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By Kwadwo Osseo‑Asare, Isehaq Al‑Nafai

The hydrometallurgical processing of bastnasite is a well-known process that is used to extract rare earth metals. However, more accurate measures are required to enhance the efficiency of extracting and recycling rare earths. In this work, Pourbaix (Eh–pH) diagrams for La-, Nd-, and Pr-(F)-(CO3)-(SO4)-(Cl)-(NO3)-(C2O4)-H2O systems were theoretically derived to investigate the stability relations during the hydrometallurgical processing of bastnasite. The diagrams for RE-H2O systems show similar trends to the original ones drown by Pourbaix. The stability domains of RE carbonates were presented by RE-CO3-H2O systems with pH range of 4.5–11. In contrast, the diagrams for RE fluorides showed a large stability region of insoluble REF3 (pH ~ − 1.7–12). The decomposition behaviors of REFCO3 were studied by constructing Eh–pH diagrams for RE-F-CO3-H2O system. The stability regions of bastnasite species extend from nearly neutral to basic media (pH ~ 6.5–12). The acid treatment (using H2SO4, HCl, and HNO3) of bastnasite was investigated by constructing Eh–pH diagrams for REF- CO3-(SO4)-(Cl)-(NO3)-H2O systems. According to these systems, REFCO3 can be decomposed at pH ~ 6.5 when treated with H2SO4 and at pH ~ 1.7 when treated with HCl and HNO3 acids. On the other hand, the alkaline treatment of REFCO3 converts it to RE(OH)3 at pH ~ 11. The recovery of rare earths ions was studied with the aid of RE-C2O4-H2O systems which shows a wide stability region for RE oxalates in pH range of − 2–11. This theoretical approach explained the aqueous relations in the hydrometallurgical processing of bastnasite ore and it can improve the practical hydrometallurgical processing of such ores.

Feb 9, 2024

By W. J. S. Craigen, G. E. Wittur

"In the context of today's continuously changing world, there are many factors which must be considered when attempting to assess the ability of Canada's primary copper producers to remain competitive in the face of increasing competition in world markets. In this paper, we have attempted to document those factors that will have the greatest impact on the future viability of Canada's copper industry, and to suggest possible strategies to fully utilize whatever inherent advantages Canada may have to enhance its competitive position. Technological factors related to the efficiency of precious and by-product metals recovery, energy type and utilization efficiency, production and sale of sulphur by-products, and control of 502 emissions are given high priority in this evaluation of Canada's future needs to remain competitive. Particular emphasis is placed on assessing the relative viability of hydrometallurgical versus pyrometallurgical processes for copper; to address uniquely Canadian conditions and problems. Due consideration is also given to the economic incentives required to allow Canada's copper producers to compete under anticipated world market conditions and to facilitate the continued development of Canada's copper resources. IntroductionWhen we try to assess the viability or competitiveness of any industry the bottom line is still usually, ""Can we produce a pound of product cheaper than the competition?"" Canada's copper industry is certainly no exception. However, as with most resource-based industries dependent upon exports, there are many factors which have a significant effect on the cost components which make up the total cost of producing and selling a pound of copper. It is desirable therefore to have as clear a picture as possible of the cost components, the major factors affecting them, and how they compare with the competition, particularly the third-world copper producers.In this paper we have attempted to provide a brief outlook for world copper markets and a brief overview of Canada's competitive position. We have also attempted to document those factors which will have the greatest impact on future production costs, and have suggested possible initiatives to utilize inherent Canadian advantages to enhance our competitive position. Special emphasis has been placed on technological initiatives designed to make full use of these ""advantages"", to develop superior beneficiation and extraction! refining technologies. Major factors considered in the present study are:"

