted from this paper and from the forms because the object is to disseminate information of constructive value rather than to point out the methods of particular companies by name.

Aug 1, 1931

By Thomas Lien

Session 1 - 1 :45 p.m. June 27,1983 Session Chairman: Robert Diederich, RMCMl New Mexico Vice President MR. DIEDERICH: My name is Bob Diederich. I'm the Vice President of the Rocky Mountain Coal Mining Insitute from the state of New Mexico. I'm manager for the Navajo Mine down in Farmington, New Mexico and also project manager for a new mine that we're starling out called the LaPlata Mine in the same area. I'd like to introduce our first speaker, Tom Lien, who is the Director of Engineering, Western Division of AMAX Coal Company. He is responsible for mine engineering, environmental engineering, permitting, reclamation, planning, design and construction plant engineering, geology exploration, quality control and real estate for the western division. He joined AMAX Coal in 1980 as manager of preparation and quality control and was promoted to the present position in August of 1980. He has a BS in geological engineering from the University of Mines. He previously worked for Kennecott Copper Corporation in Hayden, Arizona from 1965 to 1970. He worked as a mine geologist, mill metallurgist, mine production and quality control engineer. Then he also worked for Kaiser Steel Corporation, Eagle Mountain Iron Ore Mine in California, 1970 to 1977. Worked as a process engineer and plant superintendent at that place. Then he was employed by Mountain States Research and Development, Tucson, Arizona, 1977 to 1980. Worked as a senior process engineer and operation superintendent. So without further ado, I'd like to introduce Tom Lien who will talk to us about in-pit coal crushing. MR. LIEN: Thank you. The official title of my paper is actually: "The Potential for In-pit Crushing and Conveying in the Powder River Basin." The Powder River Basin is one of the world's greatest coal fields and will be an important source of energy for centuries to come. About one-eighth of the total coal producing in the United States comes from the Powder River Basin, and 80% of that production came out of Campbell County, Wyoming last year. The growth potential for this region is projected to be enormous. New technology as well as existing technology will make this region competitive in the decades ahead. Understanding the current status of the Powder River Basin, both the mines and the possible methods for changing the means of material movements within the mines is the subject of this paper. Each mine is unique and must be addressed specifically with respect to the application of new and innovative technology. There have been many articles written in the recent mining journals on in-pit crushing and conveying applications, including costs which are very interesting, enlightening and I recommend it to any company considering such installations. To give a general setting, coal production in the United States for 1982 was about 800,000.000 tons. This production came principally from six regions, the Applachian fields of the eastern states where bituminous and anthracite coals have been mined for almost three centuries, the Midwest located in the upper Mississippi Valley are often typified by huge dragline operations of which AMAX Coal has three right now, the Gulf Coast lignites. feeding mine-mouth power plants, the vast bituminous and sub-bituminous departments of the four-comer states of Arizona, New Mexico, Colorado, and Utah and finally the Northern Great Plains lignite fields currently being developed and the sub-bituminous fields of Wyoming and Montana including the Powder River Basin. The Powder River Basin is located in northeastern Wyoming and southeastern Montana. It is the darker brown right in the center of the photograph. It covers about 18,000 square miles. It's about 200 miles north to south and 90 miles east to west. The shallowest coal beds are on the east, north and northwest edges of the basin with deeper coal beds toward the center in the same kind of relationship. There are about one trillion tons of coal in the Powder River Basin, that's the one with 12 zeros after it. A little bit there. It's distributed in many, many seams at varying depths to the current topography. In 1982 about 100,000,000 tons of coal were mined from this basin and 81,000,000 tons came out of Campbell County, Wyoming. The mines that are shown in this picture are basically the mines around the basin edge. The principal area that I'll be talking about is the eastern edge down where it shows Gillette and Campbell County. Geologically the Powder River Basin is the Fort Union formation. The most productive seam is called the Wyodak or Smith-Roland or the Anderson-Canyon, depending upon where you're located. There is about 75 billion tons of coal in the Wyodak of which about 23 billion are considered surface minable today. the coal is Paleocene in age, about 40,000,000 years old. It was once an old Delta region very much like the Mississippi River delta is today. During the 100,000 years that this deposit was formed peat accumulated to a thickness of about 365 feet. It was later buried and turned into sub-bituminous coal. All of the coal mined in the basin is for the electric utility industry. This coal has a typical BTU content of about 8,300 plus or minus about 4,500 BTUs. Sulfur coal is generally less than'/ %, thereby making this coal compliance coal in terms of sulfur dioxide emissions, 1.2 pounds of sulfur dioxide per million

