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At the Orieco mine quartz veins carrying sulphides were localized in parts of an extensive fault zone in the Mathinna Beds during late Middle Palaeozoic mineralization.These deposits were subsequently exposed, and oxidation of the sulphides by percolating groundwaters resulted in the formation of gossans at the surface, and replacement close to the permanent water table of the more soluble sulphides by copper sulphides (chalcocite, coveIlite). A restricted zone containing copper oxides (cuprite, tenorite), copper carbonates (malachite, azurite), iron arsenates (scorodite, pharmacosiderite) and possibly rare copper sulphates occurred above the water table.The renewed oxidation of these deposits following mine development has been facilitated by the ready circulation of air and water combined with the formation of large free surfaces ideal for evaporation of aqueous solutions. Under these new conditions of high initial sulphate concentration, low pH, and relatively high Eh, the previously formed mineral assemblage is unstable and numerous Cu (Fe,Zn)-sulphates and Fe (Cu,Pb)-arsenates are presently forming in fractures in the fault zone and on the adit and stope surfaces for some considerable distance from the Sulphide-rich ore shoots. The observed spatial sequence of the major sulphates with respect to the sulphide-rich zones (Le. chalcanthite-antleritebrochantite and langite) is consistent with decreasing sulphate concentration and increasing pH away from the oxidizing sulphides.

Jan 1, 1970

The ready solubility of gold in dilute aqueous solutions of the cyanides of the alkalies or alkaline earths provides a convenient method for the separation of the precious metal -from the large surplus of associated materia1. The finely ground ore is pulped with a weak solution of cyanide, agitated to dissolve the gold, filtered and washed. The lowgrade filtrate is then clarified and the gold precipitated by some electronegative agent, the most usual being finely divided zinc or zinc dust. The slight precipitate is collectedon some form of filter coated with a filter aid, the filter cake being then known as "gold slime".A typical analysis of this slime is given in Table 1.

Jan 1, 1956

By K. Kasas, J Kermeci, S. Vujic, S. Secei, P. Kermeci

On the ‘Majdan III’ open pit mine, supplying with brick clays the production plants of the industry of building material ‘Potisje-Kanjiza’ from Kanjiza, a modern ECS (excavator-conveyor-spreader) complex was built, integrating four bucket excavators, six conveyors and one spreader into a whole. This complex connects the mineral-exploitation unit with the final brick-products plant of the company. Monitoring and management of the ECS complex is carried out by modern computer-supported information-management system (IMS) implementing most modern measuring-regulation, computer and GPS equipment. It was concluded that, for safety reasons, the functions of the IMS should be developed by a component of active visual monitoring of the ECS complex. For this purpose, the task of making a project on intelligent system for visual monitoring of the ECS complex was entrusted to the Department of Computer Application at the Faculty of Mining and Geology, University of Belgrade. This paper gives a review of basic project solutions. Keywords: Automation, process management, information management technology, visual system, intelligent systems, TV monitoring, surface exploitation, clay, Majdan III, Potisje-Kanjiza.

Jan 1, 2003

By Bill Loviza, Jimmy Sanders

This report is not everything we would like it to be. Access to information concerning unresolved legal actions is a sensitive matter. Obtaining the information presented in this report was a challenge alone. The Tennessee Department of Commerce and Insurance, Division of Fire Prevention, the firms and individuals that elected to share information did so with various assurances of nondisclosure, confidentiality or anonymity. All those providing information did so with the expectation that the industry and ultimately the public would benefit from this effort. We offer special thanks to Assistant Commissioner, Fire Prevention, Emmett Turner, recently retired Director, Bomb and Arson, Dick Gardner and Director, Codes Enforcement, Randy Safer for support that made this endeavor possible. We make no claim with regard to being a scientific study. We did the best we could with available information. Our task was one of assembly, sorting and reporting. Where collateral information was available we used it.

