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By K. R. Vost

Calculations are given for the reduction in amplitude and change in phase of the diurnal variation in air temperature as the air flows through a mine. The concrete lining of a typical shaft was found to have a much greater effect than the steelwork. An increase in the conductivity of the concrete, or filling of the steelwork with water, did not have enough effect on the rise in air temperatures underground during the day to justify the costs involved. The steel temperature followed the air temperature much more closely than the concrete temperature did. Calculations are given for the heat stored in steel and concrete during the day.

Jan 1, 1980

By Carlos Renato Inchoste Meure, José Ernesto Boff

Nowadays, many companies have the idea where to be occupied is to be productive, this work aims to show with practical tests that to get the best performance of the machine with tools of high performance and yield is the best option for a company to become productive and economic at the same time . The company targeted for this work began its activities in the Metallurgical branch more than 75 years, Metisa Metalúrgica Timboense serves the national and international market with several product lines. Due to its large backlog of overdue hours, a job was started in the tooling sector to make the process faster and more economical. In this context, this work has as general objective the restructuring of the critical processes of the tooling sector, aiming at a better functioning of the organization and greater satisfaction of its direct clients. In addition, this work has specific objectives, such as (1) application of high performance tools, (2) analysis and improvement of existing processes, development and application of new processes, (3) (High Speed Machining) (4) production monitoring and technical support for maintenance of new processes. Thus, after the implementation of the process improvements, it was possible to obtain a reduction of 81% in the final cost and 80.5% in the process time. In addition, with some of the new processes deployed, there was a reduction in the use of personal resources and better management of machine hour load and a significant gain in the sector response time.

Nov 22, 2018

By J. W. Wilson, P. C. Graham

SUMMARY The Witwatersrand quartzites in which South African gold mining operations are moat exclusively conducted, are notoriously difficult and costly to drill. Despite this situation, however, with the high cost of developing new mines and extending existing mines, together with the rising cost of labour and mining problems resulting from the ever-increasing depths of workings, the demand for raise-boring in these formations is increasing rapidly. Not only is the demand for raises and shafts increasing, but also the length and size of these excavations. Raise-boring studies carried out in South African gold mines have indicated that increased penetration rates and possibly reduced costs could be obtained if higher thrusts were available at the reaming head. Until fairly recently there has been no raise-boring machine suitable for underground use that possessed the thrust and torque characteristics necessary to achieve high penetration rates in hard abrasive quartzite formations and the cutters available were not really developed for high loading. In response to these requirements a raise-borer, the Robbins 83R was designed and built in Seattle, U.S.A. for the Anglo American Corporation. This machine is operating in South African gold mines and is currently being used at a depth of 12 000 ft below surface in one of the. Group's mines. The initial raises bored have substantiated that increased penetration is attainable at high thrust and it is now apparent that the machine is sufficiently versatile to drill raises of up to 12 ft in diameter in quartzite formation over a length of 2 000 ft.

Jan 1, 1974

By Sean Harvey

One of the manifestations of the dynamically induced failures in deep coal mines is the violent ejection of coal from the ribs. A possible protection against such failures is the use of a specifically designed dynamic support system with reinforcement units having the sufficient capacity to absorb the kinetic energy of the dynamic failure and a skin support that can adequately contain the disintegrated coal. With this method of mitigation in mind, a recently introduced yielding rock bolt, trade name Roofex, has been identified (Harvey and Ozbay, 2009) as a possible energy absorbing component of a dynamic support system. According to the manufacturer?s specification, the Roofex bolts can yield 300 mm (or more) displacement while holding 80 kN pull load. In order to assess the performance of this support unit in coal ribs, a series of in situ pull tests performed in two coal mines in Colorado. The results show that, under conventional pull test loading conditions, Roofex yielding bolts perform very close to their claimed specifications, thus showing a potential for their use as the main energy absorbing component of a dynamic support system. Further studies are required to confirm the in situ performance of these bolts under dynamic loading conditions and also to develop a containment component for a dynamic support system for the mitigation of dynamic coal rib failures.

