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Ion Exchange is finding a greater role in copper processing, and hydrometallurgy in general, both as a technique for removing impurities and as a means of adding value through the recovery of secondary metals. Both the gold and uranium industries use resin adsorption as a primary production technique. While hydrometallurgical processes predominantly rely on solvent extraction as the mainstay of copper recovery there are a number of projects, in particular polymetallic deposits, which are considering the use of resin recovery as an alternative or supplemental production technique. A number of applications have been developed and proven at commercial scale for the removal/control of impurities (iron, antimony and bismuth) from copper electrolytes. These are well documented ion exchange applications. Increasing metal values and scarcity of certain metals are focusing companies to look at secondary metals recovery rather than losing these often highly valuable metals to tails residues. Bleed streams are being seen as valuable opportunities to recover contained metals; iron, copper, nickel, cobalt, bismuth, antimony and rhenium are all metals being targeted for removal or recovery from process solutions, electrolytes and bleed streams. An overview of currently applied techniques as well as some developmental technologies for impurity removal and secondary metals recovery is presented to provide insight into the advantages and flexibility of ion exchange applications in metals processing.

Jan 1, 2007

By E. A. Devuyst, G. Robbins

A unique process for removing cyanide and base metal complexes from industrial waste streams was patented by G.J. Borberly et al. (1984). The process uses SO2 (liquid or gas, or solutions of sulfite salts, or from burning elemental sulfur), plus air that is dispersed in the effluent using a well agitated vessel. Acid produced in the oxidation reactions is neutralized with lime at a controlled pH generally in the range 7 to 10. The reaction requires the presence of soluble copper as a catalyst which can be supplemented by copper sulfate if necessary. The process can be applied to the detoxification of gold and silver mining waste streams, such as carbon-in-pulp (CIP) tailing pulps, barren solution bleeds, pond waters and heap leach rinse solutions and also to plating shops wastewaters. The SO.jAir process has substantial advantages over two of the main alternative methods of cyanide destruction, namely alkaline chlorination and hydrogen peroxide. Alkaline chlorination is highly penalized in terms of reagent consumption. Chlorine is a strong oxidant reacting with species other than cyanide present in the effluent such as thiocyanate and sulfides. Furthermore alkaline chlorination is an incomplete detoxification process. Iron cyanide is not removed and the potential for harmful by-products species exist. Consequently final effluents may be subject to additional treatment in order to comply with regulatory demands.

Jan 1, 1991

By M. C. Van Camp, J. D. Miller

Preliminary results are reported regarding the design and development of a pilot scale air sparged hydrocyclone for cleaning fine coal 590 pm (- 28 mesh) containing 24% ash and 1.6% sulfur. The principle of separation is the flotation of hydrophobic coal particles in the centnjugal field generated by the fluid flow in the air sparged hydrocyclone as discussed in another publication. This 152-mm (6-in.) hydrocyclone has a nominal capacity of 0.9 t/h (1 tph) and experimental results suggest that separations vastly superior to a water-only cyclone are possible. In addition the separation efficiency is as good, if not better, than that achieved with conventional flotation cells. For example, typical results indicate that 75% clean coal can be recovered at 15% ash leaving a tailing product of almost 50% ash. These experimental results coupled with the high capacity of the air sparged hydrocyclone (imagine a retention time for flotation of only two seconds compared to two minutes for conventional flotation) may represent a significant breakthrough, not only in coal preparation technology, but in the flotation of fine particles in general.

Jan 1, 1983

By Jinxing Ji

The thiosulfate lixiviant system for leaching of gold has been under extensive investigation for nearly two decades and consists of ammonium thiosulfate, copper and ammonia. There are several challenges with this system. The occurrence of ammonia must be taken into account from a health and hygiene aspect in the workplace, and also from an environmental perspective with significant levels of ammonia and copper in the tailings. Copper accelerates the leaching rate but causes excessive thiosulfate degradation. A new lixiviant system that has been investigated consists only of sodium thiosulfate without copper and ammonia. Gold leaching is carried out in an enclosed reactor with slightly elevated oxygen overpressure and temperature. Extensive leaching experiments were carried out to minimize thiosulfate degradation and polythionate formation while maximizing the gold extraction. For the preg-robbing carbonaceous ore sample tested, gold leaching was essentially complete within six hours and the thiosulfate consumption was lower than in the typical ammoniacal thiosulfate system. The gold thiosulfate complex in the pregnant leach solution was found to be quite stable under ambient conditions. This new leaching system has the advantages of being more environmentally friendly, has a shorter residence time, lower thiosulfate consumption, lower oxygen consumption, and is easier to control.

