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By C. J. Brown

"Access to the outside world is supplied by the Alaska Highway to continental Canada and the United States, the Haines Highway, and by the White Pass & Yukon Route to Skagway and Vancouver. Communities and mining developments located along the Alaska Highway are supplied daily by truck transport with commodities originating in Whitehorse, Edmonton, and Vancouver.The average payload on the Alaska and Mayo Highway is in the order of 16 to 25 tons and is subject to government regulations. Highway haulage distances to railhead at Whitehorse vary as does the direction. The Clinton Creek asbestos development is located 395 road miles north-west of Whitehorse whereas the United Keno Hill operation is 287 miles to the north. Cassiar Asbestos is located in Northern British Columbia at a distance of 357 miles south-east of railhead at Whitehorse. In order to service these various mines multipurpose highway vehicles have been designed to allow maximum backhaul of petroleum products. The White Pass & Yukon Route was established as an integrated transportation system from 1955 when it became apparent that three non-integrated systems (ship, rail and truck), with the various paper work and rising costs, could not continue to serve the needs of Yukon. Integration became the company policy and a system was developed. A special container ship (Clifford J. Rogers) was designed and built. This was the first specially built container ship in the world. The northern container integrated system was operational in 1955.In 1965 over 8.5 million dollars were spent in upgrading the container facility and the construction of a tanker-container ship designed specifically to serve Yukon and Northern B.C. This program was based largely on experience gained with the original container concept. Two tanker-container ships handled"

Jan 1, 1973

By H. J. Ramey

As fluids move through a wellbore, there is transfer of heat between fluids and the earth due to the diflerence between fluid and geothermal temperatures. This type of heat transmission is involved in drilling and in all producing operations. In certain cases, quantitative knowledge of wellbore heat transmission is very important. This paper presents an approximate solution to the wellbore heat-transmission problem involved in injection of hot or cold fluids. The solution permits estimation of the temperature of fluids, tubing and casing as a function of depth and time. The result is expressed in simple algebraic form suitable for slide-rule calculation. The solution assumes that heat transfer in the wellbore is steady-state, while heat transfer to the earth will be unsteady radial conduction. Allowance is made for heat resistances in the wellbore. The method used may be applied to derivation of other heat problems such as flow through multiple strings in a wellbore. Comparisons of computed and field results are presented to establish the usefulness of the solution. INTRODUCTION During the past few years, considerable interest has been generated in hot-fluid-injection oil-recovery methods. These methods depend upon application of heat to a reservoir by means of a heat-transfer medium heated at the surface. Clearly, heat losses between the surface and the injection interval could be extremely important to this process. Not quite so obvious is the fact that every injection and production operation is accompanied by transmission of heal between wellbore fluids and the earth. Previously, the interpretation of temperature logs',' has been the main purpose of wellbore heat studies. The only papers dealing specifically with long-time injection operations are those of Moss and White3 and Lesem, et al.' The purpose of the present study is to investigate wellbore heat transmission to provide engineering methods useful in both production and injection operations, and basic techniques useful in all wellbore heat-transmission problems. The approach is similar to that of Moss and White:' DEVELOPMENT The transient heat-transmission problem under consideration is as follows. Let us consider the injection of a fluid down the tubing in a well which is cased to the top of the injection interval. Assuming fluid is injected at known rates and surface temperatures, determine the temperature of the injected fluid as a function of depth anti time. Consideration of the heat transferred from the injected fluid to the formation leads to the following equations. For liquid, Eqs. 1, 1A and 2 are developed in the Appendix. These equations were developed under the assumption that physical and thermal properties of the earth and wellbore fluids do not vary with temperature, that heat will transfer radially in the earth and that heat transmission in the wellbore is rapid compared to heat flow in the formation and. thus, can be represented by steady-state solutions. Special cases of this development have been presented by Nowakl and Moss and White.3 Both references are recommended for excellent background material. Nowak' presents very useful information concerning the effect of a shut-in period on subsequent temperatures. Since one purpose of this paper is to present methods which may be used to derive approximate solutions for heat-transmission problems associated to those specifically considered here, a brief discussion of associated heat problems is also presented in the Appendix. Analysis of the derivation presented in the Appendix will indicate that many terms can be re-defined to modify the solution for application to other problems. Before Eqs. 1, 1A and 2 can be used, it is necessary to consider the significance of the over-all heat-transfer coefficient U and the time function f(t). Thorough discussions of the concept of the over-all heat-transfer coefficient may be found in many references on heat transmission. See McAdams5 or Jakob," for example. Briefly, the over-all coefficient U considers the net- resistance to heat flow offered by fluid inside the tubing, the tubing wall, fluids or solids in the annulus, and the casing wall. The effect of radiant heat transfer from the tubing to the casing and resistance to heat flow caused by scale or wax on the tubing or casing may also be included in the over-all coefficient. According to McAdams, on page 136 of Ref. 5>