Jan 1, 1986

By Vincent T. Ricca

Acid mine drainage is a serious water pollution problem, for its contaminants will eventually effect the quality of the receiving streams. According to the Appalachian Regional Commission (1969)1, 10, 500 miles of streams have been polluted by mine drainage, and 70 percent of this acid pollution is accounted for by underground mines. Due to the severe damage to aquatic life, to recreational and industrial use, and to domestic water supply, more stringent mining and anti-pollution laws have been legislated and coal mine operators are required to treat the mine water discharges to meet the minimum standards. For years now, abatement and treatment methods have been extensively studied. Progress reports presented in the Fourth Symposium on Coal Mine Drainage Research, 1972 1 suggest that a thorough investigation and understanding of the basin discharge is necessary in order to cope with the mine drainage problem. The extent of mine water discharge contamination can be considered as a function of the basin streamflow and acid generation load.' A conservative treatment cost estimation these days is $0.40 per 1, 000 gallons for water with 100 ppm iron, 500 ppm acidity. These figures need not include collection and pumping costs nor the cost of dispersing of chemical waste by-products. To achieve optimal abatement and treatment of mine drainage, predictions of the quantity and quality of mine water discharges are needed. Basin discharge is a continuous process and it can be considered as a. macro-system. This system can be subdivided into micro-systems to describe the various mine discharge .types in the basin. The mining activities could produce acid water discharges from deep mines, stripmines, or associated gob piles. A total study entitled ?Resource Allocation to Optimize Mining Pollution Abatement Programs?* will consider all of these sources. However, this paper will discuss only one micro-system, the drift (deep) mine type. We will look at a single mine and its watershed. The total research project considers a multiple mining complex in an extensive stream basin.

Jan 1, 1973

By Jr. Pitts

Elevation of surface charge density on colloidal particles in the presence of a high potential electrostatic field is demonstrated as a viable technique for preventing the accumulation of solids in solvent extraction circuits. The effect of the technique is manifest by relative turbidity measurements between pregnant leach solution and raffinate, by changes in the character of the sludge accumulations, by alteration of the zeta potential of particulates, and by a general reduction in the mass of solids.

Jan 1, 1992

By C Simpson, J M. F Clout, G Plummer

Detrital iron deposits (‘DID’) in the Hamersley Province of Western Australia have been successfully mined and processed as small quantities of saleable standalone or blended lump and fine ore products over many decades. Despite their past, present, and potential future exploitation, they have received far less geological attention than the economically more significant higher grade bedded iron deposits (BID) or channel iron deposits (CID). DID are composed of Pliocene to Quaternary unconsolidated colluvial/alluvial hematite gravels with minor sand, silt, and ferruginous clay, as well as minor iron rich hematite clast conglomerates. DID mineralisation at Solomon has been subdivided into six distinct stratigraphic units, DID-5 (lowermost) to DID-0 (uppermost) based on differences in clast and matrix textures and mineralogy, degree of consolidation/lithification, particle size distribution and replacement textures. The most significant accumulations of DID-1 to DID-5 are in tributary valleys that have been cut through the Joffre Member of the Brockman Iron Formation on either side of the main Kings-Queens valley which contains the CID. DID-5 and DID-4 are ferruginous conglomerate, referred to as canga, with four subtypes recognised. DID-4 is composed of BID hematite clasts cemented by hematite or goethite. DID-5 is characterised by partial to complete replacement of BID hematite clasts and matrix by the yellow ochreous and brown to black vitreous forms of goethite. DID-3 to DID-0 are unconsolidated hematite detritals composed of largely (>80 weight per cent) fine to coarse gravel, minor sand and little silt or clay. The gravel clasts are largely composed of hematite and hydrohematite that replace BID, micro-nanoplaty hematite-martite-ochreous goethite (m-nplH-M-oG) BID, reworked canga, hematite pisoids, siliceous hematite BID (micro-nanoplaty hematite-martite-quartz, m-nplH-M-quartz), chert (~10–20 per cent) and minor (<5 per cent) Banded Iron Formation (BIF). Hematite abundance decreases from DID-3 to DID-0 whilst siliceous hematite BID is highest in abundance in DID-0 and lowest in DID-3. A key finding of the study is that >90 per cent of mineralised detrital clasts are derived from hypogene altered BID micro-nanoplaty hematite-martite with subsequent later supergene ochreous goethite mineralisation hosted by the Joffre Member. The DID genesis model entails interpreted Palaeoproterozoic siliceous hematite hypogene microplaty BID mineralisation of the Joffre Member undergoing Cenozoic supergene leaching of quartz and replacement by ochreous goethite to form low phosphorous BID micro-nanoplaty hematite-martite-ochreous goethite clasts. BID martitenanoplaty hematite-martite-ochreous goethite clasts and detritus eroded from hill slopes were deposited in the valleys as an initial single DID-5-DID-4 unit over a weathered pre-CID basal conglomerate. DID-5 and DID-4 underwent goethite cementation of the matrix followed by replacement by hydrohematite, hematite, and maghemite. DID-3 formed during subsequent periods of erosion of largely DID-4 hematite clasts and pisoids. Groundwater flow-through hematite canga resulted in partial to complete hydration replacement of DID-4 hematite clasts and matrix by ochreous and vitreous goethite to form DID-5. Deposition of DID-2 to DID-0 was via reworking and deposition of DID-5 to DID-4 canga and DID-3 as clasts and pisoids/ooids, as well as siliceous hematite and BIF sourced from the Joffre Member in the hill slopes.

