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In Australian collieries, solutions to the outburst problem must be implemented in a highly competitive environment which has a low tolerance on negative productivity effects. Solutions are only applicable if the overall viability of the operation remains sound. Minimum time must be spent on alleviation and control measures. This is favoured by simple geology, advanced warning and efficient alleviation and control procedures. Research requirements in support of this include 1. an improved means of predicting the nature and location of outburst zones ahead of the face and, 2. an improved means of measuring the effectiveness of gas drainage. For additional safety at the face, a means of continuously monitoring outburst proneness is required. In general, greater emphasis is required on improved instrumentation.

Jan 1, 1987

By E. A. Devuyst, G. Robbins

A unique process for removing cyanide and base metal complexes from industrial waste streams was patented by G.J. Borberly et al. (1984). The process uses SO2 (liquid or gas, or solutions of sulfite salts, or from burning elemental sulfur), plus air that is dispersed in the effluent using a well agitated vessel. Acid produced in the oxidation reactions is neutralized with lime at a controlled pH generally in the range 7 to 10. The reaction requires the presence of soluble copper as a catalyst which can be supplemented by copper sulfate if necessary. The process can be applied to the detoxification of gold and silver mining waste streams, such as carbon-in-pulp (CIP) tailing pulps, barren solution bleeds, pond waters and heap leach rinse solutions and also to plating shops wastewaters. The SO.jAir process has substantial advantages over two of the main alternative methods of cyanide destruction, namely alkaline chlorination and hydrogen peroxide. Alkaline chlorination is highly penalized in terms of reagent consumption. Chlorine is a strong oxidant reacting with species other than cyanide present in the effluent such as thiocyanate and sulfides. Furthermore alkaline chlorination is an incomplete detoxification process. Iron cyanide is not removed and the potential for harmful by-products species exist. Consequently final effluents may be subject to additional treatment in order to comply with regulatory demands.

Jan 1, 1991

By E. A. Devuyst

A unique process for removing cyanide and base metal complexes from industrial waste streams was patented by Borberly et al. (1984). The process uses S0, (liquid or gas, or solutions of sulfite salts, or from burning elemental sulfur), plus air that is dispersed in the effluent using a well agitated vessel. Acid produced in the oxidation reactions is neutralized with lime at a controlled pH generally in the range 7 to 10. The reaction requires the presence of soluble copper as a catalyst that can be supplemented by copper sulfate if necessary. The process can be applied to the detoxification of gold and silver mining waste streams, such as carbon-in-pulp (CIP) tailing pulps, barren solution bleeds, pond waters and heap leach rinse solutions and also to plating shops waste waters. The S02/Air process has substantial advantages over two of the main alternative methods of cyanide destruction, namely alkaline chlorination and hydrogen peroxide. Alkaline chlorination is highly penalized in terms of reagent consumption. Chlorine is a strong oxidant reacting with species other than cyanide present in the effluent such as thiocyanate and sulfides. Furthermore, alkaline chlorination is an incomplete detoxification process. Iron cyanide is not removed and the potential for harmful byproducts species exist. Consequently, final effluents may be subject to additional treatment in order to comply with regulatory demands.

Jan 1, 1991

By P. Bhakta

The U.S. Bureau of Mines developed an alkaline oxidative pretreatment leaching procedure to increase the recovery of gold from arsenopyrite (FeAsS) ores. The best solution compositions for arsenopyrite dissolution were determined using cyclic voltammetry and chronocoulometry. Initial arsenopyrite dissolution occurred at -0.20 V versus standard hydrogen electrode (SHE) in a sodium hydroxide (Na0H) solution. Leaching of a high-grade arsenopyritic ore containing, in percent, 28.2 As, 25.3 Fe, 19.9 total S, and 1.0 Sb and, in troy ounces per short ton, 1.6 Au and 5.5 Ag resulted in >90 pct As extraction at 1000 C, 40 psig O2,4 h, and 2M NaOH solution in a 2-L autoclave. Cyanidation of the leach residues resulted in 90 to 93 pct Au and 60 to 80 pct Ag extractions, compared with only 5 and 15 pct, respectively, without the pretreatment. The procedure was further tested by leaching a low-grade gold ore and a bulk sulfide flotation concentrate prepared from it. Cyanidation of the leach residues resulted in 70 pct Au and 31 pct Ag extraction. The NaOH leachate was partially regenerated by precipitating the arsenate as calcium arsenate [Ca3As04)2] and the sulfate as barium sulfate (BaS04).