By Donald R. Irving

ALTHOUGH the quantity of material handled at metal and nonmetal mines in the United States in 1962 was 2.7 billion tons, the same as in 1961, a larger proportion was waste. At metal mines, crude ore production declined 1 million tons and waste output rose more than 18 million tons; at nonmetal mines crude ore production declined 6 million tons and waste output rose 36 million tons. Copper and iron ore producers increased their share of crude ore and material handled from about three-fourths to four-fifths of the national metals total, and sand and gravel and stone producers in-creased their share of the nonmetals total, also from three-fourths to four-fifths. Six States-Arizona, California, Florida, Michigan, Minnesota, and Utah-each handled more than 100 million tons of ore and waste, and together they accounted for 43 percent of the U.S. total. When the large-volume construction materials (sand and gravel and stone) were excluded from the totals, four States-Arizona, Florida, Minnesota, and Utah-supplied over half of the material handled.

Jan 1, 1963

By E Mofya, R Kaunda, P Lever

One of the fundamental requirements for being able to optimise blasting is the ability to predict fragmentation. An accurate blast fragmentation model allows a mine to adjust the fragmentation size for different downstream processes (mill processing versus leach, for instance), and to make real time adjustments in blasting parameters to account for changes in rock mass characteristics (hardness, fracture density, fracture orientation, etc). A number of blast fragmentation models have been developed in the past 40 years such as the Kuz-Ram model (Cunningham, 1983). Fragmentation models have a limited usefulness at the present time because:The input parameters are not the most useful for the engineer to determine and data for these parameters are not available throughout the rock mass. Even if the input parameters are known, the models still do not consistently predict the correct fragmentation. This is because the models capture some but not all of the important rock and blast phenomena. The models do not allow for ætuningÆ at a specific mine site. This paper describes studies that are being conducted to improve blast fragmentation models. The Split image processing software is used for these studies (Kemeny, 1994; Kemeny et al, 1999).

Jan 1, 2001

By Dean E. Matthews

The concept of a pile for construction is credited to a Neolithic tribe called the "Swiss Lake Dwellers" who lived in what is now Switzerland about 6,000 years ago. They used piling, not for supporting heavy loads as we do today, but for elevation to protect themselves from wildlife. The Romans often used piles, and built many structures, including buildings, homes, bridges, roads and viaducts on piling. The Romans built the first bridge across the Tiber River in Rome on timber piles in B.C. 1620. Homes in the cities of Venice and Ravenna were built on piles from B.C. 100 to A.D. 400. The Romans also built the first bridge across the Thames River in London in A.D. 60 on timber piling.

Jan 1, 2003

By Joseph L. Fournier

Suncor Oil Sands employs delayed coking technology in converting bitumen into synthetic crude oil. Currently up to 10,000 m3 of delayed coke (coke) is produced per day as a byproduct of the upgrading process, of which up to 9,000 m3 per day is placed in dry storage on Lease 86/17. A review was completed to examine the case history of leachate potential experiments from the dry storage of coke and the environmental relevance of coke leachate studies conducted over the past decade. The review included an evaluation of the potential impacts of environmental conditions within the location of coke storage, including precipitation pH, as well as daily and annual ozone trends. Coke leachate potential has historically been characterized using standard leachate testing protocols (i.e., TLCP, SPLP) together with other studies that have employed strong acids and oxidizing agents in the extraction fluids. The present paper highlights prevailing conditions in the Athabasca Valley air-shed with emphasis given to ambient ozone (oxidizers), as well as precipitation pH and acid input deposition rates, and will demonstrate that TCLP / SPLP tests lack the intended environmental relevance relative to the conditions under which coke is stored.

