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By Robert F. Chaiken

The U.S. Bureau of Mines conducted an experimental and theoretical study of coupled chemical kinetic and mass transport processes during leaching of pyrite from coal in a counterflow, "trickle-bed" column reactor. Spatial and temporal data on reactant and product concentrations were used as solutions to appropriate continuity equations, which in turn define chemical kinetic reaction rates. Data from four 180-by 30-cm column leaching experiments using coal, coal waste, and air-water and air-FeC13 lixiviants have been analyzed. The rate of leaching was found to be diffusion limited (probably by Fe3+) and not controlled by bacterial action. Rates of pyrite oxidation were found to vary with elapsed time (80 to 225 days) and followed a bell-shaped curve, sometimes with a delay before start of reaction. Maximum rates of reaction ranged from 3 to 10 (mmol/d)/L (column) for coal waste and 0.4 (mmol/d)/L (column) for coal. Reaction was 30 to SO pct complete, probably due to precipitation of product salts (e.g., jarosites), which impede transport of oxidant through the coal. An absorption-desorption model of solids leaching, which considers the role of heterogeneous porosity in solids leaching, was used to describe time-dependent leaching rates.

Jan 1, 2010

By Abid O. Adekunte, David Greentree, David Hilton

"The construction industry is witnessing an upsurge in demand by property developers to have basements incorporated into their residential and commercial development schemes. This is attributable to perceived improvement to aesthetic and commercial values of buildings by underground space, amongst property owners. This trend is compelling more owners of buildings with no basements to explore the possibility of creating underground additional space beneath their existing buildings. The creation of a basement beneath an existing building entails the installation of a reinforced concrete (RC) underpinning system, temporary works, bulk excavation to basement formation level and construction of the basement structure, with associated aesthetic finishes.The L-shaped segmental RC underpins are a common system of choice for such underpinning works. They are multi-functional; providing vertical support to the existing superstructure, providing lateral support to earth and groundwater, supporting temporary and permanent surcharge loads from adjacent structures and services, whilst also forming part of the basement slab. This paper focuses on the first function of the Lshaped RC underpins; capacity under vertical compressive loading from the superstructure. The most common industry approach for the prediction of vertical capacities of L-shaped underpins is the oldfashioned Meyerhof’s (1953, 1963) effective width method, which is based on the traditional bearing capacity theory, whilst accounting for correction factors for eccentricity and foundation depth.The traditional bearing capacity formula is surrounded by a significant degree of uncertainty; estimates are highly user-dependent, as capacity prediction is sensitive to the chosen angle of shearing resistance (?), while there are difficulties in accurately measuring the in-situ ??value of cohesionless soils. In addition, the effective width approach has been shown to be very conservative by many research workers. The segmental RC underpins presented in this paper have been designed with an alternative less conservative method, which involves the use of a recently proposed consistent work-hardening plasticity model calibrated with field-based tests on footings of various aspect ratios and relative embedment in sand. The paper highlights the principles behind underpinning works for urban basement construction, the design of L-shaped RC underpins with the recently proposed plasticity model and the advantages of the method over traditional bearing capacity solutions and pre-existing plasticity models."

Jan 1, 2016

By L. Li, K. Jiang

China is the world largest producer and consumer of zinc. Beijing General Research Institute of Mining and Metallurgy (BGRIMM) is one of major research and engineering institutes for nonferrous metallurgy in China. This paper (presentation) introduces the development of China’s zinc smelting industry, key production processes and main producers. The process research and development are reviewed as well as BGRIMM’s R&D activities in the last decade. China's refined zinc production was 4,829kt in 2012, accounting for 38.6% of world production. Primary production was 4,722kt. There are around 150 refined zinc producers in China. The traditional fluid bed roasting - leaching jarosite is still a dominant process for primary production and its production accounts for about 60% of country's total production. However, the direct leaching process is gaining market share. Seven direct leaching plants with 330kt/a capacity, including autoclave leaching and the Outotec direct leaching, have been put into production by June 2013. Five autoclave leaching projects with 590kt/a capacity are in the pipe line and are expected to be commissioned in 2014 and 2015. To cut the production cost and improve smelter economics, process research to optimize the production flow sheet, to improve the iron removal and to enhance the recovery of co-existed rare metals were carried out. The development trends of China’s zinc smelting industry from the view of cutting production cost, improving energy efficiency, increasing comprehensive utilization are discussed accordingly.