Jan 1, 2009

By NEWTON B. KNOX

IN Bolivia, mining is still the principal economic activity, as it was before and during the Spanish Colonial period. Tin, tungsten, antimony, copper, lead, zinc, gold, silver, sulphur, and a little bismuth are produced. The Andes mountains are divided into two main ranges in Bolivia; the Western range marks the border with Chile and the Eastern range forms the backbone of the country; in the North it drops rather abruptly eastward, to the plains of the Beni, whereas in the South it splits and is separated from the Chaco flatlands by a series of folded mountain ranges. In general the mineral deposits are found within the Eastern range or in the hills that rise from the high plateau between the ranges - really parts of the Eastern range partly submerged by recent sediments. The mineral belt is thus over 500 miles long and about 100 miles wide and includes most of the principal centers of population and the most important means of communication. The region is mountainous and the roads are bad; furthermore labor is a serious problem, for the land is poor and the agricultural population is never far from hunger. The floating supply of miners is limited and soon exhausted in any emergency like the present.

Jan 1, 1945

By H Zhang, A Lawrence

To accommodate the fast growing need for services in Singapore’s Marina Bay downtown area, Marina South, the construction of a common services tunnel (CST) was required. The CST includes various services such as telecom cables, power lines and water pipes. A deep excavation and temporary earth retaining system (TERS) was required to facilitate the construction of the tunnels. Marina Bay is reclaimed land over thick soft marine clay which is likely to be still consolidating. The deep soft marine clay poses a big challenge for deep excavations in downtown areas where highways and sensitive structures are close by. This paper presents a case study of part of the CST Phase 1B and 2 at Marina South, in particular a 26 m deep excavation supported by a 46 m diameter temporary caisson. The construction started in late 2006 and the basic structure was completed in early 2011. The caisson was formed by 1.0 m thick overlapping diaphragm wall panels with a capping beam and three ring beams at different depths. Two-dimensional finite element analyses were conducted to predict the ground settlement, lateral displacement, bending moment and hoop stresses in the diaphragm wall and ring beams during different excavation stages. A comprehensive instrumentation and monitoring scheme was established to verify the design predictions, control excavation safety and trigger the contingency plan to protect public safety. The impact of construction activity, unbalanced temporary stockpiles and adjacent deep excavation for a mole removal will be discussed.CITATION:Zhang, H and Lawrence, A, 2014. A case history of a deep excavation in a big circular shaft in Singapore marine clay, in Proceedings 15th Australasian Tunnelling Conference 2014, pp 581–588 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By L. M. Demers, D. C. Kuhn, N. El-Ayouby, C. F. Stanley

