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By A. Kontopoulos

The Olympias Mine in Northern Greece is producing an extremely refractory gold-bearing arsenical pyrite concentrate, containing on the average 41 3 S, 40 3 Fe, 10-12 3 As, 25 ppm Au and 35 ppm Ag. During the process selection stage, more than a dozen alternative technologies? were considered and an in-depth analysis was prepared for the three most promising, ie roasting, pressure oxidation and biological oxidation. Detailed capital and operating cost estimates were prepared, based, where appropriate, on laboratory and pilot-plant tests. A number of criteria was used for process evaluation and selection, including capital and operating costs; environmental impact, gold' recovery, stage of development, etc. Based on the above evaluation, the Sherritt Pressure Oxidation Process was finally selected. A detailed description of the process selection stage, supported with laboratory and pilot-plant test results on many of the processes considered, will be? presented.

Jan 1, 1989

By J. Sohn

The most promising near-term alternative to fuel cell driven vehicles is probably Hybrid Electric Vehicle (HEV or EV) technology. HEV technology combines the best characteristics of fuel-driven engines, electric motor drives, and energy storage components. It is designed with a combustion engine that functions as the primary power source, and an electric power storage system that functions as the secondary power source. The presence of the secondary power source allows designers to size the combustion engine for cruising power requirements. A new energy source for HEV or EV market will become lithium ion batteries (LIBs) in the near future. LIBs for HEV or EV has large scale about more 10,000 times than small size one for IT devices in order to achieve high electric density/capacity and high efficiency, etc. In those reasons, physical treatment of the batteries is more difficult for stable dismantling in comparison with the smaller one. Hybrid vehicle sales will grow by nearly 400 percent during the next seven years, according to a new report from analyst firm ABI Research. By 2013 hybrids will make up 6 percent of annual U.S. auto sales. The traction battery pack will become air-cooled LIBs which consists of several modules of Li ion battery and connected in series/parallel configuration to provide about >450 VDC, >150 kW peak power, and >80 Ah capacity. As the use of these batteries tends to increase significantly for the next years, it is relevant issues that development of new recycling methods as well as optimization of existing processes to treat spent LIBs for HEV have being addressed in order to obtain sustainability. In this study, physical treatment containing stable electrical discharge of spent LIBs for HEV was carried out for recovery of valuable metals from the batteries. Also In order to increase the yield of valuable metals through physical treatments such as electric discharge of spent batteries, crushing, and classification, we also focused on the recovery of cobalt from +8 mesh fraction due to its large portion in crushed intermediates.

Jan 1, 2010

By L. Crocker

The Bureau of Mines investigated processes for recovering a marketable lithium product from the montmorillonite-type clays of the McDermitt caldera. The clay deposit, located on the Nevada-Oregon border, is estimated to contain over 3 million short tons of lithium. Limestone-gypsum roasting and selective chlorination proved most successful for extracting lithium from the clays; 80-pct Li recovery was achieved using either technique. With both processes, lithium silicate in the clay was converted to a water-soluble compound-either lithium sulfate or lithium chloride. The lithium was then recovered as a carbonate by water leaching the calcine, concentrating the leach solution by evaporation, and precipitating the lithium with soda ash. The operating costs for the limestone-gypsum roast process were estimated at $2.02/lb Li2C03; selective chlorination operating costs were estimated at $3.85/1b Li2C03. The current selling price of Li2C03 is about $1.50/lb. A detailed flowsheet, material balance, and process evaluation are presented for the limestone-gypsum roast process. In addition, lithium reserves and resources are discussed and the McDermitt clays are described.

Jan 1, 1988

By Herty, C. H.

