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By Sergey Komarov, Manuela Diaz, Sano. Masamichi

"Mixing time, bubble behavior and absorption rate of gas injected into a liquid bath through rotary L-shaped lances have been studied by cold models with an effort to improve refining characteristics of metallurgical processes. Two kinds of the rotary lances were tested, namely the single-hole lance and the multi-hole lance. The effects of gas flow rate, bath depth and rotation speed were examined.It is found that when gas is injected through the rotary lances, the mixing intensity and the gas absorption rate are larger than that for the gas injection through stationary lances. The effect of rotation speed decreases as the bath depth and the gas flow rate increase.The multi-hole lance produces much smaller bubbles, which lead to an increase in the volumetric mass transfer coefficient by 3-4 times as compared with the single-hole lance. However, the effect of rotation speed is smaller for the multi-hole lance. The obtained results are explained in terms of the bubble coalescence and fragmentation, the rate of which depends on the departure bubble size and the power supplied to the liquid bath.IntroductionIn recent years, there has been a growing interest in the development of gas injector for metallurgical processes. The majority of the previous work was focused on modification to the injector design to improve mixing and to increase the of chemical reaction rate. These two goals can not be necessarily achieved by the same way. Bottom nozzles and stationary immersed top lances, which have been widely applied to steelmaking processes, are effective for the bath mixing, but have a limit to decrease in the bubble size. This results from a vigorous coalescence occurring between the bubbles when they rise in the molten bath as a bubble swarm.One of the ways to ensure the small bubble size and the effective bath stirring is the gas purging through rotary injectors. A number of studies have been undertaken to improve the refining characteristics by using rotary injectors. All of them are related to aluminum refining. The SNIF equipment (The Spinning Nozzle Inert Flotation) has significantly improved the quality of aluminum products at National Luxemburg Aluminum [1]. Rotary injectors made in the form of a disc have been applied to the Alcoa 622 [2] and the GBF processes [3]. A study of the gas injection by a rotary impeller has been carried out by C. Leroy and G. Pignacelt [4]. All researchers note the significant improvement in removal of sodium, calcium, hydrogen and non-metallic inclusion."

Jan 1, 1996

By John S. Civetta, Seth Martin, Marc J. Gallagher, Arthur J. Alzamora, Ronald Peralta

The Crown Building, built circa 1921, is a 26-story iconic building located at West 57th Street and Fifth Avenue in the heart of Manhattan. The paper highlights collaboration between the geotechnical engineer and foundation contractor to develop economical and practical solutions to foundation design and construction challenges associated with this complex redevelopment project. The project includes both below-grade and above-grade expansion of the occupied building, and required undermining the existing foundations, and essentially doubling the foundation loads. The below-grade expansion required surgical foundation work including drilling minicaissons, shoring columns, underpinning, and excavating 20 feet of rock.

By Jon G. Bredeson

A survey of electromagnetic noise reports was performed and a summary of the results are given. Industrial concerns were surveyed for techniques to minimize the effects of electromagnetic noise and are presented. The common types of communication links used in mines today are presented. A mathematical development was presented which determines the probability of bit errors versus distance for various types of communication links designed for in mine use. The probability of undetected errors for the protocols of the communication links is given together with burst error detection.