"Oxygenated metabolites of arachidonic acid (MJ are produced by the alveolar macrophage (AM) and have been shown to mediate inflammatory reactions. We therefore assessed the production of eicosanoids by AM harvested from the lungs of rats ex· posed to a bituminous coal dust for 2 wk in an inhalation chamber in order to determine if AA metabolism was altered in a manner that may promote an inflammatory response in the lung. Exposure to coal dust resulted in a 66% increase in the number of AM harvested, an increase in thromboxane A2 (TxA;i) and leukotriene 84 (LTB,j) production to 222% and 181% of control values, respectively, and a decrease in prostaglandin E2 (PGE:i) production to '62% of control values. In AM harvested from rats allowed to breath clean air for 2 wk following coal dust exposure, PGE2 production returned to control levels but TxA2 and LTB4 production remained elevated. The TxA2 synthesis inhibitor UK 38,485 reduced TxA2 production in dust-exposed AM both immediately and 2 wk following exposure. Thus, exposure of rats to coal dust significantly alters the metabolism of AA in AM, with potentially important aspects of AA metabolism remaining altered even after a 2-wk recovery period. Based on the established role of eicosanoids in inflammatory and fibrotic processes, these results suggest that the alteration of AM eicosanoid production as a result of the inhalation of coal mine dust may be an important factor in the pathophysiology of coal workers' pneumoconiosis.The authors are grateful to Joan Greenwood and Barbara Scheetz for their excellent technical assistance and to Brenda Pavone for the preparation of the manuscript. This research was supported by the U.S. Department of The Interior's Mineral Institute Program administered through the Generic Mineral Technology Center for Respirable Dust under grant 1135142.Request for reprints should be sent to Douglas C. Kuhn, Ph.D., Department of Pathology, The M.S. Hershey Medical Center, Hershey, PA 17033.INTRODUCTIONPulmonary alveolar macrophages (AM) are activated by foreign particles and microorganisms that enter the small airways (Kass et al., 1966; Herscowitz, 1985). This defensive reaction involves phagocytosis, lysosomal enzyme release, and the generation of reactive oxygen species by the AM (Snella, 1986; Rich et al., 1987). A number of agents, including phorbol esters, zymosan, adenosine diphosphate, organic hydroperoxides, and calcium ionophore, have been shown to activate the AM in vitro (Badger, 1986; Marshall and Lands, 1986; Snella, 1986). The AM response to these activators appears to be mediated in part by the oxygenated metabolites of arachidonic acid (AA) (Bertram et al., 1988; Demers et al., 1987; Mcleish et al., 1987).The AM may metabolize AA through cyclooxygenase- and lipoxygenase- catalyzed pathways to produce a variety of eicosanoids including prostaglandin (PG) E2, thromboxane (Tx) A2, leukotriene (LT) B4, LTC4, LTD4, and several hydroxyeicosatetraenoic acid derivatives (HETEs) (Willis, 1970; Camp et al., 1983; Poubelle et al., 1986). The production of these eicosanoids may enhance the. defensive ability of the challenged lung since they stimulate chemotactic cell recruitment to the site of invasion, enhance extravasation of circulating immune cells, and promote local vasodilatation. However, continued stimulation of the AM population, with the consequent production of proinflammatory eicosanoids, may ultimately enhance the disease process by contributing to chronic bronchoconstriction, fibrosis, and the persistent release of toxic oxygen species."

Jan 1, 1990

By A. J. Jager, J. A. Ryder, M. U. Ozbay

This paper deals with procedures used for designing pillar systems in hard-rock tabular mines operating at shallow depths, typically less than 1000 m. A comprehensive review if current practice identifies four types if pillars, namely non-yield, yield, crush and barrier pillars, and the main principles for designing these pillars are outlined. It is shown that the current design methods for pillar systems in South Africa are mainly empirical, each mine developing its pillar-design methods based largely on practical experience. This results in varying pillar layouts, even between neighbouring mines, despite similarities in geology, and depth if mining. It is suggested that some current layouts may fall short if being the best as regards safety, the maximum safe extraction percentages, or flexibility in accommodating future mining scenarios in deeper or otherwise different geological conditions.

Jan 1, 1995

Australia is a leading producer of mineral sands and according to U.S. Bureau of Mines, produced 24, 53 and 64% of world's production of ilmenite, rutile and zircon respectively in 1983. The industry which is mainly export oriented earned in export income about $210 million in 1985. The dominant position which Australia occupies in world produc- tion of mineral sands is also maintained in many areas of research and development work on the processing and application of these minerals. Some of this research which is leading the world has been responsible for setting up industries to produce value-added and high-tech products such as synthetic rutile and partially stabilized zirconia (PSZ). The production of high purity zirconia is due to commence shortly while research in rare earths offers an exciting prospect for future Developments.

