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Reaction between xanthate ions in solution and oxidized compounds present on the surface of galena to form lead xanthate is considered to be a side reaction not contributing to flotation, although accounting for some consumption of reagent. The direct reaction of lead sulphide with xanthate and oxygen to form lead xanthate is the most significant to flotation. Coadsorntion of dixanthogen is also involved. Previous work has shown lead recovery in lead rougher flotation to be a function of m [H+] where: m = concentration of xanthate in solution rHl = hydrogen ion concentration. A plausible explanation for this relationship is suggest-ed. Likewise, the experimental findings that the amount of xanthate adsorbed under certain conditions is a function of m'[H+] are explained in terms of reaction between xanthate ions and soluble basic lead salts such as PbO.PbS04? It is also shown that m[H+] should have a constant value in lead cleaners operating at a higher pH than the roughers. This conclusion is confirmed by plant data, and the value of the constant agrees well with the calculated value. The finding is useful in mill control.

Jan 1, 1965

By J. P. Hager

The formation of the vapor complex AgFeC14 (g) baa been identified and its thermodynamic properties determined. The vapor pressure of silver chloride can be enhanced by a factor of 15-20 due to the formation of the vapor complex. The vapor pressure of both AgCl (g) and AgFeC14(g) were measured using a double-zone transpiration .technique. Gibbs free energies have been determined for the vapor transport reactions. Laboratory kiln tests were conducted to confirm the enhanced recovery of silver through the formation of the AgFeC14(g) vapor complex and to indicate the opportunities for process development using this new vaporization chemistry.

Jan 1, 1985

Several inorganic reagents and organic polymers were tested as depressants in the single mineral flotation of ultrafine iron oxide and hydroxylapatite with Dowfroth 250 as a frother. It was observed that the inorganic reagents and the low molecular weight polymers generally caused dispersion of the ultrafine particles, and consequently their recovery into froth products more or less equaled the recovery of water. On the other hand, the high molecular weight polymers caused different degrees of flocculation of the ultrafine particles, and their recoveries were much lower than the recovery of water. These observations pointed to a need to re-define flotation depressants in fine particle flotation. The traditional definition of a flotation depressant, i.e., to make particle surfaces hydrophilic by forming a hydrophilic film and/or by removing collector and activator coatings, is sufficient for relatively coarse particles. However, to prevent fine and ultrafine particles from floating, a successful depressant should not only make the particles hydrophilic, but also enlarge the particle sizes so that they do not enter the froth product by mechanical entrainment. Polymeric depressants are ideal for these purposes. The different schemes to use polymeric depressants in the selective flotation of fine and ultrafine particles were discussed These schemes involve the integration of the polymeric depressants into other size enlargement processes such as shear flocculation, oil agglomeration, etc., for hydrophobic particles.

Jan 1, 2004

By W. C. Whittaker

"This paper gives a brief resume of the changes in the market picture for Western coal since 1948. It then analyzes present markets and recent developments in Western Canada, the western United States and Japan, and forecasts future markets in these areas to 1975.INTRODUCTIONCOAL HAS BEEN MUCH IN THE NEWS OF LATE, both in the United States and in Canada. In the United States, this is because of the booming condition of the industry and because of the purchase of control of a number of America's largest coal producers by the integrated oil and metal producing companies seeking additional fossil fuel reserves and diversification. In this regard, it is interesting to note that ownership of America's largest strip coal producer was recently acquired by one of the world's largest copper mining companies. In Canada, the conclusion of several large-scale, long-term contracts for the sale of coal to the Japan Steel Group and the projected use of Canadian coal in steel mills in the western United States has focused much attention on the coal industry."

Jan 1, 1968

By G. Ferrara

Hydrocyclones and other dynamic separators are normally fed with pulps of water and solid particles. The particles have different sizes, shapes and densities and, except in the special case of mono-characteristic particles, are segregated into size, shape and density. Segregation is magnified by the high values of centrifugal acceleration in the hydrocyclones. This paper develops the theory of the segregation, indicates the major variables involved and reports experimental data of segregation under different operating conditions for mixtures of magnetite and/or ferrosilicon and non-magnetic minerals.