Jan 1, 1989

By Don W. Dotson

In 1962, Kondner prepared several papers dealing with hyperbolic stress-strain response of cohesive soils. The following year, Brinch Hansen proposed 80% and 90% failure criteria for stress-strain behavior of cohesive soils. Fellenius was instrumental in popularizing these failure criteria for pile load tests and offered a direct solution equation for the failure load according to the 80% failure criterion. Since the 90% Criterion has been incorporated into the International Building Code, equations for the direct solution of the failure load at the 90% Criterion would be useful to practicing engineers. This Technical Note supplies the derivation methodology for the 80% Criterion and provides expressions to determine the load and deflection at failure for the 90% Criterion.

Aug 1, 2013

By George W. Lower, William A. Hockings, Donald A. Kaczynski

The rate of dissolution of polycrystalline metallic copper in aqueous cupric ammonium nitrate solutions in the non-film-forming region was investigated by the rotating disc method. The investigation was performed in solution concentration ranges applicable to hydrometallurgical processes. This investigation was an extension of a study on the cupric ammonium carbonate system previously reported by Smith, Lower and Hockings, in which the following kinetic model was proposed: (1) Diffusion of cupric ammine ions to the copper surface; (2) Forward reaction - first order reaction of cupric ammine ions with metallic copper; (3) Reverse reaction - disproportionation of cuprous ammine ions to metallic copper and cupric ammine ions ; and (4) Diffusion of cuprous ammine ions from the copper surface. The nitrate system was selected for this study because it simplified the determination of the ionic composition of the solutions. The variables studied were stirring speed and cupric, ammonia, and nitrate concentrations. The dissolution rate increased linearly with at low values of but exhibited increasingly negative deviations from linearity at higher values of m. The rate also increased with increasing cupric concentration but decreased with increasing ammonia and nitrate concentration. Good agreement was obtained between the experimental rate data and the proposed model. Further verification of the model was indicated by the close agreement of the diffusion coefficient calculated from the data and comparable literature values.

Jan 1, 1974

By A. S. Peck

This report presents the results of a cooperative study between the Bureau of Mines and the University of Utah to define the mechanism involved in the adsorption of oleic acid and sodium oleate on fluorite, calcite, and barite, using an infrared spectrophotometer for identifying and measuring the adsorbed reagents and reaction products. Fluorite, calcite, and barite react with oleic acid and sodium oleate in a water system, forming chemisorbed and solution products. The chemisorbed species is a surface mineral cation-collector anion salt, Chemical analysis of solution resulting from the adsorption reaction indicates that the adsorption process causes displacement of mineral anions, namely, fluoride, carbon ate, and sulfate from the surface of these minerals.

Jan 1, 1963

By M. Nejati, A. Paluszny, R. W. Zimmerman

A numerical method is proposed to propagate multiple discrete fractures leading to primary fragmentation in a mine that is being worked using block caving. Deformation is computed using the finite element method, fractures are represented explicitly, and the mine domain is discretized by an unstructured mesh. Bedding planes are represented by systematically varying the elastic modulus of the rock and by defining horizontal weakness planes. Fractures and matrix are represented using parametric surfaces, and tips are defined by their boundary curves. Tip advance is controlled by a failure criterion, and a criterion for propagation direction and magnitude, based on the evaluation of the modal stress intensity factors. A novel domain integral approach is applied to accurately compute stress intensity factors (K) ahead of fracture tips in three dimensions. The method does not require a structured volumetric mesh structure around the crack tip, as integration is performed over a series of virtual surface domains along the crack front. The method is efficient, as it makes direct use of automatically generated, arbitrary tetrahedral meshes, and approximates stress intensity factors (KI, KII, KIII) along each crack front using Interaction-integrals. As opposed to the JIntegral, the method does not decompose K a-posteriori, but instead uses an auxiliary field to directly compute modal K. When using this method, numerical approximations of K do not exhibit dependence on the mesh layout, and require meshes that can generally be ten times coarser than are required by displacement- and stress-based methods. Volumetric meshing requires only, on average, 17% of each computation step. Thus, cracks do not follow any pre-existing mesh structure, and the method is well suited for high-density fracture datasets. The method is demonstrated for primary fragmentation of a mine area covering 110 initial draw points, immediately beneath a 2m high undercut. Displacement is constrained at all boundaries except the surface of the undercut. The growth of the fractures is investigated at the onset of the undercut. Ninety initial disc-shaped fractures are taken into account, each having an initial radius of 10 m. Fractures grow around the undercut, intersect the bedding plane boundaries, and the domain is fragmented as a result.

