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Environmental and public concerns and the banned use of cyanide for the recovery of gold in some parts of the world have heightened the search for an alternative lixiviant to cyanide. Thiosulfate appears to be the most promising alternative to cyanide due to thiosulfate being non-toxic, relatively cheap compared to cyanide and generally gold recoveries are similar to those of cyanide. The most widely researched thiosulfate process is one where copper ions and ammonia are added to the solution. This paper reviews the leaching of gold in thiosulfate solutions and the contributions of the research at Monash University to the understanding of the gold oxidation reaction in thiosulfate solutions, the solution chemistry when copper ions, ammonia and oxygen are present, the influence of the changing solution chemistry on the gold leach kinetics, and the application of thiosulfate in the leaching of gold from ores. It is clearly shown that the gold oxidation rate is hindered in thiosulfate solutions. In the presence of copper ions the gold oxidation rate though is significantly enhanced and thus is why copper(II) is more effective than other oxidants in the thiosulfate leach system. The copper-ammonia-thiosulfate leach solution chemistry is shown to be very complex, especially in the presence of oxygen as the rate of thiosulfate oxidation increases and the majority of the copper ions are not maintained in the copper(II) oxidation state. The thiosulfate oxidation rate must also be maintained low as an intermediate thiosulfate oxidation product hinders gold leaching. In optimising the recovery of gold from ores with copper-ammonia-thiosulfate leach solutions it is important to evaluate and minimise any negative effect an ore may have on the leach solution chemistry and hence gold leaching.

Jan 1, 2003

By Earl L. H. Sackett

Barite, although not a glamour mineral and probably little known to many of those in the mining business, is produced in the US. in very respectable quantities and is an important factor in the mineral economy of this country. The scope of the various uses of this mineral is perhaps one of the most misunderstood things about it, for it is surprising how many of those with a casual knowledge of the subject speak of its primary utilization in terms of paint pigments and barium chemicals. The life blood of barite utilization, however, is the petroleum industry by virtue of its dependence on this high specific gravity, inert mineral as the weighting material in its drilling fluids. From 80 to 85% of barite usage in the U. S. is accounted for in this manner-in fact, its role in oil well drilling is the only excuse for some of the large-scale barite production facilities which have been developed. Other uses are important and widely varied, but comparatively they are of small scale. They include fine crushed barite of low iron content as a component in glass manufacture, barite as a source material for manufacture of barium chemicals, finely divided barite as a component of some rubbers and ground, bleached barite in pigments. The formerly substantial use of barite in lithopone, however, has declined markedly because of replacement of lithopone by titanium pigments

Jan 5, 1962

By Gordan Marrs, O. Matwijenko

"The Kidd Creek metallurgical site has been highly integrated to maximize revenues from its base metals mines. The site's operations include a Concentrator processing 4.3 million tonnes per year of copper-zinc ore, a Copper complex producing 100,000 tonnes per year copper cathode and a Zinc Plant producing 130,000 tonnes per year of zinc metal. To improve operating efficiency with increasing emphasis on productivity, process control, process automation and process optimization have been augmented and expanded during the last decade.New microprocessor based control systems provided the opportunity for the capturing of an expanded number of process related measurements. As supervisory computers were already in place, databases could be generated with only increased disc space and database management programs required. Once the data had been accumulated and stored, a method was then required for handling, screening and sorting large volumes of information in relatively quick and easy terms in order that the stored information could be used. By 1984, a decision to use personal computers for accounting, engineering and management reporting provided the vehicle necessary to handle this data. Using commercially available software, large volumes of stored process data can be downloaded from existing databases, filtered, sorted, analyzed, graphed, displayed, projected, reported and distributed. All this can be performed in very little time."