Jan 1, 1995

By W. J. Kuit

Since closure in 1968, the Wedge Mine, situated adjacent to the Nepisiguit River in New Brunswick, has been flooding with acidic water containing toxic levels of heavy metals. Cominco Ltd. has undertaken a series of pollution control measures to mitigate the threat posed to the river quality. Included has been a successful treatment campaign in 1976 which discharged in excess of 30 million gallons of high-quality effluent from the accumulated volume of mine water. The sources of contamination have been identified as actively leaching waste dumps. A comprehensive program of permanent corrective measures has been prepared which will culminate in mine backfilling. Once completed, the unacceptable burden of water treatment in perpetuity at a non-producing property will be removed.

Jan 1, 1977

By David G. Kidd

The principles of Ore Sorting in general and photometric sorting in particular are discussed with detailed reference to the Model 16 machine. The operating principles and design of the Model 16 are discussed and a case study presented to demonstrate the use of sorters to process an industrial mineral. In addition, an economic study is presented, to highlight the benefits of ore sorting, by evaluating the increased revenue that can be achieved using an ore sorter to process a particular ore body.

Jan 1, 1983

By Christopher Newman, Zach Agioutantis, Gabriel S. Esterhuizen

"As conventional underground deposits are continuing to be depleted, mining operations have been forced to produce at greater depths and in more geologically and geometrically challenging conditions. Over the past decade, there has been a global increase in the application of cemented paste backfill (CPB) material as a means of ground support in open stope mining operations. Although CPB has been extensively used within the industry, there are many fundamental factors affecting the design of safe and economical fill structures that are still not well understood. A critical design issue with respect to backfilled stopes is determining the stress state within the fill material as well as the surrounding rock.This paper details the development of a reliable numerical model for the simulation of stress distributions around the excavated stope area, as well as through the backfill material. Through discussions on modeling parameters and output results, one is provided with insights into the mechanisms of stress redistribution allowing for further accuracies in simulating the behavior of the CPB material as well as its interaction with the surrounding rockmass.INTRODUCTION AND BACKGROUNDModern technological innovations with respect to material processing, cementitious composition and chemical additives, and material transportation have provided the mining industry with a ground support material that greatly reduces mine waste costs, while, when used appropriately, increases reserve production and mine stability. As mining operations continue to produce in more complex geologic and geometric conditions, cemented paste backfill (CPB) has become commonly employed within primary-secondary excavation-support sequencing allowing for total extraction of the mining reserve. As shown in Figure 1, primary stopes are initially excavated and then backfilled in a two-staged pour: plug and final pours. The plug (initial pour), is initially placed at the bottom of the stope with a CPB material of heightened cementitious material. While the plug provides a strong foundation on which to build the rest of the CPB structure, it also provides protection against barricade breakthroughs (Li and Aubertin, 2009), as well as providing operations a means of underhand stope-and-fill mining through the use of an artificial sill pillar (Hughes, et al., 2011). Following placement, the plug is allowed to cure to a designated design strength. Upon completion of the plug, a less cementitious “final” pour material is used to backfill the rest of the excavated area."

Jan 1, 2018

By D. Van Tonder

ABSTRACT The comparative economics of ion exchange and direct precipitation have been analyzed by developing indicative CAPEX/OPEX models for typical alkaline leach uranium circuits. An agitated tank ore leach application is considered, comparing resin-in-pulp and direct precipitation as recovery options. Capital and operating cost estimates are derived from rates and factors used in recent studies and projects. The analysis showed the main economic drivers to be the ore grade and resin loading. The resin loading is impacted by the prevalence of competing ions, especially chloride. At resin-in-pulp solution chloride concentrations below 3 g/L and uranium grade below 640 g/t U3O8, resin-in-pulp is more economical, whereas at chloride concentrations above 3 g/L, direct precipitation is more economical.

Jan 1, 2012

By Nathaniel Arbiter

The question of automation of concentrator operations with computer control is under increasing consideration. Some of the problems involved will be discussed from the viewpoint of the availability of the requisite, detailed knowledge of the unit operations. The justification for full-scale automation of a mill must ultimately be economic--an increase in profitability over and above the cost of instrumentation and development, Potential savings would be in three probable directions: decrease in operating labor costs by substitution of machine control; improved metallurgy through continuous effective control; and decreased operating costs by achieving higher unit capacities and process efficiencies.