Jan 1, 1983

By G. H. Billings

The following data were collected some years since in the course of a series of experiments with oil as a substitute for coal in puddling, the earlier form of the Archer apparatus being employed. While I am not at liberty to give the name of the works at which the tests were made, I can personally warrant the accuracy of the record, and feel justified, therefore, in making this contribution to a discussion in which all trustworthy figures are likely to be helpful. Oil in Puddling. Starting with everything cold, we used 3518 pounds of oil to get the furnace in condition to charge a heat. After charging, we ran until we took out 13,340 pounds of puddled-blooms, using 8437 pounds, or 1333 gal1ons of oil. At 49 cents per gallon, the cost for oil per gross ton of blooms was $10.91; with coal at $4.871/2, and a consumption of 1.5 tons per ton of blooms (the usual quantity is ton for ton), the cost for coal is $7.31. The quantity of oil consumed in heating the furnace to the proper temperature and to make the bottom, is not included in the oil consumption stated. The quantity used was 3518 pounds of oil. Usually, the furnace need only be lighted, but in this case it had been repaired, and it was necessary to make a new .bottom. This required the quantity of oil necessary to make three heats of blooms, or 2109 pounds. Deducting this from the 3518 pounds leaves 1409 pounds of oil as the quantity consumed every week in lighting up.

Jan 1, 1889

By Matthew Violot

Introduction ?Located off highway 6, approximately 5 km, SW of Thompson, Manitoba ?Base metal mine: Nickel? Maximum Depth: 4100 ft ?Started Production in 1966 (INCO, 2006)?Halted in 1978?Re-opened in 1989 ?Two types of mining:?VBM (vertical block mining)?Cut and Fill 1.1 Problem ?Birchtree mine is experiencing failures and undesirable dilution in some of their stopes. ?Time can have a large effect on open stopestability. ?Birchtreeis interested in how time is affecting the stability of their stopes. ?The study focuses on the lower 84 complex, which extends from 2750 to 4100 foot level.

Nov 1, 2011

By L. M. Gochioco

The U.S. coal industry is under-going dramatic changes to meet the challenges of the keenly competitive fuels market. The application of innovative technologies is needed to improve safety and to increase productivity in order to make coal more competitive as a fuel. As more coal companies shift into capital intensive longwall mining, there is a clear need to invest more in exploration before mine plans are made. Coal seam anomalies may create adverse mining conditions. The early detection of these anomalies could make the longwall mining safer and more productive through improved planning. A standard exploratory drilling program can provide only limited geologic information. The seismic reflection technique can be used to detect coal seam anomalies and is effective in reconnaissance surveying. Recent advances in the quality of coal seismic data have increased the success rate of seismic surveying. Therefore, surface seismic surveys, coupled with selective drilling, will come to play an integral role in coal exploration in the 1990s.

Jan 1, 1990

By O&apos, M. W. Neill

Mini-piles have been found to be a practical, technically correct remedial underpinning method. They can be constructed in limited access areas with very little disruption. Experience indicated that mini-piles installed using a down-the-hole soil displacement hammer would be particularly effective in the "bottomless" Beaumont Clay formations in the Houston, Texas, U.S.A. area. The University of Houston Foundation Testing Facility was ideally suited to perform tests on mini-piles. The availability of extensive geotechnical data and previous pile test results was invaluable in evaluating the mini-pile test data. As expected, the mini-pile test results were consistant with test results from large sized driven piles in the same soil formation.