May 1, 2011

By Carl Floe

A NUMBER of proposals have been made for the hydrometallurgical recovery of copper from flotation concentrates, but as yet no process has been developed that has demonstrated an ability to compete with the present smelting methods under ordinary conditions. The treat-ment of copper concentrates by hydrometallurgical methods is in general similar to that used in the present electrolytic zinc process and involves roasting, leaching with H2S04 solution, separation of solutions, control of impurities and electrodeposition. While many of these steps are simpler and more readily carried out for copper than for zinc, a number of inherent difficulties have prevented the general adoption of the process. To compete with smelting, the following problems must still be con-fronted, although many solutions for their have been proposed: (1) con-duction of the roast in such a way that leaching will give an extraction of copper comparable to that obtained by smelting; (2) regulation of the ferric iron content of the solutions during electrolysis; (3) disposal of the excess acid regenerated from the sulphates formed in roasting; (4) eco-nomical recovery of the precious metals from the leach residues. The roasting problem is largely one of preventing the formation of copper ferrites, CuO.Fe2O, and Cu20.Fe2O3, which are quite insoluble in dilute sulphuric acid. These ferrites are apparently formed' to a small extent even at low temperatures and above 650° C. their formation is rapid1. While it is possible to carry out laboratory roasts in such a way that less than 5 per cent of the total copper is present in the insoluble ferrite form, a closer temperature control is required than can readily be obtained in industrial furnaces. The flash" roasting effects and consequent high temperatures that occur as the calcine falls from hearth to hearth in the ordinary multiple-hearth roaster are probably largely responsible for the inevitable formation of some ferrites. The result is that in a commercial plant the extraction of copper would not average more than 90 per cent in a single 10 per cent H2SO4 leach. This is

Jan 1, 1937

By J. M. Cases

Study of the normal interaction between flotation collectors and the silicates through measurement of the electrokinetic potential carried out by the streaming potential and flotation recovery methods indicates that the interaction is wholly 07 partly of electrostatic origin. In some cases, it partly consists of the chemical affinity of the polar head of the collector for the active surface sites. Reagents composed of a polar head and a paraffinic chain and forming micelles in solution were used as flotation collectors. They are sodium dodecylsulfate (anionic collector) and dode-cylammonium chloride (cationic collector). The adsorption isotherms on biotite of alkylamine chloride having 10 to 18 carbon atoms in their chain all show a sharp change in slope relevant to the condensation of alkylammonium ions into bidimensional phase.1-1 Condensation is possible because of the relative homogeneity of the adsorbing surface and of the very strong lateral binding forces through Van der Waals type bonds in the adsorption layer. The different isotherms are seen to coincide when, instead of the equilibrium concentration, the under-saturation ?µ = kT In C/C, is plotted in abscissa, C representing the concentration of the solution with which the adsorbed layer is in equilibrium and C, the saturation concentration of micelles in solution or. critical micellar concentration. More particularly, the undersaturation ?,u1*, corresponding to a surface coverage 6 of 0.5, is equal to Since silicates immersed in aqueous solutions show a surface charge which is a function of pH, it is of primary importance to study the influence of this parameter on the adsorption of collector ions acting as Strong electrolytes in the pH range where they are utilized. The aim of this present paper is to determine by studying electrokinetic phenomena and recovery curves effectuated with a cationic collector and a anionic collector, the nature of the normal adsorbate-adsorbent interaction. Tables 1 and 2 sum up part of the results previously obtained'H11 for the determination of the point of zero charge of the silicate studied by the streaming potential method. Throughout the remainder of this paper, the surface charge will be considered positive for all values of pH below the point

