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By George Filz, Peter R. Cali

"Unnecessarily restrictive specifications could be limiting the cost effectiveness of deep mixing (DM) applications and therefore limiting use of DM on projects where there are other options. Excessively restrictive standards demanded for strength and permeability certainly increase contractors’ bid prices, and costing the owners and, in the case of Government projects, the taxpayers more than necessary. Yet, lax or ineffective specifications often exist for some vital components of the quality assurance and quality control. In this paper, specifications for key elements of DM design and construction are examined. Recommendations are made to improve and streamline DM specifications to better serve the common objective of constructing a safe and cost effective ground improvement project.INTRODUCTIONSpecifications should, at their best, convey the project design requirements and provide clear direction to the contractor regarding requirements for submittals, materials, execution, measurement, schedule, and other aspects as necessary. The specifications should not be overly conservative, restrictive or ambiguous, and they absolutely should not be deficient in measurement of quality. Guide specifications or recycled sections from previous projects often form the template for new project specifications. But standards that appear in guide specifications or from former successful construction should be critically scrutinized by the designer for relevance before using the copy/paste functions of the specifications writer’s keyboard. Because work does not always go as smoothly as planned, specifications for remediation of non-compliant construction should be clearly stated and enforced. Often, non-compliancy is reviewed after-the-fact and deemed to have met the design intent, indicating that either the specifications were too restrictive or the enforcement too weak.The Federal Highway Administration Design Manual: Deep Mixing for Embankment and Foundation Support, October 2013, was written by a panel of DM expert design practitioners and contractors. Guide specifications are included as Appendix C of the FHWA manual. Those guide specifications have been updated in the deep mixing section of the www.GeoTechTools.org website, and the updated specifications represent the most complete and authoritative compilation published to date. Although the specifications for DM at www.GeoTechTools.org are current and complete, and they portray the state-ofthe- practice, they too must be modified to fit specific DM applications, project needs, and site conditions. The keys to a good set of specifications are to prescribe construction only to the level that is required to meet the design intent, to require appropriate quality control and quality assurance (QC/ QA) activities, and to clearly address remedial measures required for non-compliant work."

Jan 1, 2015

By J. Herbst, J. Groppo, A. Noble, R. Q. Honaker

"Coal and coal byproducts produced annually contain a sufficient amount of rare earth elements (REEs) to meet current U.S. demand. The REEs exist in the form of minerals, ion-adsorbed elements associated with clays, and chemically bonded elements within the organic coal matrix or host mineral. Researchers at three universities collaborated to evaluate the effectiveness of existing physical and chemical concentration processes for the recovery of the REEs. The efforts found that physical separation processes can increase the total REE content in the thickener underflow material collected from a Central Appalachian coal cleaning facility from around 300 ppm to values greater than 17,500 ppm on an ash basis. Leaching followed by solvent extraction was found to be the most effective to recover the REEs from coarse middlings materials collected from multiple coal basins, as indicated by recovery values exceeding 80 percent. Based on material characterization data and process evaluations conducted for several potential feed coal sources, economic recovery of the REEs will require byproduct production of both clean coal and REE concentrate using a process flowsheet that is unique for each source. IntroductionRecent studies initiated by the National Energy Technology Laboratory showed that U.S. coals contain significant amounts of rare earth elements (REEs), suggesting that rare earth minerals (REMs) and/or REEs can be produced as byproducts (Ekmann, 2012). According to the report, the richest source of REEs is the Central Appalachian coal. At present, there are 208 coal preparation plants located in the region consisting of areas within the states of West Virginia, Kentucky, Pennsylvania, Virginia, Alabama and Tennessee, with a total capacity of 166,495 t/h, or more than 1 Gt/y (Fiscor, 2014). If only a portion of these plants are retrofitted with advanced separation processes, the U.S. coal industry would become a significant producer of REE concentrates as byproducts. An inherent advantage of becoming a byproduct producer of REEs is that no mining cost needs to be part of the production cost."

