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By B. McFadzean, S. Pikinini, C. T. O’ Connor

Sperrylite (PtAs₂) comprises about 21% of the platinum group minerals (PGMs) in the Platreef ore and regularly reports to the tailings due to its poor floatability. Hence, improving its recovery will be of great economic value to the South African PGM industry. The reasons for its poor floatability are not yet clear. This paper seeks to understand the interactions occurring between PtAs₂ and common thiol collectors, viz. potassium normal butyl xanthate (PNBX), sodium normal dibutyl dithiophosphate (SNBDTP) and sodium normal mono butyl dithiocarbamate (SNBDTC). By understanding its interactions with these collectors, it is hypothesised that it will be possible to suggest ligands that may help improve the floatability of sperrylite. Mineral-collector interactions were studied by determining the molar energy of interaction using isothermal titration calorimetry and electrochemical techniques. The hydrophobicity of the mineral before and after adsorption of the collectors was determined by heat of immersion and its flotation response determined by microflotation tests. Microflotation tests using synthetic sperrylite at pH 9 showed low collectorless recovery of 34.8% and after adding the equivalent of one pseudo-monolayer of the PNBX collector, the recovery of 32.5% was obtained. Moreover, the addition of up to three pseudo-monolayers coverage of PNBX did not result in any increase in flotation recovery. A small recovery improvement was noted when synthetic plant water with the ionic strength of 0.0484 mol/L was used, but this did not hold for all collectors, with SNBDTP exhibiting higher recoveries in distilled water. Keywords: Sperrylite; flotation; recovery; adsorption energy; collectors; 2SPW (synthetic plant water)

Jan 1, 2020

By Antony Amberg, Gonzalo Saldías, Romke Kuyvenhoven, Catherine Souza, Heriban Soto, Francisco Soto

"Vizcachitas is an advanced stage copper–molybdenum porphyry deposit, fully owned by Los Andes Copper and located in Central Chile. The property contains an indicated resource of 1,038 million tonnes grading 0.37% Cu and 0.012% Mo, and an inferred resource of 318 million tonnes grading 0.345% Cu and 0.013% Mo (Coffey & Alquimia, 2014). The deposit occurs in the same geological belt as several other giant copper-molybdenum porphyry deposits including Río Blanco-Los Bronces, Los Pelambres-Pachon and El Teniente. In 2018, the original Preliminary Economic Assessment (PEA) study from 2014 was updated; this paper presents the geometallurgical testwork that was performed to support that update. The testwork focused on the metallurgical characterization of 40 DDH samples and the development of a more profound orebody knowledge by relating geological features with metallurgical performance. The scope of work included complete chemical and mineralogical QemSCAN characterization; SAG, ball mill and abrasion testing; complete rougher and cleaner kinetics including locked-cycle-test; environmental ABA and settling tests on rougher tailings. The results show that the ore can be classified as medium-hard, with a hardness that is slightly below the average for large Cu/Mo deposits in the region. A good correlation was found between lithology and breakage characteristics, implying that the specific energy consumption (kWh/t) is well correlated to rock type. The results of the flotation tests were very encouraging and did not show significant variability. An overall Cu recovery of 91% can be expected for the flotation circuit. The use of a relatively coarse primary grind size gave good final recovery and grade for both Cu and Mo, and deserves further attention in future work, as this impacts positively both energy consumption and water recovery.INTRODUCTION Los Andes Copper Ltd. is a Canadian exploration and development company focused on the acquisition, exploration and development of advanced stage copper deposits in Latin America. The company owns 100% of the Vizcachitas project in Chile, the largest copper deposit in the Americas not controlled by the majors. Vizcachitas is a copper-molybdenum porphyry deposit, located 120 km north of Santiago, in an area of very good infrastructure."