Iron oxide (FeO) plays an extremely important part in the manufacture of iron and steel. In the three major processes- blast-furnace, open-hearth, and Bessemer converter-iron oxide is the chemically predominant compound and controls to a large ex- tent the operation of the furnaces and the composition and quality of their respective products. In order to emphasize the importance of iron oxide in each process, they will be considered individually in some detail. THE OPEN-HEARTH FURNACE. Iron oxide is introduced into the open-hearth furnace in four ways : 1. The scrap charged into the open hearth is oxidized by the furnace gases, the amount of oxide formed depending primarily on the amount and type of scrap charged. It has been found' that with large scrap, 1.7 Ib. of FeO is formed per 100 Ib. of scrap charged, whereas with scrap of medium size about 5.3 Ib. of FeO is formed per 100 Ib. of scrap charged, when the period between the charging of the scrap and the addition of hot metal is 3 hours. 2. The decomposition of the limestone sets free CO, by the reaction

Jan 1, 1957

By Daniel I. Carey

Current and potential dragline reclamation usage was evaluated for the U.S. coalfields based on data gathered and analyzed during field surveys, literature reviews and contacts with manufacturers. It was concluded that current mining plans have been adapted to federal and state strip mine and reclamation laws in ways which limit the potential for dragline reclamation systems at active mine sites. At abandoned conventional contour mine sites in steep-sloping areas such as central Appalachia, however, it was found that dragline reclamation systems have great potential application and may be the only practical solution to many reclamation problems. Alternative dragline systems were examined for restoring abandoned sites, and it was concluded that a tower excavator system offered superior characteristics and should be evaluated and developed under field conditions. A testing program was developed to provide a framework for the monitoring and analysis of cost, production and environmental data during a field demonstration of a tower excavator system.

Jan 1, 1981

By Selvaganesh Selvaraju, Deepak Raj, Sandun N. Wimalasena

One of the world leading oil majors is carrying out a multi-billion-dollar expansion of its integrated manufacturing complex in Jurong Island, Singapore, the global oil trading and refining hub. Soil conditions at the site comprise 10-20m thick reclaimed sand, below which is 3-5m of soft marine clay underlain by stiff soils of the Jurong Formation. The conventional foundation solution would adopt driven precast concrete spun piles; however, precast spun piles have a high embodied carbon from the usage of steel and cement. In order to reduce the carbon footprint, an alternative solution comprising deep vibro techniques was developed. The EFFC-DFI carbon calculator was used to demonstrate the expected scope 1, 2 and 3 carbon emissions for both driven pile and vibro techniques. By using in-house, state-of-the-art fuel-efficient machines, alongside the innovative design concept and usage of natural materials such as sand and stones, actual CO2e emissions were reduced from a potential 21,000 tonnes, with the spun pile’s solution, to only 1,900 tonnes. The saved 20,100 tCO2e is equivalent to an average car driving 2,000x around the Earth’s equator. The paper discusses the application of soil improvement as a more sustainable, lower carbon alternative to conventional piled solutions.

May 1, 2022

By Jack Bedder, Nils Backeberg

"Native antimony metal is rare and antimony generally occurs together with gold, lead, copper and silver. There are more than 100 antimony minerals, although the sulfide mineral stibnite is the main economic mineral.Antimony enters the supply chain either as a result of mining (primary production) or recycling (secondary production). China has by far the largest antimony resources and is, as a result, the world’s center for antimony mine production. While China remains the leading primary producer, accounting for 69 percent (80.5 kt or 88,700 st) of the global 117.5 kt (129,000 st) in 2017, market consolidation and regulatory inspections across China leading to closures of facilities have caused a significant decrease in Chinese output from 115.8 kt (127,600 st) in 2015 (81 percent of global production).Tajikistan and Russia are the next largest producers of antimony after China, both ramping up production in recent years. Russia could significantly increase its supply of antimony if Polyus moves ahead with supplying 10-12 kt/a (11,000–13,200 stpy) of contained antimony from gold tailings. Australia and Bolivia are also significant mine producers outside China. The value of the different ores varies based on the metal content of the concentrates, with the most valuable gold-bearing ores sourced from Australia’s Costerfield Mine and the least valuable mercury-bearing ores sourced from the Anzob Mine in Tajikistan. On average, Bolivian and Russian ores trade at an intermediate value between those from Costerfield and Anzob. Nearly all of the rest-of-world production is exported to China, where the ores and concentrates are processed into antimony ingots and oxides.Antimony ingot production is not as widespread as is the case with antimony mine production, owing to the high levels of pollution that are associated with antimony smelting. It is for this reason that smelting has been largely confined to China and other Asian countries ,such as Vietnam and Myanmar, where environmental legislation has historically been less stringent. Tajikistan has become a growing producer of antimony ingot since 2014, coming from the commissioned metallurgical plant at the Anzob Mine.Antimony oxide production is undertaken on four continents with China being the biggest producer. There is also a considerable amount of oxide production in Europe (mainly Belgium and France), which relies on imported antimony metal feedstock, mostly from China.A new antimony project under construction by Strategic and Precious Metals Processing (SPMP) in Oman made progress in 2016 and 2017, and after producing first metal in April 2016 in test facilities, was set to be commissioned in the first quarter of 2018. Commissioning had been moved back to June 2018, with a potential ramp-up to 2-3 kt/a (2,200 to 3,300 stpy) of antimony metal by the end of 2018. SPMP is also reviewing producing antimony oxide as part of its flow sheet."

