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By J. Lu, M. Mohammadi, C. Pelletier, B. Wassink

Chemical reduction of selenate by chromous ions is proposed as a novel method to remove selenate from sulfate-bearing solutions Chromous ions were generated by electrochemical reduction of chromic ions using an electrochemical cell. The investigation was conducted in sulfate medium and under various concentrations of chromous ions (0.0062 to 0.05M), pH 1 to 2.2 and temperature 10 to 60°C. Selenate ions were rapidly reduced by chromous ions to hydrogen selenide. The overall reaction at a chromous/selenate molar ratio of 8 or higher can be expressed by the following reaction. At an initial chromous/selenate molar ratio below 8, the products are hydrogen selenide and elemental selenium. At a lower chromous/selenate molar ratio and pH, more elemental selenium and less hydrogen selenide are produced. The reduction kinetics is controlled by both chromous ion and hydrogen ions concentrations. The reaction rate is first order with respect to selenate, hydrogen ion and chromous ion concentrations. It was found that the selenate reduction rate with chromous is independent of the concentration of sulfate present in the solution. The general rate equation was proposed and the rate constant was calculated as k= 0.38 M-2s-1. An activation energy of 58.7 kJ/mol was obtained in the temperature range from 10 to 50°C. Nearly 100% of selenate can be reduced to H2Se from solution containing 17 ppm selenate in less than 30 minutes at pH 2.2 and 60°C. Various strategies have been tested to remove the produced H2Se from solution. INTRODUCTION Selenium in nature is mostly associated with metal sulfide minerals such as copper, iron, zinc, and lead sulfides (Zingaro & Cooper, 1974). The extraction of metals from ores has the potential for selenium contamination of ground and surface water which can pose an environmental and health concern. Therefore, selenium contamination in the receiving environment is a key issue for many industries (specifically copper industry) and the treatment of wastewater contaminated with selenium is a growing challenge. The effective removal of selenium from contaminated water is very important to support sustainability in the copper industry and the other industries with selenium pollution issues.

Jan 1, 2019

By M Olsson, U Nyberg, K Widenberg, P Svedensten, F Ouchterlony

During 2007 and 2008, the project Optimal Fragmentation in Blasting II was conducted at the Långåsen quarry of NCC Roads AB near Arlanda. The main goals were:an evaluation of the effect of using electronic delay detonators (EDDs) in quarry blastinga validation of the design curve concept introduced at the Vändle quarry.Five production blasts were monitored. After a first trial round, the remaining four rounds each had about 100 Ø89 mm holes in a 14–19 m high bench charged with site mixed emulsions. In rounds 1 and 2, a tighter pattern than normal was used in one half of the rounds, raising the specific charge there from 0.7 to 1.0 kg/m3. Non-electric initiation was used with two holes per 25 ms delay in-row and 67 ms between rows. In rounds 3 and 4, electronic delay detonators were used instead, with 10 and 5 ms in-row delays respectively.The monitoring encompassed drill hole collaring and alignment, in-hole deviations, the rock structure in the bench faces from 3D imaging, first row burdens, etc. Eleven 400 t samples were taken from the muck piles and sorted in the quarry and sieved in the laboratory (lab). The lab data made up a fines tail that was grafted onto the in-pit sorting data to form sieving curves for the test piles. These curves were then compensated for the absence of boulders to construct the sieving curves for the blasted muck pile.These have been used to derive fragmentation model formulas for the non-electric rounds, also called design formulas. They are based on blast geometry, charging data and the properties of the rock mass. The formulas may be used to estimate the effect of changing blasthole pattern, borehole diameter and stemming length for example.The use of EDDs gave several unexpected results. In comparison with non-electric initiated rounds with a somewhat lower specific charge the fragmentation was much coarser; x50 increased from 160 to 200 mm. The effect of raising the specific charge in the non-electric initiated rounds from 0.72 to 0.99 kg/m3 was a much finer fragmentation; x50 decreased from 160 to 120 mm.CITATION:Ouchterlony, F, Nyberg, U, Olsson, M, Widenberg, K and Svedensten, P, 2015. Effects of specific charge and electronic delay detonators on fragmentation in an aggregate quarry – building fragmentation model design curves, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 727–740 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By Charles H. Fulton