Jan 1, 2018

By W. H. Zieman

NORMAN WEISS, Milling Engineer, American Smelting• and Refining Company: The subject of the Forum on Rod and Ball Mill Liners is very fascinating, and there is no end of discussion when operators get together on grinding. However, the hypotheses and suppositions easily outrun the facts, especially when we •consider the inaccuracy of many reported observations. Still surprisingly small is the number of concentrators even reasonably well equipped to measure power consumption of each grinding mill, together with running time, so that data on this tangible factor, at least, can be obtained with precision. While the more elaborate devices of this nature, producing for each 24-hour period the total power consumption, average kilowatt hours per hour, short-term demand chart, instantaneous demand, and print-out, may cost in the neighbourhood of $2,500 per mill and may be difficult to justify, the combination of an ammeter, watthour meter, and running-time meter will cost only a few hundred dollars, so there appears to be little reason not to in-stall them in view of their numerous advantages.

Jan 1, 1959

By J F. H Thompson

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Mineral exploration and mining are challenging businesses. Remote and at times harsh conditions have always made it difficult for exploration, but modern explorers also have to deal with cover, numerous technologies, an explosion of data and critical early community engagement. Mining deals with the reality of moving and breaking thousands of tonnes of rock each day to extract what can be a very minor component of economic value, and, furthermore, society expects that this will be done in a clean and sustainable manner. The exploration and mining challenges appear disparate, but they are intimately related.Although not widely appreciated, both exploration and mining have a long tradition of innovation. Over the last 50 years, major step changes in exploration have resulted from radical advances in our understanding of ore forming processes, new geophysical, geochemical and remote sensing technologies, and new ways to integrate and interrogate data. Over a more extended period, close to 100 years, mining has developed bulk surface and underground methods, selective extraction through flotation and leaching and global positioning system–geographic information system control systems that collectively facilitate mining at a massive scale. And yet, in spite of these successes and the boom that we have enjoyed in the last ten years, the industry is under pressure and the need for innovation and change is paramount.The major drivers for innovation are the need for increased quality in discoveries and mines and the need to interact effectively with communities and jurisdictions such that the benefits of quality mines are recognised and enjoyed widely.We are still making new discoveries around the Pacific Rim and elsewhere, but many argue that the quality – grade and accessibility – of these discoveries is decreasing. The net result is that explorers are delivering resources and reserves for development at lower grades and with higher capital and operating costs than current operations. For mining, the increasing age of many existing operations contributes to increasing costs, which, when combined with decreasing cut-offs and lower grades, also results in declining quality. The combined picture does not look good.Just as the pressure to improve performance and margins in the face of declining inputs increases, we are simultaneously faced with increasing societal demands for improved environmental performance and sustainable practices. This is most apparent at the local, community level, where opposition ultimately leads to delays or even cancellation of new projects. Quality is again the issue – quality of the initial and ongoing engagement and quality of the proposed mine in terms of environmental and economic performance.CITATION:Thompson, J F H, 2015. Exploration and mining – the need for innovation , in Proceedings PACRIM 2015 Congress, pp 45–48 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By F G. Cooke

"This paper describes a medium-sized copper mine's results in making innovations and changing operational practices to combat increasing expenditures due to higher labour and supply costs, extended workings, scarcity of experienced manpower and problems created by deteriorating ground conditions.OPEMISKA COPPER MINES (QUEBEC) LIMITED is located at Chapais in the Chibougamau area, in central eastern Quebec, approximately 300 miles north of Montreal and 150 miles north west of Lake St. John. The latter area, developed by lumbering and farming, has supplied the majority of the employees, who, with training and experience and a desire to work and improve themselves, have become the backbone of the Company's 600 personnel.Opemiska began production in 1954 at a rate of 400 tons per day, using diesel power and road transportation. The rate was progressively increased and, by 1959, with hydro-electric power and rail transportation, the mine had reached its present production rate of 2,000 tons per day. It has produced concentrates containing over 430 million lbs of copper."