Jan 7, 2018

By Alfred Petrick

This study gives an analysis of the copper system byproducts and discusses the identification and classification of byproduct metals and their supply systems. Arsenic, platinum-group metals, silver, gold, selenium, tellurium, molybdenum, rhenium, uranium, aluminum, magnesium, and byproduct copper, lead, and zinc from complex ores are covered. The report describes several metallurgical systems, the marginal and incremental products costs of byproduct subsystems, industry structure and organization, and the historical data on price, consumption, and supply. Supply curves are presented for about one-half of the byproduct metals studied. The study develops a conceptual framework for analysis by reviewing the present concepts of byproduct supply and the related price theory. It gives the sources of supply of the individual byproduct metals to indicate the importance of the byproduct supply to the total supply. Mills, smelters, and refineries processing byproduct materials for their metal content are identified by geographic location and company ownership, The study also includes information on the reserves-resource base supporting byproduct output, reserve estimates, and the demand aspects of each byproduct metal.

Jan 1, 1973

By G. Upadhya

Of late, solidification modeling has progressed considerably to emerge as a viable simulation tool for the foundry engineer. A wide variety of tools exist in the commercial market to cater to the various needs of the design/ foundry engineer. In fact, recent developments in the area of solidification modeling have been so rapid that a comprehensive review of the state-of-the-art is very much needed. In this paper, an attempt is made to summarize the various issues of solidification modeling, at the same time addressing the historical evolution of the subject. The various phenomenological issues covered in this paper include: heat transfer, fluid flow during mold-filling, solidification kinetics and microstructural evolution, quick-analysis schemes for approximations, porosity prediction models, and the phenomena of fluid flow in the mushy zone. Modeling issues related to the development of solidification stresses which lead to defects such as hot tears and the development of artificial intelligence concepts in the area of rigging design are also discussed. Due emphasis is given to the various phenomena which add to the complexity of the whole subject, and the various alternatives available for solving a particular problem. For example, the heat transfer problem can be approached by the use of simple modulus schemes or by solving the conduction equation to obtain a more accurate temperature distribution. Similarly the microstructural evolution can be handled in a deterministic way by use of nucleation and growth models, or in a probabilistic way by use of empirical models. The main goal of this paper is to put the multi-faceted problem of solidification modeling in proper perspective so that it can serve as a guide for future developments in this area.

Jan 1, 1994

By Marie-Aline Van Ende, In-ho Jung

A thermodynamic database for the oxyfluoride system CaO-MgO-Al2O3-SiO2-Na2O-K2O-Li2OMnO- FeO-F has been developed based on the critical evaluation and optimization of all available experimental thermodynamic and phase diagram data. The developed database can be used for phase diagram and equilibrium solidification calculations for multicomponent systems and for understanding the solidification behavior of mold fluxes. Based on this thermodynamic database, a simple kinetic model was developed to simulate the interactions between the mold flux and molten steel using effective equilibrium reaction volumes combined with the thermodynamic database.