Jan 1, 1989

The sharp deterioration in Au~tralia'S ternn of trade in recent years and the accumulating national debt highlight the need for a restructuring of the economy which is highly dependent upon primary agricultural and mineral commodity exports (figure 1). Table I gives an indication of the value that can be added to raw material by mineral processing. Significantly higher value is added through downstream manufacturing. In 1987, the mining and rural sectors accounted for 47010 and 38010 respectively of total exports valued at $35,782 million (figure 2). The export contribution from minerals comprised $12,266 mil- lion from unprocessed ores and concentrates and $4,668 million from metals and processed minerals including some simple manufactures. Coal accounted for 450/s of total primary mineral exports. Iron ore and alumina are other important mineral exports, while gold and aluminium are major metal exports. (Figure 3) Australia's minerals are now traded in a much more competi- tive and oversupplied market in contrast to the 1960's and 1970's period which was characterised by increasing exports of largely unprocessed ores and concentrates. Since the early 1980's (I cI) resscd )ver~cas nutrkcts and km rununodlity liriccs ha~c hcen the product of excess capacity installed to satisfy a forecast high growth in demand which never eventuated due to the world reces- sion. During this period the emphasis on technology development was focussed on reducing costs through increased production effi- ciencies in order to maintain competitiveness.

Jan 1, 1988

Heap leaching has become one of the prime technologies used for the recovery of precious metals from low-grade ores over the past ten years. The recovery process involves mining and stacking the ore on engineered leach pads, with or without crushing and/or agglomeration, followed by leaching with a low concentration sodium cyanide solution. The metal-bearing, pregnant solution is then processed by zinc precipitation or activated carbon absorption to extract the precious metals. The leaching process continues until all economic metal values are removed at which time the spent heap leach pads, the leached materials and excess process solutions require decommissioning. The management of these solutions may present a potential challenge for successful and environmentally sound decommissioning due to their composition, volume or continuity of generation from the spent ore even though active leaching has been terminated. The principal objectives of solution management in decommissioning spent heap leach pads are to meet all operative environmental regulations in a cost-effective manner and to leave the pads in a condition where they do not present a long-term liability either to the operator or to the environment. This involves the reduction in volume of the residual process solutions and/or treatment of these solutions to where they meet applicable water quality criteria. In the past, the environmental and economic aspects of decommissioning and solution management have been overlooked or under-estimated during the planning of mining operations. As a result, there is a potential for long-term liabilities and costs to be recognized only at the end of active leaching, a time at which operating revenues and cash-flow are minimal. Therefore, the decommissioning process requires addressing at the mine planning stage and agencies now require that a plan for solution management after the cessation of operations be submitted prior to initiation of mining. This paper discusses aspects of process solution management during decommissioning, both in terms of quantity and quality, and how potential issues may be recognized and planned for in the initial stages of heap leach design.

Jan 1, 1992

By A. Hashempour, D. Javani

"Selection of an optimal bit is a critical issue in drilling engineering. Specific energy (SE) and Cost per Foot (CPF) are the most common methods for evaluation of bit efficiency and optimal bit selection. The major shortfall of both methods is that they do not directly account for geological and geomechanical parameters of formations being drilling. In this paper, results of using the two foregoing methods are compared using Formation Drillability (FD) method, which directly accounts for geological and geomechanical parameters of a formation. This method combines various geological and geomechanical parameters and yields a dimensionless parameter indicating the formation drilling hardness (drillability). Results of this study show that the amount of energy, cost and time spent for drilling a unit volume / length of an identical formation may vary in different wells. This is due to the fact that geological and geomechanical characteristics of a formation may vary among wells and even within short intervals of a single well. Therefore, an optimal bit may not be appropriately selected, if drilling and economical parameters are the only factors considered and the formation geological and geomechanical specifications are ignored.INTRODUCTIONMany authors such as Bilgesu, Al-Rashidi, Aminian, and Ameri (2000) and Clegg (2006) conducted research in the evaluation of bit performance and optimum bit selection. Almost all of them tried to establish a good relationship based on geomechanical parameters. Primary examples are the research done by Ubaldi (1999), Macini, Magagni, Da Dalt, and Valente (2007)."