Jan 1, 2014

By Poltak Sinaga

PT Kaltim Prima Coal?s 13.1 km overland conveyor (OLC) was commissioned in 1991. It is of conventional 3 roller 350 trough belt type. Cost and performance optimization during initial design ended up with 5.4 mps belt speed, 1000 mm belt width to convey 1350tph, and 7 mtpa of coal. Despite high initial figure, the belt speed was lifted to 6.5 mps in 1996 to accommodate mine throughput increase. In 2002, new low loss ST2100 1100mm wide belt replaced the old ST2250 due for change-out. An upgrade project was initiated at the end of 2003 to further increase the belt speed to 8.5 mps, hence to increase the OLC capacity to 30 mtpa (million ton per annum). Performance data, experience of site personnel, site observation and tests, benchmarking, and information from equipment manufacturers were major inputs to the design review. The project fast track was another challenge in addition to executing modifications on a production lifeline. The project was completed within fifteen months and the OLC was successfully commissioned at 8.5 mps belt speed in February 2005. The OLC has been to date conveying 4 200 tph satisfactorily.

Jan 1, 2008

This paper presents a theoretical investigation on the ionic equilibrium of Fe(III)?Ni(II)?H2SO4?H2O system. A non-ideal speciation model is developed to calculate the concentration distribution of iron and nickel species in a mixed ferric and nickel sulphate aqueous solution over the pH range from 0 to 4 and temperature from 25 to 100°C. A series of speciation diagrams for iron and nickel species is plotted with the effects of ionic strength and temperature on the equilibrium constants being taken into account. The ionic strength-dependent equilibrium constant is treated through a semi-empirical Vasil'eV equation, which is based on an extended Debye?Hückel theory. A Helgeson model is applied to extrapolate the equilibrium constant to elevated temperature. The ionic equilibrium reactions are described by a group of numerical equations containing the temperature and ionic strength-dependent equilibrium constants, which are solved by the Newton-Raphson method. The speciation model is also applied to estimate the hydrogen ion activities and corresponding pH values. The calculated pH values are in agreement with the experimentally measured pH, and are compared to literature data and pH values produced by the Visual MINTEQ® program (a computer code for the calculation of chemical equilibrium in natural aqueous system). This investigation provides a deep insight into the ionic equilibrium behavior of a mixed metal sulphate aqueous system which commonly occurs in hydrometallurgical processing. Keywords: speciation, chemical modelling, thermodynamics, iron, nickel

Sep 1, 2012

By Baoliang Xiao, Hui Pan, Yajun Hui, Kun Liu

The microstructure, properties, strengthening mechanism and work hardening mechanism of 600MPa grade high ductility hot-rolled sheet steel for automotive square tube were investigated by utilizing optical microscopy, scanning electron microscopy and transmission electron microscopy. The results show that the microstructures of low C-low Mn-Nb and Ti microalloyed steel (Steel A) and high C-high Mn-Nb microalloyed steel (Steel B) are composed of ferrite and a small amount of pearlite. Compared with steel B, the size of ferrite and pearlite of steel A is finer, while the size of the second phase precipitates is larger. The mechanical properties of the two tested steels are similar before tube forming, except that the yield ratio of steel A is higher. Steel A has/exhibits significant work hardening after tube forming; the yield strength and tensile strength increase by 45 MPa and 26 MPa, respectively, while the elongation decrease by 6.0 percent. The yield strength and tensile strength of steel B increase by 22 MPa and 10 MPa, respectively, and the elongation decrease by 4.0 percent. The grain refinement strengthening is the dominant strengthening mechanism, accounting for 52.9 to 61.8 percent of the total yield strength; the solid solution strengthening is the second strengthening mechanism, accounting for 17.2 to 25.3 percent, while the precipitation strengthening and dislocation strengthening contribute little to the yield strength. The dislocation strengthening increase by 82 MPa of steel A after tube forming, which is higher than that of steel B. Therefore, steel B has a low work hardening rate that is more suitable for manufacturing automotive square tube for secondary tube forming.