Jan 1, 2017

By R. C. Ernrnons, Ray Wilcox

RECENTLY completed experimental work, carried out in the department of geology at the University of Wisconsin, aiming at a prevention of silicosis in industry has been reported in the American Mineralogist. A vast amount of work on silicosis has been reported in the literature, the clinical aspects having been especially well covered. A host of critical observations have been made on the variations in the nature of the silicosis problem in different environments, and a great deal of valuable experimental work has helped to clarify these observations. At present a greater amount of information of a critical sort is available than ever before, which affords a more sound basis for interpretive thought. It has been observed in industry that essentially pure silica dust gives rise to silicosis. Jones would modify this conclusion to place the responsibility on sericite, a silicate mineral present in the siliceous dust. Material such as granite dust, which carries a high free silica (quartz) content, is also a silicosis hazard. But sericite, too, is usually present in granite. In general it is widely believed that silicosis is caused by the presence in the lung of silicic acid regardless of the source. This view is adopted here.

Jan 1, 1937

By Botond Beno, Dave Watson, Danny Read

The Hampton Roads Bridge-Tunnel (HRBT) Expansion widens the existing I-64 four-lane bridge-tunnel corridor to eight lanes through construction of two parallel tunnels, interstate widening, and bridge expansions. The design-build contract was awarded to Hampton Roads Connector Partners with HDR and Mott MacDonald retained as lead designers in a Design Joint Venture. This paper will highlight some of the e challenges related to the design of the twin bored tunnels from spaceproong, tunnel enabling wors, segmental lining design and durability considerations.

Jun 23, 2024

By R L. Verburg, R Johnstone

DeBeers Canada Mining Inc (DeBeers) recently submitted an Environmental Assessment (EA) for its proposed Snap Lake Diamond Mine located in Northwest Territories, Canada. As part of the EA process, a site water quality management plan must be developed. Plan development requires an integrated approach such that the key factors influencing water quality can be identified and managed to minimise potential impact. A system model was therefore developed to simulate the site-wide water quality conditions and mass loadings to the principal environmental receptor of concern, Snap Lake, during operations and post-closure. Requirements of the simulation included integrating hydrology, geochemistry, hydrogeology and site management practices in a dynamic way. A unique feature of the site was the need to accommodate a complex flow system that included a feedback loop between lake water and mine water. A system model was constructed using the GoldSim software package that integrated on-site water quality and flow measurements, as well as results from independent groundwater flow and geochemical modelling efforts. The GoldSim model simulated concurrently the movement of 39 solutes through the subsurface mine and surface facilities. Solute sources considered included four different waste rock and tailings types, explosives use in the mine, treatment plant discharge, and recycled process water for dust suppression. Separate solubility constraints were identified for different regions of the flow system (eg underground mine; treatment facility; surface water bodies). Kinetic test data were used to derive temperature-dependent rate constants for use in calculating mass inputs from surface sources such as waste rock piles. The model generated water quality estimates over time for a variety of management scenarios at several potential discharge locations. The integrated approach used by the model was effective in identifying the significance of key factors influencing overall water quality such as explosives use, mine water inflow rates, waste rock reaction rates, site/mine management options, and effectiveness of treatment. The model provides an example of an effective tool for comprehensive, integrated system evaluation and management.

Jan 1, 2003

By Christopher C. Jobes

Computer-assisted control of a mining machine can place the operator in a safe, remote location. A guidance system aids remote positioning of a mining machine by determining its position and heading. The mechanical position and heading system (MPHS) is one of several guidance systems being developed at the U.S. Bureau of Mines. The MPHS uses linear position transducers (LPT's) to provide navigation information during face maneuvers. This report presents an overview of the MPHS theory and implementation, including recent design modifications made for more successful underground testing. This report also presents the experimental setup and procedure for the underground test. The test showed that the MPHS provides reliable and accurate results and can, therefore, provide useful guidance information for face navigation.

Jan 1, 1992

By Palmer DJ

Mercury is introduced into EZ's electroly tic zinc/sulphuric acid plant complex at Risdon, Tasmania, in zinc sulphide concentrate. Mercury is volatilised during the roasting operation and then distributed in the sulphuric acid plant effluents and product acid. Following an investigation of the factors determining the mercury distribution, a plan was formulated to-provide an environmentally accep- table degree of mercury containment at Risdon. This paper discusses details of the various control measures investigated and out- lines the reasons for selecting the particular procedures finally adopted for the Risdon plant.