Jan 1, 2004

By Patricio Berrios, David Barriga, Peter Amelunxen, Gerson Sandoval, Roger Amelunxen

Laboratory test equipment and methods have undergone relatively little change since their introduction in the 1950’s. The Denver sub-A cell is still by far the most commonly used laboratory batch cell, but bottom-driven and instrumented cells are beginning to appear. Test procedures have also changed little over the past 60 years, and most engineers continue to rely on empirical models for predicted plant scale performance from laboratory scale tests. This approach is problematic, because changes in the froth phase characteristics in the lab hamper the reliability and reproducibility of the empirical extrapolation to plant scale. In a previous work, the authors reported on the impact of froth recovery at the laboratory cell, showing that variability in the froth recovery can lead to significant error in the modeled kinetic rate constant unless it is properly accounted for in the scale-up model. In this work, we review the role of hydraulic entrainment in the lab cell, and how variability in particle specific gravity, shape factor, and froth residence time can impact the entrainment recovery.

Jan 1, 2014

By I. Fedotov

One of the most effective methods of metal surface heat treatment is through laser hardening. In most cases, laser parameters are determined experimentally, which is expensive and time-consuming. A mathematical model for the surface heat treatment process will allow a significant decrease in costs, and reduce the time required for optimization. In the present work, the authors present a mathematical model for laser heat treatment with forced cooling which can be applied to medium carbon steel. The model is based on a three-dimensional heat transfer equation using Green?s function. The model allows one to calculate the temperature of the treated steel at different depths below the surface with and without cooling, for set values of the laser power and travelling speed, when the heat transfer coefficient is a known constant. It also takes variations in the radiation adsorption coefficient on the metal surface and laser beam spot size into account. The model was illustrated by comparing calculated and experimental temperature profiles of mild carbon steel with 0.5% C with and without cooling. A reasonably good agreement was achieved between experimental and predicted values to ensure that a high enough austenizing temperature with short enough cooling time was reached for direct martensite formation. It also predicted the depth of treatment accurately. The incorporation of cooling in the model substantially improves previous models based on heat transfer only. It delivers a tool that can with a reasonable accuracy predict the depth of surface heat treatment and cooling time required from operational parameters, such as laser power, speed of motion, and distance between laser and cooling source, that can be controlled in the work set-up. This can eliminate trial and error efforts and result insignificant time and cost savings. Keywords Laser, surface treatment, martensite transformation, carbon steel, heat treatment.

Jan 1, 2011

By M. Wittke

"In the course of the extension of the railway network in Israel, currently the two 4.6 km long tubes of the Gilon Tunnels on the line from Akko to Carmiel are being constructed. The tunnels run through the limestones of the Bina- and Yirka-formations, which locally are karstified. The maximum overburden amounts to 160 m.The limestones are mostly horizontally bedded and vertically jointed. Occasionally also inclined joints exist. The tunnels cross various fault zones, which mostly strike at an acute angle to the tunnel axis and are steeply inclined. The karstic cavities which were encountered during tunneling have partially been filled by clay. In the vicinity of the fault zones, the rock has often been strongly jointed and weathered respectively. The two single-track tubes have a cross section with vertical walls and an open invert. The tubes are connected by cross cuts with a spacing of approx. 250 m.During the tender phase, WBI has elaborated the tender design for a joint venture of a Chinese and an Israeli construction company. After the joint venture had been awarded the contract, the preliminary and the detailed design have been elaborated by WBI and the construction works have been guided. On the basis of the geological description, rock mechanical models have been elaborated, followed by stability analyses on the basis of the Finite Element method. The tunnels have been excavated according to the shotcrete method. The support in most areas only consisted of a very thin shotcrete lining and radial bolts in the area of the roof. Depending on the degree of jointing and weathering, locally advancing support by means of spiles has been applied.The internal lining of reinforced concrete has been constructed in parallel to the heading of the tubes. Mucking and delivery of materials was carried out through the cross cuts.The breakthrough was achieved in April 2014 and thus within schedule. The predicted distribution of the excavation and support classes along the tunnel has been in good agreement with reality."