Jan 1, 2014

By D Davis

The prediction of ground-borne noise levels from tunnel construction activities requires knowledge of the input vibration forces from the vibration source(s) into the cutting face, knowledge of the vibration transmissibility through the surrounding medium, and knowledge of the receiver building’s vibro-acoustic response. The conversion of this vibration energy into sound pressure within the receiver building depends upon the vibration coupling of the soil and the building’s foundations, the structure’s response including floor-to-floor attenuation and amplifi cation due to resonance, the radiation effi ciencies of the internal structural elements, and the room’s acoustical properties. Beginning with a known input vibration spectrum at the cutting face, it is possible to predict the resultant ground-borne noise levels within a receiver building using either analytical and/or empirical techniques, or by numerical modelling. This paper presents an overview of the various methods available to estimate ground-borne noise levels from tunnel construction activities and discusses the advantages and limitations of each.

Mar 8, 2011

By R. Holmwood, M. Faris, P. Holloway, M. Collins

Sulphuric acid addition is a major driver of the economics in the processing of nickel laterite ores by high pressure acid leaching (HPAL). Understanding the optimal acid addition rate is essential for the success of any HPAL operation, and this is especially true at Ambatovy, where the composition of the feed tends to vary significantly on a day-to-day basis. Most studies on the effect of acid on nickel extraction in HPAL have used laboratory testwork as their basis. Although these studies are invaluable in assessing the economics of a new project, they are limited by the range of ore composition that can be tested and the differences between the operation of the laboratory equipment and the commercial plant. To enable optimization of the acid addition at Ambatovy, operating data from the HPAL operation were obtained using OSISoft’s PI system and the data from several periods were examined to develop relationships between acid addition and nickel extraction. The initial relationships from 2014 focused on the acid required to achieve a target nickel extraction of 95%, with aluminum and magnesium in ore and feed slurry solids content as the major variables. As Ambatovy ramped up through 2015 and 2016, the calculated acid requirement was further refined to address the effects of HPAL temperature and retention time, and the oxidizing/reducing characteristics of the ore, and to generate acid requirement relationships as a function of ranges of nickel extraction. These relationships supported raising the target nickel extraction to 96% and enabled the development of an economic model between acid addition and nickel extraction.

Jan 1, 2017

By C. M. Haberfield

"1 INTRODUCTION Around the world, there is a demand for larger structures, tall buildings and large bridges. While good footing design is important for all structures, it is even more important in the case of large structures. Recent experience with footing design for tall buildings (e.g. Burj Al Alam development and Nakheel Tower in Dubai, the Gate of Kuwait in Kuwait, the City Centre Project in Bahrain and Eureka Tower and Freshwater Place in Melbourne) has shown the benefits of investing in footing planning, design and construction (Haberfield, 2011, Poulos and Bunce, 2007). The footing systems for most of these projects include the use of deep bored piles or barrettes (piles of rectangular cross-section). Many use piled rafts where the piles, while acting to support the load, are primarily used to reduce settlements. A clear understanding of the factors controlling the behaviour of the footing system is needed to enable a good engineering design to be achieved. This starts with a sound understanding of the ground characteristics and individual pile performance, including adequate collection of data and testing. The best footing solution can then be found using recent improvements in data collection and analytical techniques, complex and highly capable computer-based models and the availability of high speed computers. This paper focuses on the axial performance of deep bored piles socketed into rock – both their individual performance and their performance as part of a larger footing system. Recent research and construction practice is discussed. In practically all cases, serviceability conditions control the behaviour of the footings. Methods of establishing the parameters for input into sophisticated computer programs are described. Application of the methods to case studies is included and it is shown that the behaviour of individual piles can be closely predicted. These developments lead to lower construction costs, better constructability and shortened construction time because of the better understanding of footing behaviour. 2 FACTORS AFFECTING PERFORMANCE OF FOOTINGS ON ROCK For a typical pile-supported footing, it is necessary to consider both individual pile, pile group and raft performance. These require consideration of the behaviour of the ground immediately beneath the surface raft or footing, along the pile shaft, and at and beneath the pile toe (Figure 1). Immediately beneath the surface raft or footing, the important factors are strength for bearing capacity and stiffness for settlement and interaction effects. Along the pile shaft, of most interest are strength for bearing, excavatability and stability; stiffness for settlement and interaction effects; geology and permeability for pile stability and, most importantly, pile shaft resistance. At the pile toe all the above factors for the pile shaft are present and in addition the pile end bearing is of interest. Below the toe, stiffness for pile settlement is important to at least a depth of twice the building width."