Jan 1, 1980

By S. K. Kawatra, T. C. Eisele

"Coal-fired electrical power generation plants produce 56% of all the electricity in the U.S., burning approximately 860 million tons of coal annually. This results in the production of 58 million tons of fly-ash; 19 million tons of bottom ash and boiler slag, and 23 million tons of desulfurization sludge.s annually. These are a considerable disposal problem, and it would therefore be very valuable to be able to sell these residues and by-products as useful materials, rather than paying to dispose of them in landfills. However, utilization rates are currently very low, below 32% even for the most thoroughly commercialized combustion byproduct (fly-ash). This poor utilization rate is a result of the high impurity content of combustion byproducts, which makes them unsuitable for existing markets.Mineral processing techniques are useful for upgrading and utilizing combustion by-products. Fly-ash can be processed to remove unburned carbon, or utilized as a binder component in ore pelletization and agglomeration processes; bottom ash can be processed to produce certain aggregate grades; CO2 emissions can be sequestered using modified leaching techniques; and many scrubber sludge’s require processing before they can be used for producing gypsum products.The experiments described in this paper were carried out to study the application of mineral processing techniques to upgrading combustion by-products, particularly flue-gas scrubber sludge. A process was developed for upgrading unoxidized Flue-Gas Desulfurization (FGD) sludge’s by removing the primary impurity (unreacted limestone). A combination of hydrocycloning followed by froth flotation reduced the limestone concentration to as little as 1.7%, while recovering 66% of the sludge weight as a clean product. The recovered limestone was sufficiently concentrated that it could be recycled to the scrubber for more complete utilization."

Jan 1, 2003

By Fitzhugh T. Lee

Results from the first part of a two-part investigation of the stability of highwalls in open-pit coal mines in the Paleocene Fort Union Formation of the western Powder River Basin of Wyoming and Montana indicate that these highwalls are subject to time-dependent deformation. Field investigations and laboratory physical properties tests of coal and overburden rocks suggest that several factors influence highwall stability. Some of these factors are rebound of overconsolidated rocks, desiccation, water, orientation and spacing of fractures, and strength and deformation properties. Factors of safety for a typical highwall in the study area (calculated by the finite element method) may be less than 1.0 when open fractures are present and the highwall has degraded. Although it is concluded that most open-pit highwalls in the Fort Union Formation within the study area have adequate short-term stability, these highwalls do deteriorate and become progressively less stable. Because of this, postmining failures are common and stability conditions could become critical if mining were delayed and then resumed after a period of several months. The second part of the investigation will utilize field measurements of rock-mass properties and instrumentation of actively mined highwalls to obtain data for comparison with the results of the initial investigation. Because the height of highwalls will increase as the more shallow coal is exhausted, these data will also be used to predict the behavior of slopes higher than those presently found in the western Powder River Basin.

Jan 1, 1977

By J. G. Nalven

On July 1, 1999, most domestic metal mines will have to report releases of toxic chemicals into the environment for the first time as required by SARA Title 313. Some of these reportable releases will appear huge in relation to reports by other industries. The reasons for the potentially large reportable releases, special considerations for mining operations, and strategies for dealing with the reports are described. Data composited from experience with several mining companies is presented in the context of a typical gold mine.

Jan 1, 1999

By Xiaolong Bi, Shaohua Luo, Longjiao Chang, Shiyuan Cao, Jianan Liu

iliary agent was proposed. The mineralogical transformation and silicon extraction kinetics of laterite nickel ore in alkaline hydrothermal treatment were studied. The effects of reaction temperature (175 ~ 250℃), molar ratios of sodium hydroxide to ore (1.05 ~ 1.2:1), and laterite nickel ore particle size (44 ~ 178 μm) on the extraction ratio of silica were investigated by using the shrinking core model. The results show that the extraction ratio of silica increases with the increase of reaction temperature, sodium hydroxide to ore molar ratio, reaction time, and the decrease of raw ore particle size. The kinetic analysis shows that the separation of silica in laterite ore can be described by internal diffusion model. The apparent activation energy (Ea) of the reaction was 8.87 kJ mol− 1, and the kinetic modeling was established.

Dec 2, 2021

By Jamal Rostami, Wei Hu

Efficient performance of EPB TBMs in clayey ground is primarily dominated by the flow capability of the excavated muck in the cutterhead and screw conveyor. Currently, Consistency Index approach is used to evaluate clay clogging potential, but it does not include the effects of surcharge pressure on clay behavior. In this paper, a macro-scale soil rheometer is introduced to assess the clogging potential under various water content and surcharge loading conditions. The results show that, in addition to water content, surcharge pressure has clear impact on clay clogging too. In practice, Consistency Index chart can be refined to incorporate the impact of face pressure to better simulate the EPB tunneling conditions.

