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By Y. Q. He

The methodology of active pulsing air separation is a new method for dry material classification. Especially, it is suitable to electronic scraps disposal and re-utilization. By studying the difference of drag coefficients of the particles moving through areas of varying Reynolds numbers, and considering the extra-mass forces acting on the particles in the active pulsing air field, models of the dynamic motion which particles follow were developed. A computer simulation was prepared that showed the traces of particles with different densities and/or diameters, but similar aerodynamic characteristics, as they moved through the turbulent flow, to modify and define the parameters of the models. The simulation was found to predict the observed results with artificial tracing spheres being separated by the laboratory equipment. The separation performance, as being affected by the particles, nature, the air velocity, the pulsing frequency and the air pattern, is discussed. In general, lower density particles are more responsive to variations in airflow velocity. In addition, an industrial scale active pulsing air separator was designed, and it provides a new and efficient method for resource re-utilization in China.

Jan 1, 2014

By Russell Barr

Operational excellence is generally known as a management system integrated across critical functions that is geared towards continually improving operational performance. Functional areas such as health, environment and safety, quality and human resources are the focus of many corporate-wide operational excellence programs. Operational excellence also focuses on improving areas such as customer orientation, employee empowerment as well as process, and systems optimization. It is widely viewed as critical to sustaining business performance improvement. Although it is difficult to find a universally accepted definition, or even common foundation in many respects, operational excellence remains a popular term in the business world. Many organizations have developed their own version of organization excellence, influenced by such individual factors, other similar institutions or even third-party service providers. A mining organization is no different from other organizations in that adopting and implementing effective operational excellence programs can dramatically improve business execution and performance across regional or global interests. This paper brings together various perspectives of operational excellence and reconciles them for a useful composite for the mining industry. While most agree that operational excellence should include normal functions in a manufacturing operation such as production, maintenance and engineering and processes such as quality, environmental and continuous improvement, many other factors for operational excellence seem to vary from perspective to perspective. Thus, programs that manufacturers engage in may seem the same, but may, in fact, be different in key areas. This may affect organizational performance in tangible ways. Management must buy into the company?s definition of operational excellence and be dedicated to achieving it. A review of many of the existing definitions of operational excellence, explicit or embedded as part of a program, seems to yield the following common factors: ? It should help organizations better execute their processes and services. ? It should be geared towards improving quality ? It requires that the various operations should be aligned with the overall enterprise strategy. ? It should be geared towards continuous improvement. A composite of operational excellence definitions suggest that it is: ? Geared towards helping the organization achieve sustained profitability; ? tied to strategic alignment and business objectives; ? tied to solid investment strategies; ? integrated as part of the culture, process, time plan and performance; ? a relevant performance measurement system; ? extended to include all aspects of the supply chain (including external suppliers); ? integrated with health, safety and environmental (HSE) aspects. And, while the pursuit of operational excellence intuitively suggests that businesses should improve, it is very difficult to achieve given the difficult challenges facing companies today. Mining businesses face numerous pressures to perform in a global marketplace such as demand, energy cost, variable cost and pricing fluctuations as well as infrastructure challenges to further confound the environment. Companies generally must look to the following:

Jan 1, 2009

By J. -C. Sztuke, M. Cao

ABSTRACT The correlations between froth recovery of coal and air recovery were investigated using a hybrid mechanical flotation column. The particle slurry was fed onto the surface of air-water two phase froths to carry out the tests. Froth recovery was taken as the recovery of particles into the froth product, whereas air recovery was determined by the froth height method. The relationships between froth recovery and air recovery were nearly linear, with greater slopes for more hydrophobic particles. Inside the froth phase, the particles were stratified, with hydrophobic particles concentrated in the upper region and hydrophilic particles in the lower region.

Jan 1, 2013

By R. E. Hamilton

It is more than ten years since the first fully automated process using a computer started operation. Computer control has become common in a number of process industries, yet in spite of the tremendous incentives which ere present, there are only a few computer installations in the mining industry and none of these has announced successful control of a process. Recognizing that one of the reasons for this slow progress is the lack of adequate mathematical models of the various processes involved, the author's company started a project in the summer of 1966 to develop such models. It was early recognized that the existence of a major disturbance input, in the form of the mineral composition of the feed prevents most flotation plants from attaining a steady state condition. This makes the custom¬ary method of developing correlations from steady state plant data inapplicable and requires a more fundamental approach.