Jan 1, 2003

By E. Forssberg, T. Nordquist

Introduction In this technical note, pilot-scale tests with two types of gravity concentrators, the Knelson separator (Anon., 1983; Forssberg and Johansson, 1984) and the Mark VIIA Reichert spiral concentrator (Balderson, 1982; Forssberg and Johansson, 1984), are described. The experimental work was concentrated on the relatively untried Knelson separator. The materials tested have different concentration characteristics: one was an artificial ore with excellent liberation characteristics and with a wide difference in density between valuable and gangue minerals; the others include a spiral concentrate containing gold from the gravity circuit of Boliden, Sweden, an old scheelite tailing from Yxsjöberg, Sweden, and an auriferous ore, containing gold, that had not been crushed to full liberation. The latter three materials contained other heavy minerals, e.g. pyrite, that can interfere with concentration. Knelson separator The Knelson separator is a compact centrifugal separator with an active fluidized bed to capture heavy minerals. A centrifugal force equal to or exceeding 50 times the force of gravity acts on the particles. The strong centrifugal force traps the heavier particles in a series of rings located in the concentrator while gangue particles are flushed out (Fig. 1). The particular separator used in the tests has a 15-cm (6-in.) diam bowl and can process between ~70 and ~250 kg/h.

Jan 1, 1988

By E Wan, K Stokes

Since 1978, the nickel concentrator at Leinster has been subject to continuous change. In 1971 a significant nickel sulphide deposit was discovered on Leinster Downs Station, within three years the extent of the deposit was determined. In 1978 the Agnew Mining Company began production of nickel concentrate from the Perseverance Mine and continued to do so until production ceased in 1986. In 1988 WMC purchased the mothballed project and began the first phase of many expansion initiatives. Milestones in the life of Leinster have included:open cut mining of the Perseverance orebody and the discovery of the RockyÆs Reward orebody, as well as the metallurgical challenges in treating each of these; underground mining at both Perseverance and RockyÆs Reward; construction and commissioning of the WMC grinding and flotation circuits; variations in the reagent schemes, including the introduction of æliquidÆ reagents; development of mill linings to reduce maintenance; circuit re-configuration and simplification; development of Harmony open cut; strategies for increasing throughput at the drier; and changes to tailings facilities to cope with increased throughput. This paper outlines the steps which have been required to expand the Leinster Nickel Concentrator from 650 000 tpa to 2.5 Mtpa and those steps which will be required in the future.

Jan 1, 2000

By R. S. Shoemaker, F. W. McQuiston

EMPEROR GOLD MINES Vatukoula, Fiji 1974 Operating Data to July 1 ORE DESCRIPTION: Ore bodies occur in basalt and associated ash beds overlain by andesite tuffs and sediments. The basalt in much of the ore mined is weathered with alteration of olivine to serpentine and iron oxides, and augite to chorite. The most important host minerals for gold are the tellurides sylvanite and hessite. Next in importance the sulphide s, pyrite, marcasite and arseno-pyrite. A small amount of free gold also occurs. Chalcopyrite, sphalerite, tetrahedrite, bornite, galena and native tellurium are present in small quantities. TYPE OF MINE: Underground and open pit ORE HAULAGE TO MILL: 3.5 ton bottom dump skips from underground. 7 ton trucks from open pit. CAPACITY IN TONS/24 HRS: 1345 short tons ASSAY HEADS (1973): 0.232 oz Au per ton, 0.357 oz Te per ton PRODUCTS: Gold Bullion (400 oz bars) Metallic Tellurium (1 2 lb bars ) RECOVERIES: AU 86.2% Te 88.0% ORE GRINDABILITY: 9.25 Kwh/T TOTAL POWER: 25.7 Kwh/T WATER: Pumped 112 mile to a 318, 000 gallon head tank. Consumption: 2 140 gal per ton, no reclaimed water used. TAILINGS: Pumped 2 /3 mile through 8" pipe. Uphill sections are steel. Downhill sections are fibro asbestos.