Nov 8, 2021

By Ben Burger

This paper describes the design, the first three years of operation and optimization of a large, single stage SAG mill at Minera Yanacocha?s Gold Mill facility located in northern Peru. The Gold Mill was commissioned in March 2008 with a 32? x 32? EGL, 16.5MW single stage SAG mill, to process 5 million tonnes per annum high grade oxide Au/Ag ore. Operational control, feed size distribution, grinding media, mill liner, grate and pulp lifter optimisation have allowed the mill to operate 15-30% above design throughput rates, but with a product P80 coarser than design. As part of the optimization, full grinding circuit surveys were conducted. Historical operating data and survey data were analyzed and used to evaluate possible circuit changes and determine alternative operating strategies. A number of changes were implemented which allowed the SAG mill to operate similarly to a large ball mill and achieve finer mill product that was closer to design. This paper summarizes life to date data analysis and improvements made by Minera Yanacocha as well as the grinding circuit optimisation study conducted by Metso Process Technology and Innovation.

Jan 1, 2012

By The Staff

Introduction In this paper it is proposed to discuss briefly some of the problems confronting the management of a gold mine in choosing a method of milling to recover the gold from various classes of ore. In order to simplify the discussion, the more common types of gold ores are classified from a metallurgical point of view as follows: Class 1?A: Free-milling ores which require only relatively coarse crushing. B: Free-milling ores which require finer grinding to release the gold. Class 2?A: Gold ores which contain the gold partly in the flee state and partly associated with a small amount of iron sulphide, and which do not require fine grinding. B: Gold ores similar to 2A, but which require fine grinding. Class 3?A: Gold ores containing copper in quantities insufficient to interfere to a serious extent with cyanidation. Gold ores containing copper in sufficient quantity to interfere with cyanidation but in which a large proportion of the gold is in the free state, the remainder being chiefly associated with the copper mineral, chalcopyrite. Gold ores containing copper and other sulphides, such as pyrite, etc., in which the gold is principally associated with these sulphides.

Jan 1, 1931

By John G. Parker

The rare-earth elements, sometimes known as the lanthanides, comprise the series of 15 chemically similar elements with atomic numbers 57 through 71. Yttrium, with atomic number 39, is often included in the group, because its properties are similar and it more often than not occurs in association with the lanthanides. Thorium is included in this survey due to its close association with the lanthanides, particularly in the mineral monazite. The lanthanides were first recognized as elements around 1750 and were the subject of much study by chemists during the 19th century. The purely chemical methods then available failed to resolve the strange intimate relationships between these elements, and it was not until about 1920 that the full series was explained.