Jun 13, 2021

By W. F. James

Introduction The season of 1927, from the point of view of mining development in the area west of Rouyn, was quite satisfactory. Serious prospecting and development' were undertaken over quite a large area, though the results in the matter of discovering new deposits of economic importance were rather disappointing. A large amount of systematic prospecting and geological mapping was carried out in the course of the work, and a considerable body of information collected. A widespread occurrence of sulphide mineralization was noted, chiefly near bodies of older gabbro. The frequent occurrence of pyrrhotite in or near which local concentrations of chalcopyrite were localized, lends support to the idea that such older sulphides as pyrite and pyrrhotite are relatively easy of replacement by chalcopyrite. From the prospector's viewpoint, areas near the contacts of masses of older gabbro are favourable prospecting ground, and pyrite and pyrrhotite mineralization are favourable indications that massive chalcopyrite may be found where it has completely replaced such sulphides. Pyrrhotite being magnetic is easily located, even where drift covered, by the use of such convenient instruments as the dip-needle and the magnetometer. It is suggested that pyrrhotite bodies, when located, be thoroughly prospected because of the fairly strong probability that they may show replacement by the more valuable chalcopyrite.

Jan 1, 1928

By D Horacek, I K. Sheppard

Ok Tedi is in a period of transition. By 2008 mill feed will consist of higher levels of high-grade but metallurgically challenging skarn ores. Additionally, the Taranaki pit will start production in 2008 along with the start-up of a new pyrite concentrator. Taranaki ores are very high in sulfur. Sulfur is captured in a pyrite concentrate prior to tailing entering the Ok Tedi River. These and other complex scheduling issues will need to be resolved over a critical three-year period. With these requirements in mind, Ok Tedi contracted AMC Consultants to develop a custom version of the Life of Business Optimisation System (LOBOS¬) to assist medium-term production scheduling at Ok Tedi. LOBOS utilities enable Ok Tedi planning engineers to:import polygon-based reserve data (Blast Masters) from MineSightÆs Interactive Planning Tools (IP Tools); graphically construct block sequencing and material flow constraints; edit constraints defining standard scheduling, processing and financial relationships; define dump and stockpile attributes; and assign capacities to production systems, plants, dumps and stockpiles. LOBOS converts Ok TediÆs production scenario into a mixed integer program (MIP) and submits the resulting model to IlogÆs Cplex MIP Solver. The Solver seeks an optimal production schedule that maximises net revenue per mill hour while meeting all constraints. This paper introduces Ok Tedi and its production requirements and relates these requirements to the facilities developed for an Ok Tedi version of LOBOS.

Jan 1, 2007

By Adam Powell

A Cahn-Hilliard phase field model is formulated to describe transport-limited electrochemical reactions coupled with fluid flow in a metal reduction cell. When the reaction is limited by mass transfer of metal ions from the electrolyte to the cathode, the metal-electrolyte interface at the cathode exhibits a Mullins-Sekerka instability, leading to the growth of dendrite-like "streamers" of liquid metal into the electrolyte, which in turn significantly enhance the apparent mass transfer coefficient there. Model results for iron reduction from ferrous oxide in slag show formation of these streamers. Although the double-layer is not included in this model, the related phenomenon of electrocapillarity can be represented by a gradient penalty term which includes the electric potential gradient, such that interfacial energy is a function of the electric field normal to the interface.