Jan 1, 1962

By G. Van Weert

In the spring of 2010 double refractory ores from historical stockpiles were processed through Barrick's Goldstrike pressure oxidation facility, thereby providing preg robbing feeds for a variety of metallurgical testwork. This paper describes the effects of amount, type, place and time of addition of activated carbons on CIL gold recovery and shows that native carbon in plant PDX'ed discharge solids can still preg rob gold loaded activated carbon.

Jan 1, 2011

By Jos. R. Guiteras

This paper is one of a series describing; mining and milling methods and costs being published by the Bureau of Mines. It deals with the mineral resources of western South Dakota and describes the mining and milling of tantalite and associated amblygonite by the Black Hills Tin Co. and the Fansteel Mining Corporation. ACKNOWLEDMENTS Acknowledgment is made to Earl C. Schultz and Arthur I. Johnson, respectively superintendent and engineer for both the Black Hills Tin Co. and the Fansteel Mining Corporation, who contributed the information on mining and milling operations.

Jan 1, 1939

By Yongfeng Jia, Shaofeng Wang, Danni Zhang

Arsenic in mineral processing solutions and effluents is commonly removed and immobilized via iron(III)-arsenatecoprecipitation. The effect of re-crystallization of 2-line ferrihydrite on the long-term stability of iron(III)-arsenate coprecipitate is still not fully understood. This work investigated the redistribution of arsenic and iron during 2-line ferrihydrite transformation at different pHs and temperatures over time. X-ray diffraction (XRD), transmission electron microscopy (TEM) and chemical extraction were employed to characterize the crystallinity of the iron oxyhydroxides. Results showed that the amount of arsenic released into solution during aging increased significantly with increasing media pH.

Jan 1, 2014

By Charles L. Morgan

"In 2012 the International Seabed Authority (ISA) established nine “Areas of Particular Environmental Interest” (APEIs) for consideration as future Marine Protected Areas to help preserve the biodiversity of life on the seabed within the Clarion-Clipperton Zone (CCZ) between Baja California, Mexico, and the Hawaiian Islands. The CCZ is believed to have a high potential for future seabed mining operations. Areas under active exploration contracts in the CCZ, plus the areas currently reserved by the ISA for exploration by developing nations, comprise about 1.9 million km2 of seabed area. The currently designated APEIs consist of more than 1.4 million km2 of seabed. Each APEI includes a central primary conservation area of 200 X 200 km, surrounded by 100-km buffer areas on all sides. The 100-km buffers are intended as a very conservative spacing between the primary conservation area and potential mining activities in adjacent seabed. The selection of these nine 400 X 400 km APEIs, has been criticized as possibly not including sufficient representative habitat similar enough to the potential mining areas (identified currently as the exploration contract and reserved areas administered by the ISA within the region) to ensure protection of the biodiversity that might be impacted by mining.An area to the east of the existing exploration contracts and reserved areas is known to have substantial mineral deposits; it is very similar to the adjacent exploration contract areas in its geology, environmental setting, polymetallic nodule abundance and nodule metal content. Because it is located in the northeastern extreme of the CCZ, this area is also likely to have relatively high densities of benthic life, compared with benthic communities further westward within the CCZ. Many options for the designation of this APEI are possible, but the area designation must accommodate the boundaries of the Exclusive Economic Zones of Mexico and France.This paper discusses why the selected region in the eastern extreme of the CCZ is a good candidate for designation as a new APEI.Keywords: polymetallic nodules, Marine Protected Areas, Clarion-Clipperton Zone, Areas of Particular Environmental Interest"

Jan 1, 2017

By R. L. Bruening, J. B. Dale, N. E. Izatt, S. R. Izatt

IBC Advanced Technologies' Molecular Recognition Technology (MRT) SuperLig® products selectively and rapidly bind with target metal ions to remove them from solution. The MRT process can produce a high purity separation product of maximum added value at low cost. This paper discusses applications for MRT in the gold industry, including recovery of gold and silver as well as metal contaminants from various process and recycle streams.