Jan 1, 2015

By Avishan Atrafi

Frothing behavior of surfactants originate from their preferential adsorption at the gas-solution interface. Different surfactants may demonstrate different adsorption behaviors depending on their molecular structure and surface activity. The quantity and rate of adsorption of surfactants at the gas- solution interface in flotation systems will certainly affect kinetics of reaction and fractionation of surfactant between bulk and foam phase and subsequently their frothing characteristics. In this paper, the frothing characteristics of sodium oleate which is the main constituent of fatty acids used in flotation systems is explained. The adsorption behavior of sodium oleate is then compared to a typical non-ionic frother (Methyl Isobutyl Carbinol, MIBC) in terms of different adsorption behavior at the gas-solution interface. Since long chain fatty acids are weak electrolytes, their behavior is a strong function of pH. Also semi soluble salts including apatite contain considerable amounts of ions like calcium in their lattice, so the effect of presence of ions on the frothing behavior of fatty acids requires an investigation. A mass balance on the surfactant transferred to the foam was solved to estimate the bubble surface area flux in foam, which explained how the adsorbed surfactant at gas-solution interface controls the bubble surface area flux at foam. Since sodium oleate adsorption at foam takes place gradually, frother concentration as a function of time was monitored by the total organic carbon measurement (TOC) to compare the surfactant uptake rate at different concentrations, pH and ionic strength. The surfactant concentration adsorbed within foam together with the value of adsorption density from the Gibbs adsorption, leads to the calculation of the surface area flux and prediction of average bubble size in the foam at a specific time frame. This value was compared at different concentrations of sodium oleate. Dynamic surface tension measurements were accompanied to explain the adsorption behavior, though finally equilibrium surface tension turns out to better explain the foamability characteristics. Keywords: flotation collectors, flotation froths, foams, fatty acids, adsorption behavior

Sep 1, 2012

By Richard Campbell

Effective strata control, utilising fully encapsulated resin grouted roof bolts is dependent on the installed quality of the reinforcement elements. Resin based grouts are the main form of rock bolt anchorage in the underground coal industry in Australia and New Zealand. To be effective the system requires the mixing of the catalyst and mastic components of the resin as well as shredding of the cartridge that contains the resin. Over the past six years Solid Energy New Zealand Ltd (SENZ) has pioneered an extensive work programme quantifying the effects and extent of poor installation quality due to gloving, poor mixing and loss of encapsulation (Pastars 2003, Campbell et al 2003, Mould et al 2004, Campbell et al 2005 and Pastars & MacGregor, 2005). The One-Step Bolt (OSB), an innovative bolting solution designed and manufactured by Hilti Pty Ltd offers a self drilling, single pass bolting method that eliminates gloving, guarantees mixing quality and encapsulation performance of the installed product while not jeopardising the mechanical performance of the bolt. This paper details recent work undertaken by SENZ designed to understand and quantify the system performance of the Hilti OSB in New Zealand?s thick coal seam mining environments.

Jan 1, 2006

By P M. Outhwaite

Everyone present today is especially aware of the need for minerals in this society of ours. The words 'especially aware' were deliberately chosen because this is a meeting of the NZ Branch of The Australasian Institute of Mining and Metallurgy not a dilettante group such as some of our critics. Members of the Australasian Institute of Mining and Metallurgy knew that our great farming industry, our shelter, our transport and our energy supply, are largely dependent on a flow of minerals into this country despite the presence of large coal and natural gas reserves. Flow in was said because New Zealand imports most of its mineral requirements with all the consequential strategic and economic disadvantages. If the above statements are accepted by this gathering it would be a premise fairly stated that New Zealand has a great need to discover and develop minerals.

Jan 1, 1976

In this paper, the logic and the capabilities of a long term production planning method for open pit mining are presented. The method is the first attempt in obtaining simultaneous solutions to the four interrelated parameters of open pit mining; 1) the mine life, 2) the specific blocks to be mined each year, 3) the amount of ore and waste to be mined each year, and 4) the ultimate pit limits. An efficient cutoff grade can also be obtained through a sensitivity analysis. None of the existing methods can bring such a comprehensive solution to the problem. A production plan for a real life gold deposit is given to illustrate the logic and the capabilities of the method.

