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By R. A. Ritter, J. P. Batycky

A numerical technique has been developed to permit estimating the pressure gradient associated with laminar flow of thixotropic liquids through long Pipelines. For this purpose the pipeline is divided into a number of radial and longitudinal increments within which rheological properties of the fluid may be considered as constant at any time. Then, provided only that the fluid flow curve is defined at every duration of shear, it is possible to predict the instantaneous pressure gradient at any cross-section along the pipeline for each desired flow rate and pipe size. The technique consists of an iterative integration of shear rate to establish the appropriate value of the wall shear stress at each location. Consistency of fluid in the increment is determined by the flow history of that increment, while the radial flow associated with variations in velocity profile is accounted for by adjusting the width and radial position of the increment. A number of pressure profiles, computed at each of several flow rates, provide a convenient basis for pipeline design and pump selection. INTRODUCTION In recent years considerable attention has been given to predicting pressure drop associated with the isothermal laminar flow of time-independent non-Newtonian fluids in pipes and annuli. 6,11,12 The approach generally has been to develop analytical relationships between flow rate and pressure drop based on simple constitutive models which hopefully provide an approximate description of the rheological properties of the fluid. Analytical solutions are highly desirable since the influence of all pertinent parameters can be readily determined. Unfortunately, however, this approach is restricted to simple flow geometries and- frequently leads to erroneous results due to inadequacies in the model. In certain cases a solution may be obtained through applying appropriate numerical techniques.l,14 For example, a digital computer program is available for predicting the velocity profile and pressure drop encountered by any Newtonian or time-independent non-Newtonian fluid flowing under laminar conditions in a cylindrical pipe or annulus.l In this paper the consistency behavior of the fluid need only be described in terms of basic rheological data. Analyzing flow systems involving fluids with time-dependent rheological characteristics is considerably more complicated since substantial changes in consistency may occur because of sustained shear action. This sensitivity to shear frequently persists for several hours. Consequently, variations in pressure drop and/or flow rate resulting from the aging process and addition of unsheared or partially sheared fluid to the system must be considered for purposes of pipeline design. This paper outlines a numerical method for predicting the transient and steady-state laminar flow behavior of a thixotropic liquid in a pipeline of arbitrary length (i.e., at a specified constant flow rate, the instantaneous pressure gradient may be determined at any time after start up and at any location along the pipeline). Several such pressure gradient profiles, computed at several flow rates, may be combined to produce a complete portrait of the system response. This flow portrait provides a reasonable basis for pipeline design and for selecting a suitable pump characteristic. TIME-DEPENDENT RHEOLOGICAL BEHAVIOR The most familiar time-dependent rheological properties are those exhibited by thixotropic liquids. Many of these materials, particularly thixotropic crude oils, generally display an apparent yield stress in that a finite pressure gradient is required to initiate flow. Then, under the influence of sustained shear at a constant shear rate, the consistency systematically decreases to some final limiting value. The shear stress obtained at

A sinter plant baghouse dust has been treated as a hazardous solid waste, and disposed at a very high price. A series of leaching tests were conducted to examine the possibility to produce high grade potassium chloride from the solid waste. It is found that around 40% of the solid wastes can dissolve into water, and a deposit with more than 90% KCl can be produced after simply drying the solution.

Jan 1, 2009

By R. Mumbi, M. Peart, E. Arinaitwe, B. Mbao, J. Zulu

Since 1925, xanthates have been widely used in sulfide flotation due to their low cost, ease of manufacture, and ability to float most value species. However, the industry's increasing need for safer and more selective alternatives, driven by low head grades, poor-quality, difficult-to-process ore with complex mineralogy, and stricter environmental regulations, has led to the development of Solvay's AERO® XR series of collectors. These custom-formulated products are based on greener chemistries and offer metallurgical benefits that are similar to or better than those of xanthates, without the safety concerns. Developed through Solvay's Flotation Matrix (FM) 100 approach, the XR series collectors are suitable for a wide range of applications, including the processing of Cu, Zn, and Cu-Ni, as well as the flotation of precious metals. This paper will highlight the differences between xanthates and XR series collectors, and present case studies of their successful commercial application at various global operations.

Jan 1, 2023

By Sergio N. Monteiro

Polymeric matrix composites with dispersed hard particles are being as wear resistant tools in industrial polishing operations. In the present work, the microstructure of epoxy composites with different amounts of embedded diamond particles, up to 30 wt.%, was investigated for the effect on fracture characteristics. It was found that the introduction of diamond particles promoted an increase the porosity of the epoxy matrix. Moreover, the particle morphology associated with a non-uniform distribution within the matrix was responsible for the nucleation of cracks that caused rupture of the composites.