CHARLES H. FULTON, chairman, presided at the first session of the Mineral Industry Education Division on Wednesday morning. Reporting for the program committee, Edward Steidle, its chairman, pointed out that its function was not to arrange programs for meetings but to plan a program for the Division to follow in the development of its activities. This was appropriately followed by presentation and discussion of his paper, "Basic Trends in Mineral Industries Education," which, being available in printed form, was only presented in oral abstract. Jay A. Carpenter submitted interesting written discussion that was read, in his absence, by A. M. Smith. Most of the morning was devoted to the discussion of the paper, which was too extensive and ranged too widely to attempt to report in much detail. H. T. Mann, H. P. Hammond, Cadwallader Evans, C. H. Fulton, T. T. Read, D. F. McFarland and P. B. Bucky joined in the discussion, Mr. Hammond making a plea for more unification in mineral industry education, saying that in the study he made for the Society for Promotion of Engineering Education about 35 different curricula preparatory to work in the mineral industry were discovered to exist. He felt that most of the needs of the mining industry could he met by men who had had four years of engineering training of good enough basic quality to permit them to advance along special lines. However, there was apparently a growing demand, as reflected by the increasing number of candidates for the Master's degree in engineering, for men with more thorough training in the fundamentals.

Jan 1, 1933

By Alan Bauer

IN RECENT PAST YEARS, the mining industry has expanded rapidly and mining engineers have not been generated in sufficient numbers to sustain this growth. Canada has not been alone with this problem, which has resulted in considerable soul-searching as to what the solution might be. Because of the unfavourable economics of running small departments such as mining, metallurgy, ceramic engineering, etc., one approach in some cases has been to put these departments together to form a department of mineral science which now has a broader base structure. Another solution has been the "conversion kit" program which has been conducted both at universities and in industry. At universities, such programs have consisted of converting graduates of other engineering disciplines into mining engineers. In some of the large mining corporations, extensive training programs have been used with the same aim.

Jan 1, 1972

By Chen Wen, Li Zhao-jia, Zhao Qiang, Ning Shun-ming, Tang Sanchuan, Wang Hong-qiang

"The carbon-burdened and cold-bonded pelletizing-electrosmelting process is used to dispose low-grade manganese, and the qualified rich-manganese slag is obtained. On the condition that reduction roasting temperature was 1000?, reduction time was 45min, particle-size was -1mm, reductant dosage was 1.6%, basicity was 0.3, smelting temperature was 1410?, smelting time was 60min, it had a good effect on the melting between slag and metallographic phase, the manganese content was 32.58%, manganese recovery was 92.16% in the slag; while the iron content was 94.40%, iron recovery was 95.32% in the metallographic phase. It was proved by the demonstration tests.IntroductionManganese is an important raw material for steelmaking, which is extensively utilized in modern industry, the consumption of manganese for iron and steel industry accounts for 90% to 95%. After mining over 30 years, the high-grade manganese resources drop markedly, especially with the hypergrowth of steel industry, the domestic manganese is far from the requirement, as a result, we have to buy significant quantities of manganese overseas. Besides, the property of imported manganese is more and more complex, and the high-grade and lump manganese decrease year by year, while the fines and high-crystal water manganese are on the increase. Therefore, how to make effective use of domestic low-grade manganese and intensify the manganese’s smelting is an effective approach to reduce the cost of manganese series ferroalloy and improves market competitiveness[1-4]. It has important practical meaning."

