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By T. H. Jeffers

To help maintain an adequate supply of minerals to meet national, economic, and strategic needs, the Bureau of Mines investigated the feasibility of extracting copper from coarse native copper ore with ammoniacal ammonium carbonate solution by a simulated in situ leaching procedure. A 5.9-metric-ton (6.5-ton) sample of minus 30.5-centimeter (12-inch) conglomerate-type ore analyzing 1.96 percent copper was leached in a column for 556 days with a solu-tion that contained, in grams per liter, 2.2 NBs and 1.9 CO[3=]. The copper extraction was 71.4 percent, and reagent consumptions were, in kilograms per metric ton of ore, 1.1 NBs and 0.85 CO[3=] (in pounds per ton of ore, 2.2 NH3 and 1.7 CO[3=]). The pregnant leach solutions contained about 1.4 grams per liter copper, which was readily extracted from these low-tenor liquors with a 1:19 mixture of an organic extractant and kerosine. Copper was stripped from the loaded organic with depleted electrolyte containing 150 grams per liter H2S04, and the copper was recovered by electrowinning with antimonial lead anodes. Conditions also were established for minimal lead transfer to the cathode copper.

Jan 1, 1979

By Stephen D. Cramer

A nondestructive procedure for measuring electrodeposit porosity has been developed which records the location and number of deposit defects including pores, pits, and voids. The procedure involves the passage of an X-ray beam through the deposit-substrate system onto suitable film. The defects are recorded as images on the film. Variables studied included intensity and spectra of the X-ray beam, composition and thickness of deposit and substrate, film type and developing procedure, and limits for detecting defects. At an X-ray tube voltage of 40 kv, pores several mils thick were easily detected in copper-nickel specimens more than 20 mils thick. To illustrate the utility of the procedure, the effect of substrate oxidation and of current density on electrodeposit porosity was briefly studied.

Jan 1, 1970

By A. S. Gendron

A brief description of Inco's ORC copper refinery tankhouse and the electrowinning tankhouse is followed by a comparison of the requirements for the production of the high-quality copper in both systems. The description will focus on both tankhouses, with emphasis on experience to date in the electrowinning tankhouse. Particular attention will be paid to sensitivities of each tankhouse to process upsets which can. significantly afject the quality of the product cathodes.

Jan 1, 1977

By A. V. Neretin

This paper is a continuation and extention of the previous paper on energy-efficient placer mining methods which was presented in 2007 at the World Gold Conference in Cairns, Australia (Nere-tin, 2007a). The paper reports the results only on gravel processing as they were not fully discussed in the previous paper. It is common knowledge that placer gold mining requires processing of large tonnages of gold-bearing gravels by wash plants of different types. In Russia, gold-bearing gravels are mostly disintegrated and screened by the following types of wash plants: a water canon, a derocker or a scrubber trommel. Gold-bearing gravel processing is regarded as highly energy-intensive due to high energy consumption for transportation of large tonnage of material and high pressure water flow rate. The industries requiring a significant expenditure of energy normally estimate the process efficiency by energy consumption per product unit. In order to obtain quantitative data on energy consumption for gravel processing and to estimate placer mining costs, in 2003~2006 four placer gold mines located in the Irkutsk Region were thoroughly investigated through time and motion studies. At all these placer mines gravels were processed by a water canon, a derocker or a scrubber trommel. The objective of the study was to investigate the following parameters: ? wash plant throughput rate per hour; ? hourly diesel fuel and power consumption per cubic meter of gravel processed; ? volume per cent and shape of oversize material; ? different combinations of gravel processing methods. The results from this study were as follows: ? specific energy consumption per cubic metre of gravel processed for different combinations of gravel processing methods was estimated; ? a correlation between energy consumption and unit cost of gravel processing was determined; ? effect of yield and shape of oversize material on wash plant throughput rate per hour was de-fined; ? energy-efficient gravel processing methods were developed. Based on these results, an improved method of gold-bearing gravel processing was proposed. Implementation of this method at a placer mine saved US$ 123 000 in operating expenses only during a short-time Siberian placer mining season. At the same time, this method improved gravel disintegration, screening and processing operations used at the mine. Another advantage of the pro-posed method was higher gold recovery due to reduced yield of undersize material. In order to improve efficiency of gravel processing, a wash system including a derocker for primary gravel processing and a lightweight scrubber trommel was developed. There are two economic benefits of replacing water cannons with the proposed wash system. The first benefit includes lower operating costs for gravel processing due to lower specific energy consumption, while the second benefit is lower gold losses during slurrifying (disintegration and screening) and sluicing of the undersize material.