Jan 1, 2015

By M. Hoch

Equations are derived from statistical considerations to represent the activities of each component of an interstitial solution, and of a compound with a wide homogeneity range as a function of composition and temperature, based on the interaction energies between the various components, Eij. The equations are checked on the binary systems Fe-C, Ta-H, and Y-H, the ternary systems Ti-O-H, liquid Fe-C-0, and the compounds TiO, MnO, COO, and YH,. In all cases the present model represents the experimental data well. THE aim of this paper is to derive from statistical considerations the thermodynamic behavior of non-substitutional solid solutions. "Nonsubstitutional solid solution" means either an interstitial solid solution (carbon in iron, oxygen and hydrogen in hexagonal and bcc titanium, and so forth) or deviation from stoichiornetry in compounds (introduction of vacancies—removal of atoms in one or both lattice sites of compounds FeO, MnO, TiO, NbO, YH2). wagnerl and Fowler and Guggenheim considered the theory of compounds with small deviation from stoichiometry; Anderson includes larger deviations from stoichiometry, the defect being present in one component only, as vacancy and interstitial. Rees considers only vacancies in one of the components and introduces various kinds of sites for the component where the defect occurs; the various sites interact with different energies, thus giving isotherms with two or more plateaus. Both Rees and Anderson are mainly occupied in determining the limits of two-phase regions, and the defect interaction energy is determined from the critical point. Darken and Gurry5 gave a brief treatment of carbon solution in iron; Speiser and spretnak calculated the configurational entropy for binary interstitial solid solutions by assuming that each interstitial atom in the solution excludes a certain number of neighboring interstitial sites from occupancy. Use will be made of this concept later. Hoch et al treated transition metal oxides of the NaCl-type structure, and also oxygen solution in titanium.' The main aim was to determine the behavior of the activity of one of the components as a function of the composition in the single-phase region. In the present paper, the various interaction energies are discussed in detail and the similarity between interstitial solid solutions and deviation from stoichiometry in ionic compounds is shown. Both types of systems have in common that at least on one kind of lattice site only one kind of atom occurs; this gives a fixed frame to the system, permitting a much easier statistical treatment than for the substitu-tional solid solutions. (The theory is also applied to ternary systems.) The difference between an interstitial solution and deviation from stoichiometry can be explained as follows. In an interstitial solution in the pure or standard state the host atom or host structure is present alone and all the interstitial sites which are going to be filled when the interstitial atom is introduced are empty. The interstitial solution is now created by introducing atoms into this empty lattice. In the deviation from stoichiometry, both kinds of lattice sites are already occupied in a special fashion (all lattice sites occupied, or the same fraction of lattice sites empty, or one kind completely filled, the other only two-thirds). Deviation from stoichiometry removes atoms from lattice sites, adds them, or removes atoms from one kind of lattice site and introduces them on the other lattice site. Though both cases (interstitial solution and deviation from stoichiometry) lead almost to the same equations, they are treated separately. The treatment given below corresponds to the "regular solution"10 treatment of substitutional solid solutions. Speiser and spretnak's6 treatment is similar to the athermal solution in the substitutional use. a) INTERSTITIAL SOLID SOLUTIONS Theory. It will be assumed that there are N lat-tice sites occupied by the host atom (denoted by 1). Corresponding to those N lattice sites there are N octahedral and EN tetrahedral interstitial sites. If only one kind of interstitial atom is added, this in-

Jan 1, 1964

By L Tolmay, L Nair

Investor confidence can be compromised when one observes large discrepancies between the SAMREC reserves and the mining plan. It is therefore up to the responsible persons to ensure that all contributing factors get taken into account when determining a reserve declaration. Confounding factors could be further aggravated by large oscillations in the commodity price thus resulting in major changes to the mining plan, if the accepted price was either too optimistic or pessimistic. Additional factors that must receive our attention are, uncertainty in geological facies type, mining practices, geology and grade estimation. The paper outlines (in the authors? opinion) some of the important factors that need to be taken into account, in order to ensure proper alignment between the estimates of the life of mine (LOM) reserve grades, and the corresponding actualisation of the mining plan. These parameters provide an historical insight into what actually happens when attempts are made to implement the mining envisaged in the LOM plan. In turn these allow judicious application of discount factors that enable a realistic estimate of SAMREC reserve classification and declaration. Some of the factors that will be covered are: - 1) Flexibility of developed reserves and the ability to maintain this. 2) Mining control mechanisms and their overall efficacy. 3) The ability to extrapolate facies types and its effect on grade control. 4) The ability to control the mining mix and value variation. 5) Finding a happy medium between optimism and pragmatism.