Oct 1, 2019

By J Zhou

Gold in sulfide ores is associated predominantly with sulfide minerals and occurs as both microscopic and submicroscopic particles. In non-refractory sulfide ores, gold occurs mainly as coarse- and medium-grained particles. Minute inclusions and submicroscopic gold usually account for a minor portion. In contrast, gold in refractory sulfide ores occurs mainly as minute particles and submicroscopic gold, and microscopic gold usually accounts for an insignificant portion. In gold ores containing carbonaceous material, the preg-robbing nature of carbonaceous material may impose challenges on gold extraction and cause gold losses. To extract gold from refractory sulfide ores, the ore needs to be finely ground and preoxidation is often required. Sulfide host minerals must first be oxidised to create a porous structure through which the cyanide leach solution can penetrate to reach the colloidal gold particles. The oxidation is traditionally achieved by roasting, autoclaving or bacterial oxidation. In carbonaceous sulfide ores exhibiting a preg-robbing nature, the carbonaceous material needs to be treated by roasting, autoclaving or other means to minimise the preg-robbing effect. As a predictive and troubleshooting tool, the gold deportment study plays an important role in gold metallurgy. It determines the deportment of gold in an ore or mill product and identifies the mineralogical issues that may affect or may have affected gold extraction. The information acquired from a gold deportment study can be used to assist in process selection, flow sheet development, recovery improvement and reagent optimisation.CITATION:Zhou, J, 2013. Deportment of gold in sulfide ores and implications for gold extraction, in Proceedings World Gold 2013 , pp 433-442 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By J. W. Hawley, G. S. Austin, L. A. Brandvold, J. Renault

Soil next to a smelter abandoned about 100 years ago near Socorro, NM was found, by the US Environmental Protection Agency (EPA), to contain high Pb concentrations. Detailed characterization of the soil by the New Mexico Bureau of Mines and Mineral Resources (Bureau) shows that the highest Pb concentration is in the clay-size fraction, although this fraction accounts for only 1 to 3 wt % of the soil. The depth of contamination, determined in areas relatively undisturbed since the smelter was abandoned, is no more than 76 mm (3 in.). Because of the soil's alkalinity, the Pb mobility is dominated by the movement of Pb-bearing particles, as opposed to chemical transport in solution.

Jan 1, 1994

By T. M. Geffen, F. F. Craig

Laboratory model flow tests have been made to simulate field conditions of partial pressure rnaintenance by dispersed gas drive on rocks having sandstone-type porosity. In this production method there is a significant saturation gradient between injection and production wells. A means of calculating relative permeability characteristics. from partial pressure rnaintenance flow tests has been developed. This method takes into account the saturation gradient. These kg/ko characteristics are identical to those for solution and external gas drives. This method of calculation, which has been proved experimentally, has limitations; however, it is valid for cases likely to be encountered in field prediction of partial pressure maintenance performance. The production performance of a hypothetical reservoir has been calculated for several different injection programs, involving both full and partial pressure maintenance. Results indicate that the maxinum oil recovery by these gas injection programs is obtained by full pressure mainte- nance at the original bubble point. Correspondingly lower oil recoveries are obtained by postponing gas injection and/or by reducing the degree of pressure maintenance. INTRODUCTION Dispersed gas injection is an important method of recovering additional oil beyond that obtainable by pressure depletion alone. The injected gas acts as a source of additional energy to displace oil from the rock formation as well as to retard oil shrinkage in the reservoir. In practice, gas injection is usually started after the reservoir pressure has fallen below the original bubble point. For various reasons sufficient gas is generally not injected to completely maintain the pressure in the reservoir. So, injecting gas at a declining reservoir pressure results in a combined external and solution gas drive. These two oil displacement processes are characterized by different gross saturation distributions in the reservoir. The external gas drive, like all frontal drive processes, inherently results in an oil saturation which increases from the injection wells to the producing wells. In the solution gas drive there is essentially a uniform oil saturation throughout the reservoir, provided the field is being depleted uniformly. It has been customary to predict oil recovery performance under partial pressure maintenance by a method which does not take into account the saturation gradient1. It has been shown2 that neglecting the presence of a saturation gradient can cause considerable error. It is the purpose of this paper to develop and present an improved method of predicting partial pressure maintenance performance of reservoirs including, where necessary. the effects of well arrangement. From the laboratory standpoint, this problem involves the measurement of the basic flow behavior (relative permeability characteristics) under partial pressure maintenance conditions. Recent research- as shown that for rocks having sandstone-type porosity, the relative permeability characteristics are identical for solution gas drive and complete pressure maintenance external gas drives. Since both solution and external drives have the same basic flow behavior, it was speculated that partial pressure maintenance, being a combination of the two, would also

Jan 1, 1957

By Jonathan K. Hrica, CASSANDRA L. HOEBBEL, Jennica L. Bellanca

Accidents involving powered haulage and mobile equipment like haul trucks are a major safety concern in the U.S. mining industry. They account for more than 50 percent of surface mine fatalities each year [1]. A recent National Institute for Occupational Safety and Health (NIOSH) analysis of 91 fatal incidents identified loss of vehicle control and situational awareness as key contributors [2]. However, the first-hand perspectives of operators are often missing, emphasizing the need for deeper insights into operators’ decisionmaking, lessons learned, sensory cues and mental strategies used during near-miss events. The findings in this analysis will help inform the development of training and safety solutions to prevent or reduce haul truck accidents.