Jan 1, 2006

By I. Govender

Positron-Emission-Particle-Tracking (PEPT) has enabled the non-invasive observation of charge and slurry transport in model mills under operational conditions. We use high quality PEPT data to infer that the charge motion can be effectively described by a non-Newtonian granular fluid. An improved theory for slurry transport, including inertial effects, is presented.

Jan 1, 2012

By Robert R. Grinstead

Two new ion exchange resins have been developed, which selectively absorb copper and nickel in preference to ferric iron from dilute sulfuric acid solutions of pH 1-3. The first absorbs copper and not nickel and can be readily eluted with 1-2N sulfuric acid. This resin is well adapted to the processing of copper leach liquors, including relatively low grade liquors obtained from dump leaching. The second resin absorbs nickel as well as copper in the same pH region, but only the nickel is eluted with 1-2N sulfuric acid. Elution of the copper requires much stronger (ca. ION) acid, altho both species are readily eluted with dilute (ca. lN) ammonium hydroxide. This resin, which should be useful in processing of certain types of copper-bearing solutions, may also be suitable for treating acidic nickel leach solutions of laterites and other non-sulfide ores.

Jan 1, 1976

By John C. Ryan

The Emeca Pile Splice, an innovative mechanical prestressed concrete pile splice, is the first robotically welded splice to be fabricated in the United States. An analytical and experimental study was conducted to establish the capacity of the standard splice for 12-in. and 14-in. square piles. The study illustrates compliance of the splice with International Building Code (2006) requirements. A case study for a large petroleum tank foundation project in Port Canaveral, FL is presented, demonstrating the efficiency achieved through use of spliced-piles. For the case-study project, single-piece 18-in.-square, 100-ft-long piles were replaced with 12-in.-square, two-piece, spliced piles. As a result, a significant reduction of material, labor, handling, and equipment was documented for the project. Savings realized on the installed pile cost was estimated to be in excess of 30% by the owner.

Jan 1, 2010

By Jihoe Kwon, Daeyang Lee, Mario Fujimura-Kashiwagui, Heechan Cho

"Calcium carbonate is one of the most widely used mineral in today's industries such as plastic, paper and pigment. There are many essential physicochemical properties required by each industry field but the most common requisite is size. One way to achieve appropriate size is grinding. Grinding is typically an energy intensive process, consuming about 40% of total energy cost in mineral process. Due to that reason, optimization of grinding process is a critical element to achieve price competitiveness. Two different type of grinding apparatus were hired to find out optimum condition in terms of energy efficiency. Utilizing samples containing 10, 20, 30 and 40% solids concentrations, a 1l batch type attrition mill was operated as the first grinding step at various operating speed with 1? to 5? grinding media in order to study the optimum operating conditions to reach submicron particles. Next, a 0.15l vertical beads mill was tested as next step with 100? to 500? grinding media to study the optimum conditions in the submicron range. Net energy and the specific energy input was measured to reach stated size ranges. Also, using a back-calculation based on the population balance model further operating conditions were studied. There were several competitive combinations which showed significant energy efficiency improvement when compared with the single step grinding."

Jan 1, 2014

By Leo Panian

Over the last decade, drilled and post-grouted micropile foundations have come to be increasingly relied upon for resisting seismic loads in building foundations on the West Coast. Micropiles have been successfully deployed in a range of soil conditions, in vertical as well as battered configurations, to support a variety of structural systems difficult soils. Their high load capacity in tension as well as in compression, their ability to be installed in confined spaces with minimal overhead clearance, and their ability to be directly tested in an installation have made them indispensable for seismic strengthening of existing structures. More recently, growing industry experience along with improvements in design guidelines have led to wider acceptance of micropiles among engineers and building officials. The increasing availability of the specialized materials, coupled with growing familiarity with drilling technologies among design-build contractors has made micropiles more cost-effective and competitive. For the first time, micropiles are finding applications in the construction of new buildings, where they are combined with shallow footings in hybrid foundations to efficiently resist seismic loads. These new applications rely on more intensive engineering analyses to evaluate the performance of micropile foundation systems and develop detailed requirements for design and construction. This paper describes the design approaches and the analytical methods for the seismic design of hybrid micropile foundations, and provides examples of recent construction projects that demonstrate the application.