Jan 1, 1993

By K. E. Gonsalves, G. M. Chow

"Nanostructured powders (particle diameter of 1 - 100 nm) have uses in electronic, magnetic, structural, thermal applications as well as advanced processing of materials. Among many methods of making nanostructured powders, chemical routes offer many attractive features such as feasibility of cost-effective bulk quantity production, design of chemistry at the molecular scale, and chemical homogeneity of the powders. In this talk, two systems of chemically synthesized nanocomposite powders are presented, namely, granular magnetic materials of Fe-Cu and Co-Cu, and thermal-structural materials of AIN-BN. Synthesis and processing, characterization and properties of these materials are discussed.IntroductionNanostructured powders (particle diameter of 1 - 100 nm) are attractive materials because of many useful properties (e.g. catalytic, optical, magnetic etc.) and processing advantages (e.g. lower sintering temperature) [1]. There are many methods of making nanostructured powders, for example, physical and chemical vapor deposition, mechanical attrition, and solution chemistry [1, 2]. A common method of making composite powders involves the grinding, mixing and blending of constituents powders, but it has the limitation of inhomogeneous mixing. Chemical routes have many useful features. Using solution chemistry, precursors can be molecularly tailored and homogeneously mixed at the molecular level. The chemical approach may result in better properties of the final product. Compared to vapor-phase fabrication techniques, chemical routes are more cost-effective in producing large quantity of material. In addition, control of particle size, size distribution and stabilization of the nanoscale particles against agglomeration can be more effectively manipulated via solution chemistry.In this paper, we present an overview of some of our work in nanocomposite powders prepared by solution chemistry. Metallic systems of FeCu and Co-Cu, and ceramic system of AIN-BN are discussed. The powders were characterized using x-ray diffraction (XRD) , scanning electron microscopy (SEM), conventional and high resolution transmission electron microscopy (TEM, HRTEM), vibrating sample magnetometry (VSM), inductively coupled plasmaatomic emission spectroscopy (ICP-AES)."

Jan 1, 1994

By Filippo Verlezza

Conventional wire rod blocks have some limitations. They can only roll with fixed reduction ratios which always require the same rolling diameters within the block. With MEERdrive® SMS, as a pioneer, has introduced an innovative drive concept for wire rod blocks that can overcome the limitations of conventional solutions. The clue: the concept is based on individual drives for each stand position. The exigent wire rod market demand and the available technology melt in a new variant of MEERdrive®, the MEERdrive®PLUS, which represents a sizing block solution for finished size rolling and allows conventional as well as thermomechanical rolling. Further “one family rolling” is also possible, since all roll / size changes will occur in this block.

Oct 30, 2017

By J. L. Rodda

A large amount of time has been devoted to the microscopical study of the copper-zinc alloys, emphasis naturally being placed upon the commercially important alloys of the system. Suitable methods are available for microscopically recognizing the two phases richest in copper, but none appear to have been developed for the positive identification of the other phases. This is, however, accomplished, for the phases normally encountered, by an electrolytic method described in the following pages. Five phases of the copper-zinc diagram (Fig. I) are considered for the purpose of this paper: the solid solution of zinc in copper, alpha (a); the intermediate phases, beta (ß), gamma (?), and epsilon (e); and the solid solution of copper in zinc, eta (11). Beta prime is not considered a separate

Jan 1, 1937

By N. V. Hansell

l. INTRODUCTION. THE last few years have shown an increasing interest in the subject of beneficiating iron-ores -in all iron-producing countries. In the United States, this movement has been slower than in certain parts of Europe, for the obvious reason that the abundance and relative cheapness of the Lake Superior iron ores has hindered the development of enterprises for the preparation of low-grade ores. Gradually, however, conditions have changed. The world's consumption of iron is increasing enormously. Being in 1900 about 40,000,000 tons, in 1910 ii was already 60,000000; and there is no reason to doubt that for the near future the increase in iron-consumption will continue at the same rapid rate, especially with, the development of China, certain parts of Africa, and other regions which have hardly been touched as yet by modern industrialism. It is. therefore, not surprising that apprehension is felt that the known available iron-ore resources of the world are gradually being depleted. Signs of this feeling are the recent investigation, under the direction of the U. S. Geological Survey, of the iron-ore resources of the United States, and the estimate presented to the last International Geological Congress, at Stockholm, Sweden, of the iron-ore resources of the world. These investigations have emphasized the fact that the known high-grade ore-deposits are limited in extent, and will, at a not distant future, be exhausted, compelling the iron industry to depend for raw material on the enormous deposits of low-grade ores which are distributed over almost all the world. The discovery of new deposits of high-grade ore, in countries not yet thoroughly explored, will not materially change this prospect. Of course, the part which such new deposits will play in the future cannot be forecast. The difficulty and cost of transportation will probably exclude many of them from use at the present centers of the iron industry.