Jan 1, 2012

The solution mining review did not arrive in time for publication in the May issue. The term solution mining is commonly used to refer to heap leaching, dump leaching, in situ mining and bore hole slurry mining technologies. The US Bureau of Mines is continuing with research in these areas. Commercial application of these technologies is progressing. There is an ongoing cooperative research project between the Bureau of Mines and the Santa Cruz Joint Venture to evaluate in situ copper mining at a field site near Casa Grande, AZ. The project is currently in the environmental permitting stage. The Bureau is preparing an environmental assessment for the project as part of the National Environmental Policy Act. The Bureau is also continuing with laboratory experiments to study the leaching characteristics of atacamite ore from the field test site, as

Jan 1, 1993

By T Takayama, M Matsumura, Y Konno

The steel industry accounts for 14 per cent of domestic CO2 emission in Japan, and iron ore sintering process occupies approximately three per cent. While Fe content in iron ore is gradually decreasing. So, the amount of concentrated iron ore will increase in the future. We have focused on magnetite concentrate as sinter materials, because magnetite can be easily magnetically beneficiated. However, it is experienced that blending magnetite ore resulted in increasing Fe2+ component in the iron ore sinter, which results in lower reducibility. Therefore, promoting the oxidation reaction from magnetite to hematite in the sintering process is countermeasure for reducibility. In addition, this promotion causes increase of oxidation heat, which results in high sinter strength and reduction of coke. It is assumed that the oxidation of magnetite tends to proceed in the cooling stage, where the oxygen partial pressure increases after the combustion of fine coke, but there are few studies on the effect of heat profile, especially cooling path. The purpose of this study is to design the effective sintering heat profile to promote oxidation of magnetite ore, especially, to investigate the effect of cooling path on sintered ore microstructure. In this study, magnetite ore and magnetite reagent were respectively mixed with calcium carbonate reagent. Then the mixed samples were pressed and formed into cylindrical tablets for simulating the adhesive layer of a pseudo particle. Through examining influence of maximum temperature and cooking rate on oxidation reaction of magnetite, we confirmed that the oxidation reaction of magnetite is suppressed at above 1350°C for maximum temperature, compared to 1300°C. Sintering at lower temperature is desirable because hematite is stable below 1350°C in the Fe2O3-CaO phase diagram.

Nov 8, 2021

By D Fukuda, K Kaneko, R Kudo, J Kodama, Y Fujii, T Sasaki

"Estimation of stress state as well as elastic modulus is important for the prediction of a rock slope deformation in an open pit mine since it can strongly influence the mining-induced deformation of the rock slope. This study applies a method to evaluate regional stress state and Young’s modulus by analysing the mining-induced deformation of ground. The effect of changes in regional strain state due to tectonic plate motion can be accounted for using the proposed method. Mining-induced deformation can manifest itself as changes in ground surface geometry resulting from mining activity. There are three underlying factors that can contribute to the deformation: displacement induced by the effect of gravity displacement induced by the effect of horizontal regional strain incremental change in the horizontal regional strain. The relative displacement arising from the mining excavation at the Torigatayama limestone mine in Japan has been measured by Global Positioning System (GPS). Both the regional stress state and Young’s modulus were estimated by back analysis of the change in distance between GPS stations using a 3D finite element method. It was shown that the reliability of the estimation improved with an increase in displacement due to mining progression. It was also shown that values for Poisson’s ratios of less than 0.10 are reasonable estimates with values for Young’s modulus between about 5?GPa and 10 GPa. The magnitude and direction of the maximum compressive stress in the district surrounding the Torigatayama mine were estimated to be between -6.4 MPa and -4.4 MPa and around N25E respectively.CITATION:Kodama, J, Sasaki, T, Fukuda, D, Kaneko, K, Fujii, Y and Kudo, R, 2014. Estimation of regional stress state and Young’s Modulus of ground at Torigatayama Limestone Mine in Japan, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference, pp 135–142 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 5, 2014