Jan 1, 2014

By G DeschOnes, M Fulton

The Eleonore property (James Bay district of Northern QuTbec), owned by Goldcorp, hosts gold within stockworks of quartz-tourmaline-arsenopyrite veins and veinlets contained within microcline (potassic alteration) and brown tourmaline replacement zones. The preliminary investigation to recover gold from drill core samples showed that flotation followed by ultra-fine grinding and cyanidation is the preferred option. Ultra-fine grinding is used to liberate gold finely disseminated in sulfides. The flotation concentrate used in the investigation had a P80 of 11 ¦ and contained 75.5 g/t Au, 5.0 g/t Ag, 10.3 per cent S, 0.07 per cent Cu and traces of antimony (0.03 per cent). The mineralogical characterisation showed the presence of 65 per cent gangue minerals, 23 per cent pyrrhotite (hexagonal), 9.6 per cent arsenopyrite, 2.2 per cent pyrite and 0.08 per cent chalcopyrite with trace amounts of galena (0.05 per cent) and sphalerite (0.03 per cent). Gold was in the form of native gold and electrum. A straight cyanidation conducted at pH 11.0, DO of 3 - 5 ppm, 2000 ppm NaCN, 20¦C and for 72 hours extracted 97.0 per cent Au and consumed 31.5 kg/t NaCN. The equilibrium was reached within 24 hours. Increasing the dissolved oxygen to 16 ppm reduced the consumption of cyanide to 22.0 kg/t with 96.7 per cent Au extraction. A 16-hour pretreatment with 2.0 kg/t lead nitrate, followed by a 24-hour cyanidation reduced the cyanide consumption to 6.0 kg/t with a gold extraction of 97.5 per cent. Increasing the lead nitrate addition to 6.0 kg/t reduced the cyanide consumption to 1.2 kg/t by passivating the surface of pyrrhotite. The gold extraction remained at 97.0 per cent. It was possible to decrease the concentration of cyanide to 800 ppm NaCN without compromising gold extraction. The associated cyanide consumption was 1.2 kg/t NaCN. The passivation of gold grains was an issue when the cyanide concentration was decreased to 550 ppm NaCN. The gold extraction decreased to 92.2 per cent. The average lime addition for all the tests was 7.4 kg/t and the average silver extraction was 80 per cent. Efficient cyanidation of an ultra-fine sulfide concentrate with only 800 ppm NaCN represents an advance in leaching of ultra-fine sulfide concentrates. The high addition of lead nitrate would certainly make cyanide destruction easier; consequently reducing the effluent treatment costs and making possible to meet the discharge regulations criteria.CITATION:DeschOnes, G and Fulton, M, 2013. Design of a leaching strategy to extract gold from Eleonore Mine ultra-fine sulfide concentrate, in Proceedings World Gold 2013 , pp 71-78 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By J. D. Vincent

The Mission By-Products Plant at the Mission Concentrator of the American Smelting and Refining Company, some 20 miles south of Tucson, Arizona in the Twin Buttes mining area, has been in operation slightly over a year. The plant produces a molybdenite concentrate a copper concentrate and, at times, a zinc concentrate. An intensive test program of over three years was conducted at Mission to make the recovery of molybdenum economic. Briefly it was found necessary to make a scavenger concentrate in the copper mill before it was possible to recover economic quantities of molybdenite. By so doing there were resulting additional recoveries of copper, silver and zinc. This program resulted in the design and construction of the existing plant. A paper by the authors discussing the test work and the design was presented at the, October 1965 meeting of the American Mining Congress in Las Vegas, Nevada, by Mr. Wayne Bossard.