Jan 1, 1971

By D. G. Crosby

This paper defines the Canadian offshore areas, comparing the juridical continental shelf with the physical one. The question of jurisdiction and ownership is dealt with, and the setting out of resource administration lines to divide areas of federal and provincial administration is explained and illustrated. Offshore activity is reviewed and prospective areas for future work are mentioned.

Jan 1, 1969

By Scott Stephenson

Making a tunnel through solid rock can sometimes be a dangerous task. Many things must be considered in order to complete such a task safely, and efficiently. Prior to starting things must be known such as, the type of rock, the purpose for the tunnel, the destination point, then angle of decent (or ascent). Once these things are known, the method to proceed must be considered. Factors such as cost, feasibility, and time to completion must be taken into account.

Jan 1, 2009

By M. W. Grabinsky, P. B. Tomory, J. Carvalho, J. H. Curran

Many underground mining operations use Split Set friction stabilizer bolts for rock support. Currently, however, little has been done to quantify the effects of various rock mechanics and operational parameters on the capacity of frictional support systems. The strength of Split Sets is usually measured by means of a pull test wherein a jacking force is applied to the bolt and a slip load is obtained. In order to evolve a rational design procedure for this type of support, an extensive database of over 900 pull test results from more than 50 mines through- out North America has been assembled and analyzed. Associated relevant rock mechanics parameters (rock type and quality) and operational details (drilling method, bit size, drive time, time to pull test) were also obtained, as completely as possible, for each test. Analysis of the information has yielded several charts that relate pull-out strength to relevant parameters and simple statistical analyses were conducted where necessary. Quantified distributions for pull-out strength were also produced for several operating conditions. The factors that most significantly affect bolt strength have been identified and specific applications to design are discussed. The information presented will assist mining engineers in designing safer and more economic support using Split Sets.

Jan 1, 1998

By P. Ravanal, J. Blazquez, F. Ortega, P. Couceiro, J. Navarro

Massive blasting technique is an interesting alternative to optimize mining’s performance by enhancing digging rates and overall operation’s activities, especially when a reduced operational bench width is available. The exploitation of a huge bench through multiple blasts would mean a potential reduction in productivity and higher operational difficulties. In such hard circumstances, combined with complex geotechnical conditions, a full ground vibration analysis for near and far field vibrations are required in order to safely design and conduct the blast. In this paper, a comprehensive case study will be discussed to show how the application of massive blasting techniques was safely implemented in very complex geotechnical conditions. The proposed solution was based on performing a full ground vibration study to optimize blast design parameters, such as charging and timing, in order to fire the complete bench blast in a single shooting event, without compromising the slope stability. Thus, a massive blast with an approximate tonnage of 6.0Mt was successfully designed and blasted, attending all safety and stability criteria defined by the geotechnical and drilling and blasting departments of Minera Escondida.

Jan 1, 2024

By W. H. Jang

Although surface chemistry fundamentals of semi-soluble minerals have been studied by many researchers, detailed understanding of these systems is still incomplete. In-situ FT-IR/IRS techniques have recently been used to successfully describe the adsorption of carboxylates at semi-soluble mineral surfaces. However, the wetting characteristics of these adsorbed films require further consideration. In this regard, the hydrophobicity and stability of transferred Langmuir-Blodgett (LB) monolayers of fatty acids at fluorite and calcite surfaces has been studied by contact angle measurements with polar and apolar liquids. Generally, it was found that the transferred LB monolayers of fatty acids at a calcite surface are unstable whereas such monolayers transferred at a fluorite surface are stable, as revealed from advancing and receding contact angle measurements. These results are believed to be due to the incomplete reaction of fatty acid monolayer at the calcite surface. In addition it was found that a closely packed well-ordered stearate monolayer with good hydrophobicity, equivalent to that of a transferred LB monolayer, can be formed at fluorite surfaces by spontaneous adsorption and self-assembly from aqueous solutions.