Jan 1, 2015

By Tobias Hens, Andrew Frierdich, Joël Brugger

The rapid advancement of green technologies in recent years is closely tied to an ever- increasing demand for raw materials. Innovative forms of zero-emission transportation and sustainable power generation will require a variety of traditional metals such as Ni and Co, but also many non-traditional metals (e.g., REY). Many of these elements are known to be highly enriched in deep-sea ferromanganese (Fe-Mn) nodules and crusts. However, unlocking these metals from their deposits through metal processing is – aside from deposit exploration and production – expected to be a critical component that will affect the overall economics of the marine mining value chain. Hence, research and development of tailored metal processing solutions which can target specific metals of interest in Fe-Mn nodules and crusts, is required. Dynamic mineral recrystallization (DMR) of Fe-Mn oxide phases is a geochemical process that may have notable potential for hydrometallurgical applications. We have recently demonstrated that Ni can effectively be cycled between deep-sea Fe-Mn nodules and crusts and solutions through dynamic mineral recrystallization. DMR occurs in nature as abiotic background process during biogeochemical Mn cycling when dissolved Mn(II) is in direct contact with Mn oxides. Trace metals which are incorporated in the Mn host phases, are cycled between solid phase and solution via coupled dissolution (trace metal release) – reprecipitation (trace metal incorporation) mechanisms.

Jan 1, 2018

By C. P. Kelley, T. J. McKeon

Several recent developments in fine screening technology have been implemented at the DuPont Starke, Florida plant allowing enhanced zircon recoveries while minimizing operator requirements and total operational costs. The total design concept came about through the efforts of engineers at Derrick Corporation (Buffalo, New York), DuPont Titanium Technologies (Starke, Florida) and Roche Mining (Carrara, Australia). The use of the Kelsey Jigs for zircon recoveries from the tailings stream requires two wet sizing functions in order to operate properly. The first wet sizing is required on the initial mineral slurry feed to the Kelsey Jig. This sizing is intended to protect the Kelsey Jigs internal screen basket from plugging with nearsize particles, thereby keeping production rates maximized. The second sizing function is intended to recover properly sized garnet ragging material, which inadvertently ends up in the tailings stream leaving the Kelsey Jig. The unique machine design developed by the three partners in this project incorporated both wet sizing functions (protection and garnet recovery) into a single patented high capacity wet screening machine fitted with patented screen surface technology. This screen surface technology allowed for high capacity slurry handling capabilities at separations as fine as 230 microns while experiencing no nearsize blinding and extremely long screen panel life. The high open area urethane screen surfaces utilized in the application typically last 20 to 30 times longer than stainless steel wire surfaces. The stacked machine design minimized total equipment requirements and screen footprint requirements, and reduced power consumption and overall installation costs.

Jan 1, 2005

By C. C. Russelll, V. T. McLemore

The Metals Mining Sector of the Acid Drainage Technology Initiative (ADTI-MMS) addresses technical drainage-quality issues related to metal mining and related metallurgical operations, for future and active mines, as well as, for historical mines and mining districts. One of the first projects of ADTI-MMS is to develop a handbook describing the best sampling, monitoring, predicting, mitigating, and modeling of drainage from metal mines, pit lakes and related metallurgical facilities based upon current scientific and engineering practices. One of the important aspects of planning a new mine in today’s regulatory environment is the philosophy of designing a new or existing mine or expansion of operations for ultimate closure. The holistic philosophy taken in the ADTI-MMS handbook maintains that sampling and monitoring programs should be designed to take into account all aspects of the mine-life cycle. Data required for the closure of the operation are obtained throughout the mine-life cycle, from exploration through post-closure.

Jan 1, 2004

By S. Ranganathan

Production of ferro-chromium in the submerged-arc furnace is highly energy-intensive. Several process rates have been attempted to reduce the specific energy consumption in the production of this alloy. An exhaustive understanding of the thermo-chemical features of the production process can be used to reduce the specific power consumption significantly. The knowledge can be used to reduce the energy drain through undesired reactions in the process can be minimised. Plant trials have shown that specific energy consumption up to 100kWh/tonne of hot metal can be obtained by adopting this strategy. The process requires modification in operation practice and does not require any capital investment unlike other processes adopted for reducing power consumption. The principle of thermo-chemistry involved in this process development and results of plant trials are discussed in detail.

Jan 1, 2007

Results are presented on the elution of gold cyanide and base-metal cyanide complexes from strongand weakbase resins. It is shown that thiocyanate anions, zinc cyanide anions, and thiourea in acid solution are effective eluants of strong-base resins, but that it is generally necessary for electrowinning to be incorporated in the elution cycle if fast rates of elution are to be achieved. Weakbase resins are eluted with sodium hydroxide solution, which is shown to be far simpler and far more effective than the elution of strong-base resins. The effects of parameters such as concentration of the eluant, temperature, and electrowinning efficiency on the rate of elution of the resins are examined.