Jan 1, 1986

By Clara Godoy, Álvaro Dapía, Paulo Couceiro, Pablo Segarra, José Ángel Sanchidrián, Juan Navarro

This paper applies geostatistical tools in Measure While Drilling (MWD) data to estimate the probability distribution of values in all the points of the studied domain in order to assess the continuity of rock classes between boreholes. The analyses carried out by Ghosh et al. (2018) and Navarro et al. (2019) have been used as starting point of this work to classify the geotechnical rock condition in four classes: solid rock, fractured rock, cave- in rock and cavity. From it, an application for the geotechnical rock condition of orebodies have been developed, aiming at characterizing the rock before the charging the holes to minimize unexpected rock conditions and to address issues associated with charging and blasting operations. Such problems are closely related with non-optimal rock fragmentation after blasting.

Feb 1, 2020

By J. C. Bothan

A program to provide technical in-formation on the use of fuels in pyro-metallurgical processes, from the Canadian fuel viewpoint, was initiated about five years ago by a Canadian Institute of Mining and Metallurgy liaison grou1> composed of members from the Coal Research Committee of the Coal Division and the Iron and Steel Committee of the Metallurgy Division. This paper is another of a series prepared for this program. Previous papers included a review of pyrometallurgical processes of Canadian interest, a survey of ferrous processes relevant to the development of an integrated steel industry in western Canada and a survey of the fuel requirements of the non-ferrous metals industry in Canada. It is widely recognized among per-sons familiar with the Canadian coal industry that, because of the large resources of coking coal in western Canada, the

Jan 1, 1963

By B. T. Lu, J. L. Luo, T. Yu, C. W. Chen

In this paper, the synergism in erosion-corrosion process occurring in oil sand wastewater transportation caused by the interaction of mechanical and electrochemical factors was experimentally investigated. The erosion-corrosion tests were conducted with A1045 steel in synthetic slurries comprising tap water and silica sand. The material loss due to corrosion-enhanced erosion was assessed with the chemo-mechanical model developed by the authors recently. The results indicate that the material loss produced by corrosion-enhanced erosion at the open circuit potential can be formulated as a linear function of logarithm of corrosion current density. The wastage caused by the erosion-enhanced corrosion was analyzed based on the concept of non-equilibrium thermodynamics. The material loss induced by the erosion-enhanced corrosion is approximately a linear function of overall erosion rate measured in synthetic slurries, indicating that erosion-enhanced corrosion could be reduced by adopting surface strengthening techniques to improve the resistance to the plastic deformation in surface layer.

Jan 1, 2004

By Karl A. H iggins, James P. Racine

"Displacement Cast-in-Place (DCIP) piles are not a common deep foundation type in the Washington, DC Metro Area market. As a result, less regional data is available for these foundations compared to other alternate deep foundation types. Displacement cast-in-place piles (DCIP) differ from traditional Auger Cast-In-Place (ACIP) piles in that the pile annulus is formed by pushing a partially-flighted, auger bit to depth via a large mandrel. The auger bit includes a displacing body near the bottom of the tooling. Therefore, little to no spoils are generated during installation and the soil around the annulus is largely densified in-place due to the displacing body being slightly larger than the mandrel it is attached to.Due to this densification, one would expect that the theoretical DCIP capacities (compression or tension) would be greater than an ACIP pile (assuming a pile of similar length and diameter). After 20 static load tests and the installation of over 6,000+ piles on the MGM National Harbor Casino Project, the differences in pile support characteristics between DCIP and ACIP piles of same size and depth was small. The performance of both pile types depended on the density and type of soil within the bearing stratum. In some early cases of DCIP use, the performance exceeded expectations and appeared to be more in line (or better) than typical capacities obtained from driven displacement piles. Other times, the tip elevations could not be achieved or were so difficult to achieve that installation delays occurred and/or significant additional engineering effort was required to address piles short of their requirement embedment.This paper will discuss the limitations of DCIP pile installation in dense Coastal Plain soils and will present the lessons learned during this project. The paper will also compare the DCIP pile type to both conventional ACIP and driven displacement piles utilizing regional and site-specific load test and installation data."