Jan 1, 2007

By A. H. Winckers

"CAMIRO, The Canadian Mining Industry Research Organization, formerly known as MITEC, is a collaborative research organization of Canadian Mining Companies. It is comprised of Exploration, Metallurgical Processing and Mining Divisions.The Metallurgical Processing Division (MPD) has the mandate to contribute to the profitability, competitiveness, safety and growth of the Canadian mining industry by improving the efficiency and effectiveness of mineral processing and extractive metallurgy in an environmentally conscious manner through the development of innovative technology by managing cooperative industry focused research programs.Current membership includes about ten Canadian mining companies. Past research has largely focused on base metal mineral processing. The Division wants to expand its research base to include all areas of mineral processing and extractive metallurgy.Past performance and plans for the future will be highlighted in the presentation."

Jan 1, 1998

By Anatoly Sudnev, Vladimir Skorohodov, Igor Kudryavtsev, Boris Radionov, Dmitriy Panov

"In cobalt production technology at a stage of solutions purification manganous cake (slime) basically containing hydroxides of the specified metals is formed. The possibility of full cobalt recycling in the basic technology of metal production at slime processing with generation of pure manganous compounds is shown. After slime dissolution in sulfuric acid in the presence of reducers the solutions containing cobalt, manganese, nickel and other nonferrous metals are formed. Optimum conditions of selective precipitation major part of cobalt by sodium hydroxide from the obtained solution are defined, thus more than 95% of manganese are remained in the solution. The cobalt precipitate is directed to the basic technology and the solution is purified by sorption. The most effective sorbents are chosen, optimum modes of its use are found. Examples of manganese recovery from the purified solutions as MnO2, MnCO3, Mn(OH)2 with a ratio manganese : impurities more than 3000 are presented.In the processes of hard alloys manufacture and processing of cobalt-bearing primary raw materials various cobalt-manganous slimes are formed. After leaching by solutions of mineral acids the problem of cobalt and manganese separation becomes an actual. The common way of metals separation in a solution is the Shreyber’ alkaline method allowing rather selectively to precipitate of cobalt hydroxide by sodium hydroxide. However this way does not allow separating completely target metals because of transfer of some manganese in the hydrated precipitate, even at its rather low content.In the given work the results of researches to improvement of a traditional way by inclusion to hydrometallurgical technology of operation of sorption separation of the specified metals are presented. The main goal is definition of conditions to achievement of the complete removing cobalt at hydrolysis with the minimum sedimentation of manganese and the subsequent additional recovery of cobalt by ionites from the obtained solutions."

Jan 1, 2008

By D. D. Rabb

Originally, the term solution mining applied to a dissolution, washing, or "brining" of soluble salts such as halite (common table salt), potash or trona. After the mid-sixties, however, the definition has been expanded to include heap and dump leaching, in-place (in situ) leaching, removal of oil from tar sands, extraction of sulfur from deep wells by the Frasch process and the recovery of metalliferous solutions from geothermal sources. Solution mining is also known as borehole, non-shaft, or chemical mining; the extraction of soluble mineral values from a variety of ores using appropriate solvents and chemicals. Solution mining frequently involves chemical changes; for example, copper usually goes into solution as copper sulfate, gold and silver as a cyanide compound, and uranium as a sulfate or uranyl tricarbonate. The valuable constituent is removed from the solid body of the ore by mass transfer to a aqueous solution.

Jan 1, 1986

By N. Geoffroy, E. Benguerel, G. P. Demopoulos

In the late 1990s, a chemical process to remove mercury and selenium from weak sulphuric acid solutions was patented and implemented in the CEZinc refinery in Valleyfield, Quebec. The CEZinc process comprises two stages. In the first one, sodium sulphide is added to the weak acid solution in order to precipitate the soluble mercury. The solution is then treated with sodium dithionite in order to reduce the selenium to elemental form. Because of recent changes in the composition of the industrial solution, a project to study the background chemical reactions was started. In this paper, a review of the background chemistry is presented on the basis of several eh-pH diagrams on one hand, while on the other experimental results are reported dealing with the reaction of selenium (IV) species with either dithionite, sulphide or a combination of the two. According to this work, elemental selenium enjoys a wide pH-eh range stability with selenium sulphide being metastable. Selenium (IV) in single metal synthetic solutions was found to be reduced - to elemental state - at ambient temperature down to ppb range with dithionite as long as the stoichiometric ratio (dithionite/selenium) was in excess of two and the pH < 1.7. Under these conditions the reaction was very fast reaching completion within one minute. Sodium sulphide proved equally effective in reducing selenium (this time as selenium sulphide) to ppb range from single metal solutions. However, in mixed Se-Hg solutions deviations from this "ideal" behaviour was observed resulting in higher levels of residual soluble selenium left in solution.