Jan 1, 1984

By H. Fukushima, T. Ohgai, N. Baba

The electrodeposition behavior of Zn and the morphology of the deposited Zn were studied in electrowinning solutions containing polymer additives such as gelatin and polyethylene glycol (PEG). The cathode potential was shifted in a less noble direction and the polarization resistance for Zn deposition increased with increasing concentrations and molecular weights of both gelatin and PEG added to the electrolytic solutions. However, when the molecular weights of these additives exceeded about lxlO4, the cathode was depolarized and the polarization resistance for Zn deposition decreased with increasing molecular weight. The crystal grain size and the (002) orientation of the deposited Zn became smaller when the concentration and molecular weight of the additives increased, and the cathode was polarized.

Jan 1, 2000

By J. A. Eisele

The Bureau of Hines conducted a bench-scale investigation of a concentrated H2S04 reaction for recovering and separating rare-earth elements, barium, and strontium from a bastnasite ore and byproduct. Barium and strontium were dissolved in the concentrated acid and precipitated as a mixed product by water dilution. Separation of strontium from barium was effected by reaction with Na2C03 solution, followed by a dilute acid leach of the SrC03 formed. After removing the barium and strontium from bastnäsite are, the rare-earth elements were roasted to water-soluble sulfates. The rare-earth sulfate solution was subsequently processed by solvent extraction to produce rare-earth oxides low in lead and magnesium.

Jan 1, 1974

By E. Bakhtavar

Finding a ?practical spacing between the holes? for use of the expansive mortars is an important problem in dimension stone quarries. Objective has been to first introduce a relationship between this spacing and the dependent parameters in such a way that the required size and shape of the blocks is produced with the maximum efficiency and safety, minimum wastage, conservation of reserves and protection of environment. For this purpose, a dimensional analysis was used. On the basis of granite and marble rock types in Iran two separate relations are hence established to calculate the practical spacing between the holes.

Jan 1, 2011

By Francis R. Redfern

Newton's method of solving a nonlinear equation is employed to develop a least-squares acoustic emission source location method in which the spatial residuals of the location equations are minimized. These residuals, related to the distances from the least-squares source location perpendicular to the surfaces described by the location equations, permit location error to be estimated to first order along the spatial axes. The solutions obtained by this method are the best spatial solutions to the location equations in the least-squares sense. Also presented is a procedure by which the geometrical control of a transducer array can be evaluated using the rate of change of source location with fractional velocity change.

Jan 1, 1982

Interest in industrial minerals in recent years has increased to such an extent that it has taken them into the mainstream of the Australian mineral industry. Notwithstanding that time series data on the values of production, exports, and imports show that industrial minerals are overshadowed by metals and energy minerals, their contribution to the national economy is important and more significant than would seem to be indicated by the statistics. Whereas the ex mine value of metals generally includes some processing (at least to a concentrate stage), most industrial minerals are valued at little more than their extraction cost, in addition to which such costs are generally low because most industrial minerals are exploited in low-cost surface operations. Consequently, values of mine production of metals and industrial minerals are not strictly comparable in that values of mine production of metals tend to be overstated Short term growth of the industrial minerals sector is assured because of several new projects already commissioned but not yet reflected in the statistics. Longer term growth is also assured, based on various other major projects that are likely to come on stream in the early to mid 1990s.