Jan 1, 2010

By Konstantin G. Ashkinadze

The paper considers performance of piles supporting transient pipe anchors in heavy industrial pipelines. Events such as pump trips or opening and closing of large valves produce short-term dynamic pulses in the pipeline with variable spectral characteristics. Their magnitude is large enough to cause major damage to the pipeline and its anchors, which face horizontal impact loads amounting to hundreds of kN. Design of pile foundations supporting these anchors is often governed by limitation of deflection of the support to prevent overstressing pipeline connections and equipment nozzles. The maximum deflection does not always correspond to the largest load because the stiffness of the soil surrounding the piles heavily depends on the rate of loading. Faster actions encounter stiffer soil response while loads of smaller magnitude applied slowly may be more critical for the deflection time history of the anchor. A typical transient action has both high- and low-frequency harmonics, which makes the response complex. Using load rate-dependent p-y curves published in literature, the paper develops methods of analysis of pile foundations for transient anchors. Pile displacement amplitude – input frequency – natural frequency correlations and time histories of pile response are constructed for typical profiles of transient actions, considering nonlinear soil response to large horizontal loads.

Jan 1, 2016

By A. Lackner

Using the CFD software package FIRE, the smelting process inside a cyclone reactor is modelled. The fluid flow is calculated 3 dim., using different turbulence models. The effects of design parameters (length and diameter of the cyclone, concentrate feeding tangentially or from the top,..) and operating conditions are investigated. Single particle traces illustrate how to increase particle retention time before the particles reach the liquid film flowing down the cyclone wall. Moreover a two phase flow approach is developed, based on the "Discrete Droplet Model". The position, velocity, diameter and temperature of each reacting particle is described. The results show the advantages of top concentrate feeding, large height/width ratio of the tuyeres and increasing number of tangentially gas inlets.

Jan 1, 1995

By Eugene Jak

Copper sulphide processing technologies face increasing pressures associated with decreasing concentrate grade leading to increasing thermal inefficiency and lower productivity. Impurity concentrations are on average increasing, creating potential environmental risk and additional treatment costs. In copper flash smelters dust, partially oxidised materials and fume formed from the condensation of volatile impurities, are routinely recycled to the feed. In the converting stage the heat balance is maintained by charging anode reverts and other inert materials. In both cases, the thermal energy available from sulphide oxidation is not fully utilised or optimised. The productivities of both smelter and converter stages can be potentially increased through the addition of a high copper, low iron, low impurity precipitated copper product. Calculations are carried out for fayalite smelter and calcium ferrite converter slags using an optimised FactSage thermodynamic database. The potential for significant increases in smelter and converter productivities using existing technologies are predicted.

By Kate Willa Brown Requist, Eric Lutz, Moe Momayez

As air quality sensor networks become increasingly popular in underground coal mines, it is important to generate paradigms for the application of the collected data. To date, air quality sensing has been primarily used as an early warning system for hazardous air conditions. Using data collected from a network of sensors in a US underground coal mine, we have created multiple visualization methods to show the interactions of carbon monoxide evolution with ventilation airflow. These visualization methods can allow for further analysis of the source of contaminant, as well as better data resolution across the area of concern within the mine. By utilizing univariate spatial interpolations, we present methods for identifying the movement of carbon monoxide at one-minute intervals. The resulting visualizations display the evolution of carbon monoxide concentration across a sizeable study area over a period of 14 minutes.

Jun 25, 2023

By B. Kweto, W. Legodi, C. van Buuren, R. F. Sandenbergh

Biooxidation, and especially the BIOX® process, is a viable, economical and environmentally attractive process to liberate gold hosted in refractory sulfides by oxidatively leaching the sulfides as soluble sulfates. The moderate to high cyanide consumption during the subsequent cyanidiation of the washed biooxidation residue is probably caused by the retention on the solids of labile sulfur species formed during the multi-electron oxidation process of sulfide to sulfate. In this work the nature and mode of transport of the cyanicides in the products from the mesophile BIOX® process, as well as that of the combined mesophile and thermophile bioxidation process, were considered and strategies to reduce cyanide consumption evaluated. It was found that labile sulfur species were the major cyanide consumers in the mesophile biooxidation product, forming predominantly thiocyanate during cyanidation. The transfer of labile sulfur species was only marginally decreased by more intensive and thorough washing of the biooxidation products with warm and hot water, intense stirring and warm caustic leaching. A major reduction in cyanide consumption was however achieved by using a combined mesophile and thermophile biooxidation process. Keywords: Biooxidation, refractory sulfide gold ores, cyanide consumption