Jan 1, 2003

By R. H. Olds, B. H. Sage

The transient flow of gases in long pipe lines is a problem of industrial interest. The present discussion deals with the application of the conservation of momentum and material to the transient flow of gas in conduits which are long with respect to their diameter. Solutions of the resulting equations include consideration of variations in friction and specific volume of the fluid as functions of time and position along the conduit. The changes in state along the pipe line are established as a function of time. The methods proposed may be extended to other situations. The flow of compressible fluids under steady conditions' has been considered in detail. Primary emphasis was placed on the development of simple means of taking into account the non-uniform flow' realized in long conduits under such conditions. Binder2 discussed the essential differences between the flow of compressible and uoncompressible fluids. Bonilla" proposed direct methods of solution for equations describing isothermal flow in long pipes. Similar considerations limited to steady flow have been discussed by Ruth.' Palsgrove 5 sugrested a graphical means of solving specific problems relating to the flow of gases in conduits of uniform section. Some of the basic concepts of the flow of a compressible viscous fluid in straight tubes have been described by Kuo.6 Problems of this type require knowledge of the equation of state of the fluid. In many cases it liar been convenient to assume that the fluid follows the relationship ascribed to a perfect gas. The treatment of unsteady flow of compressible fluids is less complete. This state of affairs result* from the fact that the differential equations relating pressure and flow rate with time and position for unsteady flow are nonlinear in character.' Muskat and Wyckoff presented an excellent treatment of the situation in laminar Bow where inertia forces were not of controlling importance. Somewhat earlier Hurst9 discussed the uncteady flow of fluids in petroleum reservoirs. Helhering-ton. MarRoberts. and Huntington'" established experimentally the pressure distribution and accumulative flow rate of natural gas through an unconsolidated sand. Recently Joffe11,12 conhitlcretl the specific problem of the flow of natural gas in relatively long.,. pipe lines for unsteady conditions with emphasis upon the economic feusibility of the storage of gas in such a reservoir. These discussions were based upon approximations of the partial differential equations applying to the condititons of flow. The results were descriptive of the physical situation and indirated the effertiveness of large pipe lines as cyclic storage facilities for natural gas. The advent of analog computers" has increased materially the practicality of solving nonlinear partial differential expressions. Several iterative numerical and graphical methods14,15,16 have been developed to solve nonlinear equations. However, it appears that the pair of simultaneous nonlinear partial differential equations involved in problems of this nature are not directly susceptible to solution by presently available analog computer or formal iterative numerical techniques. Nevertheless. graphical analyses afford a means of obtaining data of engineering value without special equipment. MATHEMATICAL CONSIDERATIONS Since the length of the conduit is large in comparison to the cross section in the cases to be considered, it is possible to treat the characteristics of the flow as independent of position in the cross section of the conduit. This possibility follows since the energy- connected with the velocity profile is small compared to that required to overcome the friction associated with its movement throughout the length of the line. Average values of the pressure. velocity. kinetic energy. momentum, and specific volume may he assigned to the fluid at any particular cross section. From a mathematical viewpoint this may be expressed in the following way for velocity: µ = µ(?X)..........(1) The uncertainties introduced by such assumptions usually are negligible when the ratio of length to diameter is greater than the order of 1.000. On this basis a volume element ma!. be considered to occupy the entire cross section of the conduit. Such an element is presented in Fig. 1.

Jan 1, 1951

By R. H. Olds, B. H. Sage

The transient flow of gases in long pipe lines is a problem of industrial interest. The present discussion deals with the application of the conservation of momentum and material to the transient flow of gas in conduits which are long with respect to their diameter. Solutions of the resulting equations include consideration of variations in friction and specific volume of the fluid as functions of time and position along the conduit. The changes in state along the pipe line are established as a function of time. The methods proposed may be extended to other situations. The flow of compressible fluids under steady conditions' has been considered in detail. Primary emphasis was placed on the development of simple means of taking into account the non-uniform flow' realized in long conduits under such conditions. Binder2 discussed the essential differences between the flow of compressible and uoncompressible fluids. Bonilla" proposed direct methods of solution for equations describing isothermal flow in long pipes. Similar considerations limited to steady flow have been discussed by Ruth.' Palsgrove 5 sugrested a graphical means of solving specific problems relating to the flow of gases in conduits of uniform section. Some of the basic concepts of the flow of a compressible viscous fluid in straight tubes have been described by Kuo.6 Problems of this type require knowledge of the equation of state of the fluid. In many cases it liar been convenient to assume that the fluid follows the relationship ascribed to a perfect gas. The treatment of unsteady flow of compressible fluids is less complete. This state of affairs result* from the fact that the differential equations relating pressure and flow rate with time and position for unsteady flow are nonlinear in character.' Muskat and Wyckoff presented an excellent treatment of the situation in laminar Bow where inertia forces were not of controlling importance. Somewhat earlier Hurst9 discussed the uncteady flow of fluids in petroleum reservoirs. Helhering-ton. MarRoberts. and Huntington'" established experimentally the pressure distribution and accumulative flow rate of natural gas through an unconsolidated sand. Recently Joffe11,12 conhitlcretl the specific problem of the flow of natural gas in relatively long.,. pipe lines for unsteady conditions with emphasis upon the economic feusibility of the storage of gas in such a reservoir. These discussions were based upon approximations of the partial differential equations applying to the condititons of flow. The results were descriptive of the physical situation and indirated the effertiveness of large pipe lines as cyclic storage facilities for natural gas. The advent of analog computers" has increased materially the practicality of solving nonlinear partial differential expressions. Several iterative numerical and graphical methods14,15,16 have been developed to solve nonlinear equations. However, it appears that the pair of simultaneous nonlinear partial differential equations involved in problems of this nature are not directly susceptible to solution by presently available analog computer or formal iterative numerical techniques. Nevertheless. graphical analyses afford a means of obtaining data of engineering value without special equipment. MATHEMATICAL CONSIDERATIONS Since the length of the conduit is large in comparison to the cross section in the cases to be considered, it is possible to treat the characteristics of the flow as independent of position in the cross section of the conduit. This possibility follows since the energy- connected with the velocity profile is small compared to that required to overcome the friction associated with its movement throughout the length of the line. Average values of the pressure. velocity. kinetic energy. momentum, and specific volume may he assigned to the fluid at any particular cross section. From a mathematical viewpoint this may be expressed in the following way for velocity: µ = µ(?X)..........(1) The uncertainties introduced by such assumptions usually are negligible when the ratio of length to diameter is greater than the order of 1.000. On this basis a volume element ma!. be considered to occupy the entire cross section of the conduit. Such an element is presented in Fig. 1.