Jan 1, 1989

By J. W. Marx, R. H. Langenheim

The authors are to he complimented for a timely presentation of useful information concerning application of heat to oil reservoirs to increase the rate and ultimate recovery of oil. The solution for heated area resulting from constant rate injection of a hot fluid, presented by the authors, and the fluid-flow analogy, solved by Carter,' are particularly interesting in that 110 restriction is placed on the direction of development of the heated area. It is not necessary that the heated area grow radially. Thus the solution could provide useful information for heat injection in any type of well pattern with any specified swept area data. However, it was assumed in the development that the heated region would remain at a constant clevatcd temperature. Vertical heat losses were computed on this basis. Physically. the assumption that the heated region will remain at a constant temperature (independent of distance from the injection point) appears to require that the heat injection medium be stcam, or other condensible gases near the boding point at injection pressure. If a hot liquid below the boiling point or a hot gas considerably above saturation temperature were used, the temperature of the heated region would decrease with distance from the injection well. Lauwerier2 has discussed this problem for a linear system. (See also Jenkins and Aronolsky; and McNiel and Nelson.') Thus, the authors' solution applies more nearly to steam injection than to hot water injection or hot, non-condensable gas injection. Assuming steam as the injection medium, it appears that steam would pass through the constant-temperature heated region and condense upon contact with the unheated sand. The tempcrature in the condensing region would probably be governed by the release of heat of vaporization required for phase equilibrium at the existing pressure distribution. Temperatures in the region would also be influenced by vaporization of hydrocarbon. Thus, it is doubtful that an expression for radial temperature distribution based on heat conduction only (such as the authors' Eq. 9) would have practical significance. As pointed out by Marx and Langenheim, the growth of the heated area under constant rate steam drive will eventually be limited economically by vertical heat loss. The possibility of continuing to move heat economically by cold water injection or by increasing the steam injection rate appears to be a very important consideration. (Movement of liquids away from the injection well should increase injectivity.) Fortunately, the solution presented by the authors may be generalized to thc case of a variable heat injection rate. The general solution is:

By S. M. Bradshaw, C. Dorfling, F. Ngandu

"Selenium removal and platinum group metal (PGM) recovery from copper sulfate leach solutions form an integral part of platinum producers’ base metal refinery operations. Recent studies found that substantially higher PGM recoveries can be achieved if excess thiourea instead of sulfurous acid is used as precipitation reagent; however, the impact of the proposed process on downstream processes was unknown. The objective of the current study was therefore to investigate the effects that excess thiourea and residual selenium present in the rich copper sulfate electrolyte have on copper electrowinning. This was achieved by performing cyclic voltammetry tests using a platinum rotating disk as working electrode, a graphite auxiliary electrode and a saturated calomel reference electrode. A synthetic copper sulfate electrolyte containing 0.01 M Cu2+, 1 M H2SO4 and varying amounts of selenium (20 – 150 mg/L) and thiourea (10 mg/L and 100 – 300 % excess) was used. The results obtained have shown that both thiourea and selenium interact with the cupric ion cathodic reduction reaction. Thiourea polarized the working electrode and lowered the efficiency of the cupric reduction reaction. Tests on the solutions with high selenium concentration showed simultaneous reduction of copper and selenium, which led to copper selenide formation. Nodule formation on the deposit surface also became significant at higher selenium concentrations. Based on these results, it was concluded that precipitation of PGMs from the copper sulfate solution with excess thiourea is not feasible due to the detrimental effect on downstream electrowinning operations.INTRODUCTION During the high pressure oxidative leaching stage in a typical base metal refinery (BMR) circuit, selenium, tellurium and some platinum group metals (PGMs) are dissolved along with the desired copper ions. The impurities (selenium and tellurium) may pass to the copper electrowinning circuit where it can result in the formation of nodular copper electrodeposits or reduced current efficiency. The presence of PGMs in solution, on the other hand, increases the precious metal inventory and potential losses of the operation. Currently, sulfurous acid is widely used for selenium and tellurium precipitation from copper sulfate leach solutions. Sulfurous acid is capable of reducing cupric ions to cuprous ions; the generated cuprous ions then react with Se4+ and Se6+ to precipitate selenium as a copper selenide (Bello, Dorfling, 2014). Recent studies have, however, proposed the use of excess thiourea as a precipitating agent for the removal of selenium and tellurium; it has the advantage of improved PGM recovery in the Se/Te precipitation step (Lottering, Eksteen et al., 2012; Mulwanda, Dorfling, 2015)."

Jan 1, 2018

By Tyler R. J

Methylene blue dye adsorbs on chalcopyrite concentrates slurried in aqueous solution. Saturation adsorption can be achieved within about 24 hours for dye equilibrium concentrations greater than about 10-5 M. The dsorption coverage is obtained from a measurement of the' colour change of the solution. Comparison with BET measurement of the concentrate surface area shows that 2.4 ± 0.1 µmol of methylene blue are adsorbed per square metre of surface accessible to the dye cation. The procedure described can be used as a single-point measurement and values for the surface area can be otained to within about 10 per cent with inexpensive instrumentation.

Jan 1, 1979