Jan 1, 1975

By S. K. Kawatra

With the increasing importance being placed upon modernizing the coal industry as a result of recent developments in the international energy balance, computer control has been and is being instituted in many coal cleaning plants. Control techniques that are well established in many base metal industries have been adapted to coal washing. Essential to any control scheme is an accurate measure of the parameter which is to be controlled. A sensor is required that will provide information both quickly and precisely. In fine coal circuits, the critical parameter that must be measured and controlled is the per- cent ash contained in the clean coal product and tailings. Measuring the ash content of these slurry lines on a continuous basis enables the operating conditions in the circuit to be adjusted so as to obtain optimum separation efficiencies at all times. An on-line ash monitor has been developed and tested at Michigan Technological University which is capable of making percent ash and percent solids determinations instantaneously. Two radioisotopes are employed in this system to generate signals that can be related to the density and the ash content of the slurry. Such data provide a means to execute a short term control strategy.

Jan 1, 1982

By Ritchie I

Copper minerals are often associated with gold ores. These create processing problems since cyanide solutions are not selective for gold alone. Copper minerals are also leached by cyanide, and typically each one per cent of `reactive' copper in the ore consumes about 30 kg t 1 cyanide. Once in solution, copper cyanide species create further processing problems as they adsorb onto carbon along with the dicyanoaurate ion. These problems make conventional cyanidation of gold ore uneconomic if the ore contains too much copper. As a result, methods of economically processing gold-copper ores are becoming of increasing importance.One of the more promising methods of treating these ores is by selective leaching of the gold by an ammoniacal cyanide solution, a method first described by Hunt in 1901. This method is already in commercial use in Mauritania, treating copper/gold tailings. In general terms, the addition of I - 2 g U1 ammonia to a standard cyanide leach solution causes a significant increase in gold extraction and decrease in copper extraction. However, early testwork on this system has concluded that the optimal leach conditions are critically dependent on ore composition, and the mechanism is not well understood, making predictions of best conditions impossible.

Jan 1, 1997

By S. H. Castro

In 1997 Chile was the world's largest copper mine producer with around 3.4 million metric tomes of copper. Conventional technology (conminution-flotation- smelting-converting-electrorefining) for copper sulfide ores was used. For copper oxidized ores hydrometallurgical processes (heap leaching-solvent extraction- electrowinning) were employed. Consequently, the most important waste effluents include flotation tailings, gaseous emissions, smelter slags, acidic and alkaline wastewater, electrolytic sludges, solid residues from leaching, etc. The introduction of stricter environmental regulations are forcing the Chilean industry to minimise the generation of waste and promote cleaner production. Gas emissions such as SO2 and arsenic from smelters and process wastewater are the major problems at this stage. The environmental impact assessment of gas emissions in all six largest smelters namely Chuquicamata, Caletones, Potrenllos, Ventanas, Paipote and Chagres led to design a "decontamination plan." The implementation of this plan resulted in (i) the installation of sulfuric acid plants for SO2 abatement and (ii) the installation of electrostatic precipitators to remove arsenic oxides condensed from cooling gases. The aim of this paper is (i) to describe the type of waste associated to the various stages of the metallurgical processes and (ii) review the main abatement technologies used in medium and large size companies.

Jan 1, 1999

By S. D. Hill

State-of-the art precious metal recovery practice uses cyanide leach solutions to extract the valuable constituents from ores, wastes, and tailings. Activated carbon is then used as an adsorbent in either a carbon-in-pulp system or counter-current flow columns to concentrate and recover the precious metals. Existing techniques for recovering precious metals from carbon prior to the precipitation or electrowinning of the metal involve either the use of dilute aqueous hydroxide solutions at elevated temperature and pressure or, as in a more recent method, the use of a strong cyanide soak followed by a water strip solution at an elevated temperature. Despite past Bureau efforts in the area of precious metal recovery, the ex- traction of gold from pregnant leach solutions remains the most serious drawback in carbon-in- pulp and heap leach processing of low-grade ores containing precious metal values. A second disadvantage in the current practice is the interference in adsorption and desorption that occurs due to the presence of other heavy metal cations in cyanide leach solutions. Specific objectives of current Salt Lake City Research Center precious metals research are to develop less energy intensive and more economic methods for recovering gold, silver, and by- product metals from low-grade resources. To meet these objectives, we are investigating noncyanide leaching reagents, ion exchange resins, solvent extractants, and novel electrowinnlng procedures.