Jan 1, 1981

By Rongjie Kong, Shiwei Wang, Dongjiao Gui

Metal cations have significant effects on the flotation of coal and minerals. In this study, the effects of monovalent cations ( Na+ and K+) on the flotation of low-rank coal (LRC) were investigated using flotation and particle–bubble attachment experiments and through X-ray photoelectron spectroscopy (XPS) and molecular dynamics simulations. Oleic acid (OA), methyl linoleate (ML), hexadecyltrimethylammonium chloride (CTAC), ricinoleic acid (RA), and kerosene were used as flotation collectors. The flotation experiments revealed that the flotation yields of LRC improved when OA, ML, RA, CTAC, and kerosene were used in pure deionized water. However, flotation was suppressed for these collectors in the presence of K+ and Na+ ions. In contrast, when using CTAC, the flotation yield increased in the presence of these ions. Specifically, the flotation yield increased from 41.24 to 87.03% when 2.0 kg/t CTAC was used in 10 mmol/L NaCl solution. Particle–bubble adhesion experiments and XPS revealed that the hydrophilic groups of CTAC were adsorbed on the LRC surfaces by electrostatic forces, whereas the oxygen-containing functional groups of OA, ML, and RA formed hydrogen bonds with the LRC surface in pure water. Finally, the simulating result revealed that the hydrophobic ends of the OA, ML, and RA collectors hinder the flotation of LRC by adsorbing monovalent cations, whereas the adsorption of monovalent cations on the hydrophobic end of the cationic surfactant (CTAC) promotes flotation via strong electrostatic interactions.

Jan 31, 2024

By Simon Lekakh, Von Richards, C. Hank Rawlins, Kent Peaslee

"Batch aqueous leaching and carbonation tests were conducted using industrial steelmaking slags to determine the effect of carbonic anhydrase enzyme as a catalyst. Calcium leaching is a strong function of particle surface area, and the extent can be expressed as a function of time and particle size. Carbonic anhydrase did not affect the calcium-leaching rate, however, it did catalyze calcium carbonate formation to achieve a neutralization time near the theoretical rate. Additionally, carbonic anhydrase modified the precipitate morphology due to accelerated particle nucleation. Time controlled tests in which the pH dropped to ~6 decreased the amount of carbonate produced, and this effect was exaggerated by carbonic anhydrase, while pH controlled tests (>8.5) exhibited the highest rate of carbonation. Because the leaching rate was ~50% faster than the carbonation rate, a further increase in the amount of carbonation may be realized by using carbonic anhydrase however pH must be >10.3.IntroductionSteelmaking slag contains high fractions of alkaline earth oxide based phases (i.e., CaO and MgO) that exothermically form carbonates. Thus, it is being considered as a means of permanent carbon dioxide sequestration. At current U.S. steel production rates, approximately 13-17 million tons/year of slag are generated from basic oxygen furnace (BOF), electric arc furnace (EAF), and ladle metallurgy furnace (LMF) processes [1]. BOF and EAF slag is used as high quality mineral aggregate or cement clinker, while LMF slag, produced at ~15% the rate of BOF and EAF slags, has limited use as blast furnace flux or acid mine neutralization with the majority going to landfill [2]. Based on slag’s chemical nature and immediate availability as a co-product from steel production, the steel industry initiated a project to investigate hydrous carbonate formation in steelmaking slag as a method of sequestering carbon dioxide emitted in steelmaking offgas [3]. The goal of this project is to determine the reactor parameters suitable for the design of an industrial system for treating steelmaking offgas with raw or minimally processed slag."

Jan 1, 2009

By V. Shchukin

According to the scientific views formed by the middle of nineteen seventies there should be no possibility of commercial diamondiferous kimberlites in the north of the west European platform. However a later analysis of the geological data gave rise to the concept that diamond bearing kimberlites would be present in the north but on the mineralogical level they would differ from kimberlites of South Africa and Yakutia. Further investigations resulted in the confirmation of these conclusions and with discovery at the beginning of 1980 of diamond bearing kimberlite pipes in the Arkhangelsk region.