Jan 1, 2017

By A. Sainato, S. J. Kravits, G. L. Finfinger

This Bureau of Mines report describes and compares the procedures, capital investments, and operating costs of rotary and in-hole motor drilling techniques used to drain methane gas from the Pittsburgh Coal- bed in an underground mine located in southwestern Pennsylvania. A timestudy was conducted during the drilling of each of two boreholes, and the data were collated to serve as a base for comparing drilling procedures and operating costs. Findings indicate that drilling with an in-hole motor offers four advantages over rotary drilling; namely, an increase in drilling productivity, fewer worker-hours required, ease of maintaining vertical and horizontal bit trajectory, and less expensive drilling cost per foot of borehole.

Jan 1, 1985

By J. A. Herbst, D. W. Fuerstenau

This paper examines the zero order production phenomenon in the context of the size discretized batch grinding model. A restrictive interrelationship between the selection and breakage parameters of the model, which is mathematically sufficient to ensure zero order behavior, is delineated. Based on this interrelationship, a scheme is developed for predicting the values of the selection and breakage parameters for all size fractions from a minimum of experimental data. To test this scheme, dolomite was ground in a laboratory batch ball mill. Successful simulation of the comminution behavior of this system was achieved using the batch grinding model with the parameter values obtained from the proposed scheme. Historically, a preponderance of comminution research has centered on attempts to relate breakage energy to the performance of comminution machines. Concomitantly, grinding data were interpreted almost exclusively in terms of inherently empirical energy-size reduction relationships1-3 or "laws of comminution"4- 6 which were based on highly oversimplified descriptions of the fracture process. In some instances, these relationships provide a crude basis for the correlation of experimental data, but, invariably, this approach is inadequate for meaningful process simulation. The control and optimum design of comminution circuits require a mathematical model capable of depicting the size reduction behavior of every size fraction for grinding conditions of technological importance. Energy-size relationships do not provide this detailed information. For example, an energy-size analysis for batch ball-milled dolomite has recently been completed in the authors' laboratories.7 This analysis provided a satisfactory correlation between the hypothetical size modulus, which characterizes only the finer portion of the size distribution, and the input energy. However, this relation did not constitute an adequate description of the complete system. In general, one of two distinct viewpoints toward simulation has been adopted in recent comminution research. The first approach focuses on the fracture of single mineral specimens, with the essential aim of representing the over-all process in terms of the breakage characteristics of individual particles and the characteristics of the stress field which the particles experience within the particular size reduction device. As illustrated by Harris's review,' the actual incorporation of single-specimen fracture information into a description of the behavior of a multiparticle comminution system has seldom been attempted. The only model to accomplish this incorporation was the one developed by Schönert.8 The Schonert model treats single-passage grinding machines in terms of a distribution of effective loads acting on a particle, a distribution of required particle breakage energies, and the breakage product distribution. However, the use of single-particle fracture behavior to derive models of the size reduction process is at present limited to machines in which the particle residence time is approximately equal to the time required to apply stress. As a result, Schönert's analysis cannot be used to advantage to simulate the complex environment which prevails within a tumbling mill. For multiple-passage systems a second approach to the description of comminution processes has been more fruitful. This approach entails the formulation of a mathematical model which is phenomenological in nature in that it lumps together the entire spectrum of stress-application events which prevail in a system under a given set of operating conditions. The appropriately defined average of these individual events is then considered to characterize the over-all breakage properties of the device. Thus, to analyze the performance of a tumbling mill, the manner in which the particles of a particular size (or size fraction) are stressed need not be distinguished. Instead, a single parameter is assumed to represent the resistance of that size to fracture, given the average grinding environment which exists in the mill. The isolation of such a parameter and a related set of quantities, which constitute the breakage product size distribution for the average event in this size fraction, allows the formulation of physically meaningful descriptive equations capable of yielding precise and detailed information for simulation.