Jan 1, 1984

By E. A. Devuyst

A unique process for removing cyanide and base metal complexes from industrial waste streams was patented by Borberly et al. (1984). The process uses S0, (liquid or gas, or solutions of sulfite salts, or from burning elemental sulfur), plus air that is dispersed in the effluent using a well agitated vessel. Acid produced in the oxidation reactions is neutralized with lime at a controlled pH generally in the range 7 to 10. The reaction requires the presence of soluble copper as a catalyst that can be supplemented by copper sulfate if necessary. The process can be applied to the detoxification of gold and silver mining waste streams, such as carbon-in-pulp (CIP) tailing pulps, barren solution bleeds, pond waters and heap leach rinse solutions and also to plating shops waste waters. The S02/Air process has substantial advantages over two of the main alternative methods of cyanide destruction, namely alkaline chlorination and hydrogen peroxide. Alkaline chlorination is highly penalized in terms of reagent consumption. Chlorine is a strong oxidant reacting with species other than cyanide present in the effluent such as thiocyanate and sulfides. Furthermore, alkaline chlorination is an incomplete detoxification process. Iron cyanide is not removed and the potential for harmful byproducts species exist. Consequently, final effluents may be subject to additional treatment in order to comply with regulatory demands.

Jan 1, 1991

By A. V. Tarasov

The natural resources of lead and zinc are primarily constituted by polymetallic and lead-zinc ores. Beneficiation of these types of ores to produce standard nonmetallic concentrates inevitably results in an increase in the loss of base and precious metals with tailings. An improvement in the grades of lead and zinc concentrates can be achieved by re-cleaner flotation, but it results in production of intermediate products (middlings) to which substantial amounts of lead, zinc, copper and precious metals report. Without an appropriate technology for treating such intermediate products, the recoveries of valuable constituents from lead-zinc ores would remain unsatisfactory. A process has been developed in the Gintsvetmet Institute for processing of polymetallic intermediate products produced at the ore beneficiation plants. This process is based on electrothermic smelting to produce lead bullion containing precious metals, commercial-grade copper-lead matte and high-zinc slags (up to 15-20% Zn) from which zinc can be extracted by slag-fuming or Waelz process. Tests have indicated that the recovery of lead from intermediate products into lead bullion and matte is about 83-85% and 13-14% respectively (the total recovery is 97-98%), while copper recovery into the matte and zinc recovery into the slag is 90-92% and 95-96% respectively. Precious metals (about 96-97%) report into the lead bullion.

Jan 1, 2006

By Larry M. Southwick

Processing of ores to recover metals usually generates large amounts of waste materials, such as rejects from concentrating operations, tailings from leaching and slags from smelting. These wastes often contain substantial amounts of iron and other metals, recovery of which are often considered to be of commercial value. Earlier versions of this paper investigated a number of processes built to recover iron from a variety of copper processing residues. This paper will extend that coverage to residues from nickel/cobalt, aluminum, asbestos and oil shale processing and coal plant fly ash. Products of interest are iron, ferroalloys, magnesium and aluminum. While none of these processes achieved long-term commercial success, their efforts cover the gamut of problems that must be addressed in treating dirty and difficult materials to recover generally low-value products. An Adept is an alchemist who can create a Philosopher's Stone, which could transmute base metals into gold. In 1701 in Berlin one Johann-Freidrich Böttger, a nineteen year old apothecary's apprentice, told King Frederick I that he could discover how to make the Stone. He failed and fled Frederick's wrath to Poland. He failed again, and King Augustus II threw him in jail. Then, in 1709, he discovered instead the secret of making Dresden china, certainly a more practical search. His failures in alchemy led to the nickname Adeptus Ineptus.

