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By J. A. Eisele

The Bureau of Mines has reviewed the literature related to the recovery of A1203 (alumina) from coal ash. A small amount of unpublished data is also reported. Of the processes studied, the alkaline-sinter process is the most promising from a technical standpoint. However, owing to the high cost of processing coal ash, the dispersed location of powerplants, and the domestic availability of higher grade alternate materials, coal ash does not rank as a primary source material for replacing imported bauxite.

Jan 1, 1979

By G T. Hefter, P Singh

The effect of using SO2 as an anodic depolariser in the electrowinning of copper from aqueous acid sulphate solutions has been studied using cells without/with a ceramic diaphragm. In all cases SO2-saturation of the electrolyte/anolyte decreased the anode potential by 68 to 75 per cent largely due to a change in the anode reaction from the oxidation of water to the oxidation of SO2 . However, poor quality deposits and low current efficiencies are encountered if SO2 is allowed free-access to the copper being deposited at the cathode. This situation is easily avoided by using a diaphragm to restrict SO2 to the anode compartment and for these conditions the resultant copper deposits are of a similar (high) quality to those obtained in the absence of SO2.

Jan 1, 1999

By Robert L. Grayson, Syd S. Peng

"An airborne dust study was undertaken at a Southwestern Pennsylvania underground bituminous coal mine by the Pennsylvania Department of Mines and Mineral Industries in 1964 for the purpose of making recommendations and requirements regarding compliance with health and safety aspects of The Bituminous Coal Mining Laws of Pennsylvania, approved by the legislature on July 17, 1961. The study was designed to accurately represent the airborne dust conditions of the subject mine. Sampling by midget impinger of specific worker locations throughout the mine was accomplished. Sample analyses yielded dust concentrations to mppcf, particle size determinations in cumulative per cent less than specified cut-off diameters, and determinations of free silica percentages in total dust samples. The data from this study is further analyzed, and the results are presented.INTRODUCTIONThe Bituminous Coal Mining Laws of Pennsylvania, enacted in 1961, prompted a study of respirable coal mine dust by the Department of Mines and Minerals Industry in 1964. In recognition of their obligation for ensuring the health and safety of bituminous coal miners, the department set out to characterize the airborne dust of mines throughout the commonwealth. The purpose of the studies was to make recommendations and requirements for compliance with the law and for control of airborne coal mine dust in Pennsylvania mines.One such study was undertaken at an underground bituminous coal mine operating in the Pittsburgh Seam in Southwestern Pennsylvania. The study was desig11ed to sample specific worker locations throughout the mine site and characterize the respirable dust relative to each of them. A midget impinger was used to gather respirable range dust samples during an 8-hour shift. Continuous miner operator, roof bolter, stoper bolter, loading machine operator, shuttle car operator, gathering motorman, mainline motorman, and rotary dumper jobs were sampled underground. In addition, barge mover, coal sampler, fine coal operator, heavy media operator, and boiler room attendant occupations were sampled on the surface. The surface sampling was over a 71-hour shift because of UMWA contract provisions."

Jan 1, 1988

By M. E. Rossi

Reconciliation of production information is critical to evaluating the effectiveness of the predictive models, and to allow for optimization of mining operations. Whether mining open pit or underground, mine-to-mill reconciliations can be one of management's better tools to perform proper accounting, and a very useful evaluation and optimization tool. This paper proposes a set of criteria and objectives for a typical reconciliation program; also presents a stepwise, logic approach to performing reconciliations, and discusses the benefits and costs associated with the up-keeping of the information. It also highlights some of the potential pitfalls involved, and methods used to avoid collecting misleading information. These issues are illustrated with an example of a model-to-mine-to-mill reconciliation program being implemented at an operating mine; the program involves multiple predictive models (Long-term and Short-term block models), different open pit and underground mines, stockpiling, and at least 23 different mill streams. This paper presents the initial results of the program implemented at Minera Michilla S.A.