May 1, 2025

By David R. Wilburn

The U.S. Bureau of Mines investigated the resources, costs, capacities, market relationships, and short-and long-term supply of bauxite, alumina, and aluminum. The 45 evaluated mines and deposits in 14 market economy countries (MEC's) have a demonstrated resource of 8.4 billion mt of bauxite and an aluminum content of approximately 2.1 billion mt. Developed world bauxite resources and existing primary aluminum smelting and refining capacity are sufficient to satisfy demand through at least 1995, when additional properties (with higher cost levels) would need to be developed to satisfy future demand levels. It is anticipated that new alumina or aluminum production most likely would occur in developing regions with large bauxite potential, low-cost energy sources, and a close proximity to refining and/or smelting capacity. An increase in aluminum recycling capacity would help meet future demand increases. A series of network model supply analyses was performed for the period 1988 through 2000. Based on announced future production levels and assuming demand grows at the level outlined in the analyses, model results indicate there is sufficient material available to meet demand until 1998, where-upon an aluminum shortfall is projected. Additional analyses investigated the effect of a reduced growth rate of demand and regional production variations in Venezuela on the international aluminum industry.

Jan 1, 1993

By Juan J. Monsalve, Mario Karfakis, AMAN SONI, Nino Ripepi, Jim Hazzard

Pillar collapses are events that due to their severe consequences can be classified as high risk. The design of pillars in underground room-and-pillar operations should migrate to risk-based design approaches. The authors of this work proposed a risk-based pillar design methodology that integrates stochastic discrete element modeling for pillar strength estimation, and stochastic finite volume modeling (FVM) for stress estimation. This paper focuses on the stochastic FVM component for stress estimation. The mining and geomechanical aspects of a case study mine (CSM) are described and pillar stresses are estimated by using three approaches: (1) analytical solutions, (2) 2D finite element modeling, and (3) 3D finite volume modeling. This operation extracts a 30° dipping deposit, which makes current underground stone mine design guidelines inapplicable for this CSM. This work compares results from each stress estimation approach and discusses uses the point estimate method as a simplified stochastic approach to evaluate the effect of rock mass elastic properties variability on pillar stress distribution. Results from this work show that the three estimation approaches lead to different estimations, possibly, due to the wide range of assumptions each estimation approach considers. It was also determined that the horizontal to vertical stress ratio has a significant impact on pillar stress magnitude. Therefore, it is recommended to perform in situ stress measurements, or assume worst-case-scenario values to account and reduce uncertainty due to this parameter. The stochastic stress estimation approach used in this paper provides results that can integrate a risk-based pillar design framework.

Sep 24, 2022

Seventy-three of the 90 naturally occurring elements that are found in the earth's crust are metals or metalloids. The quantities of metals used annually in the United States range from about 100 million metric tons (steel) to a few kilograms (osmium). The recovery of metals from discarded products or industrial process wastes, especially those metals that are used in large quantity, are very expensive, or are unusually toxic, is important to the national economy and to the natural environment. From its inception in 1910, the U.S. Bureau of Mines (USBM) has been the Government's prime source of information on metals recycling, as well as a major innovator in recycling technology. Statistical data on scrap generation and processing have been summarized annually for many years in the USBM's Minerals Yearbook. Most of the data for individual metals discussed in this report were extracted from that publication.

Jan 1, 1993

By Piotr Litwa

The paper focuses on actions aiming at improvement of work safety in mines, particularly in those extracting hard coal, taking into account the characteristics of natural hazards in Polish underground mining and the reasons of mining disasters connected with those hazards. It refers to conclusions addressed to scientific and research centres, drawn during last decade by Commissions appointed by the President of the State Mining Authority in order to investigate reasons and circumstances of incidents, which till now, could not have been accomplished because of financial reasons. Furthermore, the paper presents basic assumptions of the Strategic Research Project Improvement of work safety in mines, announced by the National Centre for Research and Development at State Mining Authority?s President request.