Jan 1, 1968

By X. Tan

In this paper, the application of the metallurgical residue produced from oceanic cobalt-rich crusts leaching process is studied in the area of wastewater treatment. The modification of the sulfuric acid leached residue and the adsorption behavior behaviour of heavy metal ions such as (Pb(II), Cu(II), Zn(II), Cd(II), Ni(II), Mn(II), Co(II), As(III)) in the waste-water on the surface of the residue are investigated. The rate of adsorption efficiency of heavy metal ions in the wastewater on the modified sulfuric acid leached residue is investigated. It is showed that when the initial pH value of wastewater containing heavy metal ions including Pb(II), Cu(II), Co(II), Ni(II), Mn(II), Zn(II), Cd(II) and As(III) range from 1.4 to 1.9, with the use of the modified leached residue, As(III) ion can be selectively separated from wastewater, and the separation efficiency can reach 90%~100%. The adsorption efficiency is affected by pH, reaction time, amount of adsorbent and the initial concentration of heavy metal ions in wastewater. The results showed that the optimum pH was natural pH value and the absorption equilibrium time was 2 hours. The adsorption efficiency of heavy metal ions increases with the addition of adsorbent and de- creases with the increase of the initial concentrations of heavy metal ions in wastewater. The heavy metal ions polluted wastewater, of which concentration is about 22.5~793.6 mg/L, can meet the national disposal standard for industrial wastewaters in China very well, after 2 hours treated by 3.75~7.50 g/L modified adsorbent at room temperature. Standard methods were used to investaged investigate the absorption behaviour between abosorbentabsorbent and metal ions in the wastewater. It is concluded that the adsorption behaviour of Co(II), Mn(II) and As(III) ion fits Freundlich iso-therm, while the adsorption behaviour of Pb(II), Cu(II), Zn(II), Cd(II) and Ni(II) ions fits Langmuir isotherm, and the saturated adsorption amount of the modified adsorbent is about 54.0~336.7mg metal/g?adsorbentabsorbent. It is suggested that the modified sulfuric acid leached residue produced from oceanic cobalt-rich crusts is environmentally attractive and meaningful as absorbent used in heavy metal ions polluted wastewater.

Jan 1, 2014

By Guy Xueyi

The environmental impact assessment of the Imperial Smelting Process for metallic zinc and lead production in Shaoguan Smelter, China, was carried out by the life cycle assessment method. The detailed inventory analysis of the Input/Output in the process during 1998-2000 was conducted and the allocation was done among the main products of zinc, lead and sulfuric acid, according to the system expansion and substitution principle, The environmental impacts were assessed by using the following five Eco-indicators: Gross Energy Requirement (GER), Global Warming Potential (GWP), Acidification Potential (AP), Heavy Metal Toxicity' (HMT) and Solid Waste Burden (SWB). The results from this study are useful to address the environmental situation of the technology practice in this smelter, and provide a scientific basis for the further improvement.

Jan 1, 2003

By D Kubik, K The

The New Zealand (NZ) Transport Agency’s Waterview Connection will complete Auckland’s Western Ring Route, a 47 km north–south motorway alternative to Stage Highway 1. The project is being delivered by the Well-Connected Alliance comprising the New Zealand Transport Agency (NZTA), Fletcher Construction, McConnell Dowell Constructors, Obayashi Corporation, Parsons Brinckerhoff NZ, Beca Infrastructure and Tonkin & Taylor.The project involves construction of 5 km of new motorway, nearly half of it underground connecting State Highway 20 (SH20) to State Highway 16 (SH16). The underground portion of the project incorporates twin 13.2 m inside diameter (ID) tunnels 2.4 km long, each carrying three traffic lanes, one for north-bound traffic and one for south-bound traffic. The tunnels are being driven by a 14.46 m outside diameter (OD) 2400 t, tunnel boring machine (TBM) shield that was assembled and launched at the southern portal. It will be turned and re-launched at the northern portal for the return drive to the southern portal where it will be disassembled. This paper presents two major temporary works elements contributing to the successful launch of the TBM: the TBM assembly crane platform and the TBM shove frame and associated components.Tunnel boring machine shield assembly – crane platformThe TBM shield was delivered to site in subassemblies ranging in weight from 100 to 380 t. It was initially proposed to use a 750 t crawler crane sitting above the tunnel portal headwall to assemble and disassemble the TBM. However, this did not have sufficient capacity to allow the TBM shield to advance clear of the tunnel before disassembly commences. To reduce the crane’s working radius a temporary steel crane platform was developed that is supported on the side walls of the tunnel approach trench. This has enabled a smaller, less expensive, 600 t crawler crane to be used and will allow the TBM shield to clear the tunnel before disassembly.Tunnel boring machine launch – temporary worksTo launch the TBM a purpose built steel frame was required for the TBM thrust rams to react against. The shove frame had to be able to transfer the thrust loads from the TBM shield to the ground below and thrust wall behind. A range of potential thrust loads and jacking patterns were examined to develop the design load cases for the shove frame. The shove frame was used to launch the TBM at the southern portal and to re-launch it at the northern portal. Elements of the shove frame will also be used to support the portal faces during the TBM arrivals.CITATION:Kubik, D and The, K, 2014. Waterview Connection – temporary works for tunnel boring machine?launching, in Proceedings 15th Australasian Tunnelling Conference 2014, pp 281–288 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By Jim Pae Lem