Jan 1, 1971

By L. D. Jaffe

IN previous metallographic work on titanium and its alloys, difficulty has been encountered in distinguishing spheroidal particles of titanium hydride, dispersed in a-titanium, from other phases that may be present, such as p-titanium. This problem is common in examination of commercial unalloyed titanium.' In the course of an investigation of the Ti-H phase diagram, it was noted that titanium hydride, dispersed in a matrix of a-titanium, showed strong optical anisotropy when examined under polarized light. With sensitive tint illumination, particles of the hydride, when the stage is rotated, changed from bright yellow to bright blue in color. Since P-titanium is cubic, it showed no color change on rotation, remaining dark gray or blue-gray. Although a-titanium is hexagonal, it showed only a minor color change, going from pale pinkish-blue to pale purplish-blue. These colors could be modified somewhat by adjustment of the illumination. They were observed in specimens mechanically polished, both without etching and after etching with hydrofluoric acid-nitric acid mixtures in either water or glycerine. The strong color change of the hydride seems to offer a simple method for its metallographic identification. Optical anisotropy of titanium hydride is inconsistent with its accepted face-centered-cubic structure.' Samples of iodide titanium containing 6 to 40 atomic pct deuterium were prepared for diffraction studies. After deuterating and slow cooling' the samples were held 21 % hr at 400 °C, water quenched, held 61 hr at 100°C and quenched, then held 64% hr at 255 C and quenched. Debye ex-posures with MoKa X-rays and 1.111A neutrons were made at room temperature of samples as-deuterated and after the 100" and 255°C treatments. Table I shows the lines observed, in addition to those attributable to a-titanium. These data show that the hydride phase was not cubic, but probably tetragonal. The titanium atoms appeared to form a body-centered-tetragonal lattice complex, two titanium atoms per cell, with approximate dimensions: a = 3.12A, c = 4.18A, and c/a =1.34A. This is equivalent to a face-centered-tetragonal complex, four titanium atoms per cell, with approximate dimensions: a = 4.42A, c = 4.18A, and c/a - 0.946A. The presence of the 2.98 and 1.81A neutron lines indicates that the true Bravais lattice is not identical with this lattice complex, but may be primitive tetragonal with dimensions some multiple of those of the complex. The relative intensities of the hydride and a-titanium X-ray lines as functions of overall composition indicated that the hydride, presumably in equilibrium with the a at 100" to 255"C, contained more than 62 atomic pct H. Acknowledgments The experimental work covered in this report was done at Brookhaven National Laboratory, through the courtesy of D. Gurinsky. The cooperation of J. Sadofsky, 0. Kammerer, A. McReynolds, and A. Cendrowski is gratefully acknowledged.

Jan 1, 1957

By Louis V. Bender

THIS paper gives a short review of the installation for and the use of gas, as a. fuel, at the Anaconda Reduction Works of the Anaconda Copper Mining Co. Before putting in gas tile fuels used were pulverized coal, lump coal, coke distillate and oil. These fuels are now almost entirely eliminated. For nearly fifty years bituminous coals from Wyoming and Montana fields had been used. These coals were of a good grade, analyzing 11,300 B.t.u. and having an ash content of 12 per cent. When hydro-electric power replaced steam-driven equipment, the coal requirements were reduced; and, on account of improvements in metallurgy and/ or in furnace design, the quantity was lessened. Later, oil and distillate were introduced and used in some of the operations. All of these things tended toward the lessening of the amount of coal used, and had it not been for the increase in the size of the plant, the tonnage used would have been small when the change was made to gas.

Jan 1, 1932

The additional information that Clarke and Taylor (1982) provide about the important but poorly documented Ardlethan deposit is, of course, very welcome. However their contention that structural considerations, in conjunction with petrology, alter the interpretation of the mineralogical and geochemical data presented previously (Scott, 1981) is not accompanied by adequate supporting evidence. Indeed characteristics of the orebodies studied invalidate their arguments.Heterogeneity between matrix and fragments is not a problem in the South Cherry and Ardwest orebodies because most samples are comprised entirely of interlocking hydrothermal assemblages with a fabric and mineralogy that is uniform through both former breccia fragments and matrix. In hand specimen, the rock superficially resembles altered granite and, as indicated by Clarke and Taylor (1982), a brecciated texture is difficult to discern. In thin section, relict brecciated textures can be observed as localized changes in the grainsize or in the distribution of minerals that outline former breccia fragments (P. J. Eadington, 1982, personal communication).Because of the intense brecciation and comminution of rocks (fragments < 10 mm are usual) in the South Cherry and Ardwest breccia bodies, hydrothermal recrystallization was complete, resulting in homogenization of fragments and matrix. Furthermore, the amount of sample analysed (-100 g for drill core and 2-3 kg for hand specimens) is sufficiently large to be representative of both former breccia fragments and matrix. The Carpathia and Stackpool orebodies, with their abundance of sedimentary fragments, have alteration superimposed on a heterogeneous fabric, and were not studied. Thus the problems of differentiating between fragments and matrix (Clarke and Taylor, 1982) are irrelevant to the particular orebodies described in my paper.Within the alteration halo, which is several hundred metres wide (Paterson, 1976), the very uniformity of the alteration assemblages implies that subsequent, postmineralization brecciation is of only minor significance.Indeed tourmaline pipes in the Ardwest pit are less than several metres across (Clarke, 1979) and produce minimal alteration in the surrounding rocks. Therefore the interpretation of the mineralogical zonation is not compromised by the recognition of several periods of brecciation.