Jan 1, 1966

By Ashok Kumar, Rajendra Singh, Arun Kr. Singh

"A simple analysis of site conditions and capability of the mechanised depillaring (MD) operation found that this approach is suitable to address the strata control issues in coal pillar extraction under the weak and laminated roof strata of Pinoura mine. A continuous miner (CM) with a ram car and quad-bolter are used for single pass pillar extraction (first time in the country) to achieve a relatively faster rate of depillaring. A total of eleven panels are depillared under weak and laminated roof strata with a fair-rated rock mass rating (CMRI-RMR). It is observed that there is less influence of roof caving over the surrounding mining structures, especially those located out-bye the side of the extraction line. An attempt is made to quantify the goaf influence by field studies, which show that the maximum value of mining-induced vertical stress is 2.83 MPa, and the range of influence remains limited to around 15 m from the line of extraction. However, the problem of roof instability under the influenced zone was experienced due to the inherent nature of the weak roof strata. The chances of trapping of CM under weak and laminated roof strata of the panels is reduced by deriving a threshold value of the roof dilation, on the basis of a simple statistical analysis of the obtained field results. However, few incidences of roof collapses are observed over the CM due to the unpredictable behaviour of the geological structures below the freshly exposed strata, which also caused an obstruction in the speed of the extraction. This paper presents results of the field and laboratory studies, conducted for a successful application of the single-pass pillar extraction method, along with details of some CM trapping cases below the weak and laminated roof strata.INTRODUCTIONCoal is the major natural resource to meet the growing energy demand of India and this trend is likely to continue for the next 20 years in the country. A major part of the Indian coal belongs to Gondwana period, and only a small part belongs to Tertiary period. The estimated coal reserve in India per the exploration work done up to a maximum depth of 1200 m is 315.149 billion tonnes, including the proven coal reserve of 143.058 billion tonnes (CMPDIL, 2017). Even in presence of these huge resources of coal in India, there is a considerable gap between production and the users’ demand of coal. Most of the mines are operated by conventional semi-mechanised Bord and Pillar (B&P) methods; thus, the mining industry has gained a considerable amount of operational experience (Singh, Singh, and Dhar, 1996) and knowledge about strata behaviour (Singh and Singh, 1999; Singh et al., 2008) using this method. However, recently, the Indian coal mining industry has introduced some mechanised depillaring (MD) operations, where the level of production is relatively high. This approach of depillaring improves safety along with the production and productivity of a depillaring operation (Ram et al., 2017). The nature of the overlying strata of these depillaring operations vary greatly: from highly laminated, weak, and easily caveable to massive, strong, and difficult to cave."

Jan 1, 2018

By T Raynlyn, S Hapugoda, V Nunna

The predominant phase in most Marra Mamba, channel iron deposits and detrital iron ore deposits is goethite. Goethite abundant iron ore fines tend to have complex mineralogical associations and fine dissemination of gangue material. These ores are typically challenging to process using conventional beneficiation methods. With declining ore grades, there is a need to develop new processing routes for low-grade goethitic ores/fines.Comparative process amenability studies were carried out using two different processing options to recover iron with low alumina and silica content from a low-grade goethite-abundant iron ore fines (-2 mm) sample from the Pilbara region of Western Australia. The first option involved dehydroxylation at 350°C and 400°C, followed by grinding dehydroxylated samples to 100 per cent passing 106 µm and magnetic separation. The second option was processing raw sample by gravity separation using a Floatex density separator. The performances of the two processes are discussed in terms of the iron grade-recovery responses, and an optimal processing route is proposed based on the findings from these tests.CITATION:Nunna, V, Hapugoda, S and Raynlyn, T, 2015. Process amenability studies on goethite-abundant iron ore fines, in Proceedings Iron Ore 2015, pp 165–174 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By F. K. Ikumapayi

An approach to environmental sustainability and improved process economy, in sulphide minerals production is recycling of process water in flotation of complex sulphide ores, although the chemistry of process water may be a critical issue to flotation efficiency. The influence of major components of calcium and sulphate ions in process water on xanthate collector adsorption and flotation response using pure chalcopyrite, galena and sphalerite minerals were investigated by Hallimond flotation, zeta-potential measurement, FTIR and XPS spectroscopy studies, while bench scale flotation tests were also carried out using complex sulphide ores. The impact of the species in flotation was comprehended using deionised water, tap water, process water and simulated water containing equivalent amount of calcium and sulphate species in process water. Hallimond flotation results showed a decrease of chalcopyrite and galena recovery in process water and also in the presence of calcium and sulphate ions in both deionised and process waters, whereas sphalerite does not respond to flotation. The adsorption of calcium and metal ions but not sulphate ions on the minerals is evidenced by zeta-potential data. FTIR and XPS studies revealed the presence of surface oxidized sulfoxy species and surface calcium carbonates on chalcopyrite in the presence of process water and water containing calcium ions, surface oxidized sulfoxy and carbonate species on galena in the presence of deionised water, process water and water containing calcium and sulphate ions, all at flotation pH 10.5, and these surface species influenced xanthate adsorption. The presence of surface oxidized sulfoxy and carbonate species at the sphalerite flotation pH 11.5 were seen in the presence of deionised water, process water and water containing calcium and sulphate ions, but the surface species does not influence xanthate adsorption. Bench scale flotation using two different complex sulphide ores showed that chalcopyrite, galena and sphalerite recoveries are better in process water than tap water. The studies showed that the process water can be recycled in flotation with no detrimental effect on grade and recovery of sulphide minerals. Keywords: sulphide minerals, flotation, zeta-potential, FTIR, XPS