Jan 1, 1968

By Norbert Steiner

For the desulfurization of weak SO2 gas streams, Degussa developed a process using dilute H2SO4 solution containing H2O, instead of conventional gas scrubbing with all solid absorbent medium (limestone, MgO). The process is based on fast reaction of H2O, with SO2 yielding H2SO4 up to 70% strength, depending on off-gas temperature. Compared to the conventional systems with typically < 95% efficiency, independent on the raw gas SO2 concentration, residual SO2 concentrations of less than 20 mg/Nm3 can be easily achieved, corresponding to nearly 100% removal. These features render the H2O, process a very attractive, low capital cost technology to retrofit existing conventional desulfurization plants.

Jan 1, 1996

By N. D. Jagger

In order to maximize the benefits obtained from flocculating agents when used as settling aids in high rate and conventional thickeners, it is often necessary to dilute the thickener feed prior to flocculant addition. In some cases, no flocculation at all is possible unless dilution water is used. The most common method of diluting thickener feed has been to recirculate some of the thickener overflow by means of a centrifugal pumping system. This represents a significant capital and operating cost. Supaflo Technologies of Australia has developed and patented an internal recirculation method known as Auto Dilution (or "Autodil") which is based on the principle that an hydraulic head differential exists between the inside and outside of the feedwell because of the higher S. G. of the pulp inside the feedwell, By installing non-return ports in the feedwell wall at the appropriate level, supernatant solution flows into the feedwell at a calculated rate and dilutes the feed without any need for external recirculation of overflow.

Jan 1, 1993

By Timothy Flaherty

We observed the boiling in the water very close to the water adjacent to where we were drilling. That only happened at the very beginning before it was switched to water flushing. Yes, it was performed with water flush.

Feb 10, 2003

By Alexander N. Winchell

"The deposits of the east end of the Mesabi Range cover very large areas, and consist of the same taconite that produces the hematite of the central and western Mesabi. It is not deeply covered with drift, but outcrops boldly in large masses. It is not concentrated locally into enriched bodies separated by leaner areas, but is all a fairly uniform, hard, banded, unaltered chert, carrying about 25 to 30 per cent iron as magnetite.The Mesabi Iron Company, organized by Hayden, Stone & Co., and under the direction of D. C. Jackling, has taken over these deposits and is building a Concentrating plant at the new town of Babbitt, about fourteen miles east of Mesaba, Minn. This plant is to have a capacity of 2,000 to 3,000 tons per day, and is based on the application to this low grade material of the methods which have made the so-called porphyry copper properties so successful.In 1916, an experimental mill was built in Duluth; containing full sized machinery and capable of handling from 100 to 200 tons daily. A considerable tonnage of material was concentrated here during 1916, 1917 and 1918. The work showed that the resulting product could be varied, almost at will, between 60 per cent and 70 per cent iron and .006 per cent to .030 per&apos; cent phosphorus, and that this could be made on a large scale well within the limits of cost set by iron trade conditions. A small special cargo was sent down the lakes, late in 1918, assaying 63.27 per cent iron (natural and dry) and .008 per cent phosphorus; but it is assumed that large scale shipments will normally be of a Bessemer&apos; grade carrying about 63 per cent iron and .020 per cent to .030 per cent phosphorus. This material is a sinter, carrying only traces of sulphur and titanium, with silica between 6 per cent and 10 , per cent, and alumina, lime, magnesia, and manganese, each below 1 per cent. Some of the iron in this sinter is hematite and some is magnetite, the percentages varying according to the treatment given on the sintering machine. Like the analyses, this hematite percentage is within reasonable control. Sinter made from finely ground magnetite has much the structure of coke, being firm yet porous, and gives good account of itself in the blast furnace."