By R. J. Cefalo

Blast and mining spillover between phases or critical areas of the pit is a continuing problem in the mining industry and a safety concern for operating mines. The challenge for many mines is to produce the highest value in the shortest amount of time for any project. For any project, the top priority of any mine is producing ore as fast as possible. The next challenge is to keep that ore feed continuous. To achieve continuous ore feed, pits are designed with multiple phases that are connected and are mined at different elevations. This difference in elevation causes dangers with spillover between the phases during mining, drilling, and blasting. This paper covers an incident that occurred at an active mine and the work completed in creating a spillover control program over an active mining phase. The drill and blast technical group was responsible for creating blast patterns to reduce spillover between these phases. Unrealistic goals and expectations were initially set for the area of the pit. The drill and blast technical group needed to figure blast objectives and work with the geotechnical team to align with these goals. This paper will go over the executed example of setting up spillover targets and expectations for multiple sections of an operating mine. Different sections of the pit had different control measures and blast objectives due to narrow laybacks and double benching. The use and value of blast objectives and goals were beneficial in setting expectations and measuring design success. Having unrealistic blast goals can set up the operations to fail or get frustrated in trying to work on an impossible task. The problems and risks of phase interactions for many open pit operations need to be considered in the design process, along with designed controls that minimize the probability of any safety incident. Mine designs are being created in the industry and do not consider phase-to-phase mining interaction and the impact it would have on safety or production. The best future for safer mines is blast patterns that reduce spillover between phases of mining and pit designs that might account for spillover interaction.

Jan 1, 2024

By Roderick C. McDonald

Great Bear lake, the fourth largest body of water on this continent, comprises an area of approximately 12,000 square miles, and is set astride the Arctic circle, with a large portion of it witnessing both the Arctic winter night, and the Arctic summer day with its midnight sun. The very name itself, Great Bear, suggests an Arctic region. The seasonal contrasts at Great Bear lake are very marked by the cold and darkness of winter, and the warmth and brightness of summer. Signs of winter such as low clouds, snow, sleet, fog, and night frosts, generally appear the latter part of August, while ice forming on bays during the last two weeks in September ends boat travel on the lake about September 30th.Early in June the ice leaves the river mouths, during the last ten days of the month it disappears from small bays, and at some time during the last two weeks of July the main body of the lake becomes navigable. In 1916, the ice disappeared earlier than usual, and the lake was navigable on July 5th. Great Bear river generally breaks up about June 1st, but, on account of ice cliffs and floes, it is not navigable with safety until early in July. Even then, the traveller is confronted with the Charles rapids, but these might be overcome by a wagon or motor road, such as the one from Fitzgerald to Fort Smith: However, in 1931, Mr. A. W. Boland, Fort Norman, N.W.T., carried with scow and motorboat practically all freight between Fort Norman and LaBine point and Hunter bay, at the east end of the lake. During July and August, two types of clothing are required, for, although the days are mainly ones of warm sunshine, the nights are cloudy and cold. In the winter season, fur clothing is used exclusively. Considerable timber, mainly white spruce, suitable for fuel and building purposes, borders the lake and extends eastward to the Coppermine river. North of the lake, no timber is found except in the river valleys, but with oil and coal possibilities near Fort Norman, the fuel situation might be solved.

Jan 1, 1932

By Volker Uhlenwinkel

The design of a free fall atomizer as well as the process parameters affect the particle mass flux distribution in the spray cone. The mass flux distribution is important in spray forming because of its influence on the deposit shape and enthalpy input into the deposit. In this article the effect of different process parameters on the mass flux distribution is shown. Furthermore, different melts were atomized with the same atomizer. An empirical correlation will be introduced to predict the mass flux in the spray cone. This correlation will be compared with experimental results.

Jan 1, 1999

By John A. Riddle

Some of the pitfalls and problems in selecting and applying corrosion-resistant materials in uranium plants are discussed, together with some suggested solutions. Includes some cost data.