Jan 1, 2008

By Meifeng Zhi

Separation of uranium and molybdenum in the alkaline leach solution of a U–Mo ore was studied. A process of acidification-solvent extraction-precipitation uranium and molybdenum was determined. The influences of solution acidity and phase ratio of acidic scrubbing on separation of uranium and molybdenum were examined. The molybdenum extraction equilibrium isotherm was drawn. The results show that the separation of molybdenum and uranium can be achieved by acidifying the alkaline leach solution, solvent extracting molybdenum using trialkylamine at equilibrium pH 2.5, and scrubbing the loaded organic phase using sulfuric acid solution. The strip solution can directly precipitate ammonium molybdate. Uranium can be directly precipitated from the raffinat

By P. Sanchez-Mejorada

GEOLOGISTS who are acquainted with the mines of northeastern Mexico realize that the most important lead-silver replacement deposits of the province are confined to a single formation. But since the formation is several hundred meters thick, the author has determined the relative position of the lead mantos in the belief that this information will prove useful in the search for new mines. This article describes the stratigraphic location of lead-silver replacement deposits known in several mines situated in a region comprising part of the states of Coahuila and Nuevo Leon. The area studied extends for 200 km* (125 miles) from east to west and 70 km (45 miles) north to south. Metallogenic Province: The most important metallic deposits of the region have the following common characteristics: 1) The orebodies occur as manto replacements of calcareous sediments. 2) The horizons that have contributed large tonnages of ore are in similar positions in the corresponding stratigraphic columns (as it will be shown later on). 3) Lead is the most important metal in the ores. Silver is commonly present in small amounts. Occurrence of zinc is dependent on the degree of oxidation of the primary sulfides. 4) A large proportion of the total production has been in the form of oxidized ores. 5) The deposits are located on anticlines. Rocks of Cretaceous age crop out over large areas of the states of Nuevo Leon and Coahuila. forming part of a belt that extends to the south along the eastern Sierra Madre. The sediments are cut by a small number of intrusive stocks ranging in characteristics from rhyolite to diorite. The most prominent structural feature of the region is a series of folds trending northwest-southeast. Faulting is not conspicuous in the region, although a major fault zone is found farther East.&apos; The physiography closely reflects structural features, with mountains formed by anticlines and valleys conforming with intermediate synclines. Narrow valleys have also been developed along the axes of many anticlines, where solution of limy sedi- ments and erosion have proceeded along axial tension fractures. Stratigraphy: Rocks of the Upper Cretaceous are exposed in only a small percentage of the total area. Generally they have been eroded away from the mountains and are covered by recent talus and alluvium in the valleys. Humphrey&apos; has published an excellent paper describing the Cretaceous formations of the Sierra de los Muertos, a short distance west of Monterrey. A brief summary of these formations is given below to convey an overall picture of the stratigraphic sequence that prevails just south of the area under consideration. Upper Cretaceous Indidura: Essentially thin shaly sediments. Cuesta del Cura: Limestone in thin wavy beds

Jan 1, 1959

By I. Ward, E. Milosavljevic, M. Botz

"The silver nitrate titration method is a rapid and acceptably accurate means of analyzing for cyanide in leach solutions that contain primarily free cyanide. However, in leach solutions containing elevated levels of copper, the titrimetric method overestimates the concentration of free cyanide and underestimates the concentration of weak and dissociable (WAD) cyanide. The authors have developed a modified potentiometric (MP) titration method for determining WAD cyanide that overcomes issues associated with high copper levels in solution. The new MP-WAD method involves addition of a chemical ligand to the sample prior to silver nitrate titration to release cyanide bound to copper. Once released from copper, cyanide in solution is no longer affected by the presence of copper, and titration results are quantitative rather than empirical. In multiple laboratory trials with synthetic solutions and complex actual leach solutions, analytical results obtained with the new MP-WAD method were found to be within about ±5% of analyses obtained with the USEPA OIA-1677 WAD cyanide analytical method.IntroductionThe silver nitrate titration method is widely used to estimate the concentration of cyanide in leach solution for purposes of cyanidation process control. Cyanide determined by silver nitrate titration is commonly referred to as “free” cyanide, but frequently should be referred to as “titratable” cyanide. By definition, free cyanide is the sum of the concentrations of aqueous hydrogen cyanide HCN(aq) and the cyanide anion CN- (ASTM, 2010). Titration will only yield a reasonably accurate measurement of free cyanide when metal-cyanide complex concentrations (e.g., cadmium, copper, mercury, nickel, silver and zinc) in solution are low. In other words, titration will only yield a reasonably accurate measurement of free cyanide if the solution primarily contains free cyanide."