Jan 1, 2004

By Flavio Rojos-Tapia, Oscar Pereira-Cerda, Samuel Sánchez-Pino, Samuel Sánchez-Baquedano

"Pneumatic flotation was introduced to the Chilean Copper Mining Industry in 1993 by Ingeniería de Minerales S.A. (IDM). The technology is based on the designs of Dr. Rainer Imhof from Germany, who is the designer of several different types of pneumatic flotation cells, already sold through his Company Maelgwyn Mineral Service Limited (MMH). The company is represented by Ingenieria de Minerales S.A. (IDM) in South America.Pneumatic flotation, has been used in tough industrial applications .It has been successfully used for metallic ores such as copper sulphide and oxide minerals, copper slag, silica and silicates from iron magnetic preconcentrate (reverse flotation) and gold. It has also provided promising results when applied to molybdenum flotation. The latest applications, with ultrafine molybdenum particles in operating plants, is showing the V and G Cell (end model designed) as a real technological alternative to conventional flotation., The G Cell is an extremely high speed flotation machine with high selectivity which introduces the possibility of producing a final molybdenum concentrate with only one stage of cleaning. This is a completely new development in molybdenum flotation in the industrial circuit which has the potential to dramatically reduce the circulating load in the cleaning circuit. As a consequence the capital costs of future Molybdenum plants may also be reduced. The suitability of the G Cell will have to be determined on a case by case basis but it provides the metallurgist with an alternate flowsheet for consideration.The good performance of the G Cell can be explained by the high gas hold-up and very effective micro-turbulence which helps improve the attachment of solid particles to the bubbles. This technology may change our traditional concept of residence time in flotation. Additionally, the rotation phenomena introduced in the vessel of the G Cell ,creates radial separation forces which are critical to achieving a more rapid separation of the target minerals from the tailing. This results in a much reduced residence time requirement in the flotation machine. Some benefits associated with the use of the new G Cell are: less energy consumption, less maintenance costs, simple and reliable circuit to operate and a small area required for installing the circuits.As a result of the industrial experience in the Chile, the pneumatic flotation type G Cell can be regarded as a technology which must be considered as a replacement technology for the rougher and cleaner stages for fine particle flotation."

Jan 1, 2008

Eliminate accidental tramming of a cleanup tractor. Approach A switch was installed in the operator's seat cushion to pre-vent the cleanup tractor from tramming without an operator in the driver's seat. How It Works The operator must be seated, and the Forward/Reverse Switch (that controls tramming direction) must pass through the NEUTRAL position before the vehicle will tram. See Figure 1. A pressure-sensitive seat cushion switch, a solid-state relay, and a double-contact relay were added to the control circuitry of an S & S BMUAT -88 cleanup tractor to create this tramming interlock. The weight of the operator on the cushion closes the seat cushion switch (Figure 2, A). This activates the solid-state relay (B), which completes the initial circuitry. Moving the For- ward/Reverse Switch (C) to NEUTRAL energizes the coil in the double-contact relay (D) and closes both contacts. One contact completes a sustaining circuit which keeps the double-contact relay energized. The second contact transfers power to the remaining contacts within the Forward/ Reverse Switch. These circuits are shown in greater de- tail in Figure 2.

Jan 1, 1978

By Sheila E. Daniel

"Since 1989, the Mine Environmental Neutral Drainage Program (MEND) has sponsored research into ways of reducing the environmental impact and financial liabilities associated with Acid Mine Drainage from tailings and waste rock. Toward this overall objective, Kilborn was contracted to review the use and applicability of passive treatment systems for acid mine drainage.Experimentation using passive systems to treat acid mine drainage has been ongoing since the early 1980's in North America. Passive treatments are generally considered an attractive alternative to active lime treatment, since they require minimal human involvement, no power, and only seasonal or periodic care and maintenance after establishment. Most attractive is that initial capital cost to implement a passive treatement system is generally low to moderate. Ongoing operating costs are similarly low when compared to active treatment systems.Passive treatment systems currently used, or under investigation to treat acid mine drainage include: anoxic limestone drains, aerobic wetlands, reed bed wetlands, compost wetlands, microbial systems and bioabsorption systems. These wastewater treatment systems utilize the chemical, biological and physical removal processes that occur naturally in the environment to improve wastewater quality, including: oxidation, reduction, coagulation, adsorption, absorption and precipitation; microbial activity; and, gravity aeration and dilution. The rates at which these processes occur determines the loading which can be treated and the effectiveness of the system.The results of our literature review will be summarized, and insight provided into the applicability of passive systems to treat acid mine drainage from Canadian Mines."