Jan 1, 1995

By M. Orchin

THIS PAPER is concerned with two aspects of the behavior of coal: (1) Dispersion by solvents atmospheric pressure and high temperature and (2) the destruction and regeneration of the coking properties of coal. Several pure polycyclic compounds and a coal-tar fraction were found to extract 95 percent of the organic material of a bituminous coal. About 20 percent of the extract was soluble in benzene, and this fraction contained the ?coking principle? of the coal. From an extensive chemical spectroscopic, and x-ray study of the benzene-soluble material, some conclusions could be drawn concerning the composition and structure of this fraction of coal. A possible commercial application of the extraction technique is in the preparation of low-ash carbonaceous material for the manufacture of electrode carbon.

Jan 1, 1951

By Peter Johnson, David Barber, Lachlan Henderson

"The traditional approach to rail tunnel fire safety design is to follow NFPA 130, which assumes a major tunnel fire could occur and requires bi-directional emergency ventilation. There is no regard to the impact of ventilation on fire growth and smoke production. In Europe and other parts of the world, the need for tunnel ventilation systems to provide smoke management in the event of fire is being questioned. The European Commission’s Safety in Railway Tunnels TSI is based on a philosophy that improved running capability (preventing fires and other events stopping the train in the tunnel) and elevated fire performance of materials means the chances of a major fire in a tunnel is highly unlikely, with only small fires expected, and no tunnel ventilation required. This approach is reinforced by the International Tunneling Association which has recently published an Engineering Methodology for Performance Based Fire Safety Design on Underground Rail Systems, which includes a methodology that does not require assessment of tenability in tunnels, but requires a scenario based risk assessment to be undertaken to determine overall fire safety measures. Recent research by the University of Edinburgh has shown that forced airflow from a mechanical ventilation system may promote fire growth and increase smoke volumes much more than with natural ventilation. Whilst the concept of no mechanical ventilation (i.e. natural ventilation) is a new concept for some, for many rail tunnels it is worthy of serious further consideration. RAIL TUNNEL SMOKE MANAGEMENT AND STANDARDS Smoke management using mechanical bi-directional ventilation systems has been a central part of the fire safety design solution under NFPA 130 for rail tunnels since 1982. The current version of the standard, NFPA 130: 2014, states that mechanical ventilation should be fitted to rail tunnels of length greater than 305 meters and an engineering analysis should be undertaken for tunnels of length 61 to 305 meters to determine whether mechanical ventilation should be fitted. However, this approach is not necessarily reflected elsewhere in the world. In Europe in particular, mechanical ventilation systems for smoke control within rail tunnels have taken a much less central role within the standards framework."

Jan 1, 2016

By L MacDonald, D Molver, D Pepper

Increasing contamination/impurity levels (including arsenic, antimony, mercury etc.) of concentrates is an issue of global commercial and health / environmental significance. With increasing environmental pressures at smelters, penalties for contaminants in concentrates continue to rise, accompanied by lower reject limits. There is a strong incentive for miners to investigate alternative means to remove contaminants in order to increase the value of complex ores and concentrates. This paper discusses the global problem of contamination in complex ores and concentrates, how the Toowong Process technology is a potential solution to this problem, and the opportunities this technology brings to the business of dealing with deleterious elements. CITATION: MacDonald, L, Molver, D and Pepper, D, 2018. The Toowong process for treatment of complex ores, in Proceedings Complex Orebodies Conference 2018, pp 119–121 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

Mining is big business in Ontario. The province is Canada?s leading mining region. It consistently ranks among the top 10 jurisdictions worldwide for exploration spending, reaching about C$1 billion in 2011. More than 26 percent of all exploration and appraisal dollars spent in Canada are invested in Ontario. Minerals produced include nickel, copper, platinum group elements (PGE), cobalt, zinc, diamonds, gold and silver. It was reported that there are more than 600 mining exploration projects in the province. And, recent discoveries of chromite in northern Ontario?s Ring of Fire will add to the province?s mineral production in the coming years.