Jan 1, 1989

By P. Barnes

(Read at the Wilkes-Barre Meeting, May, 1877.) IN vol. 33 of the Proceedings of the Institution of Civil Engineers, London (part 2, for 1870-71), may be found a statement of the cost of two blast furnaces, together with a somewhat detailed description. The attempt will be made in this note to restate these items of cost, so that the information may be rendered perhaps more accessible to our members than in its present place of record, and also in order that the items may be more intelligibly compared among themselves, or with similar items in other cases.

Jan 1, 1878

By Petr Sulovsky, Pavel Leber, Jaroslava Ledererova, Miroslav Svoboda

"The properties of raw materials used for the production of building materials play an essential role in their choice. Industrial waste materials can in some cases improve the performance of new building materials, when compared with classical raw materials. The addition of waste can however negatively impact some of the building material´s characteristics, influencing its stability, service time, durability, and can introduce undesirable variation of certain characteristics over time. It is necessary that each secondary raw material intended for such use be thoroughly investigated in terms of its chemical, physical, and mechanical properties, with special attention paid to the risk components and risk parameters. It is necessary to make many- sided technological tests in relation to the required characteristics of the resulting materials for each chosen application. Moreover, the limit values for the critical (risk) parameters, which the given secondary raw material must satisfy to be used in a specific technology, need to be defined. Introduction The risk components in the industrial waste materials to be used in the production of building materials fall into two groups: - components that pose a risk of development (instant or delayed) of a process deleterious to the utility properties and durability of the resulting materials. Such processes include volume change (expansion as well as shrinkage), alkali-silica reaction, delayed ettringite formation, thaumassite attack, aggressive carbonation, etc. - elements or components that can, if released from the waste-containing building material, pollute the environment. They involve the so called potentially hazardous elements as well as compounds like fenols, PCB, PAHs etc. From the viewpoint of the presence of both groups of risk components, the wastes can be classified as: • environmentally inert waste materials. They are produced in the largest volumes and do not pose a threat to human health. Their physical and/or chemical characteristics fail to satisfy all requirements for utilization in ordinary production. The aim of technology design is to work them into the building products with suitable utility properties. • easier workable waste materials containing toxic components are produced in large volumes. In spite of the content of toxic components, their physical and chemical properties make them suitable for ordinary production, provided that the harmful substances are immobilized by the chosen technology."

Jan 1, 2008

In discussing the Asia-Pacific region weare talking about a region which has more than 60% of the world's population, a regional economy which will in 10 years be larger than the European Economic Community, and a group of countries with some of the highest electricity generation growth rates in the world. It is economically the most dynamic region in the world.

Jan 1, 1990

By W. C. Kerr

ThE distribution of gold is obviously much wider than is Commanly supposed. Resides the usual matrices, vehicles, or associates, such as quartz, pyrite, chalcopyrite, etc., I find it occurring in quite a range of common rocks. For example, at the Rhodes mine, in Gaston County, a body of 9 to 12 feet of decoroposed, light-gray gneiss was worked together with the strings of quartz, and yielded from six to ten dollars to the ton. A mine in Moore County yields its gold mainly from a feldspathic schist. In the famous King's Mountain mine, in Gaston County, the gold is obtained not only from the seams of quartz in a blue, hydromicaceous schist, but a 60-foot ledge of grayish-blue, fine-grained, schistose limestone is quarried out bodily and sent to the stamps. It is gold-bearing throughout. In Montgomery County the singular concretionary, conglomeritic, quartzite schist, which contains Emmons's palceotrochis, is gold-bearing over wide tracts of country. This fact was noticed by Dr. Emmons. But a still more striking and significant fact is, that a large part of the gold of Montgomery, Davidson, and Randolph counties,