May 1, 1912

By Matias Suarez, Diego Zenteno

It is known that the introduction of electronic timing in the sequencing of blasting has changed the vision and way in which mining is developed. It is possible to deal with more complex and sophisticated drilling designs, without compromising productivity or safety. It has been shown in various studies, that a correct timing of the blasting provides an improvement in the improvement of the processes downstream, due to a decrease in the resistance of the resulting fragments coming from the interaction of the waves generated in the detonation of explosive loads. On the other hand, it has also been shown that variations in the composition of a same type of explosive, has a significant influence over the resistance of the blasted material, also the energy associated to break it, affecting directly its degree of fragmentation. This paper is aimed to display the new advancements of blasting engineering done in different mining sites throughout the country, associated to electronic sequencing, energy of the explosive and its impact on the fragmented rock. This document explains how to define and implement selective sequencing in the blasting in order to promote the propagation of cracks, therefore impacting positively the productivity through the use of the LaGrange diagram. The LaGrange diagram is a very convenient and illustrative method to present the dynamic behavior associated with wave and crack propagation (Rossmanith. H, 2002). This study focused on the methodology of the formation and measurement of seismic pulses, through the rock massif. For this purpose, seismic pulses were acquired in the field and then, the different dynamic phases of the wave were molded mathematically, with the purpose of favoring the coupling between them.

By T Seifert, P Krolop, K Niiranen, S Gilbricht

The Per Geijer iron oxide apatite deposits (IOA) display significant potential mineral resources for Luossavaara-Kiirunavaara AB (publ), known as LKAB. LKAB continuously mines magnetite/hematite ores in northern Sweden for almost 130 years. The Per Geijer deposits reveal a high phosphorus content and vary from magnetite-dominated to hematite-dominated ores, respectively. Furthermore, they show a large variation in texture, mineral composition, and relation to wall rocks. The high phosphorus concentration of these ores results from highly elevated content of apatite as gangue mineral. Reliable, robust, and qualitative characterisation of the mineralisation is required as these ores inherit complex mineralogical and textural features. For this purpose, comminution tests at laboratory scale in combination with scanning electron microscopy-mineral liberation analysis (SEMMLA) were carried out. Based on this work, significant information on the modal mineralogy and degree of liberation of minerals of economic interest (eg magnetite, hematite, and apatite) were obtained. Results show that there is a difference in the degree of liberation of magnetite and hematite between ore types. This seems to be dependent both on the size fractions and the dominance of each iron oxide in the individual ore type. The amount of gangue minerals seems to have no significant impact on the degree of liberation after comminution. Apatite is generally best liberated in ore types associated with silicates, regardless of magnetite or hematite dominance. Based on the results of this study it can be inferred that a high degree of liberation of the minerals of economic interest can be achieved. However, results need to be verified with further beneficiation steps such magnetic separation, apatite flotation and possibly reverse silicate flotation.

Nov 8, 2021

By Murray Pearson, Jack Murray

"The danger of autoclaves lies in the high temperatures and pressures that exist in autoclave vessels. The usage of autoclaves will continue to expand in the mining industry because of their efficiency and environmental friendliness. But increasing attention must be paid to ensuring their safety. Safety Instrumented Systems (SISs) play a critical role in autoclave plants by detecting potentially dangerous conditions, taking the plant to a safe state, informing the operator about the plant status and the cause of the trip and expediting safe plant restart. The SIS should ideally be fully integrated with but functionally independent of the Basic Process Control System (BPCS) and provide redundant logic solvers to increase safety and plant availability while reducing spurious trips.INTRODUCTIONWikipedia defines an autoclave as follows: “An autoclave is a pressurized device invented by Charles Chamberland in 1879 designed to heat aqueous solutions above their boiling point to process materials.” A typical autoclave system used in the metallurgical industry includes, besides the autoclave vessel, heat recovery (heater) vessels, high pressure positive displacement (HPPD) feed pumps, vessel lining systems, specialized internals and components, agitators, pressure letdown or flash vessels, isolation and control valves, over 2,000 I/O points and related instrumentation, and emergency relief systems."

Jan 1, 2009

By Matias Suarez, Diego Zenteno

This paper is aimed to display the new advancements of blasting engineering done in different mining sites throughout the country, associated to electronic sequencing, energy of the explosive and its impact on the fragmented rock. This document explains how to define and implement selective sequencing in the blasting in order to promote the propagation of cracks, therefore impacting positively the productivity through the use of the LaGrange diagram. The LaGrange diagram is a very convenient and illustrative method to present the dynamic behavior associated with wave and crack propagation (Rossmanith. H, 2002).

Feb 1, 2020