Jan 1, 1920

By L. C. de Kooker, K. Esmaeili, I. Musonda, M. Ferentinou

This paper presents the results of an investigation into the effect of pore pressure regime on the factor of safety (FS) and the anticipated critical failure mechanism for a fly ash storage facility. In this study, pore pressure measurements from standpipe piezometers and pore pressure estimated from seepage analysis were used for a comparison of the estimated FS for a fly ash slope. This comparison was applied for static and seismic scenarios. To account for the uncertainties resulting from the limited data available and support a qualitative risk assessment evaluation, a probabilistic analysis was performed. The slope stability analysis was conducted in 2D and 3D, adopting the limit equilibrium analysis approach, and a finite element seepage analysis. The results suggest consistency of failure surfaces for 2D and 3D and an increase in FS values of 5 percent for the 3D approach, limitations of standpipe piezometers. The study demonstrated the sensitivity of the FS value, and the implication of adopting representative material properties, and water table levels, especially in cases where limited data are available, and assumptions need to be made to assess the long-term stability of a fly ash dam facility.

Aug 1, 2024

"U.S. Bureau of Mines Publications and Articles, 1994 with Subject and Author Index Compiled by Office of Public Information U.S. Bureau of Mines (USBM) Department of the InteriorINTRODUCTIONThe U.S. Bureau of Mines (USBM) was established in 1910 to conduct inquiries and scientific and technological investigations on mining and the preparation, treatment, and use of mineral substances; to promote health and safety in the mineral industries; to conserve material resources; to promote economic development; to increase efficiency in the mining, metallurgical, quarrying, and other mineral industries; and to inquire into the economic conditions affecting those industries. The organic act of the Bureau, as amended by Congress and approved February 25, 1913, made it the province and duty of the Bureau of Mines to ""disseminate information concerning these subjects in such manner as will best carry out the purpose of this Act.""In accordance with this directive, USBM reports the findings of its research and investigations in its own series of publications and also in articles that appear in scientific, technical, and trade journals; in proceedings of conventions and seminars; in reference books; and in other non-USBM publications. This edition describes reports and articles published during calendar year 1994. It supplements the 50-year list of Bureau publications issued from July 1, 1910, to January 1, 1960; 1 the 50-year list of articles by Bureau authors published outside the Bureau from July 1, 1910, to January 1, 1960; 2 andthe 5-year lists of publications and articlesfrom January 1, 1960, to December 31, 1964,3from January 1, 1965, to December 31, 1969,4from January 1,1970, to December 31,1974,5from January 1,1975, to December 31,1979,6from January 1,1980, to December 31,1984/and from January 1, 1985, to December 31,1989.8"

May 1, 1995

By M Camarda, A Pirson, F Vasconcelos, J Mesquita

ArcelorMittal Prijedor is a goethitic iron ore mine located in the north-west of Bosnia and Herzegovina, which mainly supplies ArcelorMittal’s European subsidiaries. Annual production of the asset stands at the level of 1.5–2.1 million tons of iron ore product which is sent to ArcelorMittal Zenica steelmaking plant. Two types of products with approximately 50 per cent Fe are generated in Prijedor through a process composed by crushing, screening, and magnetic separation stages. Within this process one of the tailings produced is called ‘ultrafines’. The ‘ultrafines’ product corresponds to the desliming hydrocyclones overflow in Prijedor plant, which is classified in a size fraction below 25 μm and corresponds to about 5 per cent of feed. This material is richer in iron than the coarser size fractions of the ore but do not present a good performance in concentration processes. In this way, several studies have been carried out during the last years to find solutions to use the ‘ultrafines’ material without success. In this context, the possibility of dehydroxylate the goethite contained in the material transforming the mineral into hematite and thus increasing the iron grade of the final product was investigated. During the research, several dehydroxylation tests with different temperatures and time of exposure were performed. Using dihydroxylation process at temperatures higher than 800°C it was possible to produce a material with 43 per cent Fe from the original 39 per cent Fe ‘ultrafines’ sample. In addition, the dehydroxylation tests confirmed that goethite becomes completely transformed into hematite at 400°C (with an exposure time of 60 mins) and material is completely sintered at 1200°C. A simulation study based on dehydroxylation tests results showed that it would be possible to use a ‘ultrafines’ product with Fe grade higher than 45 per cent to produce a material with 50 per cent Fe through a complete dehydroxylation process.