Jan 1, 1982

By J. P. Gous, J. J. Sutherland

"Transalloys is a silicomanganese (SiMn) producer located in South Africa, and uses only local manganese ores to produce SiMn alloy. The plant operates five open submerged arc furnaces (SAFs) with an annual capacity of 180 000 t of saleable SiMn.Maintaining tap-holes is critical for effective furnace operation, allowing proper drainage of the furnace with minimal operator interference. Using a claygun and drill arrangement installed at each furnace, tapping occurs every four hours. Tap-holes are maintained through mickey replacement and brick repairs. Three furnaces have SiC tap-holes and two have graphite tap-holes.This paper gives a review of SAF operation, furnace and tap-hole design, daily tapping operation, and maintenance practices for repairing tap-holes.IntroductionDefining tap-hole life cycle, Steenkamp et al., (2016) highlighted four main steps: installation during furnace relines, day-to-day operations, tap-hole maintenance, and tap-hole repair. The authors argued that the design of the tap-hole area should allow for all four stages in the tap-hole life-cycle. Design principles for each stage were presented using silicomanganese (SiMn) production as a case study. Here we present a further analysis of the case study by providing practical examples of how the tap-hole life-cycle is managed at Transalloys during the design, operation, and maintenance of submerged arc furnaces (SAFs) applied in the production of SiMn.BackgroundTransalloys is the largest producer of SiMn in Africa. Its smelter complex is based outside the town of eMalahleni, in the Mpumalanga Province of South Africa. Transalloys was commissioned in the mid- 1960s as a high- and low-carbon ferrochromium plant based on the Perrin process. In 1967 the plant was converted to SiMn production because of constraints in the ferrochrome market (Basson, Curr, and Gericke, 2007; Bezemer, 1995). Today, the installed production capacity is 180 000 t of SiMn annually. Plant operations consists of five SAFs (see ratings in Table I), operating 24 hours a day, 365 days a year (including maintenance), involving 280 permanent employees, with up to 120 contract employees on site at any given time."

Jun 1, 2019

By Marcel Vallée

"This text consists of two parts, comments on "Classification and Reporting of Mineral Resources for High-Nugget Effect Gold Vein Deposits," by S.C. Dominy, P.R. Stephenson and A.E. Annels, Volume 10, No. 3, pp. 215-233, and related comments on some features of the JORC Code.This paper is, in many respects, a very elaborate and valuable account of the problems encountered in the estimation and classification of high-nugget gold deposits. However, in some key areas, it appears to fall short of its objective to help "resolve satisfactorily most issues" and "contribute to improved estimation and classification" (abstract). One must realize that high-nugget effect gold deposits constitute a very narrow field, despite the occasional bonanzas. This is a field of mostly smaller sized deposits, where limited success and a significantly higher rate of failure occur relative to larger deposits of mostly lower grade. This is shown by the six deposits described in the paper. Thanks for contributing to greater understanding of these complex and nevertheless challenging deposits."

Jan 1, 2002

By V. Ramachandran

The successful advent of solvent extraction (SX) reagents for copper recovery and improvements in electrowinning of copper to produce LME grade A copper cathode have paved the way for the hydrometallurgical treatment of copper oxide and low grade sulfide ores. This has resulted in about 25-30% of the world's copper being produced today by the Leach-SX-EW process. The obvious next step was to develop processes for the hydrometallurgical treatment of copper sulfide concentrates, as an alternative to a typical smelter-refinery complex. The current paper updates the processes that have been developed to date with emphasis on processes that are being commercialized or that are seriously under consideration for commercialization. Most of the discussions relate to the hydrometallurgy of chalcopyrite concentrates, which account for about 70% of the world's known copper reserves. In summary, in the last thirty years, the hydrometallurgical treatment of copper sulfide concentrates has attained full maturity and will be a serious option to contend with while evaluating any future new copper plant.

Jan 1, 2007

By W A. Tchernykh, R P. Strelnikova

In connection with the fact that technology of ore mining by caving system is often used when mining of deposits, characterising by low stability of surrounding rock mass, the main problem for such ore mines is ensuring stability of mine workings, placing in a zone of influence of winning operations. Besides natural disturbance of ore mass, stability of workings depends on the dynamic effect of blasting operations and also on the dynamic effect of structural blocks detaching from the ore mass and colliding with crests of ore pillars in the bottom of a chamber. Decreasing of dynamic stresses may be achieved by way of creation of a compliant porous screen or an ore cushion in the chamber bottom. It is established that maximum levels of compression take place when the first impact impulse occurs, and after that increase of compression of protective slice decreases. Necessary thickness of screen slice was substantiated theoretically with due account of height of structural blocksÆ fall, their mass, deformation modulus of ore mass and ore cushion.