Jan 1, 1982

By Karl A. Higgins

In 1976, Prof. G. G. Meyerhof published a famous article in the Journal of Geotechnical Engineering titled ?Bearing Capacity and Settlement of Pile Foundations?. This article presents the authors opinions on calculating pile capacities in clays and sands, group capacities and pile settlement. A portion of the article presents correlations of shaft friction and end bearing to the Standard Penetration Test (SPT) N-value. Subsurface exploration via the Standard Penetration Test is the most widely used exploration tool in the United States, so correlations of pile capacity to N-value are significant to the practice of geotechnical engineering. Meyerhof?s SPT-N correlations are relatively simple calculations compared to other pile capacity computation methods presented in the article or found in other text books (such as the a-method, b-method, Nordlund, Vesic, Meyerhof?s semi-empirical, others) and therefore are popular amongst practicing geotechnical engineers. At the time these correlations were published by Prof. Meyerhof, utilization of dynamic testing with the Pile Driving Analyzer (PDA) was not widespread in geotechnical engineering practice. Prof. Meyerhof?s correlations appear to be based upon conventional static pile load testing of instrumented piles. Dynamic pile measurements to estimate a pile?s static capacity provides certain advantages over conventional static load testing, namely the determination of unit shaft friction values at discrete intervals along the pile, and the unit end bearing support value. The author has compiled a database of driven, displacement piles tested with dynamic methods (ref. ASTM D4945, Test Method for High-Strain Dynamic Testing of Piles). The data was collected between 2002-2010 and is comprised of displacement piles driven into coastal plain sediments in the mid-Atlantic states of Virginia, Maryland and the District of Columbia. In layered soils, dynamic testing in particularly helpful as it reveals the differences in unit shaft friction for varying soil types. One hundred ninety (190) piles are included in the database, with a corresponding 1,373 discrete shaft friction and 190 end (toe) bearing measurements. The pile type typically consisted of 12 and 14 inch square, prestressed, precast concrete piles; however, a significant number of piles were steel HP 12 or 14 inch sections. The database was sorted based upon soil type, and then correlations of shaft friction and end bearing were derived in the same or similar manner as Meyerhof?s original 1976 publication. The new correlations are compared to Meyerhof?s original values.

Jan 1, 2011

By Gary Jackson

Preliminary engineering for the Waller Creek Tunnel was completed in 2001, but the project was held in abeyance until the summer of 2007. This paper describes several features of the revised design, which required significant changes from the original concept. Most notable is the expected replacement of a tunnel boring machine (TBM) by conventional tunneling. The considerable influence of geological conditions on the tunnel vertical alignment is discussed, in particular the impact of the zones of Eagle Ford Shale with swelling potential. Other features which are described include the wide span tunnels and large diameter shaft requirements.

By Nic Slatalla

Resin anchored rock bolts are an effective tool to control the deformation of an underground opening because they combine high support capacity with fast installation. However, there are still numerous shortcomings concerning the understanding and interaction of the system bolt-resin-rock. Field and laboratory test series have been conducted for evaluating the load capacity and bond strength of resin grouted rock bolts in different host rocks under axial load. This paper describes that the behavior and shear strength of the system bolt-resin-rock depends on the rock type and discusses a simple correlation between peak shear strength and shear stiffness in the ratio 1:1000 which may moreover be helpful for estimating rock bolt capacity after installation.