Jan 1, 1999

By H. Wotruba, L. Gronen, A. Hellmann, S. Sindern, J. Katzmarzyk

"This paper focuses on the beneficiation of the REE-Y-Nb-Zr complex ore from the ‘Khalzan Buregtei’ deposit, Mongolia. Pre-concentration based on mineralogical studies was investigated at the Unit of Mineral Processing (AMR) and the Institute of Applied Mineralogy and Economic Geology of RWTH Aachen University. In order to minimize the energy consumption in the most energy intensive grinding process a pre-concentration process using dry magnetic separation of particle sizes coarser than required for the liberation of the valuable ore minerals was designed. Dry magnetic separation in the particle size range of 63-250 µm is suitable as the pre-concentration method, due to the intergrowth of REE-Y-Nb-Zr bearing minerals with magnetic minerals determined by QEMSCAN© analysis. The results showed that a mass reduction of 45.3 wt.-% at high recoveries of REE, Y, Nb and Zr (90 wt.-% and higher) in the pre-concentration product was achieved at the beginning of the process chain. The improvement of process efficiency as shown in this study depends on the abundance and association of minerals affecting the magnetic properties (e.g. hematite) of the ores. Therefore, these mineralogical parameters are as important as grain size and ore grade for the geometallurgical evaluation of potential mining operations at ‘Khalzan Buregtei’.INTRODUCTION Polymetallic deposits containing other critical elements besides REE have the advantage of being robust to economic development and fluctuations of individual metal prices. (Gronen et al., 2016). These deposits can host economic grades of heavy and light REE, Y, Nb, Ta, Zr in complex mineralogical compositions. About 120 deposits of this type are known worldwide, including ‘Norra Kärr’ in Sweden, ‘Strange Lake’ in Canada and ‘Khalzan Buregtei’ in Mongolia which are not valued economically yet. (Salvi. & Williams-Jones, 2004.)"

Jan 1, 2018

By B. J. Scheiner

Extraction of molybdenum from molybdenite ore by an electrolytic oxidation procedure was investigated by the Bureau o f Mines. Various parameters affecting molybdenum extraction, such as salt concentration, temperature, treatment rate, current density, and particle size, were studied. Molybdenum extraction of 95.2 percent was achieved on a laboratory scale from an ore containing 0.35 percent molybdenite. Corresponding power consumption was 24 kwhr per pound of molybdenum extracted with a base consumption of 4.5 pounds of sodium carbonate. Laboratory and pilot plant experiments are in progress on low-grade molybdenum concentrates containing rhenium and copper. Preliminary results indicate that molybdenum extractions in the 90- to 99-percent range and rhenium extractions of 93 to 99 percent can he obtained without appreciable oxidation of associated copper minerals.

Jan 1, 1972

By M. Bélanger, H. -L. Jacob

"The province of Quebec has a strong tradition in industrial minerals. Ten commodities are produced and the annual total shipments have exceeded $600 million in recent years. Quebec is a world renowned producer of chrysotile, titanium slag, graphite, and ilmenite. Quebec is an important North American producer of mica, talc, and peat moss. This paper reviews the main minerals and commodities that have been the object of exploration or development in recent years, namely graphite, wollastonite, dolomite, and silica. Some of the leading projects concerning magnesium minerals and apatite-ilmenite are described. IntroductionQuebec has a strong tradition in industrial minerals. It goes back to the second half of the 19th century when the first graphite and apatite mines in the Gatineau area and asbestos mines in the Eastern Townships were opened. Since then, more than 25 commodities have been produced in Quebec, making industrial minerals an integral part of the Quebec mineral industry. Today, industrial minerals and building materials count for one third of the total mineral production in Quebec.Present industrial mineral production includes 10 commodities (Table 1). In the last five years, the value of industrial mineral shipments has varied between 500 and 700 millions dollars annually, which represents 20% to 25% of Quebec’s total mineral production. For many years, Quebec has been a major producer of chrysotile and titanium slag, the only producer in eastern North America of mica, graphite and ilmenite, and a leading Canadian producer of talc and peat moss. Quebec also produces, mainly for domestic markets, dolomite, limestone, salt and silica.Quebec’s industrial mineral sector has been quite active in the recent years. Exploration by government geologists and companies has led to the outlining of new deposits, some of which are now in production; others are currently being evaluated. Technical and economic studies are also underway to determine the feasibility of various development projects."