Jan 1, 1995

By Andrew A. Cochran

Laboratory-scale research was conducted by the Bureau of Mines to develop a new process for treating electroplating and other wastes. Various acid and alkaline cyanide wastes were combined under controlled conditions to neutralize the wastes and to almost completely precipitate the metals and cyanides. The metals were subsequently recovered for recycling; the cyanides can also be easily recycled. The process was successfully used to treat the major types of electroplating and etching wastes, containing Cd, Cr, Cu, Ni, and Zn, and to treat both concentrated and dilute wastes. The economic aspects of treating concentrated electroplating, etching, and anodizing wastes are especially attractive because of the low cost of mixing two wastes, the high value of the recovered metals, and the simplicity of the recovery procedures. The filtrates from the waste-plus-waste step were relatively harmless compared with the original wastes and met Public Health Service standards for free cyanide content. Free cyanide ions were not detected in most of the filtrates; the limit of detection was 0.03 ppm. Only small amounts of HCN were produced during the neutralization; the HCN was collected and neutralized.

Jan 1, 1974

By V. A. James

The new electrolytic copper refinery situated at Copper Cliff, Ontario, has been in operation for over a year and a half. This plant is operated by the Ontario Refining Company, Limited. The associated companies behind the enterprise are the International Nickel ?company of Canada, Limited, the American Metals Company, Consolidated Mining and Smelting Company of Canada, Limited, and Ventures, Limited. The plant was an outgrowth of the rapid development of copper resources in the nickel-copper ores of the Frood and other great mines in the Sudbury district, and of the desire to have all primary production units grouped together as compactly as possible. Starting anode furnace operations in June, 1930, and electrolytic refining on July 1st of that year, after a record-breaking construction programme completed in only fifteen months, the plant soon settled into its stride and the usual starting-up difficulties were .rapidly overcome. The rated capacity of the plant, namely, twenty million pounds of refined copper per month, has, of course, never been reached, due to depressed business conditions and latterly to the world copper agreement limiting production. It may be said, however, that the present installation has proved its ability to produce in excess of its rated capacity, and with relatively minor additions to plant and equipment that capacity can be doubled. Owing to the severity of the winters, when temperatures of from 20 to 40 degrees below zero are to be expected, the building of this refinery involved a number of problems in insulation, layout, ventilation, etc., which were rather unusual in copper-refinery construction.

Jan 1, 1932

By I. Peerawattuk

Growing demand for Li-based battery technologies is leading to an unprecedented growth in the lithium industry. Although innovation in battery technologies has pushed lithium into the spotlight, lithium was not always known for its application in batteries. The primary use of lithium—prior to the introduction of commercial lithium-ion batteries in the early 2000s—was in the ceramics, glass, grease, and the medical industry. Before being converted into usable forms, lithium products must be upgraded from the raw material. Processes for recovering lithium may involve: thermal treatment, water leaching, solar evaporation, ion exchange, carbonation, and electrodialysis. Presented, is a historical review of lithium applications and the different techniques of converting lithium-rich minerals and brines into usable products with additional discussion on future lithium extraction processes.

By Roy J. M. van Lier

In industrial aqueous solutions, germanium generally occurs in trace amounts amid high concentrations of other metals, such as zinc, copper and iron. Separation of germanium from these metals as well as its isolation from gallium and indium pose a real challenge to the hydrometallurgist. After a brief discussion of the aqueous chemistry of germanium, this paper reviews the flowsheet of the Apex Mine in Utah. The Apex property was the only mine in the world to be operated primarily for production of gallium and germanium, but apparently closed due to great operating difficulties. Several process variants proposed for the treatment of the Apex ore, including bioleaching methods, are addressed. Following a more general description of the behavior of germanium in hydrometallurgical zinc processing streams, available technology for its recovery from aqueous solutions is summarized. Precipitation, solvent extraction, ion exchange, electrowinning, ion flotation and liquid-membrane separation are all outlined in terms of the aqueous chemistry of germanium. Finally, the production of high purity germanium dioxide and metal is briefly discussed