This study investigates the mode of occurrence of uranium in a copper concentrate from the Prominent Hill mine. Mineralogical and liberation studies of a high grade Cu concentrate (monthly composite) containing uranium (U) were undertaken using QEM-Scan in combination with QXRD and ICP-MS. The study aimed at determining in what form U was recovered, and by which mechanisms. The deportment of U was studied in 3 size fractions; +20µm, -20+8µm and -8µm. QEM-Scan analysis showed that uranium was present as U(Cu)-silicates, U-silicates, UPbOx/FeOx or traces of UThOx and UTiOx, with the U-silicates present across the size fractions. The association of uranium bearing minerals with copper sulphides varied across the size ranges. Interestingly, most of the U (46% by weight) was distributed in the finest fraction (-8µm), in which the deportment of Cu was low (6%). Over 40% of the U mineralisation in the -8µm was liberated. In terms of the floatation response, while recovery of the uranium minerals as a result of their association with copper sulphides (as composite particles) was evident, recovery of UPbOx locked in hydrophilic haematite in the +20µm size fraction suggests, that other mechanisms (e.g. Inadvertent activation by Pb from radioactive U decay) are possible. Furthermore, the high amount of fine liberated U bearing particles in the concentrate points at entrainment as another major mechanism for uranium recovery, and therefore, a target for process optimisation.

Sep 1, 2012

By Jim A. King

The total pressure oxidation of copper concentrates is a potentially viable option for treating copper concentrates that are either low grade or contain significant impurities. Both concentrate types are heavily penalized in smelter contracts. The total pressure oxidation process involves autoclaving the copper concentrate at temperatures of 200-220 C under oxygen pressure. The autoclave discharge can be separated into a solid (oxidation residue) and a liquid (oxidation solution) product. The oxidation solution can be treated for copper recovery by solvent extraction - electrowinning or by direct electrowinning. The direct electrowinning recovery of copper requires prior removal of selenium and tellurium by cementation on finely divided scrap copper. The oxidation residue is washed thoroughly to remove acid and dissolved copper prior to precious metals recovery by conventional cyanidation in the presence of lime. The results of a benchscale investigation involving a number of copper concentrates are reported. Copper recoveries in autoclave oxidation and gold recoveries by cyanidation of the oxidation residue exceeded 99%. The results of benchscale experiments to demonstrate copper recovery are described. Various flowsheet options are presented.

Jan 1, 1993

By J. Drzymala

Ores and raw materials are subjected to mineral processing operations to increase the content of their useful components. Upgrading of these materials can proceed with different selectivity and therefore, there is a need to know and monitor the separation results of the process. The separation results can be evaluated using tables and graphs called upgrading curves. The course of lines in the upgrading curves is usually complex and depends on the graph type and process parameters. The Halbich grade vs. recovery plot is frequently used because is practical and it indicates several characteristic features of separation results. Separations by means of flotation of several different shale, dolomite and sandstone copper ores were performed along with determination of their mineral composition, copper content, liberation degree, and the maximum theoretical copper content in the first concentrate. These data, plotted as the Halbich upgrading curves, allowed to find other characteristic points such as practical maximum copper content in the first concentrate, maximum curvature coexisting with the liberation degree, maximum recovery of ore valuable components, and the slope the recovery-grade line at high recoveries as a measure of liberation. Correlations between theoretical and practical maximum copper contents in the first concentrate as well liberation degree and maximum curvature were also presented. They show that the ore type significantly influences the shape of the Halbich curve and its characteristic points.