Jan 1, 2003

By Jim Weeks

In July 1986, the United Mine Workers of America (UMWA) asked Secretary of Labor William Brock to form an advisory committee to advise the Mine Safety and Health Administration (MSHA) on rules and regulations concerning the use of diesel powered equipment in underground coal mines. The request was made under the Mine Health and Safety Acts of 1969 and 1977. The union's principal concern was with the chronic and acute health effects of breathing diesel exhaust. In July 1988, the advisory committee recommended that MSHA promulgate a variety of health and safety regulations. It also concluded that diesel particulate matter should be considered carcinogenic (MSHA, 1988). Now, seven years later, there are nearly twice as many pieces of diesel powered equipment in underground coal mines. MSHA, however, has not promulgated a single regulation to govern the use of this equipment. MSHA must fulfill its public responsibility to protect the health of miners. Regulations that take account of the considerable body of knowledge concerning these health effects must be a top priority of the incoming assistant secretary of labor for MSHA.

Jan 1, 1993

By James R. Garvey

Coal reserves of the United States are enormous. Considered on the basis of proven reserves, and compared with reserves of other fuels, coal constitutes 88% of the proven recoverable energy resources of the nation. That includes oil, natural gas, oil shale and uranium used in burner reactors. Considered on the basis of "ultimate recoverable reserves", that is, those resources which can be extracted with improved technology and at somewhat higher costs and including those resources of all fuels not yet found but believed to be waiting discovery, coal still accounts for 75 % of the national total. In the U.S. hydrocarbon economy about 76% of the total energy needs are supplied by petroleum and natural gas and about 20% by coal. Domestic resources of oil and gas are running dangerously low, and assuming a continued hydrocarbon economy, the 20% supplied by coal may increase dramatically. Nearly a quarter of the petroleum consumed in the U.S. is imported. Natural gas is in shorter supply than petroleum and the problems of its importation seem at least as difficult as those of oil.

Jan 6, 1972

By D Brennan, S Jahanshahi, F Jorgensen

The recycling of metals can be very efficient with careful selection of the material being recycled. The volume and value of recycled ferrous scrap has lead to the development of steel mini-mills which in turn has caused major changes to the steel industry. Although much smaller in volume, the recycling of lead is very significant, with battery recycling accounting for 60 per cent of annual world production. This high recycle rate can be attributed to the relatively uniform feed-stock from lead-acid batteries. The recycling rates of other metals are considerably lower due to longer use and non-uniform product usage that results in less efficient segregation and processing. It is clear that recycling of metals has advantages but its sustainability is uncertain. What are the key benefits of metal recycling? Metal recycling has technical, economic and social impacts. It is relatively easy to assess recycling on a technical basis, but the social impacts are harder to evaluate. This paper examines some of the issues in evaluating the sustainability of metal recycling.

Jan 1, 2002

Computers are playing an increasing role in the management of technical data in mines. Companies are re-assessing the role of their data processing departments as users demand computer resources in non-accounting areas. Data of all kinds is now being seen as a, company resource, and the role of computing professionals is to help to manage the data flow, not merely to manage computers. The concept of distributed data bases puts the responsibility for data entry, editing and updating with the user. This challenges conservative views of centralized control of computing, suggesting, instead, centralized co-ordination. A survey of the possible applications of computers in technical areas points up the special requirements of handling raw, processed and consolidated technical data. Technical data bases have become flexible as mini- computer hardware and software have rapidly developed. Management has the ultimate responsibility for efficiently administering corporate data bases, and it must ensure suitable policies are developed for this purpose, with enough flexibility to cope with the impact of fast changing technology.

Jan 1, 1980