Jan 1, 2015

By Blamey Stevens

The object of this paper is to present a theory of the formation of fissures, which seems to be supported by all available data. The investigation is, in the main, an exact one, and irregularities of the rock-structure are generalized. From the conclusions drawn a general classification of fissures is made, and this should be of practical use in the comparison of mineral deposits. The theory also throws some light on the equilibrium of the earth&apos;s crust and the depth of action of surface-waters. Incidentally, additions are made to the theory of earthquake-slips. Former Theory. It has been previously pointed out that the "jointing" of homogeneous rocks occurs in two sets of planes, at right angles to one another, and making angles of 450 with the directions of greatest and least principal stress.&apos; The theory by which this fact is explained does not, however, account for fissures and faults, because normal faults are usually more vertically, and reverse faults more horizontally, inclined than 450. The "jointing law" is based on the following axiom: In a homogeneous mass under pressure, rupture must take place on the lines of maximum tangential stress."2 This law applies, with fair approximation, to the tests on jointing which can be made in the laboratory, and as nearly as can be expected to the natural jointing-planes in rock-masses, where the stresses are not very great; but it entirely fails to account for fissure-fractures.3

Jan 1, 1910

By John G. Kovac

A computer simulation has been developed by the US. Bureau of Mines to estimate the chances of a miner making a successful escape while wearing a self-contained self-rescuer (SCSR). The model takes into account (1) training in the use of SCSR&apos;s, (2) apparatus integrity, and (3) oxygen cost of a mine escape. This report examines survival odds for a prototypical escape, and illustrates how these odds change when SCSR training is improved.

Jan 1, 2009

A comprehensive analysis of rock structures in non-oriented (axially oriented) drillcore is now available (Laing, in press). The system embodies new concepts which better equip the geologist and engineer to deal from the outset with optimising the acquisition of structural information in drillcore, logging: interpreting, and graphically presenting the results. The few existing techniques for determining orientations of structures are augmented by a wide range of new techniques, and all are brought together into two solution types by considering the underlying Euclidean geometries. Analysis of these solution types in terms of what data are required to implement each solution and what assumptions need to be made, leads to strategies which facilitate intelligent design of different drilling programs for blind and outcropping situations. Drillcore is variably structurally fertile, depending on the number of different structures present. This concept fosters the selective logging only of the more fertile core. Drillholes are also variably fertile, depending on their orientational relationship to the structures in the host rocks. Structural parameters are either vectorial or non-vectorial. Vectorial structures parameters comprise normal structural orientations plus polar vectors like vergence, younging, shear sense and so on. They can be determined by one of two solution types: external solutions, which use an external reference structure to fix the drillcore and thus permit orientation of all structures within that core, and internal solutions, which use orientational data from a selected structure at three or more different drillhole orientation to determine the unique orientation of that structure, without reference to any external structure. Both solution types rely on constant orientations (orientational stability) of the selected structure, but the internal solution actually provides its own test of orientational stability. External solutions are the norm in outcropping situations and internal solutions are invaluable in blind situations. In blind situations sequential "internal then external" solutions can be used respectively to provide a reference structure and then use this for subsequent external solutions at individual points downhole. Blind prospects can now be drilled and interpreted as easily as outcropping prospects. Each solution type has its own optimum requirements. External solutions are ambiguous for certain orientational relationships between the drillhole and the reference structure (for example, a perpendicular relationship), hence drillholes in which external solutions are planned should be designed to avoid these orientations. Internal solutions are ambiguous for straight drill paths, and are most unambiguously resolved when the drill path attains maximum drillhole dimensionality, that is, it occupies a wide variety of orientations in 3D space; hence drillholes in which internal solutions are planned should be designed as combinations of non-parallel holes or as individual strongly curved holes. For both solution types an understanding of the kind of structural fertility required leads to intelligent design of drill paths, which is termed structural drill targeting. It is distinct from spatial drill targeting, which is the process which defines and (x,y,z) point-or volume-target. Effective design of drilling programs requires both structural and spatial targeting. The external and internal solutions for vectorial parameters are implemented via (1) visual (qualitative), (2) stereographic, or (3) core orienting frame procedures. Each of these has its own advantages. Stereographic procedures have been simplified via the erection of a drillcore reference frame in which three fundamental angles are defined, and the formulation of an all-inclusive set of stereographic recipes for determining orientations from the measurement of these angles. Non- vectorial structural parameters comprise an ad hoc array of useful measures which are simply described by numbers. Examples are angles between structures, and density of structures. Such parameters (some of which provide useful vectors toward ore bodies) are invaluable in drillcore because they can be measured and recorded rapidly, without determining the orientation of the core. In a summary, non-oriented drillcore can now be structurally mapped exactly as if it were outcrop. Interpretation of the significant volume of unique structural information which is beginning to flow from this system can be optimised by using, in addition to the conventional cross section and longditudinal section, three new modes of presentation. The natural cross section is that section in space normal to a principal structure of interest. It is a section in which it is advisable to drill to obtain certain structural information, and in which the results need to be presented. A newly defined unique cross sectional orientational symbol is recommended for dramatic improvement in the quality of information presented in cross sections. Stacked level maps are a powerful adjunct to cross sections.