Sep 18, 2023

By Boyd GL

Backfill applied to highwall mining is foreseen as a means to increase recovery of mineable coal to levels comparable with underground longwall mining. This paper describes the progress of research to demonstrate the role required of backfill to achieve real increases in coal rCCOvCrCd h\ hi&apos;eh ss-all mining methods.

Jan 1, 1998

By H. R. Kempthorne

"The Property of Bevcon Mines Limited, including a recently acquired adjoining south group, occupies an area of 2,625 acres in northeast Louvicourt township, Abitibi county, Quebec. It is situated 17 miles east of Val d'Or at the junction of provincial highways 58 and 59.Gold was first discovered in the area in 1931 by the late S. B. Jowsey on the present property of Buffaddison Gold Mines adjoining to the west. However, it was not until the winter of 1944-45 that diamond drilling encountered encouraging results on the Bevcon claims. During the period 1946-1948 a shaft was sunk to 1,000 feet and considerable development undertaken from the 500-foot to the 1,000-foot levels. Between 1947 and 1950 approximately 24,000 tons of dump ore and 48,000 tons of ore by stoping were milled at Perron Gold Mines. The favourable results of these tests prompted the decision to construct a milling plant at Bevcon. The mill began operating in July 1952, and presently has a capacity of 800 tons per day. In 1953 the shaft was deepened to 1,600 feet and is currently (1955) being driven to 2,225 feet.Total production of gold to the end of 1954 has been 101,024 ounces from the milling of 697,427 tons of ore of an average grade of 0·163 ounces per ton.GeologyThe Bevcon orebodies occur in a granodiorite stock which has an east-west length of approximately 4 miles and a maximum width of 1 1/2 miles. The property covers the central portion of the stock and its contacts with the Keewatin volcanics. Approximately one-third of the northern contact and one-half of the southern contact are contained within the Bevcon claims. The granodiorite has been cut by acid (feldspar porphyry) and basic dykes trending east-west. A younger diabase dyke, 300 feet wide, strikes northeasterly across the property 1,000 feet east of the shaft.The main ore zone, striking east-west, lies between the more northerly porphyry dyke and the north granodiorite-greenstone contact. It has been extensively sheared, fractured, altered, and mineralized by gold-bearing solutions. It is approximately 2,000 feet Jong from the west boundary towards the diabase dyke. The shaft is centrally located and passes through the south contact of the ore zone at the 500-foot level. The zone increases in width and trends northerly with depth, due to the porphyry and greenstone contacts having average dips of 80 degrees and 70 degrees respectively to the north. Thus on the uppermost or 500-foot level the width is 150 to 200 feet, and at the present bottom level at 1,600 feet the width is 400 to 500 feet.Another gold-bearing zone has been indicated 200 to 400 feet south of the main ore zone by limited surface drilling."

Jan 1, 1949

By J. Kallioinen

Theoretical considerations, experimental results and plant experience have lead to a new design concept called the unit reactor approach. It has been successfully implemented to the largest flotation cell on the market, the 4000 cu ft OK TankCell. The work has also lead to a new operating idea called size specific flotation. The paper discusses these concepts in the view of full scale field experiments. In large scale porphyry copper flotation experiments conducted in Chile the new large TankCell with its new low energy input Free Flow mechanism out-performed the more conventional designs. The recovery was substantially better, especially in the coarse fractions. In some experiments the difference in total recovery was up to 10%-units and the savings in total energy consumption at the same time over 40%.

Jan 1, 1995

Both the miner and the Regional Water Board have legal obligations to ensure that all discharges of water from a mine site are free of harmful wastes, and that proper authorisation is obtained to abstract, divert, or discharge water. This requires long-term planning of water management for the whole of the mine site. Guidance is given in the paper on the issues which must be covered in water right applications.