Sep 1, 2012

By Lachezar Tsotsorkov

Being a mining company, Assarel-Medet has a significant impact upon the environmental components. In order to meet the legal requirements and the requirements stipulated by the effective permits as well as to reduce the environmental imprint throughout the years, the policy of the company to implement a number of projects to improve the environmental components quality and the environmental state in the company?s region. The projects associated with atmospheric air quality management and reduction of the impact exercised by Assarel-Medet JSC by implementing various measures to eliminate the potential sources of the impact, preventive and rehabilitation initiatives as well as organizational and administrative activities are among the most important ones. A stable improvement of atmospheric air quality in the region and minimization of the company impact upon the ground air state in the region was observed in the period from 2005 to 2012 due to the applied measures. This project is a contribution to the environmental protection, in particular to atmospheric air protection, by applying integral monitoring and modeling methods to identify the negative impact by the mining companies and plan measures to reduce and restrict it as well as to improve the quality of the environment and living area of people working and living in the impact range as an element of sustainable development.

Aug 1, 2013

By J. B. Yianatos

A practical an interactive model to describe the operation of a flotation bank of mechanical cells was developed based on the hydrodynamic and metallurgical characterization of large industrial flotation cells. Thus, the mineral grade and recovery, as well as the stream properties along the flotation bank can be described in terms of the operating variables. The model was built considering the flotation bank as a distributed system, so the solution for the water and solids mass balances, per size classes, for each single cell, are sequentially solved. Also, each cell was described by two distinct zones, the collection zone characterized by the flotation rate constant and the froth zone characterized by the froth recovery. The mineral feed was described in terms of the mineral species and particle size classes, using a rectangular flotation rate constant distribution. Also, the effect of changing the actual operating variables (air flowrate, pulp level, pulp density, pulp flowrate, etc.) on the mineral collection process, in the collection (pulp) zone, was considered downstream along the bank. The froth recovery of floatable mineral has been estimated by measuring the mass flowrate of particles entering the froth by true flotation together with the concentrate mass flowrate (ton/h). The mass flowrate of collected particles at the pulp/froth interface level was calculated from direct measurement of bubble load (ton/m3) and gas flowrate (m3/h). Flotation recovery is mainly related to the froth depth and air flowrate. All parameters considered in the model have been adjusted from direct measurements in plant site. Also, the effects of other operating variables such as reagents dosage, top of froth grade, or froth discharge velocity are presently under study. This procedure has been tested using data from industrial rougher operations consisting of flotation banks with 5 cells to 9 cells in series, and different cell sizes, such as 45m3, 130m3, 160m3 and 250m3. Thus, it has been shown that the model approach is a powerful tool for flotation cells diagnosis, operation and development of new control strategies, as well as, to evaluate the effect that de-sign and operating variables have upon the collection and froth zones performance in large flotation cells.

Jan 1, 2014

By B. J. Walsh

ABSTRACT Segregation of sphalerite minerals in zinc concentrates into christophite, marmatite and ordinary sphalerite by means of magnetic fractionation is investigated. A Frantz ferromagnetic filter, 1.2 amp., and a Dings magnet, 0.3 amp., is used to fractionate seven zinc concentrates produced in the Province of Quebec. The Dings magnetic product contains the pyrrhotite, and the sphalerite as christophite. The Frantz magnetic product contains sphalerite as marmatite, while the Frantz nonmagnetic product contains ordinary sphalerite. The results indicate that the magnetic susceptibility of sphalerite increases with increasing isomorphous iron content and that a satisfactory separation into christophite, marmaite, and ordinary sphalerite may be accomplished by magnetic fractionation. INTRODUCTION SPHALERITE, the chief ore of zinc, is almost never pure zinc sulphide. Iron is almost always present isomorphously replacing an ?equivalent amount of zinc. What may be referred to as 'ordinary' sphalerite contains up to 10 per cent iron. More highly ferriferous varieties, with 10 to 26 per cent or more iron, have been named marmatite .and christophite.

Jan 1, 1951

By C. E. Jordan

Direct digestion of phosphate ores by the acid-alcohol method offers improved leaching selectivity for the exclusion of iron and aluminum in the product acid. The leaching kinetics of this process will have a major role in the eventual application of this technology. The Bureau of Mines investigated apatite dissolution to determine the reaction rate and mechanisms of the leaching kinetics. The dissolution kinetics were monitored on various sized fractions of pure apatite. The "shrinking-core" kinetics model was applied to the data to determine the rate controlling mechanisms. For each size fraction, the initial reaction rate was controlled by the dissolution reaction. After an hour the dissolution rate slowed indicating a diffusion controlled reaction caused by the formation of calcium sulfate hemi-hydrate coating on each particle. For complete dissolution of the apatite, the phosphate rock should be ground to near 10 µ m size.