Jan 1, 1995

By R. W. Bruce, K. W. Downes

"IntroductionSULPHUR production in Canada from all sources for the year 1953 amounted to about 375,000 tons. Except for 16,000 tons of elemental sulphur derived from natural gas, this production was in the form of by-product pyrites, liquid sulphur dioxide, and sulphuric acid. In the same year, Canadian industry imported 359,000 tons of elemental sulphur from the United States. The cost, including transportation charges, to Canadian consuming plants ranged from $35.00 to $45.00 per long ton, depending upon location.Although most of the sulphur consumed is used in the oxidized form it is often most convenient to buy sulphur in the elemental form, and convert it to sulphur dioxide or sulphuric acid in situ as required. This is because elemental sulphur is easily shipped and stored, weighs only half as much as an equivalent quantity of sulphur dioxide and one-third as much as the corresponding quantity of sulphuric acid, and is readily converted to these forms in a sulphur burner. A process, therefore, which could economically recover elemental sulphur from sulphide ores would be most attractive.Since the turn of the century, notable improvements have been made in extractive metallurgy, but until recently only limited attention has been paid to the possibilities of elemental sulphur recovery. This has been due to the plentiful supplies of cheaply mined Frasch sulphur which have been available on the world markets."

Jan 1, 1955

By Daniel Lachapelle, Nuri Hmidi, Turgut Yalcin

"Simulation can serve as a convenient tool in studying the behaviour and performance of grinding circuits by facilitating the evaluation of various scenarios and identification of optimum operating conditions. This technique was applied to the St Andrew Goldfields Ltd.’s Stock Mine Mill which is a 1300 tpd gold milling facility, offering custom milling services as well as processing the Company’s own ores. Lack of adequate instrumentation in the mill poses a challenge in attaining optimum performance especially with changing ore types and characteristics. The grinding process is monitored essentially by manual measurement and adjustment of pulp densities at various streams. A simulation program was designed to assist in the effective implementation of this mode of grinding control. Product sizes from both the primary and secondary grinding circuits were correlated empirically to relevant process variables using a database formed from the results of past sampling campaigns. The simulator was created in Microsoft Excel whose data analysis and optimization tools coupled with its Visual Basic Programming capabilities were found to provide an excellent environment for the development of a cost-effective, efficient and user-friendly simulation program.INTRODUCTIONGrinding is often a very costly unit process in milling operations, mainly due to the excessive energy consumption associated with it. For example, for a Canadian copper-zinc flotation mill, grinding was listed as being the most costly item taking up 30.4% of the total milling expenses, followed by the flotation cost at 2 1 .O% (Kidd Creek Mines Ltd., 1982). A survey on 45 copper flotation mills around the world showed the average grinding cost to be 34.5% of the total milling cost (Weiss, 1985).Overgrinding aggravates the cost issue, while insufficient grinding either causes loss of valuable minerals to tails or results in low-grade concentrates. Therefore, it is essential that grinding circuits be carefully controlled and monitored. To this end, a great deal of effort has been devoted over the years to the modelling and simulation of grinding systems in order to assist in the efficient running of these processes."

Jan 1, 2001

By R. M. Taylor

Lime addition to acid mine drainage (AMD) leads to precipitation, predominantly of metal hydroxides and calcium sulfate, and is the benchmark for remediation by precipitation. Geo2 Limited of Melbourne, Australia has developed and patented a novel alternative precipitation scheme based on the formation of mixed valency, M(I1)-M(III), hydroxide sulfate salts. When the composition of AMD is appropriate, the Green Precipitate Process provides a useful and more effective alternative to conventional liming. The characteristics and utility of the Green Precipitate Process are described in terms of the underlying chemistry, and a case study where the Green Precipitate process outperforms conventional liming. A mobile pilot pipe reactor rig which was built by Geo2 to demonstrate the process, and used successfully in both Australia and the United States, is described.