Jan 1, 1999

By N. Gurulaxmi Srikakulapu

The demand for high-grade iron ore has increased the importance of beneficiation of low-grade iron ores. The captive mines of Tata Steel Limited, India has reserves of Banded Haematite Jasper (BHJ) ore assayed 40% Fe, 40% SiO2 and <1% Al2O3. QEMSCAN study has revealed haematite and quartz as a major iron bearing and gangue mineral phases respectively. Liberation characteristics have showed 80% liberation can be obtained at particle size below 10µm. In the present study, reverse cationic froth flotation of BHJ using ether diamines is explored in Denver-D12 flotation cell. Polynomial response surface regression equation coupled with six-factor Box-Behnken design of experiments is used to generate the correlation between process separation efficiency and flotation parameters. Flotation studies of BHJ indicated that concentrate of 62% Fe can be achieved with 62% Fe recovery from Jig concentrate at optimum conditions. The obtained product can blend with pellet fines to feed in blast furnace. Keywords: banded haematite jasper, flotation, box-behnken design, response surface methodology

Sep 1, 2012

By Muhammad Zaka Emad, Rangzeb Goraya, Muhammad Usman Khan

"Numerical modeling has been used extensively to assess the stability of surface and underground mines. Tabular, steeply dipping ore bodies are generally mined out by open stoping methods with delayed backfill. Cemented rockfill (CRF) is employed as a backfill material for narrow vein deposits with low production rates. Sublevel stoping methods with delayed backfill are employed to mine out steeply dipping ore bodies. Backfill is exposed to blast-induced vibrations and dynamic loading due to loss of confinement, which could lead to backfill failures. Backfill failures could influence the operating cost of a mining stope and the productivity of the entire mining project. This work shows a detailed overview of the factors contributing to backfill failure. A detailed literature review is presented along with case studies of longhole stoping operations from the Canadian Shield region for this work. The backfilled stopes are analyzed with the finite difference code FLAC3D. The literature review shows that the factors primarily responsible for fill failure are the strength of backfill, stope geometry, mining sequence, and blast-induced vibrations. INTRODUCTION Sublevel stoping methods with delayed backfill are popular in Canadian hardrock and metal mines. Backfill facilitates ground control and greater recovery of ore with pillar mining. It reduces wall slough, thus decreasing ore dilution from adjacent walls. The production of cemented rockfill (CRF) is simple; rock aggregates are mixed together with cement slurry and then placed in a mined-out stope. CRF has a low water content, thus it requires no additional drainage unlike some other backfill. Low water-to-cement ratio enables faster curing rate, hence a faster mining cycle can be achieved (Annor, 1999; Hassani and Archibald, 1998; McKay and Duke, 1989). CRF is generally placed in stopes from the upper sill drift using a truck or a load haul dump machine. Some of the problems associated with CRF are the moderate to high operational cost, the difficulty to get a tight filling, and segregation. Backfill failure is a product of many factors, such as cementation, particle size distribution, placement method employed, water quality, segregation, and blast-induced vibrations. The problem of segregation in aggregates has been observed when aggregate is dumped from a backfill raise (Meech, 2012; Indiana DOT, 2013). Segregation becomes unavoidable when the aggregates are not properly sized (Yu and Counter, 1983; Stone, 2007; Yu, 1989). The exposed backfill zones will contribute to ore dilution due to backfill when subjected to dynamic loading due to fill failures. This paper presents a detailed literature review and numerical modeling results of a mine backfill, along with case studies from longhole stoping operations. The backfilled stopes are analyzed with the finite difference code FLAC3D (Itasca, 2017). The literature review shows that the primary factors responsible for fill failure are the strength of backfill, geometry of stope, sequence of mining, and the vibrations induced by blasting operations."