Jan 1, 1951

By John L. Shafer

A process for the conversion of stibnite (Sb2Sj) concentrates, crude antimony oxide, or metal to a pure cubic antimonous oxide (senarmontite) has been developed on a laboratory scale. The conversion of stibnite to senarmontite has been piloted. The high purity of the final product is the result of forming antimony trichloride as a low temperature distillable intermediate. To obtain the antimony trichloride the stibnite, or crude oxide is slurried in molten antimony trichloride and reacted with gaseous hydrogen chloride. Antimony metal is oxidized to the trichloride with chlorine. The hydrogen sulfide produced from the hydro- chlorination of stibnite can be upgraded to a strength of 95% or greater for further treatment. The crude antimony trichloride is separated from the gangue by a preliminary evaporation and then is fractionally distilled and the trichloride distillate has less than 50ppm of arsenic and lead combined (the most troublesome impurities in antimony processing). The purified antimony trichloride is then hydrolyzed with sodium or ammonium hydroxide to produce the cubic form of antimonous oxide (senarmontite) to the exclusion of the rhombic form (valentinite) which is photosensitive. The advantage of this process is the ability to treat a wide range of antimony ores, concentrates, and metal to yield a high purity oxide in a controllable range of particle sizes.

Jan 1, 1975

By M Armony, J F. C L Costa, J C. Koppe

Linear kriging methods fail to estimate local grades and local reserves for highly skewed variables due to three reasons: it uses only part of the available data information, it has no physical principles associated with the mathematical proceedings to minimise the problems, and it works with continuous variables while data are discrete because of the limited precision of any equipment. The techniques commonly used up to now to solve the highly skewed variables estimation problems were unsuccessful, unless mathematical rigor is abandoned. Even the method of multiple indicator kriging is not satisfactory. This paper presents a new framework, the field parametric geostatistics (FPG) that transforms noisy variograms into well-behaved variograms and justifies mathematically empirical procedures commonly used, as trimming or capping arbitrarily very high values. The method, when applied to non-skewed variables, yields similar results to classic kriging. The methodology is illustrated in a case study at a gold deposit in Brazil, and compared to results obtained by usual techniques.

Sep 26, 2011

By Philippe V. Scheers

Polycrystalline gold, glassy carbon and gold-activated glassy carbon electrodes were compared for the production of hydrogen peroxide by the cathodic reduction of dissolved oxygen. Gold was deposited on glassy carbon by sputtering with a sputter coater and by electrodeposition from a diluted KAuCl4 solution using short potential steps. The sputtered gold particles were not adherent enough, but there were no adhesion problems with the electrodeposited gold particles. The gold coverage of the glassy carbon surface could be varied by applying a different number of potential steps. The overpotential for the electroreduction of oxygen to hydrogen peroxide decreases with increasing gold coverage of the glassy carbon surface, and for gold coverages exceeding about 16 %, the overpotential is close to that observed on polycrystalline gold.

Oct 1, 2003