Jan 1, 1998

By Alessandro Navarra, Joël P. T. Kapusta

"The converting cost modeling software introduced by Ng et al. in 2005 [1] has been extended to consider the reprocessing of reverts and copper scrap. The original model evaluated the operational costs of a Peirce-Smith converter; algebraic relationships had been implemented with arrays (to represent matrices, vectors and scalar ratios). The new software brings flexibility to the underlying thermochemical balances, by using linked-lists instead of arrays. It is now possible to consider the blending of several feeds, including reverts and scrap.The software computes the length of the converting cycle from the Fe and S content of the charge together with the blowing rate; the times required for other operations (charging, skimming and idle time) are also accounted for. The costs of consumables such as flux, fuel, oxygen or compressed air are all evaluated. Downtime, labor, and materials for converter lining repairs are also considered. The software is easily extended to examine the costs of alternative operating strategies or injection technologies such as sonic single pipe injection and sonic shrouded injection. The potential cost benefits of alternative operating procedures and technologies are discussed through example calculations."

Jan 1, 2009

By Ingunn Opland, Silje M. Tinderholt

Drill and blast project in Norway’s capital. The contract consists of 7 rock caverns (350–950 m2), 9.2 km tunnels, and four shafts. With 110 blue-collar and 31 white-collar, the project produces an average of 16–21,000 m3 hard rock per week, with a total of 19 tunnel faces. Weekly, nine grouting rounds for water control, 800 m3 shotcrete, and 1,200 bolts are required, and 60 trucks leave the site pr. day. Challenges include blasting in densely populated areas, planning and coordination to maintain high production, obtaining a CEEQUAL certification of very good, and transporting rock on Oslo’s main highway.

Jun 13, 2023

By R. N. Orava

TO the author's knowledge, only one satisfactory high-resolution technique for etch-pitting dislocations in Cu-Zn alloys has been published.' In that account, pits in 70/30 brass single crystals were produced by etching electrolytic ally in a 30 pct orthophosphoric acid bath. Thereafter, observations were made from surface replicas by electron microscopy. The method of pitting and observation permitted the high resolution necessary for the distinction of individual dislocations in arrays of pile-ups. However, no comment was offered concerning the possibility of obtaining pits which are amenable to optical resolution. Moreover, for adequate results, the electrolytic pitting process is invariably preceded by a polishing stage which could obscure the surface features of interest. Consequently, it would be desirable to be able to delineate, by solely chemical means, dislocations which could be detected by both optical and electron metallo-graphic techniques. This was achieved by the simple expedient of modifying two etchants reported by young2 to reveal dislocations on the (100) planes of pure copper. Single crystals of 70/30 a brass, described previously,3 were sectioned to provide a surface parallel to a set of {100) planes, mechanically polished, and subsequently electropolished at 2.4 v in a solution comprised of 2 parts H3PO4, 4 parts ethanol, and 3 parts water. The inclusion of ethanol tended to inhibit nonuniform surface attack. Etch-pitting was effected by a 2 to 3 sec immersion in a 70 pct aqueous solution of HNO3. The samples were then washed in a fast-flowing stream of water, and rinsed further in distilled water, and ethanol, before drying. It is important to note that this reagent should be either used immediately after mixing, or, if allowed to cool, reheated to about 35°C prior to use. No pitting was obtained at room temperature. Typical results are shown in Fig. 1 where (a) is an optical view of the pitted surface and (b) is an electron micrograph of a silicon monoxide replica shadowed with tungsten oxide. The former is characteristic of a somewhat longer etching time (-6 to 8 sec) which varied with bath temperature. Similar pits accrued from a 1/10 aqueous dilution of another of Young's solutions2—2 M FeC1,6H20 and 7.8 M HBr.