Jan 1, 1993

By M. Lindgren, M. Latva-Kokko

Process performance can be significantly influenced by proper design of hydrometallurgical reactors. Optimal reactor configuration is case specific and depends on process requirements such as reaction rate limiting factor and particle size distribution. Choice of materials and manufacturing methods also play important roles in highly corrosive and abrasive environment often involved in hydrometallurgical industry. In this paper performance of different reactor designs has been compared in some typical hydrometallurgical applications. Results show that significant improvement in energy consumption, gas utilization efficiency and equipment lifetime can be achieved with process specific reactor design.

Jan 1, 2014

"In response to mine head grades declining and orebodies becoming more complex, Glencore Technology has developed an alternative method for recovering economic minerals once leached into solution, rather than relying on conventional flowsheet options. The method involves the precipitation and separation of base metals from solution with limestone or lime. The final grade of these precipitate is not usually high enough to attract favourable terms of sale due to dilution from gypsum and sulphate salts. A set of operating conditions have been developed to allow the separation of the base metal precipitate from gypsum by exploiting the difference in particle size. A high-grade oxide product can be easily separated from the gypsum stream at very low cost. This process was originally developed by Glencore for zinc and copper systems. This paper reports on the successful application to nickel and cobalt, and this process has significant advantages over the incumbent precipitation process utilising magnesia.INTRODUCTION During evaluation of transitional and oxide zinc ore deposits during the 1990’s, Noranda Inc. (now Glencore) developed a sulphate based ore leach process to extract zinc into solution. For flowsheet development, conventional schemes dictated that once the zinc was dissolved in an acidified solution it was recovered by means of purification or solvent extraction followed by electrowinning and casting to produce zinc ingots. The deposits Noranda evaluated were high grade but had a relatively short mine life (10 years) and economic analysis showed that the projects couldn’t sustain the investment of a full zinc refinery. Compounding this problem was the lack of power supply infrastructure and the high power cost in the region. Noranda then evaluated alternative means of recovering zinc from solution. Laboratory testwork showed that a high-grade zinc precipitate (+50 wt% Zn) could be produced as an oxide, carbonate or sulphide by contacting acidified zinc sulphate solution with a number of reagents including soda ash, sodium hydroxide, and sodium hydrogen sulphide. Economic evaluation showed that the cost of the reagents are prohibitive, especially when the final product is still a metal intermediate (ZnO, ZnCO3 or ZnS). Noranda then continued to focus on fine zinc oxide precipitation for supply into the automotive tyre industry as this product would attract favourable terms of sale as a premium on Special High Grade (SHG) zinc."

Jan 1, 2017

Cansolv® S02 Scrubbing Technology was described in a paper in Copper/Cobre 03. Four years on, the technology is operating at a full scale production facility.Hindustan Zinc Limited expanded their capacity by installing the AUSMELT process. The process proceeds through smelting, slag reduction, slag cleaning and holding stages sequentially in the same vessel, resulting in widely varying off gas characteristics. The off gas is suitable for treatment is a conventional acid plant for a modest proportion of the day, but at other times produces off gas too high in S02 to be discharged to atmosphere. Cansolv® S02 Scrubbing Technology was identified as a means of effectively removing the S02 down to low levels from the off gas during all stages of the pyrometallurgical process. Furthermore, the Cansolv® S02 Scrubbing System Technology produces high purity S02 that allowed for the captured S02 to be directed to an existing acid plant, avoiding the capital cost of new acid making capacity.