Jan 1, 2006

By R G. Barker

This paper reviews the annual status of the New Zealand mining industry (metallic minerals and coal) including key aspects such as mineral production, mineral exploration expenditure, commodity price trends, key industry players, market activity and other significant commercial factors.   Strong commodity prices during 2006 have been underpinned by a number of key factors including US dollar weakness and emerging market demand, particularly from countries such as China and India. In real terms commodity prices have recovered significantly since 2002 and are currently at 20-year highs.   New Zealand exploration spending on metallic minerals (predominantly gold) is at a 15 year high driven by rising global commodity prices. New Zealand gold production in 2006 was about 340,000 oz and is expected to grow in 2007 as new mines at Frasers and Globe-Progress (Oceania Gold) and Favona (Newmont) come on stream. Gold production broadly lags 10 years behind exploration spending and exploration activity over the last five years remains well below that seen in the early 1980Æs. Expenditure on coal exploration shows a similar trend with strong growth from a low base over the last five years, reaching over $11 M in 2006. Total coal production in 2006 was 5.9 Mt, an increase of 10% on 2005 with imports from Indonesia adding a further $1.1 Mt.   Newmont and Oceana Gold are by far the largest public gold mining companies operating in New Zealand, although only Oceana Gold maintains a presence on the local stock exchange. Other metals explorers with New Zealand projects include a range of public-listed Juniors (market capitalisation less than NZ$50m) domiciled largely in New Zealand, Australia and/or Canada. Capital-raising on public markets directed towards New Zealand exploration is estimated at around NZ$12 M for 2006, the bulk of this coming via Glass EarthÆs NZ$10 M IPO on the NZAX in October.   The New Zealand Coal sector is dominated by the state-owned enterprise Solid Energy with around 80% market share by production. Other domestic coal competition remains limited, and includes the L&M Group, Pike River Coal, Eastern Corporation, and New Vale (acquired by Solid Energy in 2007). Pricing parity comes mainly from imported coal and global thermal coal prices have remained strong during 2006 at around US$45-55/t, driven by continued expansion in Chinese demand. Coking coal prices have eased 16% since 2005 to around US$98/t in 2007.   Although recent increases in exploration spending suggest a renaissance in the New Zealand minerals sector, long-run trends indicate that we have simply rebounded from a low base over the last five years and much work is still to be done to stimulate further growth in the mining industry to maintain minerals production at current levels. Key industry challenges include marketing exploration opportunities to local and overseas investors, building a critical mass of NZX-listed explorers and providing an internationally competitive environment to attract further capital and expertise.

Jan 1, 2007

By T. C. Alex, K. M. Godiwalla, R. K. Jana

Manganese nodule, available in ocean beds, is a potential resource of the future for copper, nickel and cobalt. Recovering only these metals, containing less than 3% by weight, will result in the generation of large amount of residue. In addition to the material losses, several environmental and ecological problems arise out of this. The present study has been aimed at reducing the environmental and ecological problems associated with massive generation of this residue together with utilization of the resources. Presence of ~ 20% manganese and ~16% silicon in the residue has prompted us to check its suitability as a raw material for silicomanganese production. Lower manganese content and lower Mn/Fe ratio of the residue than that required for silicomanganese production has been corrected in this study by suitable blending. The efficacy of blending and its thermodynamic aspects using FACTSAGE software are discussed. The studies conducted indicate viability of bulk utilisation of the residue through silicomanganese production and thereby reducing the burden on environment to a great extent.

Jan 1, 2007

By Michel C. Frippel

This section of the Minerals Yearbook reviews the minerals industries of 29 countries: the 12 nations of the European Community (Belgium, France, the Federal Republic of Germany (FRG), Italy, Greece, the Netherlands, Denmark/Greenland, Spain, Portugal, Luxembourg, The United Kingdom, and Ireland); 6 of the 7 nations of the European Free Trade Association (Sweden, Norway, Finland, Iceland, Austria, and Switzerland); Malta; the 8 Centrally Planned Economies of Eastern Europe (the German Democratic Republic (GDR), Poland, Yugoslavia, Albania, Hungary, Czechoslovakia, Romania, and Bulgaria); and the U.S.S.R. Western Europe Western Europe [loosely defined to include the 12 nations of the European Com-munity (EC) and the 7 nations of the European Free Trade Association (EFTA)] is the single largest trading area and consumer of raw materials in the world. If Western Europe was at one time an important mining sector, it has now increasingly relegated the role of supplying minerals for its minerals processing industry to its ex-colonies in North and South America, Africa, and Australia. In this regard, Western Europe is the most important determinant of raw materials consumption (and thus, indirectly, raw materials production). There is an important reason for this since Western Europe lies somewhere between Japan at one extreme and the United States and the U.S.S.R. at the other extreme as regards the availability of natural resources.