Jan 1, 2017

By Northeastern University, B. Y. Cui, B. Y. Wang, D. Z. Wei, W. G. Liu, Z. C. Guan, S. L. Gao

To recover iron values from low grade ores by reverse froth flotation method, further research on cationic collectors used in reverse flotation of iron ores is launched to promote the utilization efficiency of iron ores. In this paper, one new cationic surfactant, bis(2-hydroxylethyl) dodecylamine (BHD), that could be dissolved in water easily was used as collector for quartz flotation. Flotation results indicated that BHD shows stronger collecting performance on quartz than hematite. The maximum recovery of 96.30% to quartz is obtained at a collector concentration of 20.0 mg/L in the pulp pH range from 5 to 7. This collector can be used to float quartz from hematite. And optimal separation results with 86.59% iron recovery and 66.60% iron grade to synthetic sample were achieved at a collector concentration of 20.0 mg/L and pulp pH of 5.02 when hematite and quartz were mixed at a mass ratio of 3:2. The adsorption mechanism of the collector on quartz surface was investigated by XPS analysis, infrared spectroscopic analysis and zeta-potential measurements, which revealed that electrostatic attraction and hydrogen bonding adsorption occur between collector and quartz surface.

Jan 1, 2016

By B. Dyck, L. Verhelst

"Colloidal silica in Key Lake’s Solvent Extraction (SX) feed solutions has presented an operational problem for the mill throughout its history. The colloidal silica stabilizes aqueous continuous emulsions, resulting in elevated solvent losses and operational downtime. Through the years, many attempts have been made to solve this problem, but no viable solutions were found. By revisiting an idea dating back to the 1979 feasibility study and re-evaluating it under current operating conditions, a practical solution was achieved. This paper discusses Key Lake’s history around colloidal silica removal, starting with coagulation using a polyethylene oxide polymer (PEO), and ending with coagulation using a polyethylene glycol (PEG) polymer. The results of a mill trial using POLYSIL® RM1250 introduced at doses up to 300 ppm into the counter current decantation (CCD) circuit to clarify SX feed solutions are discussed with a focus on the benefits to SX.INTRODUCTION Colloidal silica has historically been a significant operational problem in the Key Lake mill. Silica originates from clays in the ore as well as concrete backfill intermixed with the ore resulting from the mining method used at Key Lake’s ore source, the McArthur River mine. The silica is dissolved as silicic acid into solution in the mill’s sulphuric acid leaching circuit. Once in solution, silicic acid polymerizes (Hearn, Smethurst, & Boskovic, 2016) forming a fine suspension of stable colloidal particles. These silica colloids are unaffected by flocculants and sand filtration reporting to the pregnant leach solution (PLS) as a fine turbidity in solution. Silica concentrations typically ranged from 700 to 1200 mg/L Si in the PLS fed to SX. Throughout Key Lake’s history, silica interactions in the Solvent Extraction (SX) process have made SX a mill bottleneck and a source of significant reagent costs."

Jan 1, 2018

Spiral concentrators are compact, cost-effective and generally efficient gravity concentration separators for a wide range of applications (for example: coal, beach sands, iron ore, chromite and tantalite). Large mineral processing plants consist of thousands of spiral concentrators resulting in large plant footprints (capital intensive) and the adjustment of splitters is time consuming, impractical and is in many cases neglected?high capacity (HC) spiral concentrators aim to address these shortcomings. As a result Exxaro Namakwa Sands is currently investigating high capacity spiral technology for the spiral circuit upgrade at the primary concentrator plants (PCPs). This article summarizes the rougher spiral performance evaluation that was conducted on different types of spiral concentrators (the traditional MG4 spiral concentrator and the high capacity (HC) spiral concentrator) under different feed conditions. In addition, the effect of slimes on the spiral concentrator performance was also investigated. Slimes rheology was linked to the poor concentrator performance at the higher slimes concentrations. The test campaign shows a sacrifice in recovery under design-feed conditions can be expected when using high capacity spiral concentrators in the rougher stage when compared to traditional spiral technology currently in use. Both spiral concentrators show a detrimental impact of slimes on the performance, but the high capacity spiral concentrator is more sensitive to the higher slimes conditions.