Jan 1, 2020

By Niloy K. Nath

Two layer sintering by charging green sinter mix with normal coke rate in the upper layer and reduced coke rate in the lower layer, can substantially reduce the coke rate and also improve the sinter quality by producing more uniform thermal profile through out the bed height. The two-layer sintering process have been analyzed by numerical simulation of the process by a detailed CFD based model, considering all the important phenomena like gas-solid reaction, melting and solidification, flow through porous bed, heat and mass transfer etc. Optimization techniques like genetic algorithm, differential evolution is then applied to evaluate the optimum coke rate in the two layers of the bed to produce the ideal thermal profile and melting fraction in the sinter bed for optimum sinter quality. Through this optimization method both high quality sinter with minimum return fines can be achieved along with reduced coke rate. Application of a genetic algorithm for this type of process optimization has several advantages over the traditional optimization techniques since it can identify global optimum condition and perform multi-objective optimization much easily for complex industrial process like iron ore sintering. Keywords: Two-layer Sintering, Iron Ore Sinter Quality, Ergun's Equation, Gas-solid reaction, Melting Fraction, Multi Objective Optimization, Pareto Set, Genetic Algorithm

Jan 1, 2003

By A. T. Chatas

A description of the geometrical characteristics of spherical reservoir systems, a discussion of unsteady-state flow of such systems and examples of engineering applications are presented as backgmund material. The fundamental differential equation, a description of average spherical permeability and the introduction of the Laplace transformation serve as theoretical foundations. Engineering concepts are investigated to indicate particular solutions of interest, which are analytically obtained with the aid of the Laplace transform. These are numerically evaluated by computer, and presented in tabular form. INTRODUCTION A tractable mathematical analysis of unsteady fluid flow through porous media generally requires incorporation of a geometrical symmetry. The simplest forms include the linear, cylindrical (radial) and spherical. Most analytical endeavors have concentrated on cylindrical symmetry because it occurs more often in petroleum reservoirs. Nevertheless, some reservoir systems do exist that are better approximated by spherical geometry. Review of technical literature revealed but a single reference to unsteady spherical flow in petroleum reservoirs.l The motive and purpose of the present work was to remove this gap in technical information, and to provide the practicing engineer with some useful analytical tools. The mathematical details associated with the particular solutions of interest involved use of the Laplace transformation. Hurst and van Everdingen previously demonstrated the efficacy of this operational technique, and in many respects the present treatment was patterned after their earlier work.2 PRELIMINARY CONSIDERATIONS GEOMETRICAL CHARACTERISTICS Geometrically, a spherical reservoir system is defined at any instant of time by two concentric hemispheres whose physical properties of interest vary only with the radial distance. Every physical property is thus restricted to be a space function of only one variable: the distance along a radius vector emanating from the center. Such a system is composed of an outer region and an inner region, separated by a defined internal boundary. The inner region simply extends inward from this boundary, whereas the outer region extends outward from it to an external boundary. The position of the internal boundary is presumed fixed, so that the size of the inner region remains constant. On the other hand, the position of the external boundary at any given instant of time is determined by the distance into the system that a sensible pressure reaction has occurred, Thus, the external boundary may change position with time. It initially emerges from the inner region and advances outward to its ultimate position. When this ultimate position coincides with a geometric limit, the reservoir system is said to be limited. When it coincides with points subject to pressure gradients furthest removed from the internal boundary, yet short of a geometric limit, the system is said to be unlimited. In this investigation two different boundary conditions are imposed at the ultimate boundaries of limited systems. The first requires that no fluid flow occur across this boundary; the second that the pressure remain fixed at this boundary.3-5 UNSTEADY-STATE FLOW In a strict sense virtually all flow phenomena associated with a reservoir system are unsteady-state. The transient behavior of these phenomena requires accounting, however, only when time must be introduced as an explicit variable. Otherwise, steady-state mechanics may be used. Analytically, steady-state conditions prevail in a reservoir system only over that portion of its history when this relation is satisfied:

Jan 1, 1967

"Mechanical alloying (MA) synthesizing technology and thennohydrogen processing (THP) were utilized to produce nanocrystalline Ti-MMC's reinforced by TiB intermetallic compound by using TiH2-B powder mixtures. Powders MA'ed up to 8 hours were examined by X-ray diffraction and SEM study. All MA'ed powders afterwards were HIP'ed at 700, 800 and 950EC for 1 hour. Detailed XRD, SEM and TEM study of the samples were carried out to determine the structure and micrography of the Ti-TiB MMC material processed by MA+THP approach followed by HIP'ing at high temperatures.IntroductionThe fiber reinforced titanium base composites [1,2] which possess a great resistance to high temperature have been investigated. In these studies fibers of C and SiC were used as reinforcing materials. However, these fibers react with Ti-matrix at elevated temperature resulting in product formation at the interface between the matrix and the fiber. Because of the chemical reactions, strength of the product MMC material diminishes.In conventional techniques of whisker reinforced composite material production, the mixtures of matrix metal powders and dispersed fibers are consolidated by hot pressing, HIP and/or hot extrusion. These techniques, however, have some shortcomings. Hard and brittle fibers could be broken during mixing cycle of the processing. Consolidation techniques could also be the cause for fiber breakdown. Attaining of the uniform dispersion of fibers into the metal matrix is not an easy process. The chemical reactions at elevated temperature exposures in the interface between the matrix material and fiber reinforcement cause product formations leading to poor mechanical properties."

Jan 1, 1998

By Kadri Dağdelen, Matthew Deutsch, Thys Johnson

Nested pit analysis in open-pit long range mine planning is used to define approximate ultimate pit limits and an initial high-level schedule in the early stages of a project. Modern ultimate pit optimizers can solve for dozens, or even hundreds, of nested pits however often a smaller subset of pits which are evenly spaced with respect to contained tonnage are desired for downstream analysis. In situations where that pushback selection process must be automated, such as when performing sensitivity analysis, or when the best subset of pushbacks is required; an optimization procedure is warranted. This paper describes a dynamic programming algorithm for selecting pushbacks following nested pit analysis, which is performant and addresses a long-standing inconvenience faced by long range open-pit mine planners.

Jun 25, 2023

By A. G. Belova

With the federal climate change legislation in progress, there is a need for demonstration-stage technologies aimed at providing clean energy from coal. Our research aims to experimentally illustrate the feasibility of capturing CO2 on a novel sorbent system from a gaseous stream. The gas is then released resulting in a regenerated sorbent and a pressurized stream of pure CO2 to be used for storage. The proposed sorbent is a ceramic honey-comb structured monolith coated with CaO supported on a high-surface area alumina. CaO is a natural acceptor of CO2 and our design ensures the physical stability and chemical reactivity of CaO over a large number of CO2 capture/release cycles. Furthermore, the use of the monolith ensures a uniform flow through the reactor, minimizes pressure drop across the reactor, and maximizes the surface reactive area. In this paper, we will present the results from a flow-through laboratory-scale reactor that establishes the efficiency of the proposed system to capture CO2. Future applications of the reactor include integration within the new-generation coal gasification power plants, such as IGGC, as means of providing decarbonized electricity.

Jan 1, 2010

By A D. Caccioppoli

Grade control systems within Rio Tinto Iron Ore have proven to be robust, when mining full benches. The Hope Downs 1 operation hosting two Marra Mamba Iron Formation deposits (North and South Deposits) presents a new challenge, where increased mining selectivity due to moderately plunging N-verging folds has made flitch mining necessary in the South Deposit. Poor flitch blasthole sample duplicate results in South Deposit over a 12 month period, compared to North Deposit, have highlighted concerns with grade predictions. In contrast a new grade control methodology (grade splitting) was proposed to alleviate blasthole sampling bias, utilising geological mapping and mineralogical logging, currently practised throughout Rio Tinto Iron Ore Pilbara operations, to estimate theoretical grades for each flitch from a single blast cone assay. To assess this method, reverse circulation holes (RC) were twinned to blastholes establishing an ‘actual’ grade. These blastholes were assayed using current flitch sampling techniques where: flitch positions were estimated, flitch positions were marked with paint, and a full cone sample was taken for ‘grade splitting’. Using these data sets multiple grade predictions were produced, then analysed using Half Absolute Relative Difference (HARD) statistical analysis. In addition to testing these grade control methodologies two other findings were ascertained: an inherent bias in blasthole assays exists particularly in the top flitch, where an average absolute difference of 0.6 per cent in SiO2 and 0.42 per cent Al2O3 was measured; and assays derived where kaolin rich soft shales are intersected were less representative. This is likely to be due to these materials not being properly represented in blast cones. Grade splitting accurately estimated block chemistry, except for a slight under-prediction in Al2O3 and P compared to current grade control methodologies. This method is a viable alternative where grade distribution is stratigraphically controlled.

Aug 22, 2011