Aug 1, 2013

By A. U. Seybolt, R. E. Honnemon

THE purpose of this communication is to present activity data of nickel in the Ni-A1 binary system that was obtained for oxidation studies in this system. This data has been calculated from previous aluminum activity data at 1000°C1,2 by two types of Gibbs-Duhem integrations. These results should be of particular current interest to oxidation studies of aluminide coated nickel-base superalloys3 as well as other problems. The aluminum activity of Steiner and Komarek1 is plotted in Fig. 1 as a function of composition in Ni-A1 alloys at 1000°C. The dashed parts of the aluminum curves represent our approximate extrapolations from the directly measured regions. In the terminal solution regions (a and L phases) standard parabolic solution functions of the following form are assumed: where i is the component subscript, Ki is a constant at a fixed temperature, and xi is the atom fraction. The resultant nickel activity curve at 1000° C from the Gibbs-Duhem integration4 of the aluminum data is shown in Fig. 1. The solubility ranges of the phases present in the Ni-A1 binary at 1000°C are also denoted at the bottom of Fig. 1. Corresponding values of the nickel activity, aNi and yNi, are listed in Table I at useful compositional intervals. including phase boundary values. The aNi and yNi data listed in Table I are subject to the uncertainties present in the experimental aluminum activity data1 and to deviations from parabolic solution behavior in the terminal solutions. The errors introduced into aNi and yNi due to the parabolic solution assumption are expected to be relatively small (<20 pct of the values given) in all the phases except the liquid phase. Some deviation from parabolic solution behavior in the liquid phase is indicated

Jan 1, 1970

By R Dimitrakopoulos, K Kawahata, L Montiel

A method that optimises mining complexes that are comprised of multiple processing destinations, open pits and underground operations is presented. Mining, blending, processing and transportation decision variables are simultaneously optimised while accounting for geological uncertainty. The method uses a simulated annealing algorithm at different decision levels to generate a stochastic-based extraction sequence and processing policies. A case study shows its ability to generate a higher net present value while facing a reduced amount of risk when compared to traditional optimisation methods.CITATION:Montiel, L, Dimitrakopoulos, R and Kawahata, K, 2014. Globally optimising open pit and underground mining operations under geological uncertainty, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014, pp 201–212 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 24, 2014

By J. Vance Batty

Two methods were devised and evaluated for quantitatively measuring the amount of oleic acid on flotation products and in flotation waters. One method involved use of an organic solvent to remove carbon-l4-tagged oleic acid from mineral surfaces and flotation water phases with subsequent radio-metric analysis of the extracts. Studies showed this method to be slow and subject to large variations in accuracy and reproducibility. In the second procedure, tagged oleic acid was measured directly on the surfaces of dried mineral products. Oleic acid in the water phase was determined by adsorbing it on fine mineral, drying, and radiometric counting. Quantitative analysis of oleic acid on flotation products from bench-scale flotation tests with synthetic mixtures of ore minerals and quartz and with natural ores showed this method to be fast, accurate, and reproducible.

Jan 1, 1968

By Paul Worsey, Matthew Coy

In the blasting industry, many different techniques are used to estimate and examine the effects of varying explosives and blast designs on the breakage of a rock mass. The overall objective is to find a cost-minimized blasting solution that also conforms to the legal and environmental concerns related to blasting. A major drawback to current blasting methods is the inability to account for "caprock," or a thick overlying layer found in sedimentary rocks that creates large amounts of oversize blasted material, especially on the top of a muck pile. This can lead to underestimating oversize in shots with massive top layers. A better fundamental understanding of blasting processes with caprock is required.

Jan 1, 2018

By G. J. Koons, J. L. Uhrie

Field density studies carried out at the Phelps Dodge Chino Mine have found that truck-induced compaction is limited to the upper 2.4 meters (8 feet) of an individual lift. Hydraulic properties of material compacted to field densities were determined in a laboratory setting and saturated flow models were then run, simulating the effect of compacted zones within a stockpile. Modeling shows that compaction can effectively prevent solution flow through large portions of the stockpile, implying that great care must be taken to ensure that ripping is carried out to a full depth of at least 2.4 meters (8 feet) across the entire stockpile to achieve uniform solution flow. Uniform solution flow will result in maximum leach recovery.

Jan 1, 2000

By R. L. Virta

Four companies ? H.C. Spinks Clay Co., Inc., Imerys, Old Hickory Clay Co., and Unimin Corp. ? mined ball clay in four states in 2013. On the basis of preliminary data, production was 1 Mt (1.1 million st) with an estimated value of $47 million. Production increased by 3 percent in tonnage from 973 kt (1.1 million st) with a value of $45.1 million in 2012. Tennessee was the leading producer accounting for 64 percent of domestic production, followed by Texas, Mississippi and Kentucky. About 67 percent of total ball clay production was airfloat, 22 percent was crude or shredded and 11 percent was water-slurried.