Jan 1, 2010

By K. A. Natarajan, M. N. Chandraprabha

Selective separation of minerals from complex sulphide ores is a challenging task and it is often difficult to get commercially acceptable individual concentrates by conventional selective flotation using inorganic collector reagents. Microbially-induced mineral beneficiation has proved to be more effective, economically viable and an environmentally benign process for the effective separation of various minerals. Applications of microbially-induced mineral beneficiation are demonstrated in this paper with respect to beneficiation of complex multimetal sulfides. The role of adapted microorganisms and bioreagents in the beneficiation of complex sulphide minerals are also illustrated.

Jan 1, 2009

By D Ray, D Brett

A clay-capping trial was established in 1996 on Magazine Dump at the Mt Lyell Copper Mine. The trial was initially constructed under the Mount Lyell Remediation Research and Demonstration Program, a co-operative venture between the State and Federal governments. The detailed engineering design for the clay cover included the following features; reshaping and compaction of dump batters, 5 m vertical bench interval, overall side-slopes of 2.5:1, emplacement of clay in four 150 mm lifts, compaction by a 10 t vibrating roller or ætrack rollingÆ on batters with density testing for quality control. A small section at the base of the dump ( The trial also generated certain unexpected findings. Field permeability tests on the cover yielded uncertain results and oxygen remains available throughout the dump. The flow data indicate that, while total outflow has decreased as a result of storm shedding, inputs from groundwater and batter infiltration are still significant. Outflow during the driest weeks of the year may have risen following capping. Detailed assessment of the data is hampered by insufficient pre-capping information; however, there is a possibility that conductivity flux emitted when flows in the receiving environment are at their annual minimum is unchanged or worse post-capping.

Jan 1, 2003

By T Clemens, D Trumm

Adopting environmentally acceptable practices in New Zealand is a crucial requirement for mineral wealth development. Recent planned expansions in the coal and gold industry have increasingly placed mining in the media spotlight. A lack of appropriate standard environmental guidelines has resulted in inconsistent responses and assessments of current and proposed mines. These inconsistencies have lead to delays in decisions on developing economic mineral deposits that may have only minor short-term impacts, and have also allowed unacceptable environmental management practices to continue elsewhere. A research collaboration between CRL Energy, Landcare Research, University of Canterbury and University of Otago aims to provide regulator groups and the mining industry with a unified approach to the requirements of the Resource Management Act 1991,the legislation that largely drives the nationÆs environmental policies and guidelines. The tangible outcome of this research program will be water quality and impact management guidelines integrated into a decision-making framework. The result of this unification will assist in the development of viable mineral deposits and minimise environmental impacts. The framework will be derived from a synthesis of three objectives. Objective 1 identifies potential water quality impact. This objective is based on a targeted geochemical study of the lithology and waterways of the West Coast and Southland regions. Objective 2 categorises the degree of impacts on the ecology of receiving aquatic ecosystems and determines the processes that drive aquatic ecosystem recovery. Objective 3 identifies best strategies to sufficiently manage impacted ecosystems, and to prevent future unacceptable impacts. Wide consultation with representatives of the mining industry and regulator groups will occur frequently during the development stages of the framework. It is anticipated that this multidisciplinary approach will provide a robust and coherent, standardised system that will assist in achieving industry and environmental targets.

Jan 1, 2004

By J. D. Robertson

An in situ water sampling device has been developed to measure biologically-available or “labile” metals in natural waters and effluents. The active mechanism involves the use of a polyacrylamide gel layer to quantitatively control metal transfer to a trace-metal-adsorbing, gel-imbedded resin. Because the resin only adsorbs free metal ions (the gel sampler methodology is a kinetic speciation technique), and because metal bioavailability is related to the free-ion activity, the device provides a direct measure of the biological-availability of metals in the environment sampled. The prototype consists of a layer of ion-permeable polyacrylamide gel which separates the solution to be sampled from an ion exchange resin. Because approximately 90% of the polyacrylamide gel is water, mass transport through the gel is diffusion-controlled, and is therefore well defined. Metal ions are rapidly bound by the resin, creating a steep concentration gradient in the gel. The amount of labile trace metal that accumulates on the resin can be related directly to the concentration of the metal in solution, the exposure time and the molecular diffusion coefficient of the labile species. In addition, the passive nature of this device affords it the potential to address many of the limitations presented by conventional sampling methods, such as sample contamination introduced during collection or filtration and changes in trace metal speciation prior to analysis. Laboratory studies and limited field trials indicate that the sampler behaves as anticipated and illustrate that biologically- available metal concentrations in many environments are a small fraction of the total concentrations and often significantly less than the dissolved concentration. The implications of this on regulatory criteria are discussed. Additional field trials and correlation with bioassays are currently underway.