Sep 1, 2012

By Dennis C. Martin

Assessment of the potential for mining induced subsidence and determination of ultimate design requirements for a mining operation should be based on a number of assessment approaches. Although the rock mechanics engineer has a variety of limit equilibrium and numerical modeling tools available for assessment and prediction of subsidence effects, empirical approaches based on precedent experience provide a powerful tool for calibration/verification of analytical models and prediction of subsidence. Three separate analyses approaches have been applied to the assessment of potential subsidence for a proposed block caving mine in eastern Canada. The investigations have included an assessment of documented historical information from previous block cave mining at the site, deterministic analyses using limit equilibrium approaches to assess kinematically possible failure mechanisms, and three-dimensional numerical modeling techniques. Analyses results have been used and compared with precedent experience and documentation of subsidence behavior from previous mining to optimize the subsidence predictions for the proposed mine.

Jan 1, 1998

By The Staff

THE property of McKenzie Red Lake Gold Mines, Limited, consists of eleven claims located on McKenzie island in Red lake. The mine is about 4,Y:l miles by water from the Howey townsite on the same lake, and about 95 miles north of Kenora, Ont. (see Figure 4). Mail and express are flown-in daily, winter and summer, from Sioux Lookout, Hudson, Kenora, and Winnipeg. All heavy supplies are freighted-in during the summer over a water route, using four marine railway portages, from Hudson, Ont., a distance of about 180 miles. During the winter, freighting over the same route is clone by tractor if necessary, but costs are three to four rimes the summer rate. Due to these conditions, large inventories of supplies must be kept on hand, varying from a spring minimum of $45,000 to a peak of $110,000 early in November. The average cost of all freight brought in from steel during 1937 was $0.01 per pound.

Jan 1, 1938

By T Wellman, G Sternadt, R Hingston

The 335 000 oz Wilber Deposit is located within the Meekatharra-Wydgee Archaean greenstone belt in the Murchison District of Western Australia. The deposit comprises high-grade gold mineralisation hosted within a steeply west-dipping quartz lode, which lies within a broader (20–60?m) north-east striking shear zone envelope. Locally, the northerly-trending host rock geology includes greenschist facies high-Mg basalt (albite, actinolite, chlorite, biotite, calcite, zoisite, muscovite and titanate) intruded by at least two generations of felsic to intermediate porphyries (albite, actinolite, zoisite, chlorite, sericite, biotite, quartz and titanate). The Archaean rocks are cross-cut by a number of east–west striking Proterozoic dolerite dykes (biotite (50 per cent), albite, carbonate, epidote, titanate and actinolite) that are interpreted to have intruded pre-existing regional structures. The entire mine package is cross-cut by a system of shallow north-east-striking, north-west-dipping, barren quartz veins that commonly contain large (up to 30 cm), euhedral, smokey quartz megacrysts.The north-east-trending lode lies within a 3 m wide shear zone and varies from a single discrete 0.5 to 4 m wide laminated, massive or brecciated quartz-carbonate vein to multiple laminated veins up to 1 m wide within the shear. The veins exhibit strong boudinage, with cross-cutting quartz-carbonate seal veins in the boudin necks. The boudin necks often contain pink calcite. The shear zone fabric wraps closely around the boudin necks proximal to the vein, becoming more lode parallel distal to the vein. The lode is offset by a north to north-north-west trending fault.Mineralisation occurs as free gold within the quartz carbonate veins, with accessory sulfides including pyrite ± chalcopyrite, ± galena ± sphalerite. Fuchsite is observed in the veins, as laminar wall rock inclusions, with visible gold commonly associated with the wall rock laminations.Gold grades range from less than 1 g/t within the hosting shear zone, either at the margins or interstitial to the veins, to approximately 30 g/t in the single vein, and up to greater than 60 g/t in the multiple vein areas. Gold is commonly visible and disseminated throughout laminated, breccia and massive quartz veins, although laminations show the highest concentration of gold grains.CITATION:Hingston, R, Wellman, T and Sternadt, G, 2014. The geology of the Wilber Deposit, Andy Well Gold Project, Murchison District, Western Australia, in Proceedings Ninth International Mining Geology Conference 2014 , pp 55–64 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 18, 2014