Jan 1, 1992

By E. C. L. Cardoso

Hydrocarbon polymers, as PP, made from cheap petrochemical feedstock are important in many branches of industry. However, they have an undesirable influence on the environment and cause problems due to waste deposition and utilization. Polymeric materials composites account for an estimated from 20 to 30% of total volume of solid waste disposed. Thus, there is a tendency to substitute such polymers by those ones that undergo biodegradable processes. Polypropylene (PP) is a commodity, with high melting point, high chemical resistance, low density, with a balance between physical and mechanical properties and easy processing at low cost. Nevertheless, PP shows limitations for some special applications in automotive industry and civil construction. In order to minimize this deficiency, related to rheological behavior of polymer melt, especially referring to viscosity in processing temperature, a 50% mixture with HMSPP (High melt Strength Polypropylene) was used. PP/HMSPP was blended with 10, 15, 30 and 50% of natural (sugarcane bagasse) and synthetic polymers (PHB and PLA) aiming to partially biodegradable materials. The admixtures were subjected to gamma-irradiation at 50, 100, 150 and 200 kGy and then further assessed by mechanical tests in order to evaluate their degradability.

Jan 1, 2015

By S. J. Hruska

Rate expressions for the formation of two-and three-dimensional nuclei on foreign substrates are developed, taking into account previously neglected contributions to the standard Gibbs free energy of formation of critical nuclei. The temperature dependence of critical super saturation data predicted using these expressions is in accord with data for cadmium on copper and sodium on CsCl. EXPERIMENTAL data on the heterogeneous nuclea-tion of metal crystals from the vapor phase1&apos;2 exhibit the temperature dependence predicted by a nucleation rate equation derived by Pound et al.3 In their treatment, the critical nuclei are visualized according to the Volmer4 model as cap-shaped (three-dimensional). Accordingly, it seems desirable to compare these data with a nucleation rate equation which is derived on the assumption of disk-shaped (two dimensional) nuclei. Further, Lothe and Pound5 have recently shown that the standard Gibbs free energy of formation of these critical nuclei contains a contribution which has heretofore been neglected. Thus it is necessary to re-examine these nucleation data using a rate equation which contains this contribution. The van&apos;t Hoff isotherm relates n(i), the concentration of nuclei of critical size i (i = number of atoms), to nil), the concentration of adsorbed single atoms: where standard Gibbs free energy of formation of critical nuclei given by is temperature insensitive and is the bulk free energy change/volume of transformed material], T = substrate temperature and k = Boltzmann&apos;s constant. Previously,3 was determined by considering only the contributions of bulk and surface free energies in transforming i atoms from the population nil) to a cluster of i atoms. It has been shown5 that this procedure does not take into account the free energy contribution arising from the multiplicity of sites, q, where the clusters can be situated. If this contribution, -kT In q/n(l),is added to iG3 [Note that this increases n(i) by a factor q/n(l).] Since the above does not affect the remaining terms in the rate expression of Pound et al., the details are referred to their paper. The resulting nucleation rate is If the experimental AGV and T values at some common value of are employed, a plot of vs T(ln C3/l + In p&apos;) should yield a straight line of slope k/B<p and intercept . The corresponding plots for / = 1 nucleus per sq cm sec and C3 = 1018 are shown in Figs. 1 and 2 for cadmium on copper1 and sodium on CsCl2 and the values of obtained therefrom are entered in Table I. It is apparent that the data yield reasonable straight lines with about the same scatter as found using the equation of Pound et al. When the configuration of minimum free energy for a nucleus is a circular monatomic layer, the standard free energy of formation is

Jan 1, 1963

By Richard S. Della Valle

Sandstone and shale samples from the Morrison (Late Jurassic) and Dakota formations (Cretaceous) from northwestern New Mexico have been analyzed for the major elements Na, K, Fe and the trace elements Sc, Cr, Co, Rb, Sb, Cs, Ba, Hf, Ta, Th, iJ and the rare earth elements (REE) in whole rock and clay sized fractions by instrumental and delayed neutron activation analysis. The clay sized fraction clearly shows enrichment patterns and halo effects ; whereas, the whole rock fraction does not. Important elemental dispersion halos associated with uranium in sedimentary environments include the REE, Hf, and Sb. The distribution of these halos are due to a combination of complexation, chelation and the orignal paleoenvironments.

Jan 1, 1984