Jan 1, 1990

By A. Barba, M. P. Gómez, F. Puertas, M. Palacios, M. F. Gazulla, S. Martínez-Ramírez, I. García-Díaz

"The present study explores the reactivity and burnability of cement raw mixes containing fired red or white ceramic tile wastes or combinations of the two as alternative raw materials. The results showed that the new raw mixes containing these wastes are technically viable. The reactivity and burnability of the new raw mixes have been evaluated; confirming very good results when the particle size of wastes was less than 90 µm. The chemical and mineralogical compositions of the new clinkers were comparable to clinker manufactured with conventional raw materials. The mix of red and white ceramic tile waste was found to perform as well or better than each type of waste separately, a promising indication that separation of the two would be unnecessary for these purposes.IntroductionPortland cement clinker production consumes large amounts of energy (850 kcal/kg clinker) and has a considerable environmental impact. This involves massive quarrying for raw materials (limestone, clay etc), as it takes 1.7 tonnes to produce one tonne of clinker, as well as the emission of greenhouse and other gases (NOx, SO2, CO2) into the atmosphere. Around 850 kg of CO2 are emitted per tonne of clinker produced.The cement industry is looking for solutions to these problems, to attain sustainability and comply with the Kyoto Protocol commitments [1,2]. For that reason, experimental ways are being explored to develop cements whose manufacture is less energy-intensive, less damaging to the surrounding environment and with lower tendency to emit polluting gas. One of the reach this objective is the use of industrial waste and by-products as alternative materials for cement manufacture. Such alternative materials may partially replace fuel [3,4], conventional raw materials [5-8] or clinker in the final composition of the cement [9]."

Jan 1, 2008

By G. S. Knoke

This report presents the results of a demonstration of the technical, economic, and environmental feasibility of hydraulic borehole mining of shallow oil sands. Borehole mining offers a method for extracting the oil sands with minimal disturbance to environmental quality because (1) no overburden is removed, (2) no waste rock piles are required, (3) the tailings can be backfilled into the borehole cavity, (4) the ground water quality should be undisturbed, (5) a closed-loop water system can be employed so that no surface streams are polluted, and (6) surface subsidence can be minimized by backfilling the mined cavities. This project consisted of two concurrent tasks: mining operations and environmental monitoring. To generate the environmental impact, nearly 1000 tons of oil sands were mined from two boreholes. Water quality and ground subsidence were monitored. No significant changes occurred in the chemical composition of the process water, indicating that the borehole mining process does not dissolve the mined material. The average subsidence in the immediate vicinity of the boreholes was about 1/2 inch, although some points were noted to be slightly elevated. In general, the amount of subsidence increased with time and decreased with distance from the bore-hole. A mining cost analysis was used to project an estimated cost for production mining of about $38 per barrel of oil.

Jan 1, 1980