By M. C. Furerstenau

Adsorption behavior of various surfactants on sulfide minerals is very much affected by the nature of the surface of the mineral. Since sulfides are naturally meta-stable, oxidation occurs when they are exposed to air, especially in aqueous environments. As a result. oxygen assumes a major role in sulfide flotation. Mechanisms of adsorption of various thiol collectors on sulfide minerals have been reviewed. The electrochemical behavior of various sulfide minerals has also been reviewed. Flotation behavior of galena, chalcocite, sphalerite, pyrite, chalcopyrite and pentlandite has been presented together with the. flotation of copper sulfide- nickel sulfide ore.

Jan 1, 1993

"Accelerated expansion of Western Canada's metallurgical coal industry has again stimulated considerable exploration activity in the Rocky Mountain Foothills Belt and influenced much of the R&D related to transportation, processing and carbonization. Preparation R&D has included further pilot-plant work on desulphurization, spherical agglomeration and modified compound cyclones (which are also proving themselves in other mineral beneficiation studies). Combustion research, aside from increasingly stressing control of combustion source pollution, has directed special attention to lignite PF firing and problems arising from lignite ash. Studies directed toward the non-fuel utilization of coal have centered on such diverse topics as active carbons, carbonaceous filter media, plant nutrients and industrial applications of humic acid derivatives. In addition, a number of long-range research projects related to such matters as coal chemistry and pyrolysis have been actively pursued, and further attention has been given to improved sampling techniques and analytical methods."

Jan 1, 1969

Conditional simulation can be used to determine the probabilities of block iron-grades being above selected cut-offs. However, there are much faster alternatives that can produce acceptable results. In this paper blasthole data from a selected area of Joffre Member hosted ore of the Brockman Iron Formation at the Mt Whaleback orebody is used as the basis of a case study to assess alternatives to simulation. Iron grade, in per cent, is interpolated from a blasthole dataset into a block model using ordinary kriging. Samples are then removed from this blasthole dataset to produce data subsets. A complete distribution of iron grades for points or blocks is obtained utilising the data subsets and the following techniques: conditional simulation, median indicator kriging, the probability from conditional expectation and confidence intervals attached to the estimation of blocks in the framework of the discrete Gaussian model. The complete blasthole dataset is considered to represent the true iron grades at sample point support while the ordinary kriging estimate derived from these samples is considered to represent the true block grades. The distributions obtained from point estimates, block estimates and simulations are compared to each other and to the true estimates of iron grades using graphs and statistics. The conditional expectation technique reproduced the results obtained from conditional simulation extremely well and it is a viable alternative to simulation at point support. At block support the confidence intervals technique reproduced the results of the conditional simulation more closely than the median indicator kriging and in the data subsets tested the confidence intervals technique actually reproduced the true grade distribution more closely than the conditional simulation.

Jan 1, 2005

By J. M. Skeaff

As much as 100% of the gold and 67% of the silver in a sulphur-bearing hydrometallurgical leach residue have been transferred to copper metal at copper smelting temperatures by dissolving the partially calcined residue in an iron-bearing slag maintained in equilibrium with the liquid copper metal and matte phases. The precious metals can then be recovered by conventional refining techniques. Copper can be recycled at least four times without any detrimental effects on gold and silver transfers and recoveries. Apparent copper recovery in the .process can be over 100% because of the copper content of the residue. Based on slag analys.es, the overal1 recovery of gold in the copper metal and matte phases varies from 94% to 100% under all conditions investigated. On the? same basis, silver recovery varies .from 9S% ?to 99% under optimum conditions, but is only 4S% to 73% under other, less attractive conditions. Unaccounted for silver losses of' about 30% make it difficult to determine the major factors affecting ?silver transfer and recovery. A method for implementing the technology on a commercial scale at a Canadian copper/zinc smelter has been proposed. A preliminary economic assessment and comparison of the proposed pyrometallurgical process with conventional cyanidation indicates that either process is economically attractive for recovering gold and silver from leach residues. Although the capital costs are higher, the pyrometallurgical process is simpler, has higher recoveries, lower operating costs and no .potential environmental problems related to cyanide disposal.