Jan 1, 1882

By M. Kumral, E. Dilhuydy, B. Ozdemir

"In-pit crushing and conveyor (IPCC) systems have become increasingly popular in the mining industry as an alternative to truck-and-shovel systems. Deciding whether to haul waste rock by truck or IPCC represents an important gap to be investigated in semi-mobile IPCC systems. A cost analysis is presented to evaluate the feasibility of crushing and conveying waste material in IPCC systems, along with sensitivity and risk assessments through Monte Carlo simulation. Although the capital expenditure is higher, results showed waste crushing will be feasible in deep pits and over long mine life and haul distances.RÉSUMÉ La popularité des systèmes de concassage et de transport dans la fosse minière (IPCC, de l’anglais In-pit crushing and conveyor) n’a cessé de croître dans l’industrie minière ; ils constituent en effet une option intéressante de remplacement des systèmes par camions et pelles mécaniques. Le choix entre le transport des stériles par camions ou par IPCC est encore difficile à faire et devra faire l’objet d’une étude approfondie au niveau des systèmes d’IPCC semi-mobiles. Une analyse des coûts est présentée pour évaluer la faisabilité du concassage et du transport des stériles par les systèmes d’IPCC, de même que des évaluations de la sensibilité et des risques par le biais de la simulation de Monte Carlo. Si les dépenses en immobilisations s’avèrent être plus élevées, les résultats ont cependant montré que le concassage des stériles sera envisageable dans des fosses profondes ainsi que sur une longue durée de vie et de longues distances de transport. INTRODUCTIONThe mining industry is currently facing many challenges such as low commodity prices, increasing environmental concerns and regulations, lower grades, deeper mines, and greater waste-rock quantities. As a result, the profitability of mining operations has decreased, with many mines stopping or suspending operations, and many new projects being postponed. Mining companies have therefore focused on improvements and innovations to increase the cost effectiveness of operations, for example, increasing production capacity to take advantage of the economies of scale (Crowson, 2003) and decreasing the unit operation cost. Changes in production capacity force mining companies to evaluate alternative material handling systems.During the past few decades and within material handling systems, significant improvements have been made to truck performance and capacity. Consequently, operating expenditures (OPEX) associated with fuel and maintenance have risen swiftly. In a mining operation, truck hauling systems now represent 40–50% of the capital cost and approximately 45% of the OPEX (Tutton & Streck, 2009). Additionally, material transportation costs are expected to increase due to longer haul distances arising from deeper and larger mines (Fleet et al., 2015). Finally, large fluctuations in fuel prices result in high risks associated with truck OPEX. According to the United States Energy Information Administration (2015), the cost of crude oil—the largest component of the retail price of diesel fuel—increased from US$24.31/barrel in 1986 to US$46.92/barrel in 2016, peaking at US$151.72/barrel in 2008 (Macrotrends, 2016)."

Jan 1, 2017

By D. L. Johnson

Only general treatment of a subject of such scope can be given in a short paper, therefore, except in a few instances, statistics and descriptions of specific installations are omitted. The earlier applications of electricity to the production of petroleum in the Mid-Continent field were widely separated chonologically, each holding a special interest, and each contributing greatly to the present development. Electric Pumping One of the first installations of electric pumping was on a lease near Jenks, Okla., in the Arkansas River bed, where a difficult problem was solved by the use of motors. The Arkansas River had frequent flood periods which interfered seriously with the use of jacks and pull rods. Small piers were built with old casing used as piling, and upon these were set small jacks driven by 3-hp. squirrel-cage motors. The starting switches were located on a bank and the power was furnished by a small generator, which was driven by an oil country gas engine. This installation was made in 1913 and is, I believe, still in satisfactory operation. In 1914, the Cushing field came in and the Hill Oil & Gas Co. electrified its Shamrock property, using eight-pole Star Delta motors, rated at 10 to 30 hp. and belted through countershafts to the band wheel. Power was furnished by a small generating plant consisting of two 135-kw. machines, gas-engine driven. Considerable difficulty was experienced in the early operation of this station because of low voltage. It is characteristic of small alternating-current generators that voltage regulation will be poor with widely fluctuating loads. This field had three producing sands, and a number of wells were redrilled with the motors, and this, together with a great deal of swabbing, was responsible for the bad load conditions. However, when the wells had settled down to steady operation, the electric equipment functioned satisfactorily, and continued in use as installed until a few years ago when the present owners contracted for service from a central-station company and shut