Jan 1, 2011

By Chuanhong Li, Zuohua Lin, Zhancheng Guo

"Catalytic mechanism of CeO2 in combustion of coals was investigated in this paper. Catalytic combustion of four kinds of coals with different metamorphic grades by CeO2 was examined, suggesting that catalytic function of CeO2 increases with increase of metamorphic grade of the coals. One important reason for CeO2 promoting combustion of the coals is that pyrolysis of anthracite is advanced by CeO2, which not only raises the pyrolysis rate and pyrolysis conversion ratio, but increases contents of light components in pyrolysis gas; and both pore space and specific surface area of the pyrolysis char are enlarged by CeO2, which is another reason. In order to realize in situ catalysis for reducing catalyst consumption, it is crucial to increase catalyst particle number and enhance the bonding force between catalyst and coal. In addition, remarkable energy saving effect was observed when a nanometer calcium-based rare earth catalyst obtained by hydro-thermal synthesis was applied to catalytic combustion of coal injection into blast furnace.Introduction Coal combustion is acknowledged as one of the most important coal applications. Since addition of catalysts could reduce the ignition temperature of pulverized coal and accelerate the coal combustion, catalytic combustion is generally accepted as an effective measure to realize fast combustion of coal. Furthermore, different catalysts added may produce different effects on ignition temperature of coal. It is reported activity of catalysts with the same cation follows this order: OH->CO3 2->Cl->SO4 2-; while that of the catalysts which have the same anion follows: Cs+>Rb+>K+>Na+>Ba2+>Li+>Sr2+>Ca2+>Mg2+>Be2+ [1-4] .Due to the special physical and chemical structure, CeO2 plays an important role in the catalysis field. Many literatures point out that CeO2 not only has great catalytic effect on energy conversion, succeeded in catalyzing combustion of gaseous fuels such as CH4, CO, etc. but also can catalyze combustion of some liquid and solid fuels such as JP-10, black carbon, carbon deposit in the automobile exhausts and so on [5-9].Pyrolysis, the first step of combustion, directly influences ignition temperature and combustion rate of coals. So a great variety of catalysts were applied to catalyze pyrolysis of coals. And plenty of studies suggest that the alkali and alkaline-earth metal compounds inherent in the coals show apparent catalytic effect on coal pyrolysis. Meanwhile, addition of alkali and alkaline-earth metals into coal combustion process also indicates obvious catalysis effect, accelerating coal pyrolysis, improving pyrolysis conversion ratio, increasing contents of pyrolysis gases and changing composition of the pyrolysis gases [10-15].Although alkali and alkaline-earth metal compounds have good catalysis effect on coal combustion, their application in the catalysis field was limited because of their erosive attack to the combustion equipments. In contrast, CeO2, as a substitution of the traditional coal catalysts, presents widely potential application due to its good catalysis ability, non-corrosive and nontoxic. However, investigation on CeO2 catalyzing coal combustion is rarely reported. In this work, catalytic mechanism of CeO2 in coal combustion was studied, in an attempt to provide theoretical foundation for developing new catalysis technologies."

Jan 1, 2009

"SAMPLING: THE IMPACT ON COSTS AND DECISION MAKING1. INTRODUCTIONFor years those in the minerals industry have been taking samples to assist them in making decisions; whether they be about investing billions of rand in a new mining operation, or simply whether a truck load of mineralised material should go to the mill or the waste dump, - we need a sample to help us make our decisions. This paper emphasises the importance and significance of sampling as a process, some of the associated technical problems and some of the advantages, especially in the light of traditional approaches that has usually left mine sampling to the least educated and lowest paid individuals on the mine. Perhaps the most important aspect that requires attention is the variability, usually measured in terms of precision, that tends to infect the sampling procedures. Francis Pitard 12 has stated: ""There is no such thing as reliable feasibility studies, unbiased ore grade control, accurate environmental assessments or effective process control, if you cannot identify and minimize the seven (ten) major sources of sampling variability. "" It is these ten sources of sampling variability and the way they arise that are briefly investigated. Variability is measured in terms of variances and rather than being self-compensating, there is good evidence to indicate that they are in fact additive at every step in the sampling and analytical process."