Jan 1, 2007

By M L. Leybourne

In 2012, in response to an increasing potential unfunded liability, the Western Australian Government passed the Mining Rehabilitation Fund Act 2012. The intent of this Act was to introduce an annual levy on tenements covered under the Mining Act 1978 based on the area of disturbed land. The fund generated from these levies could then be used to rehabilitate mining sites where all other options to ensure rehabilitation had been exhausted. The fund could also be used to rehabilitate abandoned sites or features which, in Western Australia, number over 10 000.The Mining Rehabilitation Fund (MRF) was implemented on 1 July 2013 for an initial voluntary year. It becomes compulsory on 1 July 2014. By the end of March 2014, nine months into the voluntary period, over $6.5 million had been paid into the fund. The incentive for tenement holders to voluntarily enter the fund was the opportunity to have unconditional performance bonds held against their tenements retired. While there will be circumstances where bonds will continue to be applied, it is the State Government’s intention to retire most of the bonds.The MRF has received mostly accolades from industry and companies that have entered. Most have found the system easy to use. The MRF was also cited as a reason for Western Australia’s improved position in the Fraser Institute’s annual survey of mining jurisdictions. Work is now starting on processes to select priority abandoned mines for rehabilitation.This paper explains the background to the MRF and its development, and reviews its implementation during the first, voluntary, year. It also discusses how the fund will be managed into the future and what this will mean for both abandoned mine features across Western Australia and any future abandoned mine sites.CITATION:Leybourne, M L, 2014. Ensuring rehabilitation into the future – The Western Australian Mining Rehabilitation Fund, in Proceedings Life-of-Mine 2014 , pp 441–448 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 16, 2014

By Lance Rasband, Richard Hanke

"Seattle Tunnel Partners (STP) started mining on Seattle’s SR99 tunnel on July 30, 2013, working slowly through a 15 ft (4.6 m) thick fiber-reinforced concrete headwall. Once through the headwall, the machine would move through roughly 400 lineal ft (122 m) of jet grout-improved soil at a rate slightly over 6 ft (1.8 m) per day. It was anticipated that once through the improved area, Bertha—the world’s largest tunnel boring machine—would move at a rate of 35 ft (10.7 m) per day. By the end of October 2013, Bertha had mined roughly 430 ft (131 m), averaging 4.73 ft (1.4 m) per day, and had begun mining within native soils. By the start of December 2013, tunneling reached the 800 ft (244 m) mark and Bertha averaged 12 ft (3.7 m) per day, achieving as much as 42 ft (12.8 m) of progress on some days. However, on December 6, 2013, Bertha began to stumble and all progress quickly came to a halt. Preliminary InvestigationInitial reports stated that an obstruction had stopped the machine in its tracks. Malcolm Drilling received an early morning call on Sunday, December 8, 2013, from STP to rapidly mobilize a Bauer BG-50 drill rig with crews to investigate what was hindering Bertha’s progress. Malcolm’s equipment and crews flew into action and were completely mobilized and operational by mid-week. The preliminary investigation involved installation of 10 deep dewatering wells to reduce the hydrostatic head within the ground around the machine and allow STP personnel to inspect the cutter head from within the shaft for presence of obstructions. By the close of December 2013, the wells were installed and the dewatering system was fully commissioned. STP crews were then able to inspect the cutter head and found small fragments of a steel pipe wrapped around the outside of the shield. The steel was apparently from an abandoned 10 in (0.25 m) diameter monitoring well casing previously installed by WSDOT (Washington State Department of Transportation) to monitor groundwater conditions for the design and planning of this very project. After the steel was cut out of the head and cleared from Bertha’s path, she attempted to move forward but was only able to manage a slow crawl"

Jan 1, 2015

By C. Maltesh

Anionic conditioning of phosphate ores prior to fatty acid flotation is a very critical step that determines the eventual selectivity, recovery and hence the economics of the process. However the chemical mechanisms operating during this conditioning step are not established. Several studies have been conducted in the past to determine the mode of interaction of collectors with the phosphate fractions however these have been done on a laboratory scale using pure phosphate minerals. In order to test the relevance of the observed effects to plant practice in this work a comprehensive survey of plant practice was first conducted and then adsorption on flotation feed and francolite were studied under simulated plant conditions. Effects of conditioning energy and water chemistry as well as solids loading and fuel oil were determined. Most importantly, different adsorption mechanisms were found to be dominant under laboratory and plant conditions. In plant water, there was some physisorption of oleic acid on phosphate flotation feed and francolite in addition to chemisorption. However, in distilled water under laboratory conditions only chemisorption was detected. Fuel oil reduced the residual oleic acid in solution after adsorption, which explains the beneficial role of extender in phosphate flotation. The dissolved species in solution arising from the flotation feed or plant processing water are shown to clearly play a major role in determining the adsorption of oleic acid on the substrates. The study also specifically demonstrates the importance of conducting research tests under plant mixing conditions and plant water chemistry for the results to be useful commercially.

Jan 1, 1996