Jan 1, 1928

By W. E. STOKES

A GENERAL extension and appreciation of the stereocartographic principle of precise mapmaking is evident. Under the stimulus of war, many radical improvements in aerial photography, and in airplane and motor con? struction are indicated for the future. A survey of advanced military designs points to the conclusion that the familiar radial motor is destined for oblivion under the impact of the inverted "V" type.' The latest German inverted "V" design of 1000 hp. is 68 in. long whereas British and American motors of the same power are 72 and 94 in. respectively, suggesting a horsepower-weight efficiency ratio in favor of the former. Application of the pressure cooling principle has made possible the development of in-line air? cooled engines which offer many advantages, such as small frontal area, unobstructed vision for the pilot, freedom from vibration because rotative speeds are not limited by fundamental unbalance of reciprocating parts, freedom from excessive bearing loads, and less weight per horsepower.

Jan 1, 1940

Effective gas management in coal mines, as well as proper ventilation design, is very important for maintaining the safety of underground coal miners. Advances in numerical modeling techniques have enabled evaluations of the coal mining environment using advanced grid designs and computed gas distributions through detailed mathematical models. These models help engineers to see the unseen areas of the mine through visualization of the data and ultimately help improve worker safety. This paper summarizes the modeling efforts conducted by NIOSH in the U.S. and CSIRO in Australia to address various gas management issues encountered in longwall mines. The modeling studies involved two of the most widely used grid-based techniques, namely computational fluid dynamics (CFD) and numerical reservoir modeling. This paper discusses the application of these techniques for gob inertization and gas control for spontaneous combustion, pre-mining degasification of coalbeds, gob gas venthole design and performance evaluation in longwalls, and gas management during development mining.

Jan 1, 2009

By Dight P. M

The challenge of narrow vein mining is to produce ore with as little dilution as possible, at the least cost -commensurate with the increasing degrees of safety being demanded for mine workers by the modem 'duty of care' legislation. Geotechnical factors play an important, if not overriding, role in these areas. The geotechnical factors cover the complex interaction over a period of time, between the in situ and induced rock stresses, rock structures, rock mass strength and the cable, rock bolt and other ground support members. In the Archaean schist belt areas where many of our narrow vein mines occur the pre-mining in situ rock stresses are commonly significantly higher than the overburden stresses. These are concentrated in areas beneath previous open pits and may be highly concentrated in the pillars and abutments of stopes on narrow veins. The presence of high in situ stresses may be suspected from the appearance of drill cores and underground development long before they become sufficiently concentrated by mining to cause damage or bursts. These initial indications are discussed and modem low cost methods of stress measurement are described. Practical and quick methods of analysing the stress redistribution around scopes and other underground excavations are now available and guidelines for interpreting them in terms of rockmass characteristics, stope stability and support requirements are developed with the object of increasing safety, whilst reducing overall costs and dilution.

Jan 1, 1993

By J. B. Forrester

In the operation of the coal mines in Utah few adverse conditions confront us. Physical conditions for the economical extraction of the coal are as near perfect as it is possible for them to be. Still several obstacles are encountered to keep up our interest and prevent us from getting in a rut. Of these I shall speak only of Burning, Wants, and Sluffing of Ribs. Should one travel the outcrop from Ivy Creek in Emery county to the Utah-Colorado line, there would be one outstanding feature indelible impressed upon one's mind. That feature is the omnipresent indications of burning in place. Viewing the eastern escarpment of the Wasatch Plateau from a distance, many splotches of dark red are plainly seen always lying above the coal floor. This stratum is a felspathic sandstone, appearing as a white line running the full length of the above escarpment and about midway between the floor of the valley and the top of the plateau. The coal bearing complex consists of shales, sandstones and coal. This complex varies from two hundred to eleven hundred feet in thickness. The number of coal seams are exceedingly variable. As a rule the argilutites form the bulk of this complex. This material is baked by the burning of the coal and the iron present is oxidized to the ferric state, coloring the shale to a dark red. This baked material forms a shingle tales that in places cover the entire complex. It is natural to expect that the most extensive burning is in the canyons facing to the south and east and on the south slopes of the ridges running to the east or west. Such, indeed, is the case. Still in this arid region many crop fires have existed upon the north slopes, especially in those canyons that face to the east. In fact today, instances are not rare where grassy north slopes, heavily timbered with balsam and fir that have attained a diameter of 14 to 24 inches, are found growing upon the disintegrated baked shingle and later development proves that the coal has been burned at least 500 feet back from the outcrop. Still these conditions are not normal. In this arid climate the south and east exposures are steep and barren, except for the scrub pine, cedar, mahogany and kindred semixerophytes. Bunch grass is also a lover of such exposures. There is very little soil found in such places; it is either blown away as fast as formed or washed away by the rare torrential rains, or the rapidly melting snow. Thus we see that the physical conditions are favorable for the starting and maintainence of outcrop fires. This brings us to the probable origin of this phenomenon. There are four probable ways' that such fires, could be started, namely:

Jan 1, 1921

By L. F. Mondolfo, B. E. Sundquist

The undercooling associated with the nucleation of the secondary phase from the liquid by the solid primary phase was studied in sixty binary alloys by means of a hot-stage microscope. It was found that in a system of a and ß, a usually nucleates ß at low undercoolings, but ß does not nucleate a, except possibly at undercoolings approaching homogeneous nucleation. This behavior can be explained in terms of relative interfacial energies and shows that crystallographic disregistry is only a minor factor in heterogeneous nucleation from metallic liquids. PREVIOUS experimental work1-6 on nucleation of solids from liquids has shown that normally nucleation is heterogeneous, and that small solid particles present in the liquid are responsible for the nucleation. These experiments and the theory that has evolved from them have made apparent that there is a "characteristic undercooling" associated with the nucleation of the solid from a given liquid by a given impurity. Little is known, however, about the chemical and structural relationships between the nucleating agent and nucleated solid that control the effectiveness of the nucleating agent in catalyzing the nucleation, as measured by the required undercooling. A review of the literature has yielded seventeen undercoolingsL-6 for the nucleation of solid from liquid metals by "known" nucleating agents. All values come from experiments in which the metal studied was divided into a number of particles (10 to 300 pin diam.) much larger than the number of extraneous impurity particles so as to obtain a large number of particles free of foreign nucleating catalysts. Known nucleating agents are then introduced by coating the droplets with particles or a thin film of the catalyst. Six of the seventeen undercooling values referred to cases where, for various reasons, the identity of the nucleating species was not at all certain. Another six cases involved nucleating agents with a crystal structure that was not known. Four other cases involved undercoolings listed as greater than or equal to undercoolings which were very likely those for homogeneous nucleation. One investigation3 involved adding to droplets powdered oxides, carbides, and so forth that were doubtlessly covered with adsorbed oxide or nitride films. The highly variable nature of these films resulted in highly variable undercooling (as was also found in preliminary work in this investigation). It is apparent that the information on heterogeneous nucleation in liquid metals is too limited to give rise to any definite conclusions on the nature of the catalytic process. With these problems in mind a new method was

Jan 1, 1962

By Stephen C. Blair

Laboratory permeability measurements at elevated pressure and at temperatures ranging from 20º to 150°C have been conducted on samples of Ironton-Galesville sandstone. The purpose of this testing was to identify and characterize important physicochemical processes occurring in association with the injection and withdrawal of heated ground water at the U.S. Department of Energy's Aquifer Thermal Energy Storage (ATES) field site in St. Paul, Minnesota. Results indicate that permeability decreased significantly as temperature was increased and that dissolution of the dolomite and silicate cementing agents and accompanying changes in mechanical properties may occur in the heat storage aquifer at St. Paul. Further, loss of permeability with temperature in laboratory samples may be caused by the change in the mechanical structure of the sample. Tests at ambient temperature to evaluate the effect of particle migration under conditions of reversed flow indicate that this process will not significantly impair formation permeability at the St. Paul site.

Jan 1, 1984