Jan 1, 2013

By David R. Delling

Tenneco is a large, diversified, energy-based company which has grown rapidly during its forty year life. We&apos;re the youngest corporation among Fortune&apos;s top 20 companies. Tenneco Minerals Company is the division of the Corporation responsible for nonfuel minerals exploration, development and operations. Tenneco Minerals Company is headquartered in Lakewood, Colorado. Exploration offices are in Colorado, Nevada, Alaska, and Perth, Australia. We currently operate two gold mines in Nevada and a large underground trona mine and soda ash processing plant in Wyoming. The latter has a capacity of 907 000 tonnes per year of soda ash and is the subject of my presentation today.

Jan 1, 1984

By V. F. Petrov

Cyanide is widely used gold lixiviant for hydrometallurgical processes. The resulting tails contain complex toxic compounds. With reference to this, the protection of the environment should be the major issue. A complete detoxification of cyanides before disposal, a partial detoxification to the allowable concentrations and a disposal of tails at a polygon followed by the detoxification of excess water into the environment are offered as an environmentally friendly way of disposal. However, a complete detoxification of the cyanidation tails does not give the required results due to the presence of toxic compounds, cyanides and thiocyanates in tailings ponds. This is due to adsorption-desorption process occurring between solid and liquid phases. A partial detoxification is used to down cyanide to the allowable concentrations, which are safe to the environment. The storage of tails without detoxification is mainly used at low concentrations of toxic compounds in the disposed tails. With reference to this, water recycling is practiced by Russian plants in order to reduce as much as possible or almost eliminate toxic effluents into the environment. Fresh water is applied if necessary and to make up for water losses, with 8-12% of total water supply. This allows for the stability of water balance and the decrease of consumption of the reagents applied. The conditioning technologies of water recycling followed by regeneration of free cyanide and metals recovery as saleable concentrates are specially developed due to adverse impact of water recycling on gold recovery processes due to high concentration of base metals (copper). These technologies are also profitable. In order to detoxify cyanide in the tails for tailings dam, effective and inexpensive technologies involving a seasonal use of detoxified reagents were developed. For example, a technology with aldehydes use which is applied by a series of operations. Effluents disposed to the environment are detoxified using chlorination followed by almost a complete destruction of toxic cyanides and thiocyanates. Before disposal, chlorinated water is settled to precipitate the resulting hydroxides of metals and complete chemical reactions such as a full decomposition of hypochlorite ions. In order to protect ground water, watertight screens from local water-resistant materials are used. The samples of these materials were previously tested and chosen according to their maximum ability to adsorb toxic compounds in the tailings pond. If local water-resistant materials are not available, whole welded impermeable polymer screens are used. The options mentioned allow the storage of cyanidation tails in accordance with national ecological standards. Keywords: cyaninides, thiocyanates, wastes, environmental safety, recycled water-supply, detoxification, storage

Sep 1, 2012

By W. J. Wiehagen

The Work Crew Performance Model (WCPM) seeks to define performance variability within similar tasks of an underground work crew and relate observed variability to a cost consequence. Performance variability is described using work site observations to determine the adherence to job elements con¬tained within a standard operating procedure. Key components of the WCPM include (1) job definition through task analyses and the ranking of job elements by perceived cost consequence, (2) observational techniques for establishing performance baselines by measuring adherence to safe and proficient job procedures, and (3) cost linkages between adherence to task procedures and measures of consequence for noncompliance. Data presented within this report were obtained through the study of shuttle car operation in an underground mine in Appalachia. Observed adherence to safe and proficient job procedures by opera¬tors matched well with the consensus profiles (measured through a nominal group technique) with min¬ing personnel. It was also found that experienced operators consistently outperformed less experienced, incidental operators. These findings imply potential use of the WCPM as a practical procedure for thinking systematically about the choices available to reduce performance variability. Field application of the model can offer useful data to evaluate training and financially support performance improvement strategies that can be tested for their ability to reduce human error.

Jan 1, 1994