Jan 1, 2014

By M. Jayaraman

With the ever increasing demand for commodities, due to changes in lifestyle and increase in population, people are striving to find ways to keep up. Mining is one essential element in the solution. Though being a powerful boost to a country?s economy, mining can have disastrous effects in the absence of waste management practice and technologies; because of the harmful heavy metals and toxic chemical waste that is generated as a by-product in mining operations. It is an established and documented fact that pollution is a major concern for communities having to live with it. Disproportionate water consumption significantly impacts local rivers and ponds thereby reducing freshwater availability and have given rise to social conflict. In light of these misgivings, management and treatment of mine water and waste has gained considerable attention recently. In this paper, we summarize some of the treatment methods that can be adopted by mining companies to reduce their environmental footprint. Appropriate treatment solutions depend on various factors including available space and capital cost for treatment solutions, type of mining waste generated, current state of the mining plant, geographical location, and other location specific issues. Incorporating waste and water management solutions as a priority within mining operations is critical for addressing increasing regulatory requirements and a starting point for initiating other Corporate Social Responsibility (CSR) programs. Collaboration among mining companies, NGOs, local community, and government facilitates successful projects which build trust leading to long term relationships. In this paper we also talk about the benefits of implementing a CSR project that captures the focus of local communities and allows the mining company to focus on operations. Implementing a sustainable business model that incorporates the broader community impacted by projects will continue to benefit even after the mining company ceases operation in that location. The challenges involved with implementing effective CSR projects, which require measuring and reporting effectiveness to create a positive social, economic, and environmental impact is also presented in this paper.

Aug 1, 2013

By T. Xue, A. Singhal, D. Wrana, I. Mihaylov

"At Vale's Thompson Nickel Refinery, the copper and arsenic in the nickel electrolyte are removed by precipitation using H2S, generating a sulphide precipitate containing about 40% Cu, 8% Ni, 2 to 4% As and 30% S. This residue has been typically stored in impoundment ponds within the plant site. Various options for reprocessing it have been investigated over the years. One of the options involved oxidative pressure acid leach, whereby over 95% Cu, Ni and As were extracted. More recently, an atmospheric alkaline sulphide leaching process for selective removal of 70 to 90% As was developed and mini-plant tested. After alkaline sulphide leaching, the dissolved arsenic is precipitated as stable basic ferric arsenate (BFA) with the addition of ferric sulfate, while the low-arsenic Cu/Ni sulfide is suitable for processing in Vale's operations elsewhere in Canada.INTRODUCTIONVale’s Thompson Nickel Refinery was commissioned in 1961 and currently it has the capacity to produce about 56,700 tonnes per year of electrolytic nickel as cathode slab and rounds products. A sulphate and chloride mixed electrolyte is used in the Thompson refining process and it typically contains 75 to 85 g/L Ni, 50 to 60 g/L Cl, 90 to 120 g/L SO4 2-, 25 to 30 g/L Na and 8 to 9 g/L boric acid. The main impurities in the Thompson anolyte are copper, cobalt, arsenic, iron and lead.The simplified Thompson electrolyte purification flowsheet is shown in Figure 1 (Oliver & Wrana, 2009, Goble & Chapman, 1986); it consists of precipitation of copper, arsenic and lead with H2S, followed by nickel replenishment with ground matte and acid and removal of cobalt and iron with Cl2 and NiCO3."

Jan 1, 2012

By W. L. Ennis

Introduction This paper outlines the causes of underground fires at Noranda Mines and the precautionary measures taken to guard against such fi res. Shafts There are six shafts (Figures and lA) on the property, of which N os. 1 and 2 are abandoned. Nos. 3, 4, and 5 are the present working openings from surface and No 6 is an internal shaft. No. 3 is used primarily as a service shaft, while Nos.?1 and 5 are the main hoisting shafts. Orebodies The orebodies are of two distinct types. There are the massive sulphide bodies, and the areas of mineralized rhyolite containing gold values and a silica content high enough for fluxing purposes. The massive sulphide bodies contain chalcopyl'ite, pyrite, pyrrhotite, and minor amounts of sphalerite and magnetite. The concentration of particular sulphides varies even within the same body. It is the areas high in pyrite, and to a lesser degree those, high in pyrrhotite, that are of particular interest.

Jan 1, 1950