Jan 1, 1900

By A. D. McMahon

Changes in world mine and smelter supply sources of zinc have led to changes in zinc supply patterns in the United States during the past 3 years, 1970-72. The result has been a growing reliance on foreign sources of zinc metal to furnish an ever-increasing portion of expending domestic requirements. This review of fundamentals and historical developments is intended to provide background in order to place the future of the U.S. zinc industry fn perspective. The properties and uses of zinc are described. A new study on U.S. reserves is presented with description by geographical region and comparisons with older reserve data. The technology of the zinc industry from prospecting through refining is described with emphasis on the metallurgy involved in the various methods of smelting. Production, consumption, and imports are discussed and illustrated with graphs and tables to review the past and present patterns. Government actions affecting the industry are shown.

Jan 1, 1974

By R. Hogg

"The basic population balance models for agglomeration processes are reviewed and procedures are described for extending their applicability to systems with size-dependent rate constants and to the formation and growth of porous agglomerates from rigid, solid-particles. Simplified procedures for the further extension of the models to include simultaneous agglomerate growth and breakage are also described.INTRODUCTION The association of small particles into clusters or agglomerates is a significant factor in many facets of particle processing. Agglomeration processes are widely used to facilitate handling, storage and utilization of fine powders. Processes such as coagulation or flocculation are used to aid solid-fluid separation in dispersed particulate systems. Agglomeration also occurs as an accompaniment, often unwanted, to other particulate processing operations such as fine grinding, mixing and blending, transport and flow.Reliable agglomeration models are needed for improved understanding of the processes in general and of the complex role of numerous, interacting variables as well as for direct application to the design and control of industrial processes such as flocculation, granulation and pelletization. Ideally, the models should account for the primary forces responsible for agglomerate formation and growth, the effects of external forces on process dynamics, the development of agglomerate structure and its role in the process itself, and the effects of concurrent processes such as structure modification (e.g. compaction) and agglomerate breakage or degradation."

Jan 1, 1989

By Xavier Pita, Alexandre Pinto, António Cristovão, Rui Tomásio

"The cutter soil mixing technology was been applied in Portugal since the last seven years. The aim of this paper is to present the main design and execution criteria, related with both the cofferdam and foundations solutions, using soil-cement panels, reinforced with steel profiles, at the new Leixões Cruise Terminal, located at the Leixões Port, in Portugal. The Terminal building was built with one basement on a marine environment, over very difficult geological and geotechnical conditions, which demanded the use of some unusual and integrated geotechnical solutions. It is also pointed out the importance of the QC/QA, as well as the technical, economic and environmental advantages of the cutter soil mixing technique, comparing with same more conventional solutions.1 INTRODUCTIONThe construction of the new Cruise Terminal at Leixões, main gate of the Atlantic Ocean to the North of Portugal and Spain, as a consequence to the constant increase of the cruise traffic, was a challenge from both the geotechnical and structural point of views, mainly due to very difficult and unusual conditions, ranging from the geological and geotechnical scenario to the existent and under operation Leixões Port infrastructures, mainly the South break water, as well as the existent cruising boarding deck (Figure 1).According to the Terminal Project it was necessary to build one basement below the water table level, including several earth retaining structures in order to allow the excavation works on dry conditions leading to a global cofferdam effect. For this purpose soil - cement panels, using CSM technology, reinforced with steel profiles, micropiles (both for foundation and cut off effect) and the existent sheet piles were used. Also pointed out are the adopted special foundations of a very complex structure, including bored piles and micropiles (Figure 1)."