Jan 1, 1989

By P J. Cullen, B P. Banerjee, S Raval

Continuous monitoring of mining impacts on the surrounding environment is a necessary sustainability criterion. Traditional monitoring approaches such as in situ sampling and airborne and satellite-based remote sensing have several limitations. Over the past few decades, unmanned aerial vehicles (UAVs) have evolved into popular platforms for remote sensing. UAV-based remote sensing has been successfully applied in different sectors, including agriculture, forestry, urban environments and disaster management. However, the potential of UAVs for mine environmental monitoring has not yet been fully established. This paper envisages the use of UAVs and sensor systems to monitor the environment of future mines.CITATION:Banerjee, B P, Raval, S and Cullen, P J, 2015. Unmanned aerial vehicles for mine environment monitoring, in Proceedings Third International Future Mining Conference, pp 137–144 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 4, 2015

By B. F. Dickerson

STRATEGIC METALS! Recently, this money accented cry has been heard in such diverse locales as Mining company boardrooms, Banker's offices, Stockbroker's quarters, Swindler's dens and Congressional committee rooms. (In some cases, these locales are one and the same). Is the strategic metals rush for real? Should it be? Our paper attempts to give a very generalized view of the subject for a few metals, points to a few potential, but generally overlooked sources of these metals, and offers conclusions based on our studies.

Jan 1, 1981

By A. Ehsani

"Seas and oceans constitute about 70% of the earth’s surface. They contain an enormous stock of various mineral resources such as sedimentary (marine placers), massive sulfide ore deposits, manganese nodules and cobalt-rich ferromanganese crusts. Sea and ocean floor ore deposits could well contribute to the meeting of ever-rising demand for raw materials in the metal industry. In this regard, more research and development in science and technology appear to be required to ensure maximum benefit from the mineral resources of seas and oceans. Since the 1960s, a variety of mineral and metallurgical processes have been studied and developed to deal with marine ores and to extract metals such as gold, nickel, copper, cobalt, manganese, tin, platinum group metals (PGM), zirconium, thorium, etc.In marine environments, there are many parameters which can affect the selection of the mineral and metallurgical processes. These include the extent and grade of the deposit, mineralogical and chemical properties of the deposit, and physical properties of minerals present with particular reference to particle size distribution and mineral liberation size.In this paper, we briefly review the latest trends in processing and extraction of marine mineral resources. Mineral processing technology is mostly applied for recovery of precious metals i.e. gold and PGM, in particular, from marine placers. In general, pre-treatment (sizing, classification, dewatering), gravity concentration techniques (shaking tables, spirals, jigs, etc.,), flotation, magnetic, and electrostatic separation are the options for enrichment of marine placer ore deposits. In the case of massive sulfides, manganese nodules/cobalt-rich crusts, hydrometallurgical and pyrometallurgical methods (as proven technological methods) can be exploited for extraction of metals from concentrates after physical separation or directly from marine ores. The hydrometallurgical treatments involve acid (e.g., sulfurichydrochloric) and alkaline (e.g., ammonia) leaching with different reducing agents and pre-treatments such as roasting. Alternatively, pyrometallurgical treatments involve mostly smelting, chlorination and segregation processes."

Jan 1, 2016

By R F. Sandenbergh

Due to environmental considerations, mineral processing plants are increasingly recycling water to decrease the impacts of wastewater on environment and the depletion of fresh water resources. Industrial experience has shown that increasing recycling water in flotation typically negatively impacts the recovery and selectivity, especially in the selective flotation of minerals from complex sulfide ores. The major reason for the reduced selectivity is typically the inadvertent activation of sphalerite or pyrite by the heavy metal ions (HMI) in solution. These HMI are often produced during milling and flotation and absorbed by other minerals. In the normal flotation pH value range (8 - 10), these HMI are often in the form of precipitates or complex ions that may re-appear in solution or become active should conditions favour this. In this paper, microflotation, batch flotation and XPS surface measurement were used to investigate the use of HMI absorbents additions to the pulp to improve flotation selectivity of a complex sulfide ore. It has been demonstrated that HMI removal does improve flotation selectivity by facilitating more effective depression of the sphalerite. Microflotation and XPS surface measurements have shown that HMI absorbents compete with sphalerite to absorb HMI, and thus reduce the surface concentration of HMI on those sulfides. The practical use of HMI absorbents in complex sulfide ore flotation is also discussed.

Jan 1, 2005