Jan 1, 1969

By L. J. Murphy

The production of crude oil in the United States is exceeding consumption by one-quarter million barrels per day and, with the possibilities of West Texas, this condition of overproduction, unless controlled, is likely to continue for some time. The resulting low price of oil has caused the operator to observe closely his lease operating costs. The installation of more efficient and reliable machinery has followed and it can well be said that the art of producing oil is on the threshold of a new era. In this advancement electricity has played a leading part. This paper covers only the problem of electricity as applied to lease operation and does not consider other phases of the industry, such as drilling and pipe-line pumping, in which electric power has been utilized economically. In considering electrification of pumping wells, the first question the operator asks is whether or not his costs will be reduced and the second question is whether or not the production will be increased. The third question, although in effect it is closely allied to the first, is the cost of power. The last question can be answered only after a thorough analysis of operating conditions and a study of the power rates prevailing in the particular field under consideration. Within the past few years, the power companies have realized the desirability of a steady 24-hr, pumping load, have made their rates for oil-field service particularly attractive, and in general have shown splendid cooperation in assisting the oil companies in the satisfactory application of electric power to their leases. When everything is taken into consideration, the first cost is practically the same for electric drive as for gas engines when pumping on the beam with individual motors. This cost, at prevailing prices, should aver-age approximately $2200 to $2400 per installation when using 15 to 35-hp., two-speed pumping equipment, including motor and control, countershaft, motor house, belt, installation charges, and a prorated portion of the cost of transmission lines and transformers for serving a number of wells. Since there is practically no difference in the cost of the two installations, it is evident that electricity, to justify its consideration, must have a lower operating cost or produce more oil.

Jan 1, 1928

By M. A. von Below, I. C. Robinson

A mineral economic analysis of South Africa's mineral-beneficiation industry, comprising both economic theory and case studies, suggests that the domestic market has proved to be a more effective vehicle for promoting the establishment of advanced beneficiation projects than the availability of domestic raw materials. Although the domestic market plays an important role in the promotion of beneficiation by providing a secure outlet for sales, its most vital role is in the development of technological and marketing know-how that may give South African beneficiated products the competitive advantage required to penetrate export markets. The real wealth of a country lies primarily in the skills of its people rather than in its natural resources, and the domestic market plays a pivotal role in the development of these skills.

Jan 1, 1990

By C. V. Millikan

New developments in air-gas lift practices in the Mid-Continent area since our Pall meeting in Fort Worth have done much to increase the efficiency of installations, and thus bring within economic limit of air-gas lift many wells which could not have been flowed profitably before. After the gas-lift had so thoroughly demonstrated its value in the Seminole field, its use spread to other areas and many installations were made of which the economy could be questioned. In the Seminole area, when production began to decline it was necessary either to increase the efficiency of the air or gas-lift or to put the wells on the pump, and pumping was not a process of lifting oil to which any operator looked forward with confidence. These conditions have resulted in the development of many practices which increase the efficiency and permit wells to be flowed with air or gas which earlier could not have been flowed economically, and wells which have been flowing to continue to a lower rate of production. The practices which have come into more common usage in the Mid-Continent area recently are mostly revivals of and improvements on practices which have been known in air-lift work for several years. Many arc peculiar to the individual well on which they are used. Intermittent Flowing Some interesting results are being obtained in Seminole and other districts by intermittent injection of gas. Gas is introduced during per-iods iods of 3 to 5 min. at a rate considerably over that necessary to acquire the production at a steady rate of injection, and is then cut off for a period of 3 to 15 min. Two to five wells are run from the same group of conlpressors. The total volume of gas required is sometimes reduced as much as one-third of that required when it is introduced at a constant rate, without changing the amount of oil production. The maximum pressure required is usually higher, but the average equal to or lower than that required for constant rate of flow. The effect on the wells is usually an irregular rate of flowing which may cause inconvenience where recycling is practiced. It would seem that this increase in efficiency is due to less slippage when the gas is introduced intermittently than when it is intro-