Jan 1, 2000

By M. A. Halim, V. I. Lakshmanan, Z. Jankovic

An innovative mixed-chloride process for the separation of iron from lateritic ore is described. The separation of Fe(III) from leach liquor is an important process step for the recovery of nickel and cobalt. The patented process of Process Research ORTECH Inc. uses a lixiviant containing hydrochloric acid (HCl) and magnesium chloride (MgCl2) for the leaching of lateritic ores/concentrates followed by the selective solvent extraction step of Fe(III) over other value metals such as Ni and Co. The use of MgCl2 increases the activity of the hydrogen ion in the lixiviant, which reduces the consumption of HCl in the leaching stage and enhances the formation of HFeCl4-, thereby increasing the solvent extraction efficiency of Fe(III) with ketone. The process produces high purity iron oxide (Fe2O3) and regenerates HCl by the pyrohydrolysis of the FeCl3 rich pregnant strip solution. The developed process flowsheet is in closed loop, economically attractive and environmentally friendly.

Jan 1, 2015

By A. Khan, C. Ciriello

The purpose of this paper is to demonstrate the value of constraint modelling in optimization of mineral processing systems. This will be achieved by first understanding the overall concept of variation and constraints present in any system. Next, the value of using a Constraint Model in optimization is demonstrated through comparison of business cases. The benefit of understanding the severity of constraints and movement of the bottleneck within a mineral processing system will be understood through the use of a case study. Paper will conclude with a summary of all optimization benefits that utilization of a constraint model can bring.

Jan 1, 2015

By G. W. Reimers

Exothermic oxidation reactions of sulfide minerals can produce self-heating situations in underground mines. If the self-heating is unchecked and the resulting heat is not sufficiently dissipated, the result can be spontaneous combustion fires. This U.S. Bureau of Mines report describes laboratory tests conducted to measure the reactivity of pyrite following treatment with additives to counter its self-heating tendencies. Thermal gravimetric analysis (TGA) and isothermal oxidation procedures were used to obtain information on pyrite ignition and the behavior of pyrite during low-temperature oxidation to ferrous sulfate. The determination of treatment effectiveness was evaluated by adding 5 wt pct of the compound to the pyrite before milling. The resulting samples were then heated in moistened air and after 24 h, the amount of pyrite oxidation determined. Results of these tests indicated that several phosphate compounds reduced the oxidation of pyrite to sulfate to about 50 pct or less compared with the oxidation of untreated sample at 200° C. Cupric sulfate reduced oxidation to about 20 pet untreated sample at 200° C. Sodium, calcium, and potassium chloride reduced pyrite oxidation to levels of approximately 15 pct or less of the untreated sample. Using only 1 pct of sodium or calcium chloride was effective in slowing pyrite oxidation to less than 20 pct of the untreated sample.

Jan 1, 2010

By B. K. Slone

The depth at which it becomes more economical to use slope access as opposed to box-cut access for near-surface coal reserves, termed "transition depth," can be established for a given coal property by considering cost estimates for those parameters that determine respective access method. Fourteen parameters that influence access cost were identified and ranges determined. A Transition Depth Formula was developed to permit determination of the better method of accessing a reserve, given such information as highwall slope, road width, total bench width, pit dimensions, road grade, belt component costs, pumping costs, and cost of overburden removal and reclamation. In most cases, in Appalachia, studies indicate that the transition depth ranges between 20 and 30 m.

Jan 1, 1998