Jan 1, 1995

By Kostas Fytas

Canada still remains today a strong resource nation with a huge geological potential. Canada ranks among the top five leading countries in the production of 15 major minerals. Acid mine drainage (AMD) is a serious environmental problem that preoccupies the Canadian Mining Industry. Considerable amounts of money are spent every year in an effort to prevent or reduce the acid mine drainage production. It is estimated that across Canada there are a few thousand abandoned mine sites as a result of the last fifty years of mining. Most of these sites are acid producing presenting a serious threat to the environment. It has been estimated that the cost of stabilizing and reclaiming these sites across Canada will be over $5 billion over the next twenty years. Current practices for decommissioning acid producing sites are water covers (flooding), dry covers, revegetation and treatment of the acid effluents. This paper presents the technical and legal issues of mine closure and reclamation in Canada. The methods used in the revegetation of acid producing mine sites is also presented This paper also reviews the financial guarantee requirements for mine closure by the provincial legislations in Canada. A case study of stabilizing and reclaiming a sulphide tailings area in the Sudbury region is presented. It illustrates the challenges facing the Canadian Government and the mining companies in restoring and revegetating the closed and abandoned mine sites across Canada.

Jan 1, 2002

By Abbas Zaidi, Betty L. W. Ou

Wastewaters generated during the extraction of gold from the ore can contain a variety of contaminants such as cyanide, heavy metals and arsenic. Proper management of these wastewaters is therefore necessary to minimize the negative impact of gold mining and milling operations on the environment. The Wastewater Technology Centre (WTC),located in Burlington, Ontario, Canada, has been involved in several studies related to the evaluation of various effluent treatment technologies which are relevant to the treatment and proper management of gold mill effluents. These studies have included bench and pilot scale tests, and the evaluation offull-scale systems. Furthermore, the WTC staff developed protocols for cyanide analysis in gold mill effluents, and a mathematical model for predicting the degradation of cyanide in tailings ponds. The information generated by the WTC staff has been referenced in several reports and papers published over the last ten years (Schmidt et.al. 1982, Simovic & Snodgrass 1989, Whittle et.al. 1989, Zaidi et.al. 1989, Zaidi et.al. 1991). Recently, the WTC has started to develop a micro­computer based expert system for use by decision makers in the gold mining industry and relevant government agencies who are involved in process design, process evaluation, costing, evaluation of the best practicable technology, approval of suggested effluent management systems, and so on. This paper presents some relevant background information and a discussion of the latest version of the expert system being developed by the WTC.

Jan 1, 1992

By G. Deschenes, M. Fulton

The New Britannia Mine processes a qumtz-carbonate gold ore containing 4.63 git Au at a rate of 2,200 tpd. The ore contains approximately 3 .0% arsenopyrite, 2. 7% pyrite and the rest is gangue minerals. Eight to ten percent of the gold is refractory to leaching. Two years ago, New Britannia Mine experienced cyanidation problems. Gold extraction was not stable and occasionally decreased significantly. Preliminary test work, at laboratory scale and in the plant, indicated that lead nitrate addition was beneficial. A laboratory study was initiated to evaluate the level of control of the parmneters (grinding size, dissolved oxygen, pH, free cyanide and lead nitrate) to optimize the efficiency of the process. It was found that lead nitrate addition is required to alleviate the effect of metallic sulphides. This addition causes a significant increase in the gold leaching kinetics and a reduction in the cyanide consumption. The optimum system appeared to be: leaching for 24-30 hours at pH 11.8, 50 git lead nitrate, 250 ppm NaCN and 8 ppm 02. The gold extraction was 89.8% with grinding at 89%-74Fm (leached tail at 0.48 git). Cyanide and lime consumption are 0.40 kglt NaCN and 1.9 kglt respectively. Following the incorporation of lead nitrate, overall gold extraction was increased from 89.2% to 91.1 % but no change was noticed in cyanide consumption. The gross profit is $CDN 988,000 per year.

Jan 1, 1999