Jan 1, 2015

By John D. Ridge

Here are summarized 162 papers, published between 1933 and 1967, that deal with various aspects of ore genesis. Emphasis is placed on additions to, or modifications of, ore-formation theory, no matter what type of deposit is discussed. More space is given to papers on the formation of base-metal sulfides solely because more papers are written on this subject. The final conclusion is reached that a chemically and geologically sound theory for the genesis of ore deposits can be built around the concept of concentration of ore e’ements in a magmatically produced ore fluid and around such surface processes as may act to concentrate economically valuable materials from rocks of any origin exposed at the surface.

Jan 1, 1968

By F. P. Haver

Because of increasing concern with air pollution, the Bureau of Mines has developed a hydrometallurgical procedure to obtain elemental sulfur from chalcopyrite (CuFeS2) by means of the following reaction: CuFeS2 + 3FeCl3 ? CuCl + 4FeCl2 + 2S. Under optimum conditions, 99.6 percent of the copper and 71.6 percent of the iron were extracted in 2 hours from a typical mill concentrate containing 75 percent CuFeS2 and 15 percent pyrite (FeS2). At the same time, 68.2 percent of the sulfur in the concentrate was oxidized to the elemental form. The leach was highly selective; gangue minerals, including pyrite, were not attacked, thus accounting for the relatively low recoveries of iron and sulfur. To obtain these results, the concentrate was ground to 98.9 percent minus 325 mesh, and 300 grams was treated with 1 liter of boiling ferric chloride (FeCl3) solution. The FeC13/CuFeS2 ratio was 2.7. Cement copper containing 99.9 percent copper was recovered from the leach solution by cementation on sponge iron. Excess iron, dissolved during leaching and cementation, was removed from the stripped solution by crystallization. Ferrous chloride (FeCl2?4H2O), obtained as a byproduct, was converted to high-purity ferric oxide (Fe203) and HCI by an oxidizing roast. The hydrochloric acid was then electrolyzed to obtain chlorine, which was used to regenerate the leach solution. The leach residue, which contained ~50 weight-percent elemental sulfur, was treated with an organic solvent to recover the sulfur and cyanided to reclaim gold and silver.

Jan 1, 1971

"Energy efficiency in mining and minerals processing has attracted considerable public and industry attention because of the significant quantities of energy consumption involved. In this context the question of what are worthwhile targets for energy efficiency improvements ought to be of the highest priority. It is however worth taking a step back to avoid falling in the trap of taking preconceived ideas that have been reiterated repeatedly before as gospel. The aim of this paper is to highlight areas where new or alternative approaches could potentially be the better way forward. Some may come as a surprise to conventional industry thinking. Ultimately any such solutions are attractive to practitioners not just in an environmental but also in an economic sense, and hence should be targeted through applied research and development efforts. This paper highlights key aspects of each group of opportunities and some of the individual approaches to provide an overview of the current status quo.MINING INDUSTRY POWER UTILISATION – WHERE IS THE BIGGEST BANG FOR THE BUCK?The question of where is the biggest bang for the buck when trying to determine worthwhile targets for energy efficiency improvements has not always been reported on broadly enough, typically because industry practitioners operate in specific areas of expertise and comfort zone. Looking beyond the familiar doesn’t always come easy. Any technology or methodology consideration to address energy efficiency needs to take into account the context of alternative opportunities of superior value or risks not achieving desired uptake. The following sub-chapters have been ordered by magnitude of improvement potential as best as is possible, starting with the biggest first, and the smallest last. Some may be a surprise relative to conventional mining industry thinking."

Jan 1, 2016

By Alton B. Cook

A material balance equation was derived for calculating (1) the initial oil volume and (2) the relationship of average reservoir pressure to net gas in storage in reservoirs used for natural gas storage operations. The equation is also applicable to secondary-recovery operations where reservoirs are completely repressured and gas cycled. Using this equation minimized two probable sources of appreciable error in conventional material balance calculations: inaccurate measuring of and accounting for produced gas, and differences between true reservoir pressure and average reservoir pressures as derived from bottom-hole pressure measurements. A new procedure is presented for calculating water encroachment. By solving the conventional material balance equation and the derived equation for gas storage simultaneously, the values for initial oil in place and net water encroachment can both be determined.

Jan 1, 1966