Jan 1, 1928

To improve the ventilation of large-opening under-ground stone mines by using stoppings made from stone left in place. Background Underground stone mines typically use large room-and-pillar openings with little ventilation control. Stone miners may be exposed to contaminants that include silica dust, diesel particulate matter (DPM), exhaust gases, nuisance dust, and face shot (blasting) fume gases. The health risks from breathing these fine particles and toxic organic materials are well documented. Although contaminants such as dust or diesel exhaust can be some-what controlled at the source, the escaping contaminants are often diluted and removed from work areas using ventilation with minimal controls. In many cases, current mine ventilation practices use trial-and-error techniques to improve ventilation. The growing realization of the importance of a healthy work environment along with increased regulations will require many stone mines to implement new ways to improve ventilation. In-place stone stoppings are one option. Mine air flows from one point to another because of a pressure differential between those points. This pressure differential is established using a mechanical fan in conjunction with separations (stoppings) between high-pressure (intake) and low-pressure (return) airways. The separation of intakes and returns is an important concept that is used in most other types of mines. Normally, air moves through underground stone mines with minimal control technology. Fans are placed in locations where they are thought to be most beneficial, and intakes are not separated from returns. In a few smaller underground stone mines, proper ventilation can be achieved with a few strategically placed fans. However, as these mines increase in size, moving adequate quantities of air through-out the mine becomes harder, and separation of intakes and returns becomes a problem. Building traditional mine stoppings to separate the intake and return airways in entries with a cross-section area often exceeding 800 ft2 is difficult. The stoppings must be able to withstand both the dynamic pressure from face shots and the static pressures created by the fans. Construction and maintenance difficulties, as well as high costs, are the main factors preventing these traditional mine stoppings from gaining wide acceptance by the stone mining industry.

Dec 1, 2002

By A. Bhagavatula, M. Rezaee, M. J. Kiser, R. Q. Honaker

"A field study of the coal preparation plant fleet in the eastern United States was undertaken to determine if quantify of rare earth elements (REEs) present in the product streams are large enough to justify further concentration. Representative composite samples were taken from the clean product, coarse refuse, and fine refuse streams from 20 coal preparation plants. Each stream was then separated into various size and density classes and analyzed for ash and REE contents. The large database showed that coarse refuse contained the largest amount of REEs, although the ratio of heavy to light REEs was greater for the clean coal products. The concentration of REEs was also compared to that typically seen in the earth’s crust. This enrichment ratio ranged from approximately 1.5 to more than 4.0 as the ash content varied. The database also showed that a linear correlation existed between La and Ce for many REEs of interest, although there were several notable exceptions for some of the high-value REEs. INTRODUCTION Worldwide energy demand is expected to grow by as much as 37% by 2040 according to the International Energy Agency (2014). This growth, coupled with a decrease of the reliance on coal to generate energy, means that it is more important than ever for countries to secure the materials necessary to meet its energy projections. For the United States, the U.S. Energy Information Administration (EIA) predicts that total domestic electricity use will increase roughly 25%, from 3,836x109 kWh in 2013 to 4,797x109 kWh in 2040 (EIA, 2015). In the EIA’s reference case, coal’s contribution to electricity generation drops from 39% in 2013 to 34% in 2040. On the other hand, renewables share of electricity generation grows from 13% to 18% for the reference case. Compared to its current state, renewable energy electricity production is predicted to grow as little as 50% to as much as 121% over this time period, depending on the economic case being examined. This growth will largely be seen in the wind and solar sectors (EIA, 2015). The focus on viable renewable energy resources will be crucial to the future of fueling American growth. Many of the renewable energy technologies, such as wind turbines and photovoltaic films, rely on materials and supply chains outside of the United States. The lack of a reliable and low-cost domestic supply could pose a threat to the growth of the renewable energy markets in the United States. This potential vulnerability recently led the United States Department of Energy (DOE) to create a Critical Materials Strategy Report. In this report, 15 elements were identified as critical for the continued growth of the renewable energy market. Eight of these elements were rare earth elements (REEs). Five REEs (dysprosium, neodymium, terbium, yttrium and europium) were identified as highly critical and vulnerable to shortages (Bauer et al., 2012)."

Jan 1, 2016