Jan 1, 1968

By R. T. Jones

"SynopsisScientific progress relies on the publication of ideas and experimental results that can be replicated, tested, and improved over time. The first printed book on metallurgy to have been published in Europe is considered to be De la Pirotechnia, written in Italian by Vannoccio Biringuccio, and published in Venice in 1540. Together with De Re Metallica, written by Georgius Agricola and published in Latin in 1556, this can be considered to mark the start of scientific and technical literature in this field. Scientific publishing of journal papers has been in existence for 350 years, since the world's oldest and longest-running scientific journal, the Philosophical Transactions of the Royal Society, was first published in London in 1665.The nature of scientific societies has changed significantly since the early days when regular meetings were held to discuss science and conduct experiments, and the reading of scientific papers took place, and publication of papers was undertaken to record the proceedings of meetings, often including rather robust debate. In today’s world, there is a plethora of publications, and it is close to impossible for anyone to keep up with the vast flow of information. International conferences with hundreds of presentations have taken the place of the local meetings that used to discuss a single paper or experiment. In this frenetic environment, it is essential that researchers are able to trust the material they read.The system of peer review is used to maintain standards and to improve the quality of papers. This vital system is, however, significantly flawed. There is little incentive for reviewers to invest sufficient time in picking up all errors in publications, and any ineptitude on their part is usually protected by anonymity. It has reached the point where some reviewers have mistakenly permitted the publication of hoax papers deliberately presented with a complicated scientific facade. In light of such astounding inadequacies, perhaps a more open review process would be an improvement. Electronic publishing allows errata to be linked to the original papers.There is an increasing trend towards open access for papers in scientific journals and conference proceedings, which helps to reach as wide an audience as possible. This also supports the statement in the Universal Declaration of Human Rights, which says ‘everyone has the right freely to … share in scientific advancement and its benefits’."

Jan 1, 2015

By K. C. Dean

This report is the first of a series concerned with processes for producing magnesium. These reports will evaluate metallothermic, carbothermic , and electrolytic production methods, and will furnish a cost basis for comparing the processes. Areas deemed most promising for future research will be delineated for each procedure. This report presents briefly the history of the metallothermic process, and describes the operations of the Defense Plant Corp. (DPC) plants that employed the process. A hypothetical plant designed to produce 12,000 tons of magnesium per year, using ferrosilicon as a reductant, is described, and raw materials, energy, and major equipment requirements are estimated. Several process modifications are suggested for future research.

Jan 1, 1965

By D. C. Seidel

The role of surface charge in soluble salt flotation, which was developed in Part 1, is extended to relate the theory to the specific phenomena of KCI- NaCl separations. Temperature-collector solubility relationships, metal ion activation, and particle size effects are discussed.

Jan 1, 1967

By A. V. Bogdanovich

In diamond ores processing, final waste tailings size, rejected to dump, is one of the most important parameters. On one side, it is necessary to minimize losses of diamonds, whose size exceeds 1 mm, on the other side ? to provide for the plant high throughput and sufficiently low capital and energy costs, which is in greater part connected with disintegration process. Extensive laboratory, pilot-scale and commercial-scale dressability studies of different types of diamond ores have been performed at JSC ?Mekhanobr Engineering? in recent years. With that, special consideration was given to determination of the required ores? disintegration size that would provide for a high recovery of diamonds. In diamond ores processing, in order to exclude breaking of large diamonds, stage disintegration is used with regrinding of light fractions and heavy fraction X-ray fluorescent separation tailings. On account of rather weak bonds of diamonds with enclosing minerals, in crushing and grinding of diamond ores, selective disintegration takes place, with aggregates? breakup along plane surfaces of least bonding, which facilitates liberation of diamonds and their transition to free state. Heavy components losses with different sizes of final dump tailings were studied in processing of large samples. It was established, that in order to almost completely exclude losses of heavy components over 1 mm size, light fractions had to be ground to 2.5-3 mm size, while X-ray fluorescent separation heavy tailings of -15+3 mm size do not contain diamonds larger 1 mm in aggregates, and their regrinding does not increase total recovery of diamonds. On the basis of the conducted studies, relationships regarding heavy components and diamonds losses with respect to diamond ores final disintegration size were obtained, providing for more rational organization of the ores disintegration and processing flow sheet. Keywords: diamond, waste tailings size, disintegration process, recovery of diamonds

Sep 1, 2012