Jan 1, 1986

By Grigory Voyloshnikov, Sergey Petrov, Vladimir Petrov

"The treatment of high-grade copper gold-bearing ores is practiced extensively. However, due to low concentration of copper the application of a separate process for copper recovery can make this process uneconomical. The copper, in particular: in oxide minerals, intensively bounds with cyanide during conventional cyanidation. In this case, cyanide is not able to react with precious metals and the consumption of cyanide increases. The resulting copper cyanide complexes have a negative effect on the recovery of gold. Due to decreasing of the process parameters, a repeated use of the recycled solutions can be hindered, especially in the case of heap leaching. The technology of copper removal from the process solutions with simultaneous regeneration of free cyanide from copper-cyanide complex and producing of a saleable high-grade copper concentrate was developed. An important feature of this technology is simplicity, the absence of complex or dangerous operations and the use of common reagents. The choice of equipment depends on the ore treatment option: heap or vat leaching. Also, simpler equipment schemes are available. The studies, tests and industrial practice show that if the concentration of copper can be decreased down to the first numbers of mg per ppm or lower, it is reasonable to maintain the process copper grade in the recycled solutions at 30-50 mg/L. In this case, recycling of cyanide-bearing solutions is unlimited. The regeneration of free cyanide from that of bound with copper and other cyanide complexes is 95-98%. The grade of copper in the concentrate is 55-60%. This technology is an economically competitive option, in particular: with the account of the sales of copper concentrate. The removal of copper has a positive effect on gold recovery, especially during heap leaching. In addition to, this offers significant benefits in reduced costs."

Jan 1, 2014

By Edward S. Hsia

Pluor Utah has been closely associated with the engineering and construction of earth bottom thickeners for porphyry copper operations, for the counter-current decantation circuit of a gold cyanide plant and similar applications in mineral processing. During the past 13 years, some 18 of these thickeners have entered service and the bottoms have proved to be watertight structures with no particular problems encountered. In the course of this work, technological advances have been realized in the procedures for engineering and construction of these units to assure watertight basins and achieve all possible economies in construction. This paper describes the successful application of engineering and construction techniques for a number of these thickeners.

Jan 1, 1977

By C. P. Mabie

This report summarizes studies by the Bureau of Mines in developing a simple method for estimating the phosphorus pentoxide (P205) content of finely ground sedimentary phosphate ores and beneficiated products. The method used involved leaching, filtration, and precipitation. The Bureau found that measurement of the volume of ammonium phosphomolybdate precipitate obtained from samples containing 16.8 to 37.7 percent P205 and the use of an appropriate calibration curve permitted estimates of percentage of P205 content accurate within ± 1.1 to ± 2.6 percent, respectively, at the 95-percent confidence limits. Incidental to mineral dressing and petrographic investigations of western phosphate ores in 1959, the Bureau of Mines undertook development of a simple process-control method for rapid on-the-spot evaluation of phosphate-mineral recovery. Because of the fine-grained and obscure character of western phosphate ores, chemical, rather than microscopic or petrographic, techniques were investigated. The described method involves acid decomposition of the ore or product, filtration, addition of ammonium molybdate reagent to the filtrate, and centrifuging and measuring the volume of yellow ammonium phosphomolybdate precipitate produced.

Jan 1, 1961

By L. MacHue

Sulfur containing collectors have been shown over the years to function as strong, selective and non-selective sulfide mineral collectors. Unfortunately, the majority of the widely known sulfur based collectors are of low molecular weight, volatile and subsequently, possess an objectionable odor. Higher molecular weight sulfur based collectors (C9 and higher) are significantly less odiferous due to lower volatility and lower vapor pressures. In this study, a specific proprietary higher carbon number collector, Orfom® MC 37, was blended and used successfully to recover 2-3% additional molybdenum in a laboratory flotation system, when compared to a standard collector blend. Copper recoveries were also positively affected. Further testing is required to give additional conditions favorable to increased copper and molybdenum recoveries, but indications at this time show the proprietary sulfur based collector blend to be a selective collector of molybdenum, while providing a significant increase in copper recoveries.

Jan 1, 2010